EP0885999A2 - Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren - Google Patents
Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren Download PDFInfo
- Publication number
- EP0885999A2 EP0885999A2 EP98810524A EP98810524A EP0885999A2 EP 0885999 A2 EP0885999 A2 EP 0885999A2 EP 98810524 A EP98810524 A EP 98810524A EP 98810524 A EP98810524 A EP 98810524A EP 0885999 A2 EP0885999 A2 EP 0885999A2
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- EP
- European Patent Office
- Prior art keywords
- weight
- amino
- ink
- water
- reactive dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/382—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
- D06P1/50—Derivatives of cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
Definitions
- the present invention relates to a method for printing on textiles Fiber materials with reactive dyes using the inkjet printing process (for jet and Ink jet process) and corresponding printing inks.
- Inkjet printing processes have been in the textile industry for several years applied. These methods make it possible to produce a Eliminate the printing stencil, so that considerable cost and time savings are achieved can be. Especially in the production of sample templates can within reacted to changing needs much less time.
- Corresponding inkjet printing processes should in particular be optimal have application properties. Worth mentioning in this Relationship properties such as viscosity, stability, surface tension and Conductivity of the inks used. There are also increased demands on quality of the prints obtained, e.g. regarding color strength, fiber-dye binding stability as well as wet fastness properties. Of the known methods these requirements are not met in all properties, so there is still a need for there are new processes for textile inkjet printing.
- An ink is preferably used which contains at least one reactive dye of the formulas (1a) to (1h), in particular of the formulas (1a) to (1g). Particularly preferred an ink is used which contains at least one reactive dye of the formulas (1b) to (1j), in particular of the formulas (1b) to (1h) and preferably of the formulas (1b) to (1g) contains.
- the reactive dye of the formula (1j) is preferably used in a mixture with one Reactive dye of the formula (1i).
- the reactive dyes of the formulas (1a) to (1j) are known or can be used in analogy to known compounds, e.g. through usual diazotization, Coupling and condensation reactions.
- the reactive dyes of the formulas (1a) to (1j) used in the inks should preferably low in salt, i.e. a total salt content of less than 0.5 wt .-%, based on the weight of the dyes.
- Reactive dyes that due to their manufacture and / or the subsequent addition of coupé agents have higher salt contents, e.g. by membrane separation processes, such as Ultrafiltration, reverse osmosis or dialysis.
- the inks preferably contain exclusively those of the above formulas as dyes (1a) to (1j).
- the inks preferably contain a total reactive dye content of the above Formulas (la) to (1j) from 5 to 35 wt .-%, in particular 10 to 35 wt .-% and preferably 10 to 20% by weight based on the total weight of the ink.
- the content of N-methyl-2-pyrrolidone or 1,2-propylene glycol in the ink is usually 5 up to 30% by weight, in particular 5 to 20% by weight and preferably 10 to 20% by weight, based on the total weight of the ink.
- the inks preferably contain 1,2-propylene glycol, usually in an amount of 5 to 30% by weight, in particular 5 to 20% by weight and preferably 10 to 20% by weight on the total weight of the ink.
- the inks contain N-methyl-2-pyrrolidone, usually in an amount of 5 to 30% by weight, in particular 5 to 20% by weight and preferably 10 to 20% by weight based on the total weight of the ink.
- water-soluble, non-ionic cellulose ethers e.g. Methyl, ethyl, Hydroxyethyl, methylhydroxyethyl, hydroxypropyl or hydroxypropylmethyl cellulose in Consideration. Methyl cellulose or, in particular, hydroxyethyl cellulose are preferred.
- Alginates are in particular alkali alginates and preferably sodium alginate.
- the cellulose ethers and algnates are usually used in the ink in an amount of 0.01 to 2% by weight, in particular 0.01 to 1% by weight and preferably 0.01 to 0.5% by weight, based on the total weight of the ink used.
- Both the water-soluble, non-ionic cellulose ethers as well as the alginates are called thickeners used and allow the setting of a certain viscosity of the ink.
