EP0576940B1 - Agent pesticide et retardateur de feu pour le bois et d'autres matières organiques - Google Patents

Agent pesticide et retardateur de feu pour le bois et d'autres matières organiques Download PDF

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Publication number
EP0576940B1
EP0576940B1 EP93109822A EP93109822A EP0576940B1 EP 0576940 B1 EP0576940 B1 EP 0576940B1 EP 93109822 A EP93109822 A EP 93109822A EP 93109822 A EP93109822 A EP 93109822A EP 0576940 B1 EP0576940 B1 EP 0576940B1
Authority
EP
European Patent Office
Prior art keywords
whey
wood
resins
products
whey according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP93109822A
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German (de)
English (en)
Other versions
EP0576940A1 (fr
Inventor
Hubert Fritz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP0576940A1 publication Critical patent/EP0576940A1/fr
Application granted granted Critical
Publication of EP0576940B1 publication Critical patent/EP0576940B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16—Inorganic impregnating agents
    • B27K3/20—Compounds of alkali metals or ammonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B27K3/36—Aliphatic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00—Purpose of the treatment
    • B27K2240/30—Fireproofing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/02—Staining or dyeing wood; Bleaching wood

Definitions

  • the invention relates to the use of a pest and fire protection agent for wood and other organic materials.
  • Protective agents for wood and other organic materials are primarily intended to protect them from pests, in particular from fungi, destructive insects and bacteria. In addition, the protective agents also have to reduce the flammability of wood in many cases.
  • protective effects should, if possible, be achieved by the protective means without endangering humans and farm animals or the environment. Furthermore, protective agents should be environmentally friendly and inexpensive to manufacture.
  • the invention has set itself the task of creating a protective agent that optimally fulfills the aforementioned conditions.
  • whey which is preferably saponified by dilution with approximately the same amount of water, with bases or substances with a basic action, as pesticides and fire protection agents for wood and other organic materials.
  • DE-C-35 18 188 describes a process for producing lactic acid clay, the clay having obtained its lactic acid properties by slurrying with fermentation whey.
  • the alumina thus created is used as an antiseptic, bactericide and / or bacteriostat.
  • the invention proposes a new use of a whey treated in this way.
  • Whey is produced in comparatively large quantities as a cheap by-product when processing milk. If fat and casein are excreted from the milk by acidification or rennet, the whey remains, which, among other things, still contains about 0.9 g protein, 0.3 g fat and 4.5 g lactose per 100 g.
  • This whey is saponified basic for the preparation of protective agents according to the invention, preferably with dilution with approximately the same amount of water. Fresh whey or the appropriate amount of whey powder dissolved in water can be used for the saponification.
  • the basic saponification of the whey can preferably be carried out using alkali solutions such as sodium hydroxide solution or potassium hydroxide solution.
  • the saponification is generally carried out by mixing the reaction components dissolved or suspended in water in stoichiometric or non-stoichiometric proportions, preferably with an excess of base, and optionally with heating.
  • the saponification extends not only to the residual fat content in the whey, but also to the remaining components.
  • the amount of base or basic reacting substances added is chosen so that a pH value of 7.5 to 14, preferably 8 to 13, in particular 9 to 12 results in the saponification product.
  • pest and fire-retardant substances in dissolved, emulsified or suspended form can be added to the protective agent, for example boron salts, ammonium compounds, amines, aminoplast resins, sugars, starches, polyols, phosphates, silicates or carbonates and also organic ones and inorganic fungicides and insecticides.
  • the protective agent in dissolved, emulsified or suspended form, e.g. B. water repellents such as waxes or silicones, binders such as alkyd, acrylate, vinyl resins or drying oils.
  • B. water repellents such as waxes or silicones
  • binders such as alkyd, acrylate, vinyl resins or drying oils.
  • dyes e.g. Carotene, or pigments, e.g. Earth colors
  • the materials to be protected are treated with the protective agent according to the invention by brushing, spraying, pouring, flooding, dipping or soaking.
  • the protective effect the surface treatment of the materials to be protected with the protective agent is sufficient.
  • the partial or complete impregnation of the material for example by using vacuum, pressure or pressure-vacuum methods, can be advantageous.
  • the amount of protective agent applied to wood chips is 0.5-2, preferably 0.8-1.2 kg / kg.
  • the material treated with the protective agent is then subsequently dried in air at normal or elevated temperatures.
  • the material treated according to the invention has excellent, long-term resistance to pests of all kinds, in particular to discoloring and destructive fungi (e.g. mold, blue stain, rot), against destructive insects (e.g. anobia, house goat, lyctus) and against bacteria.
  • the material treated according to the invention is also avoided by other vermin that otherwise nest in appropriate materials, e.g. Ants, mice, etc.
  • the effectiveness of the protective agent against pests is mainly due to its alkalinity.
  • the treated material has a significantly reduced flammability.
  • the whey constituents contained in the protective agent form an insulating carbon protective layer in the event of fire and, by splitting off non-flammable gases, develop an inert gas atmosphere which hinders the supply of oxygen.
  • the overall effect of the protective agent is essentially based on the interaction of the special material structure of the whey with the alkalinity caused by the saponification.
  • the effective components of the protective agent also penetrate into the materials to be protected and therefore achieve more than just superficial protection.
  • the protective agent according to the invention is preferably used for the treatment of wood, in particular in the construction field. It is particularly suitable for the treatment of solid wood and wood-based materials Protection of small-sized wood materials such as wood wool and especially wood chips. Small-scale wood products treated in this way can be used, for example, for insulation purposes, in particular for environmentally friendly and inexpensive heat insulation in the construction sector.
  • the protective agent according to the invention is also advantageously suitable for protecting organic materials other than wood, in particular in the construction sector.
  • the risk of pests or fire can be reduced for the following materials: for cellulose and cotton products, construction paper, cellulose or paper flakes, peat, cork, coconut, jute, wool, straw, reed, hay -, bark products and products made from pods and skins of fruit.
  • the protective agents can achieve an advantageous fire protection effect, e.g. for molded parts, films, tapes, chips, fibers, granules, powder and corresponding foams made of polyethylene, polypropylene and other polyolefins, also polystyrene and other styrene polymers, acrylates, rubbers, alkyd resins, formaldehyde resins, polyester resins etc.
  • the protective agents achieve positive effects such as reduced brittleness and reduced insect nesting.
  • the binding forces of the protective agent also reduce the formation and release of dusts.
  • the protective agent according to the invention also has a preserving action against metals. This will e.g. Iron or steel parts, such as fasteners, not only do not attack, but even protect against corrosion.
  • the protective agent according to the invention has the advantage of being simple, non-hazardous and inexpensive to produce from inexpensive raw materials that largely arise naturally. Residual or old materials treated with the protective agent can also be disposed of without major problems. This means that thermal recycling by combustion is possible without the creation of particularly polluting substances. Composting is also an option. If necessary, the disposal can be further facilitated by first eliminating the alkalinity of the protective agent by neutralization, preferably with non-environmentally relevant acids such as acetic acid, citric acid, etc.
  • Fresh whey is saponified by stirring with an aqueous base at 50 ° C.
  • the base is prepared beforehand by dissolving and / or suspending the corresponding basic substance in 50 ° C warm water.
  • the saponification is carried out in different versions with the proportions and bases given in the table below.
  • Example No. Whey parts by mass Water mass parts Base bulk parts pH of the end product 1 47 47 soda 6 10th 2nd 47 48 soda 2nd 8th NaHCO3 3rd 3rd 70 22 soda 4th 11.5 lime 4th 4th 70 24th soda 2nd 9.5 borax 4th 5 50 45 NaOH 2nd 11 Al (OH) 3 3rd 6 70 24th NaOH 1 10th borax 4th 7 50 49.5 NaOH 0.5 12th 8th 50 47 NaOH 3rd 13
  • Another part of the treated and dried shavings is briefly flamed with a Bunsen burner.
  • the one with the Shavings treated with different whey saponification products only smolder and extinguish themselves after the flame is removed.
  • a comparison sample made from untreated shavings immediately catches fire with the same flame treatment and then burns completely.
  • Example 4 70 parts by mass of the whey saponification product prepared according to Example 4 are mixed with 30 parts by mass of a paraffinic wax emulsion. With the mixture, wood chips are treated on all sides and dried. The chips thus prepared are artificially irrigated for three hours and then dried to a moisture content of 30%. Storage and fire tests are then carried out with the chips as in Examples 1 to 8. The chips show no fungal attack during storage and flame retardancy during fire testing.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Seeds, Soups, And Other Foods (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Mattresses And Other Support Structures For Chairs And Beds (AREA)

Claims (9)

  1. Utilisation de petit-lait, dilué avec la même quantité d'eau, saponifié de préférence avec des bases ou avec des substances ayant des propriétés basiques, comme insecticide ou comme protection contre le feu pour le bois ou pour autres matériaux organiques.
  2. Utilisation de petit-lait suivant la revendication 1 caractérisée en ce que les substances saponifiantes ont été soude caustique, potasse, carbonate de sodium, carbonate de potassium, hydroxyde de calcium (chaux éteinte, lait de chaux), carbonate de calcium (pierre à chaux), phosphate de sodium ou borax, ainsi que leurs mélanges.
  3. Utilisation de petit-lait suivant l'une des revendications précédentes, caractérisée en ce que la saponification a été effectuée avec un excès de bases, ainsi que le cas échéant avec chauffage.
  4. Utilisation de petit-lait suivant l'une des revendications précédentes, caractérisée en ce que la quantité de base ou de substances ayant des réactions basiques, ajoutée, a été choisie telle que le pH résultant soit entre 7.5 et 14, de préférence entre 8 et 13 et plus précisément entre 9 et 12.
  5. Utilisation de petit-lait suivant l'une des revendications précédentes, caractérisée en ce que l'on ajoute au petit-lait d'autres substances comme des pesticides ou des substances qui protègent contre le feu sous forme dissoute, émulsionnée ou suspendue, de préférence des sels de bore, des composés d'ammonium, des amines, des résines aminoplastiques, des sucres, des fécules, des polyols, des phosphates, des silicates ou des carbonates, ainsi que des fongicides ou des insecticides organiques ou inorganiques.
  6. Utilisation de petit-lait suivant l'une des revendications précédentes, caractérisée en ce que l'on ajoute au petit-lait saponifié des substances rendant le mélange hydrophobe, comme les cires ou les silicones et/ou des substances agglutinantes comme des résines d'alkyle, des résines acryliques, des résines de vinyle ou des huiles siccatives et/ou des colorants comme le carotène et/ou des pigments comme les couleurs de terre.
  7. Utilisation de petit-lait suivant l'une des revendications précédentes pour le traitement de bois ou des matériaux en bois, de préférence des morceaux de bois de petite taille, comme de la laine de bois et surtout des copeaux de bois, particulièrement des matériaux isolants dans le domaine de la construction.
  8. Utilisation de petit-lait suivant l'une ou plusieurs des revendications précédentes pour le traitement des produits de cellulose et de coton, des papiers de construction, des flocons de pâte de bois ou de papier, des produits de tourbe, de liège, de coco, de jute, de laine, de paille, de roseau, de foin, et d'écorce, ainsi que des produits des cosses et des peaux de fruits, de préférence comme matériau d'isolation dans le domaine de la construction.
  9. Utilisation de petit-lait suivant l'une ou plusieurs des revendications précédentes pour le traitement des produits synthétiques organiques comme les moules, les feuilles, les rubans, les rognures, les filaments, les granules, les poudres et les mousses correspondantes de polyéthylène, de polypropylène et d'autres polyoléfines, de plus le polystyrène et autres styrolpolymérisats, les acrylates, des caoutchoucs, des résines d'alkyle, de formaldéhyde et les résines de polyester.
EP93109822A 1992-07-01 1993-06-19 Agent pesticide et retardateur de feu pour le bois et d'autres matières organiques Expired - Lifetime EP0576940B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4221624 1992-07-01
DE4221624A DE4221624C1 (fr) 1992-07-01 1992-07-01

Publications (2)

Publication Number Publication Date
EP0576940A1 EP0576940A1 (fr) 1994-01-05
EP0576940B1 true EP0576940B1 (fr) 1996-01-24

Family

ID=6462257

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93109822A Expired - Lifetime EP0576940B1 (fr) 1992-07-01 1993-06-19 Agent pesticide et retardateur de feu pour le bois et d'autres matières organiques

Country Status (9)

Country Link
US (1) US5476686A (fr)
EP (1) EP0576940B1 (fr)
JP (1) JP3378051B2 (fr)
AT (1) ATE133365T1 (fr)
DE (2) DE4221624C1 (fr)
DK (1) DK0576940T3 (fr)
ES (1) ES2083226T3 (fr)
FI (1) FI932994A (fr)
NO (1) NO301265B1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19853496C1 (de) * 1998-11-19 2000-08-03 Hubert Fritz Verfahren und Vorrichtung zur Herstellung von Spänen
KR20030082698A (ko) * 2002-04-18 2003-10-23 표옥근 가공 목재의 방부 및 염색 방법
CN100588687C (zh) * 2002-07-19 2010-02-10 佛蒙特大学及州农业学院 木质涂饰剂及其生产方法
DE102007048422A1 (de) * 2007-10-09 2009-04-16 Homatherm Ag Holzfaser-Wärmedämmmaterial und Verfahren für dessen Herstellung
DE102011055188A1 (de) * 2011-11-09 2013-05-16 Volker Fritz Wässrige Lösung
CN110523023A (zh) * 2019-07-18 2019-12-03 山东农业大学 一种降低森林抚育采伐剩余物燃烧性的方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB130981A (en) * 1918-08-03 1920-05-06 Claude Roy Process and Apparatus for Rendering Wood Impermeable and Recovering Liquids Contained therein.
GB455533A (en) * 1935-11-08 1936-10-22 Gideon Scott May Means for preserving, waterproofing, and fireproofing stone, brick, wood and like work
US2904437A (en) * 1954-06-01 1959-09-15 Wilson & Co Inc Treating whey
US3616386A (en) * 1969-08-08 1971-10-26 Purity Electrochemical Co Electrodialytic demineralization of whey using neutral membranes
BE791350A (nl) * 1971-11-15 1973-05-14 Stichting Bedrijven Van Het Werkwijze voor de bereiding van een melkeiwit-coprecipitaat
US3864506A (en) * 1974-03-20 1975-02-04 Stauffer Chemical Co Process For Pretreating Raw Cheese Whey
US4076800A (en) * 1975-01-13 1978-02-28 The Procter & Gamble Company Protein-containing detergent compositions for protecting keratinous materials
US4064283A (en) * 1976-06-14 1977-12-20 The United States Of America As Represented By The Secretary Of Agriculture Preparation of protein concentrates from whey and seed products
FR2391653A1 (fr) * 1977-05-23 1978-12-22 Nestle Sa Soc Ass Tech Prod Procede de traitement du lactoserum
US4225629A (en) * 1977-08-15 1980-09-30 The United States Of America As Represented By The Secretary Of Agriculture Preparation of protein concentrates from whey and seed products
US4227981A (en) * 1979-08-31 1980-10-14 Borden, Inc. Electrodialysis of acid whey
AU552141B2 (en) * 1980-11-25 1986-05-22 Unilever Plc Coluble protein product from whey
US4444792A (en) * 1981-07-20 1984-04-24 Stauffer Chemical Company Fermentation of whey to produce a thickening polymer
US5098472A (en) * 1983-06-17 1992-03-24 Commonwealth Scientific & Industrial Research Organization Preservative composition
DE3518188C1 (de) * 1985-05-21 1986-10-23 Meinhardt, Horst, 5419 Herschbach Milchsaure Tonerde sowie ein Verfahren zur Herstellung derselben und deren Verwendung
US5078912A (en) * 1985-06-07 1992-01-07 Dr. Wolman Gmbh Wood preservative
DE3522655A1 (de) * 1985-06-25 1987-01-08 Vft Verkaufsges Teer Holzschuetzendes impraegnieroel und seine verwendung
US4956177A (en) * 1985-11-04 1990-09-11 Microlife Technics, Inc. Method for inhibiting fungi
US4786326A (en) * 1986-11-12 1988-11-22 Mooney Chemicals, Inc. Process for penetrating difficult-to-treat wood with wood preservative liquids
SE459140B (sv) * 1986-11-25 1989-06-12 Albuglobe Ab Hydrolys av vassleprotein foer att underlaetta avskiljning av fett daerifraan
EP0291980B1 (fr) * 1987-05-20 1992-01-02 Chugai Seiyaku Kabushiki Kaisha Substitut du sel et denrées alimentaires contenant la même
US4950329A (en) * 1988-10-11 1990-08-21 Hickson Corporation Wood preservative composition and method of treating wood with same
US4973488A (en) * 1989-05-17 1990-11-27 Excelpro, Inc. Hydrolyzed proteinaceous milk solid and process of making
US4988545A (en) * 1989-08-17 1991-01-29 Board Of Control Of Michigan Technological University Method for treating wood against fungal attack

Also Published As

Publication number Publication date
US5476686A (en) 1995-12-19
JP3378051B2 (ja) 2003-02-17
DE4221624C1 (fr) 1993-07-15
EP0576940A1 (fr) 1994-01-05
NO301265B1 (no) 1997-10-06
FI932994A0 (fi) 1993-06-29
FI932994A (fi) 1994-01-02
ES2083226T3 (es) 1996-04-01
DK0576940T3 (da) 1996-03-18
ATE133365T1 (de) 1996-02-15
JPH06206207A (ja) 1994-07-26
DE59301493D1 (de) 1996-03-07
NO932268L (no) 1994-01-03
NO932268D0 (no) 1993-06-21

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