EP1323852B1 - Vorrichtung zur Herstellung einer Spinnvliesbahn - Google Patents
Vorrichtung zur Herstellung einer Spinnvliesbahn Download PDFInfo
- Publication number
- EP1323852B1 EP1323852B1 EP01129946A EP01129946A EP1323852B1 EP 1323852 B1 EP1323852 B1 EP 1323852B1 EP 01129946 A EP01129946 A EP 01129946A EP 01129946 A EP01129946 A EP 01129946A EP 1323852 B1 EP1323852 B1 EP 1323852B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- drawing die
- temperature
- nozzle
- gap
- temperature equalisation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D4/00—Spinnerette packs; Cleaning thereof
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
- D04H3/03—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments at random
- D04H3/033—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments at random reorientation immediately after yarn or filament formation
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/084—Heating filaments, threads or the like, leaving the spinnerettes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
- D01D5/0985—Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
- D04H3/03—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments at random
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
Definitions
- the invention relates to a device for producing a spunbonded nonwoven web from aerodynamically stretched filaments of thermoplastic material, having a spinner head with a plurality of spinneret bores from which emerges a curtain made of thermoplastic filaments and a drawing die with two opposing die gap forming draw jet units.
- the filaments are stretched, with the aid of process air flowing through the drawing die.
- the process air in the nozzle gap of the drawing-out nozzle usually has a higher temperature than the ambient temperature, for example a temperature of 35 to 45 ° C.
- two opposing die-splitting draw-jet units does not fail to recognize the fact that these two draw-jet dies are combined into a single drawing die and can be connected to one another at their end faces.
- a cooling device for the filaments is provided.
- a depositing belt is provided.
- a special web laying device is arranged.
- the technical problem underlying the invention is to specify a device of the type mentioned at the beginning, with which spunbond webs with narrow basis weight tolerances can be produced.
- the invention teaches a device of the type described above, which is characterized in that at least one tempering device for temperature control of the Verstreckdüsenaggregates is connected to at least one Verstreckdüsenaggregat. It is within the scope of the invention that in each case at least one tempering device is arranged on both opposing nozzle-gap-forming stretching nozzle assemblies, preferably at the rear side of each stretching nozzle assembly facing away from the nozzle gap.
- a tempering device is attached to a carrier element of a Verstreckdüsenaggregates. This is preferably a rear-side carrier element or a rear-side carrier bar for the draw-jet unit. The reverse side here means the side of the draw-jet unit facing away from the nozzle gap.
- Tempering means in the context of the invention means for heating or cooling of a stretching nozzle.
- the tempering is a heater for heating the Verstreckdüsenaggregates.
- the term heating device is used instead of the term tempering device, although the technical features explained below can in principle generally also apply to a tempering device.
- the heating of the stretching nozzle assemblies is carried out with the proviso that a temperature difference between the temperature in the stretching nozzle gap and the process air temperature in the stretching nozzle gap and the ambient temperature is compensated and a deformation of the stretching nozzle assembly resulting from this temperature difference is counteracted.
- the entire draw-jet unit can be heated to the process air temperature or to the temperature in the drawing-die gap.
- the invention is based on the knowledge that, given differences between the temperature in the stretching die gap and the ambient temperature, deformations can occur or occur on the stretching die assemblies, and the stretching die assemblies then bulge, in particular in their middle towards the die gap.
- the invention is further based on the finding that due to such deformations of the draw-jet aggregates or of the nozzle-gap-side inner surfaces of the draw-jet aggregates, the differences in the basis weight of a spunbonded nonwoven web occur.
- the undesirably high basis weight tolerances which occur in the devices known from the prior art, an immediate consequence of the deformations or bends of the stretching jet aggregates.
- At least one heating device for heating the Verstreckdüsenaggregates is provided at each Verstreckdüsenaggregat.
- the temperature differences can be compensated within the Verstreckdüsenaggregate and thus avoided the deformations or at least reduced sufficiently.
- the temperature in the drawing die gap or the temperature of the process air in the drawing die gap is higher than the ambient temperature (for example about 20 ° C.).
- the draw-jet aggregates then bulge with their nozzle-gap-side inner walls, as a rule, toward the nozzle gap. This can be avoided by the heating according to the invention.
- the draw-jet unit is heated to the temperature in the nozzle gap.
- At least one temperature sensor is provided for measuring the ambient temperature and, in accordance with the measured ambient temperature, the heating of a stretching nozzle assembly takes place.
