EP0576940B1 - Pesticidal and fireproofing agent for wood and other organic materials - Google Patents
Pesticidal and fireproofing agent for wood and other organic materials Download PDFInfo
- Publication number
- EP0576940B1 EP0576940B1 EP93109822A EP93109822A EP0576940B1 EP 0576940 B1 EP0576940 B1 EP 0576940B1 EP 93109822 A EP93109822 A EP 93109822A EP 93109822 A EP93109822 A EP 93109822A EP 0576940 B1 EP0576940 B1 EP 0576940B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- whey
- wood
- resins
- products
- whey according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002023 wood Substances 0.000 title claims abstract description 27
- 239000011368 organic material Substances 0.000 title claims description 7
- 239000003795 chemical substances by application Substances 0.000 title claims 4
- 230000000361 pesticidal effect Effects 0.000 title claims 2
- 238000004079 fireproofing Methods 0.000 title 1
- 239000005862 Whey Substances 0.000 claims abstract description 33
- 102000007544 Whey Proteins Human genes 0.000 claims abstract description 33
- 108010046377 Whey Proteins Proteins 0.000 claims abstract description 33
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 21
- 238000007127 saponification reaction Methods 0.000 claims abstract description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 13
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000003513 alkali Substances 0.000 claims abstract description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 3
- 239000011810 insulating material Substances 0.000 claims abstract 3
- 239000000463 material Substances 0.000 claims description 20
- 239000000126 substance Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 238000010276 construction Methods 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- 210000002268 wool Anatomy 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 229920000180 alkyd Polymers 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 4
- 239000000920 calcium hydroxide Substances 0.000 claims description 4
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 3
- 244000060011 Cocos nucifera Species 0.000 claims description 3
- 235000011777 Corchorus aestuans Nutrition 0.000 claims description 3
- 240000000491 Corchorus aestuans Species 0.000 claims description 3
- 235000010862 Corchorus capsularis Nutrition 0.000 claims description 3
- 235000014676 Phragmites communis Nutrition 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000007799 cork Substances 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000005871 repellent Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- 239000010902 straw Substances 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 2
- 235000019738 Limestone Nutrition 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000003868 ammonium compounds Chemical class 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims description 2
- 150000001638 boron Chemical class 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 150000001746 carotenes Chemical class 0.000 claims description 2
- 235000005473 carotenes Nutrition 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims description 2
- 239000006028 limestone Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- 239000003415 peat Substances 0.000 claims description 2
- 239000000575 pesticide Substances 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229940072033 potash Drugs 0.000 claims description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- 235000011181 potassium carbonates Nutrition 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 235000000346 sugar Nutrition 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims 1
- 239000004925 Acrylic resin Substances 0.000 claims 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 1
- 229920001131 Pulp (paper) Polymers 0.000 claims 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 claims 1
- 229920001821 foam rubber Polymers 0.000 claims 1
- 239000010903 husk Substances 0.000 claims 1
- 229920001195 polyisoprene Polymers 0.000 claims 1
- 235000011118 potassium hydroxide Nutrition 0.000 claims 1
- 239000008107 starch Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000009435 building construction Methods 0.000 abstract 1
- 239000003223 protective agent Substances 0.000 description 27
- 239000000047 product Substances 0.000 description 13
- 239000002585 base Substances 0.000 description 9
- 241000607479 Yersinia pestis Species 0.000 description 7
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- 241000257303 Hymenoptera Species 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000001066 destructive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011814 protection agent Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010017533 Fungal infection Diseases 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- UPYKUZBSLRQECL-UKMVMLAPSA-N Lycopene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1C(=C)CCCC1(C)C)C=CC=C(/C)C=CC2C(=C)CCCC2(C)C UPYKUZBSLRQECL-UKMVMLAPSA-N 0.000 description 1
- 241001177134 Lyctus Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 229910000831 Steel Chemical group 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
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- 239000000975 dye Substances 0.000 description 1
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- 238000000855 fermentation Methods 0.000 description 1
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- 239000007789 gas Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229940108461 rennet Drugs 0.000 description 1
- 108010058314 rennet Proteins 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Chemical group 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- NCYCYZXNIZJOKI-UHFFFAOYSA-N vitamin A aldehyde Natural products O=CC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C NCYCYZXNIZJOKI-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/20—Compounds of alkali metals or ammonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/36—Aliphatic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/02—Staining or dyeing wood; Bleaching wood
Definitions
- the invention relates to the use of a pest and fire protection agent for wood and other organic materials.
- Protective agents for wood and other organic materials are primarily intended to protect them from pests, in particular from fungi, destructive insects and bacteria. In addition, the protective agents also have to reduce the flammability of wood in many cases.
- protective effects should, if possible, be achieved by the protective means without endangering humans and farm animals or the environment. Furthermore, protective agents should be environmentally friendly and inexpensive to manufacture.
- the invention has set itself the task of creating a protective agent that optimally fulfills the aforementioned conditions.
- whey which is preferably saponified by dilution with approximately the same amount of water, with bases or substances with a basic action, as pesticides and fire protection agents for wood and other organic materials.
- DE-C-35 18 188 describes a process for producing lactic acid clay, the clay having obtained its lactic acid properties by slurrying with fermentation whey.
- the alumina thus created is used as an antiseptic, bactericide and / or bacteriostat.
- the invention proposes a new use of a whey treated in this way.