- a preferred embodiment of the present invention is characterized in that that the inks contain an alginate, usually in an amount of 0.01 to 2% by weight, in particular 0.01 to 1 wt .-% and preferably 0.01 to 0.5 wt .-%, based on the Total weight of the ink included.
- the inks contain one water-soluble, non-ionic cellulose ether, usually in an amount of 0.01 to 2 % By weight, in particular 0.01 to 1% by weight and preferably 0.01 to 0.5% by weight on the total weight of the ink.
- inks which 1,2-propylene glycol or N-methyl-2-pyrrolidone together with an alginate or a contain water-soluble, non-ionic cellulose ether.
- quantities to be used come here e.g. consider each of the above.
- the inks may also contain buffer substances, e.g. Borax, borate or citrate.
- buffer substances e.g. Borax, borate or citrate.
- borax sodium borate, sodium tetraborate and sodium citrate.
- she are used in particular in amounts of 0.1 to 3% by weight, preferably 0.1 to 1% by weight, based on the total weight of the ink used to achieve a pH of e.g. 4 to 9, especially 5 to 8.5.
- Preferred inks for the process according to the invention are those which have a viscosity from 1 to 40 mPa ⁇ s, in particular 1 to 20 mPa ⁇ s and preferably 1 to 10 mPa ⁇ s exhibit.
- the inks can also contain conventional additives, e.g. foam suppressants or in particular substances that inhibit fungal and / or bacterial growth. This are usually in amounts of 0.01 to 1 wt .-%, based on the total weight the ink used.
- inks that do not contain thioglycol.
- the inks can be prepared in the usual way by mixing the individual components in the desired amount of water can be produced.
- the method according to the invention for printing textile fiber materials can with performed on known ink jet printers suitable for textile printing will.
- ink jet printing process individual drops of the ink are checked out sprayed onto a substrate using a nozzle.
- the continuous ink jet method is predominantly used for this as well as the drop on demand method.
- the ink-jet method creates the drops continuously, not for printing required drops are drained into a collecting container and recycled.
- Drop on demand method drops are created and printed as desired; i.e. drops are only generated when this is necessary for printing.
- the Generation of the drops can e.g. by means of a piezo inkjet head or by means of thermal Energy (bubble jet). Pressure is preferred for the method according to the invention according to the continuous ink-jet method.
- fiber materials containing hydroxyl groups come as textile fiber materials into consideration.
- cellulose-containing fiber materials which are made up entirely or in part Cellulose exist. Examples are natural fiber materials such as cotton, linen or Hemp and regenerated fiber materials such as Viscose and lyocell. Especially viscose or preferably cotton are preferred.
- the fiber materials mentioned are preferably in the form of flat textile fabrics, knitted fabrics or webs.
- the aqueous alkaline liquor contains at least one of the usual bases, which in conventional Reactive printing processes are used to fix the reactive dyes.
- the base is e.g. in an amount of 10 to 100 g / l liquor, preferably 10 to 50 g / l Fleet, deployed.
- Sodium bicarbonate is preferred, sodium carbonate or a mixture of water glass and sodium carbonate is used.
- the pH the alkaline liquor is usually 7.5 to 13.5, preferably 8.5 to 12.5.
- the aqueous alkaline liquor can contain other additives, e.g. Hydrotrope, contain.
- Urea is preferably used as the hydrotroping agent, e.g. in a Amount of 25 to 200 g / l liquor, preferably 50 to 150 g / l liquor is used.
- the fiber material is preferably dried after the above pretreatment.
- the fiber material is advantageously dried, preferably at temperatures up to 150 ° C, especially 80 to 120 ° C, and then a heat treatment process subjected to complete the print, or the dye to fix.
- the heat treatment can e.g. through a warm dwell process, a thermal insulation process or preferably be carried out by a steaming process.
- the printed fiber material is e.g. one treatment in one Damper with possibly superheated steam, conveniently at one temperature from 95 to 180 ° C, advantageously in saturated steam.
- the printed fiber material is usually washed with water in the usual way washed out to remove non-fixed dye.