- the ambient temperature is usually about 20 ° C.
- a temperature sensor on the back that is arranged on the side facing away from the nozzle gap of a Verstreckdüsenaggregates.
- a temperature sensor may in particular be provided on a rear-side support element or on a rear-side support beam of the draw-jet unit.
- at each draw-jet unit expediently at the Rear side of each Verstreckdüsenaggregates, arranged at least one temperature sensor.
- control and / or regulating device for controlling and / or regulating the heating of a drawing jet aggregate. It is within the scope of the invention that the control and / or regulating device is used to heat up a hiding-machine aggregate in accordance with the measured ambient temperature. It is also within the scope of the invention that a measuring device is provided for measuring the temperature in the stretching nozzle gap or the process air temperature in the stretching nozzle gap. Then can be made in accordance with this measured temperature with the control and / or regulating device, the heating of a Verstreckdüsenaggregates.
- a device for determining the weight per unit area of a spunbonded nonwoven web produced is provided and the heating takes place as a function of this determined basis weight. It is within the scope of the invention that with the control and / or regulating device in accordance with the determined basis weight, the heating of the draw-jet unit is carried out.
- At least one cooling device is arranged between the spinning head and the drawing-out nozzle in the device according to the invention.
- the cooling device may for example consist of a cooling chamber having a in horizontal direction has rectangular chamber cross-section.
- the chamber cross section expediently decreases in the running direction of the filaments.
- the Verstreckdüse is followed by a web laying device.
- This nonwoven laying device can be designed in the form of a jet pump with a venturi-like intake in the vertical direction and a diffuser outlet. Expediently, the nonwoven laying device has a rectangular flow cross section in the horizontal direction. In the region of the collection of the fleece laying device or the jet pump, at least one outdoor suction opening is provided.
- a continuously moving deposition screen is expediently provided, under which a suction fan is arranged in the area of the nonwoven laying device. It is within the scope of the invention that the amount of air that is sucked in by the non-woven laying device operating as a jet pump can be controlled or regulated with the aid of the suction fan.
- the drawing die according to the invention is designed as a gap nozzle.
- the drawing-out nozzle expediently has a nozzle cross-section that is rectangular in the horizontal direction.
- the nozzle gap thickness of the nozzle cross-section is adjustable.
- a return is provided at least one Verstreckdüsenwand at the outlet of the Verstreckdüse.
- the Verstreckdüse or a Verstreckdüsenaggregat is suitably designed as a box-like component with nozzle wall made of sheet metal.
- a drawing jet aggregate has a sheet-metal wall on the nozzle side.
- the invention is based on the finding that the surface weight tolerances of the finished spunbonded nonwoven web can be kept very low with the inventive design of the device or with the inventive possibility of heating the draw-jet unit. While undesirable basis weight tolerances of the order of magnitude of ⁇ 20% are achieved with the devices known from the prior art, substantially lower basis weight differences or surface weight tolerances can be achieved with the device according to the invention. For example, basis weight tolerances of the order of ⁇ 6% and less are achieved.
- an apparatus for producing a spunbonded web 1 of aerodynamically stretched filaments of thermoplastic material has a spinner head 2 with a plurality of spinneret holes. From the spinning head 2 exits a curtain 3 of thermoplastic filaments. At the spinning head 2 includes a thread forming space 4. Further down in Fig. 1 is the Verstreckdüse 5 recognizable, consisting of two consists of opposite nozzle gap forming stretching jet 6 aggregates. The Verstreckdüse 5 is followed by a fleece laying device 7, which is in the form of a jet pump with venturiartigem in the vertical direction feeder 8 and diffuser outlet 9 is formed. The fleece laying device 7 or the jet pump has at least one outdoor suction opening 10 in the region of the intake 8. The spunbonded web 1 is deposited on a Ablegesiebband 11, which is moved continuously. Under this Ablegesiebband 11, a suction fan 12 is arranged in the region of the fleece laying device 7.
- the Verstreckdüse 5 is designed as a Spaltdüse.
- Fig. 1 It can be seen that the nozzle-gap-side inner walls 13 of the two drawing-jet aggregates 6 are arranged convergent with each other over at least a majority of the vertical length of the drawing-out die 5.
- the two Verstreckdüsenaggregate 6 are suitably connected to each other at their ends in a manner not shown.