- Whey is produced in comparatively large quantities as a cheap by-product when processing milk. If fat and casein are excreted from the milk by acidification or rennet, the whey remains, which, among other things, still contains about 0.9 g protein, 0.3 g fat and 4.5 g lactose per 100 g.
- This whey is saponified basic for the preparation of protective agents according to the invention, preferably with dilution with approximately the same amount of water. Fresh whey or the appropriate amount of whey powder dissolved in water can be used for the saponification.
- the basic saponification of the whey can preferably be carried out using alkali solutions such as sodium hydroxide solution or potassium hydroxide solution.
- the saponification is generally carried out by mixing the reaction components dissolved or suspended in water in stoichiometric or non-stoichiometric proportions, preferably with an excess of base, and optionally with heating.
- the saponification extends not only to the residual fat content in the whey, but also to the remaining components.
- the amount of base or basic reacting substances added is chosen so that a pH value of 7.5 to 14, preferably 8 to 13, in particular 9 to 12 results in the saponification product.
- pest and fire-retardant substances in dissolved, emulsified or suspended form can be added to the protective agent, for example boron salts, ammonium compounds, amines, aminoplast resins, sugars, starches, polyols, phosphates, silicates or carbonates and also organic ones and inorganic fungicides and insecticides.
- the protective agent in dissolved, emulsified or suspended form, e.g. B. water repellents such as waxes or silicones, binders such as alkyd, acrylate, vinyl resins or drying oils.
- B. water repellents such as waxes or silicones
- binders such as alkyd, acrylate, vinyl resins or drying oils.
- dyes e.g. Carotene, or pigments, e.g. Earth colors
- the materials to be protected are treated with the protective agent according to the invention by brushing, spraying, pouring, flooding, dipping or soaking.
- the protective effect the surface treatment of the materials to be protected with the protective agent is sufficient.
- the partial or complete impregnation of the material for example by using vacuum, pressure or pressure-vacuum methods, can be advantageous.
- the amount of protective agent applied to wood chips is 0.5-2, preferably 0.8-1.2 kg / kg.
- the material treated with the protective agent is then subsequently dried in air at normal or elevated temperatures.
- the material treated according to the invention has excellent, long-term resistance to pests of all kinds, in particular to discoloring and destructive fungi (e.g. mold, blue stain, rot), against destructive insects (e.g. anobia, house goat, lyctus) and against bacteria.
- the material treated according to the invention is also avoided by other vermin that otherwise nest in appropriate materials, e.g. Ants, mice, etc.
- the effectiveness of the protective agent against pests is mainly due to its alkalinity.
- the treated material has a significantly reduced flammability.
- the whey constituents contained in the protective agent form an insulating carbon protective layer in the event of fire and, by splitting off non-flammable gases, develop an inert gas atmosphere which hinders the supply of oxygen.
- the overall effect of the protective agent is essentially based on the interaction of the special material structure of the whey with the alkalinity caused by the saponification.
- the effective components of the protective agent also penetrate into the materials to be protected and therefore achieve more than just superficial protection.
- the protective agent according to the invention is preferably used for the treatment of wood, in particular in the construction field. It is particularly suitable for the treatment of solid wood and wood-based materials Protection of small-sized wood materials such as wood wool and especially wood chips. Small-scale wood products treated in this way can be used, for example, for insulation purposes, in particular for environmentally friendly and inexpensive heat insulation in the construction sector.
- the protective agent according to the invention is also advantageously suitable for protecting organic materials other than wood, in particular in the construction sector.
- the risk of pests or fire can be reduced for the following materials: for cellulose and cotton products, construction paper, cellulose or paper flakes, peat, cork, coconut, jute, wool, straw, reed, hay -, bark products and products made from pods and skins of fruit.
- the protective agents can achieve an advantageous fire protection effect, e.g. for molded parts, films, tapes, chips, fibers, granules, powder and corresponding foams made of polyethylene, polypropylene and other polyolefins, also polystyrene and other styrene polymers, acrylates, rubbers, alkyd resins, formaldehyde resins, polyester resins etc.
- the protective agents achieve positive effects such as reduced brittleness and reduced insect nesting.
- the binding forces of the protective agent also reduce the formation and release of dusts.
- the protective agent according to the invention also has a preserving action against metals. This will e.g. Iron or steel parts, such as fasteners, not only do not attack, but even protect against corrosion.
- the protective agent according to the invention has the advantage of being simple, non-hazardous and inexpensive to produce from inexpensive raw materials that largely arise naturally. Residual or old materials treated with the protective agent can also be disposed of without major problems. This means that thermal recycling by combustion is possible without the creation of particularly polluting substances. Composting is also an option. If necessary, the disposal can be further facilitated by first eliminating the alkalinity of the protective agent by neutralization, preferably with non-environmentally relevant acids such as acetic acid, citric acid, etc.
- Fresh whey is saponified by stirring with an aqueous base at 50 ° C.
- the base is prepared beforehand by dissolving and / or suspending the corresponding basic substance in 50 ° C warm water.
- the saponification is carried out in different versions with the proportions and bases given in the table below.
- Example No. Whey parts by mass Water mass parts Base bulk parts pH of the end product 1 47 47 soda 6 10th 2nd 47 48 soda 2nd 8th NaHCO3 3rd 3rd 70 22 soda 4th 11.5 lime 4th 4th 70 24th soda 2nd 9.5 borax 4th 5 50 45 NaOH 2nd 11 Al (OH) 3 3rd 6 70 24th NaOH 1 10th borax 4th 7 50 49.5 NaOH 0.5 12th 8th 50 47 NaOH 3rd 13
- Another part of the treated and dried shavings is briefly flamed with a Bunsen burner.