- the prints obtainable by the process according to the invention have good prints General realities on; e.g. they have high fiber-dye binding stability both in the acidic and in the alkaline range, good lightfastness, good Wet fastness properties, such as fastness to washing, water, sea water, over-dyeing and perspiration, one good chlorine fastness, rubbing fastness, ironing fastness and pleating fastness as well as sharp contours and high color strength.
- the printing inks used are characterized by good stability and good viscosity properties.
- the procedure is as in one of Examples 21 to 29, but using an ink which additionally 15 wt .-% 1,2-propylene glycol and instead of the specified amount Water contains a correspondingly reduced amount of water and carries the pressure with it a drop-on-demand piezo inkjet head, so you get analog prints with good Fastness to washing.
- the procedure is as in one of Examples 6 to 9 and 25 to 29, but is used an ink, which additionally 0.5 wt .-% borax and instead of the specified amount Water contains a correspondingly reduced amount of water, so you get analog Print with good wash fastness.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
mit der Massgabe, dass, falls die verwendete Tinte einen Reaktivfarbstoff der Formel (1a) enthält, dieser in der Tinte zusammen mit N-Methyl-2-pyrrolidon, Alginat oder einen wasserlöslichen, nichtionogenen Celluloseäther enthalten ist.
- 15 Gew.-% des Reaktivfarbstoffs der Formel
- 15 Gew.-% N-Methyl-2-pyrrolidon und
- 70 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel
- 15 Gew.-% 1,2-Propylenglykol und
- 70 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel
- 15 Gew.-% 1,2-Propylenglykol und
- 70 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel
- 15 Gew.-% 1,2-Propylenglykol und
- 70 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel
- 15 Gew.-% 1,2-Propylenglykol und
- 70 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel
- 15 Gew.-% 1,2-Propylenglykol und
- 70 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel
- 15 Gew.-% 1,2-Propylenglykol und
- 70 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel
- 15 Gew.-% 1,2-Propylenglykol und
- 70 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel
- 15 Gew.-% 1,2-Propylenglykol und
- 70 Gew.-% Wasser
- 15 Gew.-% einer Mischung im Gewichtsverhältnis von 1:1 des Reaktivfarbstoffs der Formel (109) mit dem Reaktivfarbstoff der Formel
- 15 Gew.-% 1,2-Propylenglykol und
- 70 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel (101),
- 15 Gew.-% 1,2-Propylenglykol,
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 69,7 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel (102),
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 84,7 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel (103),
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 84,7 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel (104),
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 84,7 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel (105),
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 84,7 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel (106),
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 84,7 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel (107),
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 84,7 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel (108),
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 84,7 Gew.-% Wasser
- 15 Gew.-% des Reaktivfarbstoffs der Formel (109),
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 84,7 Gew.-% Wasser
- 15 Gew.-% einer Mischung der Reaktivfarbstoffe der Formeln (109) und (110) im Gewichtsverhältnis von 1:1,
- 0,3 Gew.-% Hydroxyaethylcellulose und
- 84,7 Gew.-% Wasser
Bsp. | Zusammensetzung der Tinte |
48 | - 10 Gew.-% des Reaktivfarbstoffs der Formel (101) |
- 0,3 Gew.-% Natriumalginat | |
- 89,7 Gew.-% Wasser | |
49 | - 20 Gew.-% des Reaktivfarbstoffs der Formel (102) |
- 0,3 Gew.-% Natriumalginat | |
- 79,7 Gew.-% Wasser | |
50 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (103) |
- 0,3 Gew.-% Natriumalginat | |
- 84,7 Gew.-% Wasser | |
51 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (104) |
- 0,3 Gew.-% Natriumalginat | |
- 84,7 Gew.-% Wasser | |
52 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (105) |
- 0,3 Gew.-% Natriumalginat | |
- 84,7 Gew.-% Wasser | |
53 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (106) |
- 0,3 Gew.-% Natriumalginat | |
- 84,7 Gew.-% Wasser | |
54 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (107) |
- 0,3 Gew.-% Natriumalginat | |
- 84,7 Gew.-% Wasser | |
55 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (108) |
- 0,3 Gew.-% Natriumalginat | |
- 84,7 Gew.-% Wasser | |
56 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (109) |
- 0,3 Gew.-% Natriumalginat | |
- 84,7 Gew.-% Wasser | |
57 | - 15 Gew.-% einer Mischung der Reaktivfarbstoffe der Formeln (109) und (110) im Gewichtsverhältnis von 1:1 |
- 0,3 Gew.-% Natriumalginat | |
- 84,7 Gew.-% Wasser |
Bsp. | Zusammensetzung der Tinte |
58 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (102) |
- 15 Gew.-% 1,2-Propylenglykol | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
59 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (103) |
- 15 Gew.-% 1,2-Propylenglykol | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
60 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (104) |
- 15 Gew.-% 1,2-Propylenglykol | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
61 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (105) |
- 15 Gew.-% 1,2-Propylenglykol | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
62 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (106) |
- 15 Gew.-% 1,2-Propylenglykol | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
63 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (107) |
- 15 Gew.-% 1,2-Propylenglykol | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
64 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (108) |
- 15 Gew.-% 1,2-Propylenglykol | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
65 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (109) |
- 15 Gew.-% 1,2-Propylenglykol | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
66 | - 15 Gew.-% einer Mischung der Reaktivfarbstoffe der Formeln (109) und (110) im Gewichtsverhältnis von 1:1 |
- 15 Gew.-% 1,2-Propylenglykol | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
67 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (102) |
- 15 Gew.-% N-Methyl-2-pyrrolidon | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
68 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (103) |
- 15 Gew.-% N-Methyl-2-pyrrolidon | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
69 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (104) |
- 15 Gew.-% N-Methyl-2-pyrrolidon | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
70 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (105) |
- 15 Gew.-% N-Methyl-2-pyrrolidon | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
71 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (106) |
- 15 Gew.-% N-Methyl-2-pyrrolidon | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
72 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (107) |
- 15 Gew.-% N-Methyl-2-pyrrolidon | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
73 | - 15 Gew.-% des Reaktivfarbstoffs der Formel (108) |
- 15 Gew.-% N-Methyl-2-pyrrolidon | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
74 | -15 Gew.-% des Reaktivfarbstoffs der Formel (109) |
- 15 Gew.-% N-Methyl-2-pyrrolidon | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser | |
75 | - 15 Gew.-% einer Mischung der Reaktivfarbstoffe der Formeln (109) und (110) im Gewichtsverhältnis von 1:1 |
- 15 Gew.-% N-Methyl-2-pyrrolidon | |
- 0,3 Gew.-% Natriumalginat | |
- 69,7 Gew.-% Wasser |
Claims (15)
- Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren, dadurch gekennzeichnet, dass man diese Fasermaterialien mit einer wässrigen Tinte bedruckt, welchea) mindestens einen Reaktivfarbstoff der Formeln und worin CuPhC ein Kupferphthalocyaninrest ist, undb) 1,2-Propylenglykol, N-Methyl-2-pyrrolidon, Alginat oder einen wasserlöslichen, nichtionogenen Celluloseäther
mit der Massgabe, dass, falls die verwendete Tinte einen Reaktivfarbstoff der Formel (la) enthält, dieser in der Tinte zusammen mit N-Methyl-2-pyrrolidon, Alginat oder einen wasserlöslichen, nichtionogenen Celluloseäther enthalten ist. - Verfahren gemäss Anspruch 1, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche mindestens einen Reaktivfarbstoff der Formeln (1a) bis (1h) enthält.
- Verfahren gemäss einem der Ansprüche 1 und 2, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche mindestens einen Reaktivfarbstoff der Formeln (1a) bis (1g) enthält.
- Verfahren gemäss einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche mindestens einen Reaktivfarbstoff der Formeln (1b) bis (1g) enthält.
- Verfahren gemäss einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche 5 bis 30 Gew.-% 1,2-Propylenglykol enthält.
- Verfahren gemäss einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche 5 bis 30 Gew.-% N-Methyl-2-pyrrolidon enthält.
- Verfahren gemäss einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche 0,01 bis 2 Gew.-% Alginat enthält.
- Verfahren gemäss einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche 0,01 bis 2 Gew.-% eines wasserlöslichen, nichtionogenen Celluloseäthers enthält.
- Verfahren gemäss einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche
5 bis 30 Gew.-% 1,2-Propylenglykol oder N-Methyl-2-pyrrolidon zusammen mit 0,01 bis 2 Gew.-% eines Alginats oder eines wasserlöslichen, nichtionogenen Celluloseäthers enthält. - Verfahren gemäss einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche einen Gesamtgehalt an Reaktivfarbstoffen der Formeln (1a) bis (1j) von 5 bis 35 Gew.-% enthält.
- Verfahren gemäss einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, man eine Tinte verwendet, welche eine Viskosität von 1 bis 40 mPa·s, insbesondere 1 bis 20 mPa·s, aufweist.
- Verfahren gemäss einem der Ansprüche 1 bis 11, dadurch gekennzeichnet, dass man eine Tinte verwendet, welche eine Puffersubstanz enthält.
- Verfahren gemäss einem der Ansprüche 1 bis 12, dadurch gekennzeichnet, dass man cellulosische Fasermaterialien, insbesondere Baumwolle oder Viskose, bedruckt.
- Wässrige Drucktinte für das Tintenstrahldruck-Verfahren, dadurch gekennzeichnet, dass siea) 5 bis 35 Gew.-% mindestens eines Reaktivfarbstoffes der Formeln (1a) bis (1j) gemäss Anspruch 1 undb) 0,01 bis 2 Gew.-% eines Alginats
- Wässrige Drucktinte für das Tntenstrahldruck-Verfahren, dadurch gekennzeichnet, dass siea) 5 bis 35 Gew.-% mindestens eines Reaktivfarbstoffes der Formeln (1a) bis (1j) gemäss Anspruch 1,b) 0,01 bis 2 Gew.-% eines Alginats oder eines wasserlöslichen, nichtionogenen Celluloseäthers, undc) 5 bis 30 Gew.-% 1,2-Propylenglykol oder N-Methyl-2-pyrrolidon
Applications Claiming Priority (3)
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CH147497 | 1997-06-17 | ||
CH1474/97 | 1997-06-17 | ||
CH147497 | 1997-06-17 |
Publications (3)
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EP0885999A2 true EP0885999A2 (de) | 1998-12-23 |
EP0885999A3 EP0885999A3 (de) | 2000-02-23 |
EP0885999B1 EP0885999B1 (de) | 2005-07-27 |
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EP98810524A Expired - Lifetime EP0885999B1 (de) | 1997-06-17 | 1998-06-09 | Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren |
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US (1) | US6007611A (de) |
EP (1) | EP0885999B1 (de) |
JP (1) | JPH1112957A (de) |
KR (1) | KR100538665B1 (de) |
CN (1) | CN1140666C (de) |
BR (1) | BR9803345A (de) |
DE (1) | DE59812953D1 (de) |
ES (1) | ES2246526T3 (de) |
ID (1) | ID20433A (de) |
MX (1) | MX227075B (de) |
MY (1) | MY117132A (de) |
PT (1) | PT885999E (de) |
SG (1) | SG79981A1 (de) |
TR (1) | TR199801118A2 (de) |
TW (1) | TW503250B (de) |
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WO2000015898A1 (de) * | 1998-09-16 | 2000-03-23 | Ciba Specialty Chemicals Holding Inc. | Verfahren zum bedrucken von textilen fasermaterialien nach dem tintenstrahldruck-verfahren |
DE10135042A1 (de) * | 2001-07-11 | 2003-02-06 | Dystar Textilfarben Gmbh & Co | Wässrige Tintenformulierungen für das Tintenstrahldruck-Verfahren |
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CN104131478A (zh) * | 2014-07-24 | 2014-11-05 | 哈尔滨市朗威尔科技发展有限公司 | 活性墨水染料在亚麻纺织物上彩色印染工艺 |
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CN106752077B (zh) * | 2016-11-28 | 2018-07-24 | 浙江瑞华化工有限公司 | 一种蓝色活性染料组合物及其制备方法和用途 |
EP3342927B1 (de) | 2016-12-28 | 2019-08-14 | Seiko Epson Corporation | Tintenstrahltintenzusammensetzung für textildruck, tintensatz und aufzeichnungsverfahren |
JP6954053B2 (ja) * | 2016-12-28 | 2021-10-27 | セイコーエプソン株式会社 | 捺染用インクジェットインク組成物、インクセット及び記録方法 |
JP2019060051A (ja) | 2017-09-27 | 2019-04-18 | セイコーエプソン株式会社 | 記録方法 |
JP7017054B2 (ja) | 2017-09-29 | 2022-02-08 | セイコーエプソン株式会社 | インクジェット捺染インク、インクジェット捺染インクセットおよび捺染方法 |
JP2019137793A (ja) | 2018-02-13 | 2019-08-22 | セイコーエプソン株式会社 | 捺染インクジェットインク組成物セット及び記録方法 |
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- 1998-06-02 US US09/089,145 patent/US6007611A/en not_active Expired - Lifetime
- 1998-06-09 DE DE59812953T patent/DE59812953D1/de not_active Expired - Fee Related
- 1998-06-09 PT PT98810524T patent/PT885999E/pt unknown
- 1998-06-09 EP EP98810524A patent/EP0885999B1/de not_active Expired - Lifetime
- 1998-06-09 ES ES98810524T patent/ES2246526T3/es not_active Expired - Lifetime
- 1998-06-11 ID IDP980859A patent/ID20433A/id unknown
- 1998-06-12 SG SG9801402A patent/SG79981A1/en unknown
- 1998-06-15 TW TW087109451A patent/TW503250B/zh not_active IP Right Cessation
- 1998-06-15 JP JP10167253A patent/JPH1112957A/ja active Pending
- 1998-06-16 KR KR1019980022468A patent/KR100538665B1/ko not_active IP Right Cessation
- 1998-06-16 CN CNB98103229XA patent/CN1140666C/zh not_active Expired - Fee Related
- 1998-06-16 MX MX9804842A patent/MX227075B/es not_active IP Right Cessation
- 1998-06-16 TR TR1998/01118A patent/TR199801118A2/xx unknown
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- 1998-06-17 BR BR9803345-0A patent/BR9803345A/pt not_active Application Discontinuation
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DE10135042A1 (de) * | 2001-07-11 | 2003-02-06 | Dystar Textilfarben Gmbh & Co | Wässrige Tintenformulierungen für das Tintenstrahldruck-Verfahren |
Also Published As
Publication number | Publication date |
---|---|
PT885999E (pt) | 2005-10-31 |
JPH1112957A (ja) | 1999-01-19 |
ID20433A (id) | 1998-12-17 |
US6007611A (en) | 1999-12-28 |
EP0885999A3 (de) | 2000-02-23 |
TW503250B (en) | 2002-09-21 |
MX227075B (en) | 2005-04-01 |
EP0885999B1 (de) | 2005-07-27 |
CN1140666C (zh) | 2004-03-03 |
CN1202550A (zh) | 1998-12-23 |
MX9804842A (en) | 2000-04-30 |
TR199801118A3 (tr) | 1999-10-21 |
KR100538665B1 (ko) | 2006-03-23 |
ES2246526T3 (es) | 2006-02-16 |
BR9803345A (pt) | 1999-11-03 |
TR199801118A2 (xx) | 1999-10-21 |
KR19990007012A (ko) | 1999-01-25 |
MY117132A (en) | 2004-05-31 |
DE59812953D1 (de) | 2005-09-01 |
SG79981A1 (en) | 2001-04-17 |
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