- a heating device 14 according to the invention is arranged on each of the two opposing nozzle gap-forming stretching nozzle units 6, preferably on the rear side of each stretching nozzle assembly 6 facing away from the nozzle gap (see FIG. Fig. 1 and 2 ).
- each heating device 14 is fastened to a carrier beam 15 of a stretching nozzle assembly 6.
- a support beam 15 extends in the embodiment perpendicular to the direction of filaments.
- a heater 14 may be formed for example as a plate heater or as a heater.
- - In the operation of the device is usually a temperature difference between the temperature in the nozzle gap 16 and the process air temperature in the nozzle gap 16 and the ambient temperature before.
- the temperature in the nozzle gap 16 is for example 35 to 45 ° C, while the ambient temperature is 20 ° C, for example.
- the invention is based on the finding that, due to these deformations, undesirably high basis weight tolerances result in the spunbonded nonwoven web 1 produced. According to the invention is therefore heated by means of the heaters 14 so that temperature differences within the Verstreckdüsenaggregate 6 are balanced as possible and the undesirable deformations are thus avoided.
- a heater 14 recognizable, which is attached to the back of a support beam 15 of a Verstreckdüsenaggregates 6.
- an insulation 17 is provided above the heater 14.
- temperature sensor 18 for measuring the ambient temperature can be recognized. Conveniently, the heating of the stretching jet aggregates 6 takes place in accordance with the measured ambient temperature.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Treatment Of Fiber Materials (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SI200130865T SI1323852T1 (sl) | 2001-12-17 | 2001-12-17 | Naprava za proizvodnjo traku predene pletenine |
DE50114266T DE50114266D1 (de) | 2001-12-17 | 2001-12-17 | Vorrichtung zur Herstellung einer Spinnvliesbahn |
ES01129946T ES2214983T3 (es) | 2001-12-17 | 2001-12-17 | Dispositivo para producir una banda de un velo de hilatura. |
AT01129946T ATE406470T1 (de) | 2001-12-17 | 2001-12-17 | Vorrichtung zur herstellung einer spinnvliesbahn |
EP01129946A EP1323852B1 (de) | 2001-12-17 | 2001-12-17 | Vorrichtung zur Herstellung einer Spinnvliesbahn |
DK01129946T DK1323852T3 (da) | 2001-12-17 | 2001-12-17 | Anordning til fremstilling af en bane af spunbonded stof |
US10/294,480 US6908292B2 (en) | 2001-12-17 | 2002-11-14 | Apparatus for producing a nonwoven web |
MYPI20024335A MY129489A (en) | 2001-12-17 | 2002-11-20 | Apparatus for producing a nonwoven web |
CA002412719A CA2412719C (en) | 2001-12-17 | 2002-11-26 | Apparatus for producing a nonwoven web |
CNB02152453XA CN1274896C (zh) | 2001-12-17 | 2002-11-28 | 用于制造纺粘型非织造织物幅的装置 |
JP2002351432A JP3645887B2 (ja) | 2001-12-17 | 2002-12-03 | スパンボンデット不織布を製造するための装置 |
MXPA02012303A MXPA02012303A (es) | 2001-12-17 | 2002-12-11 | Dispositivo para producir un ancho de fibras sinteticas no tejidas. |
BRPI0205177-0B1A BR0205177B1 (pt) | 2001-12-17 | 2002-12-12 | Dispositivo para produzir uma seção de velo de filamentos contínuos |
KR10-2002-0079595A KR100493981B1 (ko) | 2001-12-17 | 2002-12-13 | 열가소성 합성수지로 이루어지고 공기 역학적으로 연신된 필라멘트로 스펀본드 웹을 제조하는 장치 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01129946A EP1323852B1 (de) | 2001-12-17 | 2001-12-17 | Vorrichtung zur Herstellung einer Spinnvliesbahn |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1323852A1 EP1323852A1 (de) | 2003-07-02 |
EP1323852B1 true EP1323852B1 (de) | 2008-08-27 |
Family
ID=8179571
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01129946A Expired - Lifetime EP1323852B1 (de) | 2001-12-17 | 2001-12-17 | Vorrichtung zur Herstellung einer Spinnvliesbahn |
Country Status (14)
Country | Link |
---|---|
US (1) | US6908292B2 (zh) |
EP (1) | EP1323852B1 (zh) |
JP (1) | JP3645887B2 (zh) |
KR (1) | KR100493981B1 (zh) |
CN (1) | CN1274896C (zh) |
AT (1) | ATE406470T1 (zh) |
BR (1) | BR0205177B1 (zh) |
CA (1) | CA2412719C (zh) |
DE (1) | DE50114266D1 (zh) |
DK (1) | DK1323852T3 (zh) |
ES (1) | ES2214983T3 (zh) |
MX (1) | MXPA02012303A (zh) |
MY (1) | MY129489A (zh) |
SI (1) | SI1323852T1 (zh) |
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WO2010141578A1 (en) | 2009-06-03 | 2010-12-09 | The Procter & Gamble Company | Structured fibrous web |
WO2010141577A1 (en) | 2009-06-03 | 2010-12-09 | The Procter & Gamble Company | Fluid permeable structured fibrous web |
WO2010141643A1 (en) | 2009-06-03 | 2010-12-09 | The Procter & Gamble Company | Fluid permeable structured fibrous web |
WO2012125701A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Structured fibrous web |
WO2012125707A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Fluid permeable structured fibrous web |
WO2012125538A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Structured fibrous web |
WO2012125281A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Acquisition system for an absorbent article comprising a fluid permeable structured fibrous web |
WO2012125336A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Structured fibrous web |
WO2012162083A1 (en) | 2011-05-20 | 2012-11-29 | The Procter & Gamble Company | Fibers of polymer-oil compositions |
WO2012161840A1 (en) | 2011-03-15 | 2012-11-29 | The Procter & Gamble Company | Fluid permeable structured fibrous web |
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WO2014081765A1 (en) | 2012-11-20 | 2014-05-30 | The Procter & Gamble Company | Method of molding thermoplastic polymer compositions comprising hydroxylated lipids |
WO2014081789A1 (en) | 2012-11-20 | 2014-05-30 | The Procter & Gamble Company | Thermoplastic polymer compositions comprising hydroxylated lipid, methods of making, and non-migrating articles made therefrom |
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US8759606B2 (en) | 2009-06-03 | 2014-06-24 | The Procter & Gamble Company | Structured fibrous web |
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KR19990009821A (ko) * | 1997-07-11 | 1999-02-05 | 구광시 | 장섬유 부직포의 제조방법 및 그 장치 |
JPH11286823A (ja) * | 1998-04-01 | 1999-10-19 | Teijin Ltd | 溶融紡糸装置 |
KR100534520B1 (ko) * | 1998-10-28 | 2006-03-14 | 주식회사 코오롱 | 스펀본드 부직포의 제조방법 및 그의 제조장치. |
JP3855546B2 (ja) * | 1999-08-04 | 2006-12-13 | 東レ株式会社 | ポリエステル繊維の製造方法 |
-
2001
- 2001-12-17 EP EP01129946A patent/EP1323852B1/de not_active Expired - Lifetime
- 2001-12-17 DE DE50114266T patent/DE50114266D1/de not_active Expired - Lifetime
- 2001-12-17 AT AT01129946T patent/ATE406470T1/de not_active IP Right Cessation
- 2001-12-17 DK DK01129946T patent/DK1323852T3/da active
- 2001-12-17 SI SI200130865T patent/SI1323852T1/sl unknown
- 2001-12-17 ES ES01129946T patent/ES2214983T3/es not_active Expired - Lifetime
-
2002
- 2002-11-14 US US10/294,480 patent/US6908292B2/en not_active Expired - Lifetime
- 2002-11-20 MY MYPI20024335A patent/MY129489A/en unknown
- 2002-11-26 CA CA002412719A patent/CA2412719C/en not_active Expired - Lifetime
- 2002-11-28 CN CNB02152453XA patent/CN1274896C/zh not_active Expired - Lifetime
- 2002-12-03 JP JP2002351432A patent/JP3645887B2/ja not_active Expired - Lifetime
- 2002-12-11 MX MXPA02012303A patent/MXPA02012303A/es active IP Right Grant
- 2002-12-12 BR BRPI0205177-0B1A patent/BR0205177B1/pt active IP Right Grant
- 2002-12-13 KR KR10-2002-0079595A patent/KR100493981B1/ko active IP Right Grant
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WO2010138832A1 (en) | 2009-05-28 | 2010-12-02 | Biomet Manufacturing Corp. | Knee prosthesis |
WO2010141578A1 (en) | 2009-06-03 | 2010-12-09 | The Procter & Gamble Company | Structured fibrous web |
WO2010141577A1 (en) | 2009-06-03 | 2010-12-09 | The Procter & Gamble Company | Fluid permeable structured fibrous web |
WO2010141643A1 (en) | 2009-06-03 | 2010-12-09 | The Procter & Gamble Company | Fluid permeable structured fibrous web |
US9439816B2 (en) | 2009-06-03 | 2016-09-13 | The Procter & Gamble Company | Structured fibrous web |
US8759606B2 (en) | 2009-06-03 | 2014-06-24 | The Procter & Gamble Company | Structured fibrous web |
WO2012125701A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Structured fibrous web |
WO2012125707A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Fluid permeable structured fibrous web |
WO2012125538A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Structured fibrous web |
WO2012125281A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Acquisition system for an absorbent article comprising a fluid permeable structured fibrous web |
WO2012125336A1 (en) | 2011-03-15 | 2012-09-20 | The Procter & Gamble Company | Structured fibrous web |
WO2012161840A1 (en) | 2011-03-15 | 2012-11-29 | The Procter & Gamble Company | Fluid permeable structured fibrous web |
WO2012162130A1 (en) | 2011-05-20 | 2012-11-29 | The Procter & Gamble Company | Fibers of polymer-wax compositions |
WO2012162085A1 (en) | 2011-05-20 | 2012-11-29 | The Procter & Gamble Company | Fiber of starch- polymer -oil compositions |
WO2012162083A1 (en) | 2011-05-20 | 2012-11-29 | The Procter & Gamble Company | Fibers of polymer-oil compositions |
EP3085733A1 (en) | 2011-05-20 | 2016-10-26 | The Procter and Gamble Company | Fibers of polymer-oil compositions |
EP3103833A1 (en) | 2011-05-20 | 2016-12-14 | The Procter and Gamble Company | Fibers of polymer-wax compositions |
WO2014081778A1 (en) | 2012-11-20 | 2014-05-30 | The Procter & Gamble Company | Starch-thermoplastic polymer-soap compositions and methods of making and using the same |
WO2014081765A1 (en) | 2012-11-20 | 2014-05-30 | The Procter & Gamble Company | Method of molding thermoplastic polymer compositions comprising hydroxylated lipids |
WO2014081789A1 (en) | 2012-11-20 | 2014-05-30 | The Procter & Gamble Company | Thermoplastic polymer compositions comprising hydroxylated lipid, methods of making, and non-migrating articles made therefrom |
WO2014081751A1 (en) | 2012-11-20 | 2014-05-30 | The Procter & Gamble Company | Polymer-grease compositions and methods of making and using the same |
WO2014081753A1 (en) | 2012-11-20 | 2014-05-30 | The Procter & Gamble Company | Thermoplastic polymer compositions comprising hydrogenated castor oil, methods of making, and non-migrating articles made therefrom |
WO2014081791A1 (en) | 2012-11-20 | 2014-05-30 | The Procter & Gamble Company | Starch-thermoplastic polymer-grease compositions and methods of making and using the same |
WO2014081749A2 (en) | 2012-11-20 | 2014-05-30 | The Procter & Gamble Company | Polymer-soap compositions and methods of making and using the same |
Also Published As
Publication number | Publication date |
---|---|
CA2412719A1 (en) | 2003-06-17 |
ES2214983T1 (es) | 2004-10-01 |
US6908292B2 (en) | 2005-06-21 |
JP3645887B2 (ja) | 2005-05-11 |
KR100493981B1 (ko) | 2005-06-13 |
ATE406470T1 (de) | 2008-09-15 |
MXPA02012303A (es) | 2006-09-14 |
CN1274896C (zh) | 2006-09-13 |
DK1323852T3 (da) | 2008-11-17 |
KR20030051303A (ko) | 2003-06-25 |
BR0205177B1 (pt) | 2013-11-26 |
ES2214983T3 (es) | 2008-12-16 |
CN1427106A (zh) | 2003-07-02 |
SI1323852T1 (sl) | 2008-12-31 |
JP2003213561A (ja) | 2003-07-30 |
DE50114266D1 (de) | 2008-10-09 |
CA2412719C (en) | 2007-01-16 |
US20030113394A1 (en) | 2003-06-19 |
EP1323852A1 (de) | 2003-07-02 |
MY129489A (en) | 2007-04-30 |
BR0205177A (pt) | 2004-06-29 |
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