- the one with the Shavings treated with different whey saponification products only smolder and extinguish themselves after the flame is removed.
- a comparison sample made from untreated shavings immediately catches fire with the same flame treatment and then burns completely.
- Example 4 70 parts by mass of the whey saponification product prepared according to Example 4 are mixed with 30 parts by mass of a paraffinic wax emulsion. With the mixture, wood chips are treated on all sides and dried. The chips thus prepared are artificially irrigated for three hours and then dried to a moisture content of 30%. Storage and fire tests are then carried out with the chips as in Examples 1 to 8. The chips show no fungal attack during storage and flame retardancy during fire testing.
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Abstract
Description
Die Erfindung betrifft die Verwendung eines Schädlings- und Brandschutzmittels für Holz und andere organische Materialien.The invention relates to the use of a pest and fire protection agent for wood and other organic materials.
Schutzmittel für Holz und andere organische Materialien sollen diese vor allem vor Schädlingen schützen, insbesondere vor Pilzen, zerstörenden Insekten und Bakterien. Daneben müssen die Schutzmittel in vielen Fällen auch die Brennbarkeit von Holz herabsetzen.Protective agents for wood and other organic materials are primarily intended to protect them from pests, in particular from fungi, destructive insects and bacteria. In addition, the protective agents also have to reduce the flammability of wood in many cases.
Diese Schutzwirkungen sollen durch die Schutzmittel nach Möglichkeit erzielt werden, ohne daß Menschen und Nutztiere oder die Umwelt gefährdet werden. Ferner sollen Schutzmittel umweltschonend und billig herstellbar sein.These protective effects should, if possible, be achieved by the protective means without endangering humans and farm animals or the environment. Furthermore, protective agents should be environmentally friendly and inexpensive to manufacture.
Weitere Forderungen an die Schutzmittel sind einfache und ungefährliche Aufbringungsmöglichkeiten auf die zu schützenden Materialien sowie problemlose Entsorgungsmöglichkeiten für Reststoffe und behandelte Altstoffe.Further requirements for the protective agents are simple and harmless application options to the materials to be protected, as well as problem-free disposal options for residual and treated waste.
Die Erfindung hat es sich zur Aufgabe gemacht, ein Schutzmittel zu schaffen das die vorerwähnten Bedingungen möglichst optimal erfüllt.The invention has set itself the task of creating a protective agent that optimally fulfills the aforementioned conditions.
Zur Lösung dieser Aufgabe wird die Verwendung von Molke vorgeschlagen, die vorzugsweise unter Verdünnen mit etwa der gleichen Menge Wasser, mit Basen oder basisch wirkenden Stoffen verseift ist, als Schädlings- und Brandschutzmittel für Holz und andere organische Materialien.To solve this problem, the use of whey is proposed, which is preferably saponified by dilution with approximately the same amount of water, with bases or substances with a basic action, as pesticides and fire protection agents for wood and other organic materials.
In der DE-C-35 18 188 wird ein Verfahren zur Herstellung von milchsaurer Tonerde beschrieben, wobei die Tonerde durch Aufschlämmung mit Gärungsmolke ihre milchsauren Eigenschaften erlangt hat. Die so geschaffene Tonerde wird dabei als Antiseptikum, Bakterizid und/oder Bakteriostatikum verwendet. Durch die Erfindung wird eine neue Verwendung einer so behandelten Molke vorgeschlagen.DE-C-35 18 188 describes a process for producing lactic acid clay, the clay having obtained its lactic acid properties by slurrying with fermentation whey. The alumina thus created is used as an antiseptic, bactericide and / or bacteriostat. The invention proposes a new use of a whey treated in this way.
Molke fällt in vergleichsweise großen Mengen als billiges Nebenprodukt bei der Verarbeitung von Milch an. Wenn dabei aus der Milch Fett und Casein durch Säuerung oder Lab ausgeschieden ist, verbleibt die Molke, die unter anderem je 100 g noch etwa 0,9 g Eiweiß, 0,3 g Fett und 4,5 g Lactose enthält. Diese Molke wird zur erfindungsgemäßen Herstellung von Schutzmittel basisch verseift, vorzugsweise unter Verdünnung mit etwa der gleichen Menge Wasser. Für die Verseifung kann Frischmolke oder in der entsprechenden Menge in Wasser aufgelöstes Molkepulver eingesetzt werden. Die basische Verseifung der Molke kann vorzugsweise mit Alkalilaugen wie Natronlauge oder Kalilauge erfolgen. Es ist aber auch möglich, andere Basen oder basisch wirkende Stoffe zu verwenden, zum Beispiel Natriumcarbonat (Soda), Kaliumcarbonat (Pottasche), Calciumhydroxid (gelöschter Kalk, Kalkmilch), Calciumcarbonat (Kalkstein), Aluminiumhydroxid, Natriumphosphat oder Borax. Ferner ist es auch möglich, Mischungen unterschiedlicher Basen, zum Beispiel von Soda und Kalk, einzusetzen.Whey is produced in comparatively large quantities as a cheap by-product when processing milk. If fat and casein are excreted from the milk by acidification or rennet, the whey remains, which, among other things, still contains about 0.9 g protein, 0.3 g fat and 4.5 g lactose per 100 g. This whey is saponified basic for the preparation of protective agents according to the invention, preferably with dilution with approximately the same amount of water. Fresh whey or the appropriate amount of whey powder dissolved in water can be used for the saponification. The basic saponification of the whey can preferably be carried out using alkali solutions such as sodium hydroxide solution or potassium hydroxide solution. But it is also possible to use other bases or those with a basic effect Use substances such as sodium carbonate (soda), potassium carbonate (potash), calcium hydroxide (hydrated lime, lime milk), calcium carbonate (limestone), aluminum hydroxide, sodium phosphate or borax. It is also possible to use mixtures of different bases, for example soda and lime.
