EP0461695A1 - Procédé et appareil pour la purification d'effluents de gaz poussiéreux et nocifs - Google Patents

Procédé et appareil pour la purification d'effluents de gaz poussiéreux et nocifs Download PDF

Info

Publication number
EP0461695A1
EP0461695A1 EP91201274A EP91201274A EP0461695A1 EP 0461695 A1 EP0461695 A1 EP 0461695A1 EP 91201274 A EP91201274 A EP 91201274A EP 91201274 A EP91201274 A EP 91201274A EP 0461695 A1 EP0461695 A1 EP 0461695A1
Authority
EP
European Patent Office
Prior art keywords
stage
liquid
precipitation
electrodes
tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP91201274A
Other languages
German (de)
English (en)
Other versions
EP0461695B1 (fr
Inventor
Karl Steinbacher
Hermann Schmidt
Wilhelm Leussler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
Original Assignee
Metallgesellschaft AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE4018488A external-priority patent/DE4018488C1/de
Priority claimed from DE19904023723 external-priority patent/DE4023723C1/de
Application filed by Metallgesellschaft AG filed Critical Metallgesellschaft AG
Publication of EP0461695A1 publication Critical patent/EP0461695A1/fr
Application granted granted Critical
Publication of EP0461695B1 publication Critical patent/EP0461695B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/40Electrode constructions
    • B03C3/45Collecting-electrodes
    • B03C3/53Liquid, or liquid-film, electrodes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/40Electrode constructions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/01Pretreatment of the gases prior to electrostatic precipitation
    • B03C3/011Prefiltering; Flow controlling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/017Combinations of electrostatic separation with other processes, not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/02Plant or installations having external electricity supply
    • B03C3/025Combinations of electrostatic separators, e.g. in parallel or in series, stacked separators, dry-wet separator combinations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/74Cleaning the electrodes
    • B03C3/76Cleaning the electrodes by using a mechanical vibrator, e.g. rapping gear ; by using impact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/88Cleaning-out collected particles

Definitions

  • the invention relates to a method for cleaning dust and pollutant-containing exhaust gases, in which the exhaust gases are first subjected to dry cleaning in a mass separator and then to electrostatic cleaning in an electrostatic filter in a second stage, and to a device for carrying them out of the procedure.
  • DE-OS 2907081 describes a device for dry removal of dust from exhaust gas, consisting of a centrifugal separator with numerous dedusting cells and a downstream, horizontally flowed, dry electrostatic filter.
  • the teaching described in DE-OS 2907081 is based on the task of designing the centrifugal separator in a simple and compact manner, so that it can be arranged directly in front of the electrostatic filter without difficulty.
  • the device described in DE-OS 2907081 has the disadvantage that the exhaust gases which are passed through the device can only be freed of dust and other pollutants contained in the exhaust gas remain in the exhaust gas.
  • the invention is therefore based on the object of providing a method for cleaning exhaust gases containing dust and pollutants, in which the exhaust gases are first subjected to dry cleaning in a mass separator in a first stage and then to electrostatic cleaning in an electrostatic filter in a second stage, and in which dust and pollutants are separated from the Exhaust gas is reached.
  • the invention is also based on the object of providing an apparatus for carrying out the method.
  • the object on which the invention is based is achieved in that the exhaust gases are passed in the second stage through one or more fields with liquid-wetted, gas-forming precipitation electrodes.
  • “Dust” means the solid particles contained in the exhaust gas; For example, in sintering plants, the dust consists mainly of iron oxide-containing solid particles and in combustion plants, it consists of the small fly ash particles.
  • the term “pollutants” includes the acidic components contained in the exhaust gas such as HF, SO2, SO3 and HCl, and the non-ferrous metals such as Pb, Cd, Hg and As present in the exhaust gas in gaseous or sublimed form. Centrifugal separators, such as cyclones or multicyclones, can be used as mass separators.
  • Metal plates, metal nets, plastic mesh or plates made of ceramic materials can be used as precipitation electrodes.
  • the liquid applied to the precipitation electrodes in the second stage is an aqueous solution.
  • the field strength is, for example, 1.5 to 5 kV / cm, and the precipitation area of the precipitation electrodes is in the range of 200 to 800 m2. It has surprisingly been found that the process according to the invention separates dust and pollutants in such a way that the limit values according to TA Lucas of 27.2.1986 for dust and pollutant concentrations in the clean gas are undershot.
  • a preferred embodiment of the invention consists in that the liquid is applied in the second stage at the upper ends of the precipitation electrodes and collected directly under the lower ends of the precipitation electrodes and discharged laterally from the separator and that the substantially dry dust still accumulating in the second stage is fed to a dust collecting device.
  • a dust collecting device Various types of devices such as dust bunkers, dust collecting channels and discharge elements, such as screw conveyors, can be used as the dust collecting device. While the vast majority of the dust is separated in a dry form in the first stage, the dust that still enters the second stage can also be largely separated in a dry form and thus separated from the pollutants. It is advantageous that in the second stage there is no sludge which contains a relatively large amount of pollutants in addition to the dust and which would have to be treated. This is achieved in that only the precipitation electrodes are wetted and that the liquid used for sprinkling is drained off immediately below the precipitation electrodes in collecting channels, while the actual gas lane space and the space below the electrodes remain dry
  • German patent application P 39 28 808 describes a process for the electrostatic cleaning of exhaust gases containing dust and pollutants in multi-field electrostatic precipitators, in which the exhaust gases are fed to dry electrostatic cleaning in a first stage and then in a second electrostatic stage in which liquid is wetted Precipitation electrodes are arranged, are freed from the pollutants.
  • the liquid applied is collected directly under the lower ends of the precipitation electrodes and laterally discharged from the separator and the essentially dry dust still present in the second stage is fed to a dust collection device, it has surprisingly been found that also A separate separation of dry dust on the one hand and pollutants on the other hand is possible if the first stage is not a dry electrostatic precipitator but a mass separator is executed. In the second stage of the process according to the invention, therefore, there is also no sludge loaded with pollutants, the disposal of which is problematic.
  • the residence time of the exhaust gases in the second stage is 2 to 6 seconds.
  • This measure has the effect that the gas temperature in the second stage only drops by approximately the temperature by which the gas temperature is reduced by the downstream Fan increased again due to gas compression.
  • the water dew point is raised by only 4 ° C.
  • the distance between the gas temperature and the water dew point in the second stage is chosen so large that the water dew point is not fallen below and thus the acidic pollutants do not condense on the non-wetted dry parts of the second stage. Special measures to avoid corrosion in the second stage are therefore not necessary.
  • the residence time of the exhaust gases in the second stage is 2 to 6 seconds, the coarse grain fraction of the dust is separated in the first step and the fine grain fraction of the dust is separated in the second step.
  • the process can thus be carried out successfully at low gas speeds, the residence time in the second stage being sufficient to also remove the pollutants from the exhaust gas to a sufficient extent.
  • a further preferred embodiment of the invention consists in that an alkaline aqueous solution with a pH of 7 to 9 is used as the liquid.
  • an alkaline aqueous solution with a pH of 7 to 9 is used as the liquid.
  • NaOH and / or KOH and / or Ca (OH) 2 is added to the liquid.
  • These substances are readily soluble in water, so that the pH in the range from 7 to 9 can be adjusted quickly and easily in the aqueous solution.
  • the spray system of the second stage and / or the housing wall of the second stage is tapped. It has surprisingly been shown that the majority of the dust cleaned by the knocking is not deposited on the precipitation electrodes wetted with liquid, but partly in agglomerated form in the dry gas alley space or directly on the housing walls of the second stage and thus falls down is fed directly to the dust collecting device.
  • the tapping is not limited to the use of a specific tapping device.
  • the spray system is tapped once in 2 to 20 minutes.
  • minutes means the switch-on minutes in the operation of the second stage. If the spray system is tapped once in 2 to 20 minutes, the spray system is thoroughly cleaned without the actual process of electrostatic cleaning being adversely affected in the second stage.
  • the individual spray electrodes or the individual suspension devices of the spray system of a gas lane are tapped one after the other. This has the advantage that strong swirling of dust and briefly increased dust concentrations in the clean gas are avoided.
  • Another preferred embodiment of the invention is that the housing wall of the second stage in 20 to 120 Minutes is knocked once.
  • the term "minutes" means the switch-on minutes in the operation of the second stage. This measure thoroughly removes dust from the housing wall during operation without adversely affecting the process of electrostatic cleaning in the second stage.
  • the dead space between the precipitation electrodes and the housing wall is flushed with hot gas in the second stage.
  • the hot gas reaches the dead space via nozzles. This prevents condensation of the water vapor contained in the exhaust gas on the walls caused by the temperature falling below the dew point and the associated corrosion of the components of the second stage.
  • part of the clean gas discharged from the second stage is used as the hot gas. This measure ensures that pollutants do not reach the second stage again by flushing the dead space.
  • the injected clean gas is largely freed of pollutants, so that corrosion, especially on the housing walls of the multi-field separator, is almost completely avoided.
  • the object on which the invention is based is further achieved by the provision of a device for carrying out the method, which consists of a mass separator arranged as a first stage and an electrostatic filter arranged as a second stage, liquid-wetted, gas-forming precipitation electrodes being arranged in the electrostatic filter. Dust and pollutants can be largely removed from the exhaust gas with the device at low gas speeds, so that the prescribed limit values for dust and pollutant concentrations are undershot.
  • overflow channels are arranged at the upper ends of the precipitation electrodes and collecting channels at the lower ends, the precipitation electrodes being attached to the lower end of the respective overflow channels.
  • this design ensures that the precipitation electrodes are sprinkled evenly, on the other hand it is ensured that the liquid loaded with the pollutants is collected relatively free of dust directly below the lower ends of the precipitation electrodes and then discharged.
  • the collecting troughs are dimensioned so that they can hold the amount of liquid, the throughput of which is usually 40 to 80 m3 / h with an exhaust gas amount of 100,000 m3 / h.
  • the overflow channels are dimensioned so that the precipitation electrodes are evenly wetted with a liquid film. If the precipitation electrodes of the second stage are attached to the lower end of the respective overflow channels, a uniform wetting of the precipitation electrodes - starting from their upper end - is achieved.
  • At least one edge of the individual overflow channels is comb-shaped. This measure ensures that the precipitation electrodes are uniformly wetted with a liquid film and that the thickness of the liquid film is approximately constant over the precipitation surface of the respective precipitation electrode. This enables a uniform separation of the pollutants in the second stage, whereby almost the entire precipitation electrode surface is available for the separation of the pollutants and oversizing of the individual precipitation electrode surfaces is reliably avoided.
  • a liquid distributor pipe connected to the liquid supply and provided with openings is arranged in each overflow channel. According to this arrangement, the liquid can be fed to the individual overflow channels directly from above. With this arrangement it is also possible to circulate the liquid.
  • each overflow channel is connected to the respective liquid distributor pipe. This measure ensures that each precipitation electrode is connected directly to the respective liquid distribution pipe via the respective overflow channel, which allows quick access to the precipitation electrode during repair work.
  • a tube is arranged at the upper end of each precipitation electrode of the second stage, which is connected directly to the precipitation electrode, which has holes on the side facing away from the precipitation electrode in the plane of the precipitation electrode and which is connected to the liquid supply, wherein collecting troughs are arranged at the lower ends of the precipitation electrodes of the second stage.
  • the tube can be connected to the precipitation electrode, for example, by welding, gluing or by a screw or rivet connection. It has surprisingly been found that there is no crystal formation when the liquid emerges from the bores, so that a uniform irrigation of the precipitation electrodes is ensured over a long operating time.
  • the thickness of the liquid film can also be optimized by changing the amount of liquid supplied. It can also be advantageous change the flow rate of the liquid in a fixed cycle during the continuous supply of the liquid.
  • the diameter of the bores is 8 to 12 mm. This measure results in a particularly uniform distribution of the liquid on the respective precipitation electrode.
  • the hole spacing of the bores is 20 to 40 mm. If the hole spacing of the bores is 20 to 40 mm, the thickness of the liquid film on the precipitation electrode can be set particularly advantageously, since a liquid film with a constant thickness is already formed on the outer surface of the tube.
  • the diameter of the tube is 60 to 140 mm. This has the advantage that when such a tube is used, the usual throughputs for the liquid, which are between 40 and 80 m3 / h with an exhaust gas quantity of 100,000 m3 / h, can be applied to the precipitation electrodes without problems. If the tube has a diameter of 60 to 140 mm, it can be used in many ways, so that the costs for the device according to the invention are reduced by series production of the tube.
  • the tube is additionally connected to the precipitation electrode via at least one plate arranged in the longitudinal direction of the tube.
  • This measure has the effect, on the one hand, that the liquid film between the bores of the tube and the precipitation electrode does not tear off, on the other hand, strengthened the connection between the tube and the precipitation electrode.
  • Each plate can be connected to the tube and the precipitation electrode, for example by welding, gluing or by a screw or rivet connection.
  • At least one plate is connected tangentially to the tube. This measure ensures a continuous transition of the liquid film between the tube and the plate.
  • a hot gas supply is arranged in the second stage.
  • the arrangement of a hot gas supply in the second stage enables the dead space between the precipitation electrodes and the housing wall of the separator to be flushed with hot gas in the second stage.
  • Another embodiment of the invention is that the edges of each precipitation electrode of the second stage are connected to a pipeline which is connected to the liquid supply. This has the advantage that the liquid can be fed directly to the individual precipitation electrodes, the individual gas lanes between the precipitation electrodes being kept free for gas passage, so that the separation process in the second stage of the multi-field separator is not hindered.
  • the pipeline is provided with openings on the lower edge of each precipitation electrode of the second stage.
  • FIG. 1 shows a longitudinal section of the mass separator arranged as the first stage (1) and of the electrostatic filter arranged as the second stage (2).
  • the exhaust gas loaded with dust and pollutants enters the first stage (1), in which dry cleaning takes place in a mass separator, horizontally in the direction of the arrow.
  • a multicyclone is shown as a mass separator.
  • the dry dust separated from the exhaust gas in the first stage (1) is collected in the lower, funnel-shaped part of the mass separator and discharged via a lock (1 '').
  • the exhaust gas enters the second stage (2) immediately after the dry cleaning via the lock (1 ').
  • In the second stage (2) there are liquid-wetted precipitation electrodes (3) and spray electrodes (4) which are electrically insulated with post insulators (19).
  • the liquid loaded with pollutants runs down the respective precipitation electrode surfaces and reaches the respective collecting troughs (8).
  • a dust collecting device (5) and a discharge device (6) are provided for separating the dust which is dry in the second stage (2).
  • a hot gas supply (11) is arranged in the second stage (2). The hot gas (21) passes through the nozzles of the hot gas supply (11) into the dead spaces between the precipitation electrodes (3) and the housing wall (9) of the second stage (2). The clean gas leaves the second stage (2) horizontally in the direction of the arrow.
  • the dust collecting device (5) is designed according to FIG. 2 as a discharge screw, which conveys the dry dust accumulating in the second stage (2) to a discharge member (6) feeds.
  • the liquid, which is collected by the collecting troughs (8) and is loaded with pollutants, is discharged laterally via an outlet (20). Via the outlet (20), the loaded liquid, in which dissolved salts are present, can be fed to a downstream crystallization system, in which the dissolved salts are obtained as solids.
  • a wetted precipitation electrode (3) with a liquid supply (13) and the collecting channel (8) is shown.
  • the liquid passes from the liquid supply (13) via the pipeline (12) to the overflow channel (7) and from there via the surface of the precipitation electrodes (3) into the collecting channel (8).
  • the loaded liquid is discharged via the outlet (20).
  • FIG. 4 shows a perspective section of some gas lanes between the precipitation electrodes (3) with hot gas supply (11), overflow channels (7) and collecting channels (8).
  • the liquid is fed through the pipeline (12) to the respective overflow channel (7) and reaches the precipitation electrode (3) via the edges (10) of the overflow channel (7).
  • the hot gas (21) is injected through the hot gas supply (11) into the dead space between the precipitation electrode (3) and the housing wall (9) of the separator.
  • a precipitation electrode (3) with overflow channel (7) and collecting channel (8) is shown, in which the liquid is supplied to the overflow channel (7) from above.
  • the liquid reaches the overflow channel (7) via a liquid distributor pipe (15) which is provided with openings (16) and is connected to the liquid supply (13).
  • the precipitation electrode (3) is through a weight (17) weighed down. This enables them to be fixed centrally in the collecting trough (8).
  • a valve (23) is arranged outside the housing wall (9) of the separator in the liquid feed (13) with which the amount of liquid can be metered exactly.
  • the liquid feed (13) and the liquid distributor pipe (15) are connected to the overflow channel (7) by webs (22).
  • the precipitation electrode (3) can thus be held on the liquid distributor pipe (15) and the liquid feed (13) via the overflow channel (7).
  • FIG. 9 shows a collecting trough (8) with a part of the pipeline (12) on the lower edge of a precipitation electrode (3). Part of the liquid supplied passes through the openings (14) directly into the collecting channel (8) and rinses it out. The unloaded liquid is discharged from the collecting channel (8) together with the loaded liquid.
  • spray electrodes (4) of the second stage (2) are shown schematically together with a tapping device.
  • Metal wires, metal strips or plastic fibers coated with electrically conductive substances can be used as spray electrodes, for example.
  • Each spray electrode (4) is clamped vertically in a frame (4a) belonging to the suspension device (18), on which an anvil (4b) is arranged.
  • the monkey (23) is firmly connected to a rotatably mounted shaft (24).
  • a lifting lever (25) is attached to the shaft (24) and is pivoted (26) is connected to a pull rod (27).
  • the pull rod (27) is arranged to be vertically displaceable by the bearing (28). If the pull rod (27) is now moved in the direction of the arrow, the monkey (23) strikes the anvil (4).
  • FIG. 11 the housing wall (9) of the second stage (2) is shown together with a knocking device.
  • the knocking device corresponds to that knocking device which is shown in FIG. If the pull rod (27) is moved in the direction of the arrow, the drop hammer (23) strikes the anvil (9a), which is arranged directly on the housing wall (9).
  • FIG. 12 shows the top view of the knocking device shown in FIG. 11.
  • the shaft (24) is shown enlarged in FIG.
  • the drop hammer (23) is welded to the shaft (24).
  • the lifting lever (25) is also welded to the shaft (24).
  • the head device shown in FIGS. 10 to 12 is only given as an example. Other knocking devices can also be used.
  • FIG. 13 shows a tube (29) which is connected to the precipitation electrode (3).
  • the tube (29) On its side facing away from the precipitation electrode (3), the tube (29) has bores (30) in the plane (32) of the precipitation electrode (3) through which the liquid exits from the inside of the tube to the outside.
  • the tube (29) is additionally connected to the precipitation electrode (3) via the plates (31a) and (31b).
  • the plates (31a) and (31b) are connected at points (X) and (X ') tangentially over the entire length of the tube (29) to the tube (29).
  • the liquid escaping through the bores (30) runs on the outer wall of the tube (29) the plates (31a) and (31b), whereby a liquid film with a constant thickness is formed.
  • the liquid reaches the surface of the precipitation electrode (3) via the plates (31a) and (31b) and flows downwards.
  • FIG. 14 shows the section B-B through the tube (29) in the plane (32) of the precipitation electrode (3) according to FIG. 1.
  • the liquid is discharged to the outside in the direction of the arrow and forms a liquid film of almost constant thickness on the outer surface of the tube (29).
  • the amount of exhaust gas from a sintered belt is 400,000 Nm3 / h, whereby the exhaust gas has a temperature of 120 ° C, a dew point of 40 ° C and a dust content of 1.5 g / Nm3.
  • the exhaust gas is passed horizontally into a multi-cyclone arranged as the first stage (1).
  • the gas quantities are divided into many cyclones of small diameter, but arranged in parallel in a common housing, but with high centrifugal force.
  • the multicyclone used has the following fraction separation levels with regard to the grain size: Grain size in ⁇ m Fractional separation degrees in% 0-2 0 2 - 5 50 5 - 10 80 10-15 93 15-20 95 20-30 97 > 30 99
  • the overall separation efficiency of the multicyclone is 91.5%.
  • the exhaust gas with a dust content of 0.128 g / Nm3 thus enters the electrostatic filter arranged as the second stage (2).
  • the precipitation area of the liquid-coated precipitation electrodes (3) of the second stage (2) is 1500 m2.
  • the throughput for the liquid for wetting the precipitation electrodes (3) is 300 m3 / h.
  • a residual dusty substance content after treatment is measured in the electrostatic filter arranged as second stage (2) of 18 mg / Nm3.
  • the emission values for dusty inorganic substances are below the second stage (2) for class I (Cd, Hg, etc.) below 0.2 mg / Nm3, for class II (from As, Ni etc.) 1.0 mg / Nm3 and for class III (Pb, F, Sn etc.) below 5.0 mg / Nm3 (classification of the dusty inorganic substances according to TA-Luft from 27.2.1986).
  • the limit values for vaporous or gaseous inorganic substances - especially for SO2 with 500 mg / Nm3 - were not exceeded in the test.
  • the temperature drop in the area of the wetted precipitation electrodes (3) is approx. 25 ° C, causing the gas temperature to drop to 95 ° C and the dew point to be raised to 44 ° C.
  • the downstream fan increases the gas temperature by 24 ° C, which in turn raises it to 119 ° C.
  • the gas therefore has a gas inlet temperature at the chimney base of 119 ° C.
  • the relatively slight cooling of the exhaust gas which is brought about according to the invention in the second stage (2), achieves an energy saving of approximately 120 kW for the 3 MW blower used at a gas inlet temperature of 95 ° C. and a dew point of 44 ° C. .
EP91201274A 1990-06-09 1991-05-29 Procédé et appareil pour la purification d'effluents de gaz poussiéreux et nocifs Expired - Lifetime EP0461695B1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE4018488A DE4018488C1 (en) 1990-06-09 1990-06-09 Removing dust and hazardous materials from waste gases - by sepg. dust in dry multi-cyclone stage, and wet electrostatic precipitator stage
DE4018488 1990-06-09
DE4023723 1990-07-26
DE19904023723 DE4023723C1 (fr) 1989-08-31 1990-07-26

Publications (2)

Publication Number Publication Date
EP0461695A1 true EP0461695A1 (fr) 1991-12-18
EP0461695B1 EP0461695B1 (fr) 1995-02-15

Family

ID=25893988

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91201274A Expired - Lifetime EP0461695B1 (fr) 1990-06-09 1991-05-29 Procédé et appareil pour la purification d'effluents de gaz poussiéreux et nocifs

Country Status (7)

Country Link
US (1) US5160510A (fr)
EP (1) EP0461695B1 (fr)
JP (1) JPH04227075A (fr)
KR (1) KR920000359A (fr)
AT (1) ATE118371T1 (fr)
AU (1) AU643794B2 (fr)
DE (1) DE59104573D1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008046410A1 (de) * 2008-09-04 2010-03-11 Eisenmann Anlagenbau Gmbh & Co. Kg Vorrichtung zum Abscheiden von Lack-Overspray
DE102008046414A1 (de) * 2008-09-04 2010-03-18 Eisenmann Anlagenbau Gmbh & Co. