EP0655468B1 - Process for preparing vinylidenefluoride polymers - Google Patents

Process for preparing vinylidenefluoride polymers Download PDF

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Publication number
EP0655468B1
EP0655468B1 EP94118400A EP94118400A EP0655468B1 EP 0655468 B1 EP0655468 B1 EP 0655468B1 EP 94118400 A EP94118400 A EP 94118400A EP 94118400 A EP94118400 A EP 94118400A EP 0655468 B1 EP0655468 B1 EP 0655468B1
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EP
European Patent Office
Prior art keywords
vdf
polymerization
hcfc
transfer agent
chain transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94118400A
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German (de)
English (en)
French (fr)
Other versions
EP0655468A1 (en
Inventor
Vincenzo Arcella
Bradley Kent
Patrizia Maccone
Giulio Brinati
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Solvay Specialty Polymers Italy SpA
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Ausimont SpA
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP

Definitions

  • the present invention relates to a process for preparing vinylidenefluoride (VDF) polymers by polymerization in an aqueous medium in the presence of radical initiators and of a suitable chain transfer agent.
  • VDF vinylidenefluoride
  • PVDF polyvinylidenefluoride
  • VDF copolymers with other fluorinated olefins for instance hexafluoropropene or tetrafluoroethylene
  • DTBP diterbutylperoxide
  • IPP diisopropylperoxydicarbonate
  • trichlorofluoromethane is a polluting product for environment, since it is a perhalogenated chlorine-containing compound and therefore having a high ozone depleting potential.
  • HCFC-123 1,1,1-trifluoro-2,2-dichloroethane is a chain transfer agent particularly effective during VDF polymerization in an aqueous medium, and allows to obtain a final product with very good appearance, substantially devoid of discoloration effects at high temperatures.
  • Object of the present invention is, therefore, a process for preparing vinylidenefluoride (VDF) polymers, which comprises polymerizing VDF, optionally in association with other fluorinated olefins, in an aqueous medium in the presence of a radical initiator and of 1,1,1,-trifluoro-2,2-dichloroethane (HCFC-123) as chain transfer agent.
  • VDF vinylidenefluoride
  • HCFC-123 is a product substitutive for conventional chlorofluorocarbons, having an ozone depleting potential which is substantially zero. It can be prepared by hydrofluorination of tetrachloroethylene as described, for instance, in US Patent 4,967,023.
  • the amount of HCFC-123 to be added to the reaction medium can vary within a wide range, depending on the molecular weight to be obtained. For instance, to obtain a PVDF having a Melt Flow Index (MFI) from 1 to 25 g/10' (measured at 230°C with a 5 kg load according to ASTM D-1238 standard), a total amount of HCFC-123 from 0.1 to 6%, preferably from 0.3 to 3.0%, by weight with respect to the total amount of monomer fed into the reactor.
  • MFI Melt Flow Index
  • the transfer agent is continuously fed into the reactor in discrete amounts during the polymerization. Moreover, it is possible to add the transfer agent as a whole at the beginning of the polymerization.
  • a particularly preferred way of feeding HCFC-123 is that described in European patent application No. 94107588.9, filed on May 17, 1994 in the name of the Applicant.
  • the polymerization reaction can be generally carried out at a temperature of from 20° to 160°C, preferably from 30° to 130°C.
  • the reaction pressure can generally vary from 30 to 100 bar, preferably from 40 to 90 bar.
  • any compound capable of generating active radicals at the chosen (co)polymerization temperature can be used. It can be selected for instance from: peroxide inorganic salts, such as for instance sodium, potassium or ammonium peroxydisulphate; dialkylperoxides, such as for instance diterbutylperoxide (DTBP); dialkylperoxydicarbonates, such as for instance diethyl- and diisopropyl-peroxydicarbonate (IPP), bis-(4-t-butyl-cyclohexyl)-peroxydicarbonate; t-alkylperoxybenzoates; t-alkylperoxypivalates, such as for instance t-butyl and t-amylperpivalate; acetylcyclohexanesulphonyl peroxide; dibenzoyl peroxide; dicumylperoxide.
  • peroxide inorganic salts such as for instance sodium, potassium or ammonium peroxydis
  • the amount of initiator to be used is not critical, and it is generally from 0.1 to 10 g/l H2O , preferably from 0.5 to 5 g/l H2O .
  • the reaction is usually carried out in the presence of a suitable surfactant (see for instance those described in US Patents 4,360,652 and 4,025,709), to form a stable emulsion.
  • a suitable surfactant see for instance those described in US Patents 4,360,652 and 4,025,709
  • they are fluorinated surfactants, selected from the products of general formula: R f -X - M + wherein R f is a (per)fluoroalkyl chain C 5 -C 16 or a (per)fluoropolyoxyalkylene chain, X - is -COO - or -SO 3 - , M + is selected from: H + , NH 4 + , an alkali metal ion.
  • the polymerization can be carried out without surfactants, as described in US Patent 5,095,081, or in suspension in the presence of a suitable suspending agent, for instance polyvinylalcohol or water-soluble cellulose derivatives, as described in US Patent 4,524,194.
  • a suitable suspending agent for instance polyvinylalcohol or water-soluble cellulose derivatives, as described in US Patent 4,524,194.
  • HCFC-123 is used as chain transfer agent in a VDF polymerization process in aqueous emulsion at a temperature of from 95° to 120°C, preferably from 100° to 115°C, as described in the above mentioned European patent application No. 94107588.9.
  • the organic proxides having a self-accelerating decomposition temperature (SADT) higher than 50°C are preferably used as initiators, such as for instance: diterbutylperoxide, diterbutylperoxyisopropylcarbonate, terbutyl(2-ethyl-hexyl)-peroxycarbonate, terbutylperoxy-3,5,5-trimethylhexanoate.
  • SADT self-accelerating decomposition temperature
  • VDF polymerization it is meant both the VDF homopolymerization reaction and the copolymerization of a monomer mixture wherein the VDF content is prevailing, so as to obtain copolymers containing at least 50% by moles of VDF copolymerized with at least another fluorinated olefin C 2 -C 6 .
  • fluorinated olefins copolymerizable with VDF particularly the following can be used: tetrafluoroethylene (TFE), trifluoroethylene, chlorotrifluoroethylene, hexafluoropropene (HFP), vinylfluoride and pentafluoropropene.
  • TFE tetrafluoroethylene
  • HFP hexafluoropropene
  • vinylfluoride vinylfluoride
  • pentafluoropropene particularly preferred are copolymers consisting of 70-99% by moles of VDF and 1-30% by moles of TFE and/or HFP.
  • the process object of the present invention can be carried out in the presence of an emulsion, or, preferably, of a microemulsion of perfluoropolyoxyalkylenes, as described in US Patents 4,789,717 and 4,864,006, or also in the presence of a microemulsion of fluoropolyoxyalkylenes having hydrogen-containing end-groups and/or hydrogen-containing repetitive units, as described in European patent application No. 94107042.7, filed on May 5, 1994 in the name of the Applicant.
  • a mineral oil or a paraffin, liquid at the polymerization temperature can be added to the reaction mixture, in order to inhibit coagulation of the polymer and to hinder its adhesion to reactor walls.
  • HCFC-123 Fixing a total amount of polymer to be produced equal to 1000 g, corresponding to a final concentration of polymer in water equal to 143.0 g/l H2O , HCFC-123 was fed in 10 portions at regular 10% intervals of increase in polymer concentration with respect to the final concentration, according to the following scheme: Polymer concentration (g/l H2O ) Amount of added transfer agent (moles) 0 0.007 (6.1%) 14.3 0.026 (22.0%) 28.6 0.015 (12.2%) 42.9 0.013 (11.0%) 57.2 0.012 (9.8%) 71.5 0.010 (8.5%) 85.8 0.010 (8.5%) 100.1 0.009 (7.3%) 114.4 0.009 (7.3%) 128.7 0.009 (7.3%) 143.0 ---
  • the polymer concentration in the reaction medium was monitored measuring the amount of gaseous monomer fed into the reactor after the initial charging step.
  • the MFI was measured at 230°C with 5 kg according to ASTM D-1238 standard.
  • DSC differential scanning calorimetry
  • ⁇ H m ' second melting enthalpy
  • T m ' second melting temperature
  • Example 1 was repeated in the same conditions, using as chain transfer agent methyl-terbutylether in a total amount of 0.07 moles subdivided in 10 portions and introduced into the reactor according to the same modalities of Example 1.
  • the VDF polymerization was carried out in a 7.5 l horizontal reactor equipped with a mechanical stirrer. 5.5 l of water, 4 g of paraffin wax and 115 ml of a 2% by weight aqueous solution of fluorinated surfactant Surflon (R) S111S (produced by Asahi Glass Co.) were loaded. The reactor was then brought to the working temperature of 115°C and to a pressure of 50 absolute bar by feeding gaseous VDF. 15.1 g of diterbutylperoxide were then added and VDF was continuously fed during polymerization to maintain the pressure constant. At the polymerization start 0.279 moles of HCFC-123 as chain transfer agent were fed. The polymerization was carried out for 269 min until 2291 g of polymer were obtained, corresponding to a concentration of 417 g/l H2O .

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
EP94118400A 1993-11-25 1994-11-23 Process for preparing vinylidenefluoride polymers Expired - Lifetime EP0655468B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI932491 1993-11-25
IT93MI002491A IT1265223B1 (it) 1993-11-25 1993-11-25 Processo per la preparazione di polimeri del vinilidenfluoruro

Publications (2)

Publication Number Publication Date
EP0655468A1 EP0655468A1 (en) 1995-05-31
EP0655468B1 true EP0655468B1 (en) 1997-04-16

Family

ID=11367250

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94118400A Expired - Lifetime EP0655468B1 (en) 1993-11-25 1994-11-23 Process for preparing vinylidenefluoride polymers

Country Status (11)

Country Link
US (1) US5473030A (ko)
EP (1) EP0655468B1 (ko)
JP (1) JP3547182B2 (ko)
KR (1) KR100332261B1 (ko)
CN (1) CN1107164A (ko)
AT (1) ATE151781T1 (ko)
CA (1) CA2136462A1 (ko)
DE (1) DE69402670T2 (ko)
ES (1) ES2102124T3 (ko)
IT (1) IT1265223B1 (ko)
RU (1) RU2128668C1 (ko)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5696215A (en) * 1996-02-28 1997-12-09 Central Glass Company, Limited Elastic fluorohydrocarbon resin and method of producing same
IT1295535B1 (it) * 1996-07-01 1999-05-12 Ausimont Spa Processo di polimerizzazione di vinilidenfluoruro (vdf)
EP0931795A4 (en) * 1996-10-11 2000-04-12 Nippon Carbide Kogyo Kk POLYMER OBTAINED BY AN EMULSION POLYMERIZATION PROCESS
IT1296968B1 (it) 1997-12-15 1999-08-03 Ausimont Spa Elastomeri termoplastici fluorurati
IT1307756B1 (it) 1999-02-05 2001-11-19 Ausimont Spa Polimeri elettroliti per batterie ricaricabili al litio.
US6649720B2 (en) 2001-02-14 2003-11-18 Atofina Chemicals, Inc. Ethane as a chain transfer agent for vinylidene fluoride polymerization
EP1432744B2 (en) * 2001-05-02 2014-10-01 3M Innovative Properties Company Aqueous emulsion polymerization in the presence of ethers as chain transfer agents to produce fluoropolymers
FR2842203A1 (fr) * 2002-07-12 2004-01-16 Atofina Procede de fabrication du polymere du fluorure de vinylidene
FR2850387B1 (fr) * 2003-01-23 2005-03-04 Atofina Procede de fabrication de pvdf
US7122610B2 (en) * 2004-04-27 2006-10-17 Arkema Inc. Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants
ITMI20050007A1 (it) * 2005-01-05 2006-07-06 Solvay Solexis Spa Uso di dispersioni acquose di polimeri a base di vdf nella preparazione di vernici per rivestimenti di substrati architettonici
WO2009020187A1 (ja) * 2007-08-07 2009-02-12 Daikin Industries, Ltd. 低分子量ポリテトラフルオロエチレン水性分散液、低分子量ポリテトラフルオロエチレン粉末及び低分子量ポリテトラフルオロエチレンの製造方法
US20090281261A1 (en) * 2008-05-09 2009-11-12 E. I. Du Pont De Nemours And Company Abatement of Fluoroether Carboxylic Acids or Salts Employed in Fluoropolymer Resin Manufacture
US11098177B2 (en) * 2013-09-30 2021-08-24 Arkema Inc. Heat stabilized polyvinylidene fluoride polymer composition
CN103739756B (zh) * 2013-12-04 2016-08-17 中昊晨光化工研究院有限公司 一种改善热稳定性的聚偏氟乙烯聚合物制备方法
CN104448077B (zh) * 2014-12-06 2017-01-04 常熟丽源膜科技有限公司 聚偏氟乙烯的生产工艺

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3193539A (en) * 1960-05-31 1965-07-06 Pennsalt Chemicals Corp Process for polymerizing vinylidene fluoride
US3235537A (en) * 1961-06-23 1966-02-15 Du Pont Fluorine containing terpolymer of a perfluorovinyl ether, vinylidene fluoride and a monomer of the structure cfx=cfy
GB1057088A (en) * 1964-12-29 1967-02-01 Kali Chemie Ag Process for the preparation of high molecular weight vinyl fluoride and vinylidene fluoride polymers and copolymers
US3475396A (en) * 1966-07-06 1969-10-28 Diamond Shamrock Corp Process for polymerizing vinylidene fluoride
DE2229607A1 (de) * 1972-06-19 1974-01-17 Dynamit Nobel Ag Verfahren zur herstellung von thermoplastisch verarbeitbaren fluorolefin-polymerisaten
US4000356A (en) * 1972-06-19 1976-12-28 Dynamit Nobel Aktiengesellschaft Process for the preparation of thermoplastically workable fluoro-olefin polymers
JPS5224557B2 (ko) * 1973-12-13 1977-07-01
FR2286153A1 (fr) * 1974-09-24 1976-04-23 Ugine Kuhlmann Procede de polymerisation ou de copolymerisation en emulsion du fluorure de vinylidene
JPS5141085A (ja) * 1974-10-05 1976-04-06 Daikin Ind Ltd Tetorafuruoruechirenwatsukusuno seizoho
JPS5525412A (en) * 1978-08-11 1980-02-23 Asahi Glass Co Ltd Preparation of fluorine-containing copolymer
US4360652A (en) * 1981-08-31 1982-11-23 Pennwalt Corporation Method of preparing high quality vinylidene fluoride polymer in aqueous emulsion
FR2542319B1 (fr) * 1983-03-10 1985-07-19 Solvay Procede pour la polymerisation dans un milieu aqueux de mise en suspension du fluorure de vinylidene
US4569978A (en) * 1984-07-25 1986-02-11 Pennwalt Corporation Emulsion polymerization of vinylidene fluoride polymers in the presence of trichlorofluoromethane as chain transfer agent
US4569973A (en) * 1984-08-24 1986-02-11 General Electric Company Copolyetheresters from caprolactone
IT1189092B (it) * 1986-04-29 1988-01-28 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri fluorurati
IT1204903B (it) * 1986-06-26 1989-03-10 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri florati
IT1202652B (it) * 1987-03-09 1989-02-09 Ausimont Spa Processo per la preparazione di 1,1,1-trifluoro-2,2-dicloroetano mediante idrofluorurazione in presenza di catalizzatori
IT1230650B (it) * 1988-11-17 1991-10-28 Ausimont Srl Procedimento per la preparazione di copolimeri tetrafluoroetilene etilene
FR2644466B1 (fr) * 1989-03-15 1992-08-14 Solvay Procede pour la fabrication de polymeres du fluorure de vinylidene et utilisation des polymeres du fluorure de vinylidene pour la formulation de peintures
JPH059169A (ja) * 1991-06-28 1993-01-19 Kyowa Hakko Kogyo Co Ltd ベンゼンスルホンアミド誘導体
DE4139665A1 (de) * 1991-12-02 1993-06-03 Hoechst Ag Verfahren zur herstellung von polymerisaten des tetrafluorethylens
IT1265067B1 (it) * 1993-05-18 1996-10-30 Ausimont Spa Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati

Also Published As

Publication number Publication date
ITMI932491A1 (it) 1995-05-25
DE69402670T2 (de) 1997-07-31
KR100332261B1 (ko) 2002-08-08
CN1107164A (zh) 1995-08-23
EP0655468A1 (en) 1995-05-31
ES2102124T3 (es) 1997-07-16
JPH07196735A (ja) 1995-08-01
ATE151781T1 (de) 1997-05-15
KR950014151A (ko) 1995-06-15
JP3547182B2 (ja) 2004-07-28
RU94041702A (ru) 1996-10-10
US5473030A (en) 1995-12-05
DE69402670D1 (de) 1997-05-22
RU2128668C1 (ru) 1999-04-10
CA2136462A1 (en) 1995-05-26
IT1265223B1 (it) 1996-10-31
ITMI932491A0 (it) 1993-11-25

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