Die Durchführung der Verseifung erfolgt in der Regel durch Vermischen der in Wasser gelösten oder suspendierten Reaktionskomponenten in stöchiometrischen oder nicht stöchiometrischen Mengenverhältnissen, vorzugsweise mit Basenüberschuß, sowie gegebenenfalls unter Erhitzen. Die Verseifung erstreckt sich nicht nur auf den Restfettanteil in der Molke, sondern auch auf deren übrigen Bestandteile. Die Menge an zugegebener Base bzw. basisch reagierenden Stoffen wird so gewählt, daß sich im Verseifungsprodukt ein pH-Wert von 7,5 bis 14, vorzugsweise 8 bis 13, insbesondere 9 bis 12 ergibt.
Dem erfindungsgemäßen Schutzmittel können zur Abrundung des Eigenschaftsbildes oder Erzielung spezieller Zusatzeigenschaften andere schädlings- und brandhemmende Stoffe in gelöster, emulgierter oder suspendierter Form beigemischt werden, z.B. Borsalze, Ammoniumverbindungen, Amine, Aminoplastharze, Zucker, Stärke, Polyole, Phosphate, Silikate oder Carbonate sowie organische und anorganische Fungizide und Insektizide.The saponification is generally carried out by mixing the reaction components dissolved or suspended in water in stoichiometric or non-stoichiometric proportions, preferably with an excess of base, and optionally with heating. The saponification extends not only to the residual fat content in the whey, but also to the remaining components. The amount of base or basic reacting substances added is chosen so that a pH value of 7.5 to 14, preferably 8 to 13, in particular 9 to 12 results in the saponification product.
To round off the property profile or to achieve special additional properties, other pest and fire-retardant substances in dissolved, emulsified or suspended form can be added to the protective agent, for example boron salts, ammonium compounds, amines, aminoplast resins, sugars, starches, polyols, phosphates, silicates or carbonates and also organic ones and inorganic fungicides and insecticides.
Für spezielle Anwendungen kann es vorteilhaft sein, dem Schutzmittel weitere Zusatzstoffe in gelöster, emulgierter oder suspendierter Form beizumischen, z. B. Hydrophobierungsmittel wie Wachse oder Silikone, ferner Bindemittel wie Alkyd-, Acrylat-, Vinylharze oder trocknende Öle. Dadurch kann die Auswaschbeständigkeit des Schutzmittels verbessert und die Feuchtigkeitsaufnahme des mit dem Schutzmittel behandelten Materials verringert werden. Schließlich kann es auch vorteilhaft sein, dem Schutzmittel Farbstoffe, z.B. Karotin, oder Pigmente, z.B. Erdfarben, beizumengen, um dadurch eine Kennzeichnung der behandelten Materialien, eine dekorative Gestaltung oder einen verbesserten Lichtschutz zu erreichen.For special applications it may be advantageous to add additional additives to the protective agent in dissolved, emulsified or suspended form, e.g. B. water repellents such as waxes or silicones, binders such as alkyd, acrylate, vinyl resins or drying oils. As a result, the washout resistance of the protective agent can be improved and the moisture absorption of the material treated with the protective agent can be reduced. Finally, it may also be advantageous to add dyes, e.g. Carotene, or pigments, e.g. Earth colors, to be added in order to achieve a marking of the treated materials, a decorative design or an improved light protection.
Die Behandlung der zu schützenden Materialien mit dem erfindungsgemäßen Schutzmittel erfolgt durch Streichen, Sprühen, Gießen, Fluten, Tauchen oder Tränken. Im allgemeinen ist für die Schutzwirkung die oberflächliche Behandlung der zu schützenden Materialien mit dem Schutzmittel ausreichend. In besonderen Fällen kann die teilweise oder vollständige Durchtränkung des Materials, z.B. durch Anwendung von Vakuum-, Druck- oder Druck-Vakuum-Verfahren vorteilhaft sein. Die Aufbringmenge des Schutzmittels beträgt bei Holzspänen 0,5 - 2, vorzugsweise 0,8 - 1,2 kg/kg. Das mit dem Schutzmittel behandelte Material wird in der Regel anschließend an der Luft bei normaler oder erhöhter Temperatur getrocknet.The materials to be protected are treated with the protective agent according to the invention by brushing, spraying, pouring, flooding, dipping or soaking. In general, is for the protective effect the surface treatment of the materials to be protected with the protective agent is sufficient. In special cases, the partial or complete impregnation of the material, for example by using vacuum, pressure or pressure-vacuum methods, can be advantageous. The amount of protective agent applied to wood chips is 0.5-2, preferably 0.8-1.2 kg / kg. The material treated with the protective agent is then subsequently dried in air at normal or elevated temperatures.
Das erfindungsgemäß behandelte Material besitzt eine hervorragende, anhaltende Beständigkeit gegen Schädlinge aller Art, insbesondere gegen verfärbende und zerstörende Pilze (z.B. Schimmel-, Bläue-, Fäulnispilze), gegen zerstörende Insekten (z.B. Anobien, Hausbock, Lyctus) sowie gegen Bakterien. Das erfindungsgemäß behandelte Material wird auch von anderem Ungeziefer gemieden, das sich sonst in entsprechenden Materialien einnistet, z.B. Ameisen, Mäusen usw. Die Wirksamkeit des Schutzmittels gegenüber Schädlingen beruht hauptsächlich auf seiner Alkalität. Daneben besitzt das behandelte Material eine deutlich verringerte Brennbarkeit. Diese kommt offensichtlich im wesentlichen dadurch zustande, daß die im Schutzmittel enthaltenen Molkebestandteile im Brandfalle eine isolierende Kohleschutzschicht bilden sowie durch Abspaltung unbrennbarer Gase gleichsam eine Schutzgas-Atmosphäre entwickeln, die die Sauerstoffzufuhr behindert. Die Gesamtwirkung des Schutzmittels beruht im wesentlichen auf dem Zusammenspiel des besonderen stofflichen Aufbaus der Molke mit der durch die Verseifung bewirkten Alkalität. Die wirksamen Bestandteile des Schutzmittels dringen auch in die zu schützenden Materialien ein und erzielen deswegen einen mehr als nur oberflächlichen Schutz.The material treated according to the invention has excellent, long-term resistance to pests of all kinds, in particular to discoloring and destructive fungi (e.g. mold, blue stain, rot), against destructive insects (e.g. anobia, house goat, lyctus) and against bacteria. The material treated according to the invention is also avoided by other vermin that otherwise nest in appropriate materials, e.g. Ants, mice, etc. The effectiveness of the protective agent against pests is mainly due to its alkalinity. In addition, the treated material has a significantly reduced flammability. This obviously comes about essentially because the whey constituents contained in the protective agent form an insulating carbon protective layer in the event of fire and, by splitting off non-flammable gases, develop an inert gas atmosphere which hinders the supply of oxygen. The overall effect of the protective agent is essentially based on the interaction of the special material structure of the whey with the alkalinity caused by the saponification. The effective components of the protective agent also penetrate into the materials to be protected and therefore achieve more than just superficial protection.
Das erfindungsgemäße Schutzmittel wird vorzugsweise zur Behandlung von Holz, insbesondere auf dem Baugebiet, benutzt. Es eignet sich außer zur Behandlung von Massivholz und Holzwerkstoffen vorzugszum Schutz von kleinteiligen Holzmaterialien wie Holzwolle und insbesondere Holzspänen. Derartig behandelte kleinteiligen Holzerzeugnisse können beispielsweise für Isolierzwecke eingesetzt werden, insbesondere zur umweltfreundlichen und kostengünstigen Wärmeisolierung im Baubereich.The protective agent according to the invention is preferably used for the treatment of wood, in particular in the construction field. It is particularly suitable for the treatment of solid wood and wood-based materials Protection of small-sized wood materials such as wood wool and especially wood chips. Small-scale wood products treated in this way can be used, for example, for insulation purposes, in particular for environmentally friendly and inexpensive heat insulation in the construction sector.
Das erfindungsgemäße Schutzmittel eignet sich auch vorteilhaft zum Schutz anderer organischer Materialien als Holz, insbesondere im Baubereich. Beispielsweise kann damit die Gefährdung durch Schädlinge oder Feuer bei folgenden Materialien verringert werden: bei Cellulose und Baumwolleprodukten, Baupapieren, Zellstoff- bzw. Papierflocken, Torf-, Kork-, Kokos-, Jute-, Wolle-, Stroh-, Schilf-, Heu-, Rindenprodukten sowie Erzeugnissen aus Hülsen und Schalen von Früchten.The protective agent according to the invention is also advantageously suitable for protecting organic materials other than wood, in particular in the construction sector. For example, the risk of pests or fire can be reduced for the following materials: for cellulose and cotton products, construction paper, cellulose or paper flakes, peat, cork, coconut, jute, wool, straw, reed, hay -, bark products and products made from pods and skins of fruit.
Auch bei synthetischen organischen Produkten wie Kunststoffmaterialien kann durch die Schutzmittel insbesondere eine vorteilhafte Brandschutzwirkung erzielt werden, z.B. bei Formteilen, Folien, Bändern, Schnitzeln, Fasern, Granulat, Pulver und entsprechenden Schaumstoffen aus Polyethylen, Polypropylen und anderen Polyolefinen, ferner Polystyrol und anderen Styrolpolymerisaten, Acrylaten, Kautschuken, Alkydharzen, Formaldehydharzen, Polyesterharzen usw.Even with synthetic organic products such as plastic materials, the protective agents can achieve an advantageous fire protection effect, e.g. for molded parts, films, tapes, chips, fibers, granules, powder and corresponding foams made of polyethylene, polypropylene and other polyolefins, also polystyrene and other styrene polymers, acrylates, rubbers, alkyd resins, formaldehyde resins, polyester resins etc.
Selbst bei bestimmten anorganischen Materialien wie künstlichen Mineralfasern werden mit den Schutzmitteln positive Wirkungen erzielt wie verringerte Brüchigkeit und reduzierte Einnistung von Ungeziefer.Even with certain inorganic materials such as artificial mineral fibers, the protective agents achieve positive effects such as reduced brittleness and reduced insect nesting.
Bei allen genannten Materialien wird durch die bindenden Kräfte des Schutzmittels auch die Bildung und das Freiwerden von Stäuben vermindert.In all the materials mentioned, the binding forces of the protective agent also reduce the formation and release of dusts.
Das Schutzmittel gemäß der Erfindung besitzt aufgrund seiner Alkalität auch eine konservierende Wirkung gegenüber Metallen. Dadurch werden z.B. Eisen- oder Stahlteile, etwa Befestigungsmittel, nicht nur nicht angegriffen, sondern sogar gegen Korrosion geschützt.Due to its alkalinity, the protective agent according to the invention also has a preserving action against metals. This will e.g. Iron or steel parts, such as fasteners, not only do not attack, but even protect against corrosion.
Neben der schädlings- und feuerabweisenden sowie staubbindenden und konservierenden Wirkung hat das erfindungsgemäße Schutzmittel den Vorteil der einfachen, ungefährlichen und billigen Herstellbarkeit aus großteils auf natürlichem Wege entstehenden, kostengünstigen Rohstoffen. Mit dem Schutzmittel behandelte Rest- oder Altstoffe lassen sich auch ohne große Probleme entsorgen. So ist die thermische Verwertung durch Verbrennung ohne Entstehung besonders umweltbelastender Stoffe möglich. Auch die Kompostierung kommt in Betracht. Gegebenenfalls kann die Entsorgung dadurch weiter erleichtert werden, daß zuvor die Alkalität des Schutzmittels durch Neutralisation vorzugsweise mit nicht umweltrelevanten Säuren wie Essigsäure, Citronensäure usw. beseitigt wird.In addition to the pest and fire-repellent as well as dust-binding and preserving action, the protective agent according to the invention has the advantage of being simple, non-hazardous and inexpensive to produce from inexpensive raw materials that largely arise naturally. Residual or old materials treated with the protective agent can also be disposed of without major problems. This means that thermal recycling by combustion is possible without the creation of particularly polluting substances. Composting is also an option. If necessary, the disposal can be further facilitated by first eliminating the alkalinity of the protective agent by neutralization, preferably with non-environmentally relevant acids such as acetic acid, citric acid, etc.
Frischmolke wird durch Verrühren mit einer wäßrigen Base bei 50 °C verseift. Die Base wird zuvor durch Auflösen und/oder Suspendieren des entsprechenden basischen Stoffes in 50 °C warmem Wasser zubereitet. Die Durchführung der Verseifung erfolgt jeweils in unterschiedlichen Ausführungen mit den in der folgenden Tabelle angegebenen Massenanteilen und Basen.
Mit den oben erhaltenen unterschiedlichen Molke-Verseifungsprodukten werden jeweils gesondert Holzspäne unter ständigem Umwälzen allseitig besprüht. Die Aufnahme der Späne an Molke-Verseifungsprodukt beträgt jeweils ca. 1 kg/kg.With the different whey saponification products obtained above, wood shavings are sprayed separately on all sides with constant agitation. The absorption of the chips on whey saponification product is approx. 1 kg / kg each.
Jeweils ein Teil der behandelten Späne wird auf einen Feuchtigkeitsgehalt von 30 % getrocknet und bei einer relativen Luftfeuchtigkeit von 80 % sowie einer Temperatur von 23 °C gelagert. An keinen der mit den unterschiedlichen Molke-Verseifungsprodukten behandelten Spänen tritt unter diesen Bedingungen im Verlauf von Wochen ein erkennbarer Pilzbefall auf. An einer Vergleichsprobe aus unbehandelten Spänen zeigt sich unter gleichen Bedingungen innerhalb von Tagen ein intensiver Befall unterschiedlicher Schimmelarten.In each case a part of the treated chips is dried to a moisture content of 30% and stored at a relative humidity of 80% and a temperature of 23 ° C. Under these conditions, no recognizable fungal infection occurs on any of the chips treated with the different whey saponification products over the course of weeks. A comparison sample of untreated chips shows an intensive infestation of different types of mold within days under the same conditions.
Jeweils ein anderer Teil der behandelten und getrockneten Späne wird kurzzeitig mit einem Bunsenbrenner beflammt. Die mit den unterschiedlichen Molke-Verseifungsprodukten behandelten Späne kommen jeweils lediglich zum Glimmen und erlöschen nach Entfernung der Flamme von selbst. Eine Vergleichsprobe aus unbehandelten Spänen fängt beim gleicher Beflammung sofort Feuer und verbrennt anschließend vollständig.Another part of the treated and dried shavings is briefly flamed with a Bunsen burner. The one with the Shavings treated with different whey saponification products only smolder and extinguish themselves after the flame is removed. A comparison sample made from untreated shavings immediately catches fire with the same flame treatment and then burns completely.
Werden die mit den unterschiedlichen Molke-Verseifungsprodukten behandelten Holzspäne in die Nähe von Ameisen gebracht, so werden die Späne von den Ameisen gemieden.If the wood chips treated with the different whey saponification products are brought close to ants, the chips are avoided by the ants.
Entsprechende Ergebnisse wie bei der oben beschriebenen Behandlung von Holzspänen werden erreicht, wenn mit den einzelnen Molke-Verseifungsprodukten jeweils andere organische Materialien wie Papierflocken, Kork-, Kokos-, Jute-, Wolle-, Stroh- oder Schilfmatten bzw. -schnitzel behandelt werden.Similar results as in the treatment of wood chips described above are achieved if the individual whey saponification products are used to treat other organic materials such as paper flakes, cork, coconut, jute, wool, straw or reed mats or chips.
70 Massenteile des gemäß Beispiel 4 hergestellten Molke-Verseifungsproduktes werden mit 30 Massenteilen einer paraffinischen Wachsemulsion vermischt. Mit der Mischung werden Holzspäne allseitig behandelt und getrocknet. Die so präparierten Späne werden drei Stunden lang künstlich beregnet und anschließend auf 30 % Feuchtigkeitsgehalt getrocknet. Mit den Spänen werden dann wie in den Beispielen 1 bis 8 Lagerungs- und Brandprüfungen durchgeführt Die Späne zeigen bei der Lagerung keinen Pilzbefall und bei der Brandprüfung Schwerentflammbarkeit.70 parts by mass of the whey saponification product prepared according to Example 4 are mixed with 30 parts by mass of a paraffinic wax emulsion. With the mixture, wood chips are treated on all sides and dried. The chips thus prepared are artificially irrigated for three hours and then dried to a moisture content of 30%. Storage and fire tests are then carried out with the chips as in Examples 1 to 8. The chips show no fungal attack during storage and flame retardancy during fire testing.
Claims (9)
- Use of whey, which has been saponified preferably by dilution with approximately the same quantity of water, alkali or alkaline acting substances, as a pesticide or fire-retardant agent for wood and other organic materials.
- Use of whey according to claim 1, characterized in that the agents employed for saponification are caustic soda, caustic potash solution, sodium carbonate (soda), potassium carbonate (potash), calcium hydroxide (caustic lime, slaked lime), calcium carbonate (limestone), sodium phosphate or borax as well as mixtures thereof.
- Use of whey according to one of the preceding claims, characterized in that saponification was effected by an excess of alkali and possibly by heating.
- Use of whey according to one of the preceding claims, characterized in that the quantity of alkali or alkaline reacting substances added has been chosen in such a way that a pH of 7,5 to 14, preferably 8 to 13, in particular 9 to 12 results.
- Use of whey according to one of the preceding claims, characterized in that other pesticidal or fire-retardant substances have been added in a dissolved, emulsified or suspended state, preferably boron salts, ammonium compounds, amines, aminoplastic resins, sugar, starch, polyols, phosphates, silicates or carbonates as well as organic and inorganic fungicides and insecticides.
- Use of whey according to one of the preceding claims, characterized in that the saponified whey has been mixed with water-repellent agents such as waxes or silicones and/or binding agents such as alkyd resins, acrylic resins, vinyl resins or drying oils and/or dyestuffs such as carotenes and/or pigments such as earth colours.
- Use of whey according to one of the preceding claims for the treatment of wood and derived timber products, preferably in the form of small-size wood materials such as wood wool and first of all wood chips, in particular as insulating material in the construction field.
- Use of whey according to one or more of the preceding claims for the treatment of cellulose and cotton products, building papers, woodpulp flakes or paper flakes, peat, cork, coconut, jute, wool, straw, reed, hay and bark products as well as products from skins, hulls and husks of fruit, preferably as insulating material in the construction field.
- Use of whey according to one or more of the preceding claims for the treatment of synthetic organic products such as form parts, sheets, tapes, chips, fibres, granulates, powders and corresponding foam rubbers made from polyethylene, polypropylene and polyolefines, as well as polystyrene and other styrene polymerizates, acrylates, caoutchouc, alkyd resins, formaldehyde resins and polyester resins.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4221624A DE4221624C1 (en) | 1992-07-01 | 1992-07-01 | |
| DE4221624 | 1992-07-01 |
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| Publication Number | Publication Date |
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| EP0576940A1 EP0576940A1 (en) | 1994-01-05 |
| EP0576940B1 true EP0576940B1 (en) | 1996-01-24 |
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| EP93109822A Expired - Lifetime EP0576940B1 (en) | 1992-07-01 | 1993-06-19 | Pesticidal and fireproofing agent for wood and other organic materials |
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| Country | Link |
|---|---|
| US (1) | US5476686A (en) |
| EP (1) | EP0576940B1 (en) |
| JP (1) | JP3378051B2 (en) |
| AT (1) | ATE133365T1 (en) |
| DE (2) | DE4221624C1 (en) |
| DK (1) | DK0576940T3 (en) |
| ES (1) | ES2083226T3 (en) |
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| NO (1) | NO301265B1 (en) |
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| DE19853496C1 (en) * | 1998-11-19 | 2000-08-03 | Hubert Fritz | Method and device for producing chips |
| KR20030082698A (en) * | 2002-04-18 | 2003-10-23 | 표옥근 | dyeing and embalmment method for process timber |
| WO2004009252A2 (en) * | 2002-07-19 | 2004-01-29 | University Of Vermont And State Agricultural College | Wood finishes and methods for their production |
| DE102007048422A1 (en) * | 2007-10-09 | 2009-04-16 | Homatherm Ag | Wood fiber thermal insulation material and method for its production |
| DE102011055188A1 (en) * | 2011-11-09 | 2013-05-16 | Volker Fritz | Aqueous solution |
| CN110523023A (en) * | 2019-07-18 | 2019-12-03 | å±±ä¸œå†œä¸šå¤§å¦ | A kind of combustible method of reduction tending and cutting of forest residue |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB130981A (en) * | 1918-08-03 | 1920-05-06 | Claude Roy | Process and Apparatus for Rendering Wood Impermeable and Recovering Liquids Contained therein. |
| GB455533A (en) * | 1935-11-08 | 1936-10-22 | Gideon Scott May | Means for preserving, waterproofing, and fireproofing stone, brick, wood and like work |
| US2904437A (en) * | 1954-06-01 | 1959-09-15 | Wilson & Co Inc | Treating whey |
| US3616386A (en) * | 1969-08-08 | 1971-10-26 | Purity Electrochemical Co | Electrodialytic demineralization of whey using neutral membranes |
| BE791350A (en) * | 1971-11-15 | 1973-05-14 | Stichting Bedrijven Van Het | PROCESS FOR THE PREPARATION OF A MILK WHITE COPRECIPITATE |
| US3864506A (en) * | 1974-03-20 | 1975-02-04 | Stauffer Chemical Co | Process For Pretreating Raw Cheese Whey |
| US4076800A (en) * | 1975-01-13 | 1978-02-28 | The Procter & Gamble Company | Protein-containing detergent compositions for protecting keratinous materials |
| US4064283A (en) * | 1976-06-14 | 1977-12-20 | The United States Of America As Represented By The Secretary Of Agriculture | Preparation of protein concentrates from whey and seed products |
| FR2391653A1 (en) * | 1977-05-23 | 1978-12-22 | Nestle Sa Soc Ass Tech Prod | WHEY TREATMENT PROCESS |
| US4225629A (en) * | 1977-08-15 | 1980-09-30 | The United States Of America As Represented By The Secretary Of Agriculture | Preparation of protein concentrates from whey and seed products |
| US4227981A (en) * | 1979-08-31 | 1980-10-14 | Borden, Inc. | Electrodialysis of acid whey |
| AU552141B2 (en) * | 1980-11-25 | 1986-05-22 | Unilever Plc | Coluble protein product from whey |
| US4444792A (en) * | 1981-07-20 | 1984-04-24 | Stauffer Chemical Company | Fermentation of whey to produce a thickening polymer |
| US5098472A (en) * | 1983-06-17 | 1992-03-24 | Commonwealth Scientific & Industrial Research Organization | Preservative composition |
| DE3518188C1 (en) * | 1985-05-21 | 1986-10-23 | Meinhardt, Horst, 5419 Herschbach | Aluminium lactate solution and a process for the preparation thereof and the use thereof |
| US5078912A (en) * | 1985-06-07 | 1992-01-07 | Dr. Wolman Gmbh | Wood preservative |
| DE3522655A1 (en) * | 1985-06-25 | 1987-01-08 | Vft Verkaufsges Teer | WOOD-PROTECTING IMPREGNATION OIL AND ITS USE |
| US4956177A (en) * | 1985-11-04 | 1990-09-11 | Microlife Technics, Inc. | Method for inhibiting fungi |
| US4786326A (en) * | 1986-11-12 | 1988-11-22 | Mooney Chemicals, Inc. | Process for penetrating difficult-to-treat wood with wood preservative liquids |
| SE459140B (en) * | 1986-11-25 | 1989-06-12 | Albuglobe Ab | HYDROLYSIS OF WHEAT PROTEIN TO PROVIDE SEPARATE SEPARATION OF FAT |
| ES2028940T3 (en) * | 1987-05-20 | 1992-07-16 | Chugai Seiyaku Kabushiki Kaisha | A SUBSTITUTE FOR SALT. |
| US4950329A (en) * | 1988-10-11 | 1990-08-21 | Hickson Corporation | Wood preservative composition and method of treating wood with same |
| US4973488A (en) * | 1989-05-17 | 1990-11-27 | Excelpro, Inc. | Hydrolyzed proteinaceous milk solid and process of making |
| US4988545A (en) * | 1989-08-17 | 1991-01-29 | Board Of Control Of Michigan Technological University | Method for treating wood against fungal attack |
-
1992
- 1992-07-01 DE DE4221624A patent/DE4221624C1/de not_active Expired - Fee Related
-
1993
- 1993-06-19 DK DK93109822.2T patent/DK0576940T3/en active
- 1993-06-19 AT AT93109822T patent/ATE133365T1/en active
- 1993-06-19 ES ES93109822T patent/ES2083226T3/en not_active Expired - Lifetime
- 1993-06-19 DE DE59301493T patent/DE59301493D1/en not_active Expired - Lifetime
- 1993-06-19 EP EP93109822A patent/EP0576940B1/en not_active Expired - Lifetime
- 1993-06-21 NO NO932268A patent/NO301265B1/en not_active IP Right Cessation
- 1993-06-29 FI FI932994A patent/FI932994A/en not_active Application Discontinuation
- 1993-06-30 JP JP16188393A patent/JP3378051B2/en not_active Expired - Fee Related
- 1993-07-01 US US08/084,482 patent/US5476686A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| NO932268D0 (en) | 1993-06-21 |
| FI932994A0 (en) | 1993-06-29 |
| NO932268L (en) | 1994-01-03 |
| ATE133365T1 (en) | 1996-02-15 |
| NO301265B1 (en) | 1997-10-06 |
| DE4221624C1 (en) | 1993-07-15 |
| JP3378051B2 (en) | 2003-02-17 |
| ES2083226T3 (en) | 1996-04-01 |
| JPH06206207A (en) | 1994-07-26 |
| EP0576940A1 (en) | 1994-01-05 |
| DK0576940T3 (en) | 1996-03-18 |
| US5476686A (en) | 1995-12-19 |
| FI932994A (en) | 1994-01-02 |
| DE59301493D1 (en) | 1996-03-07 |
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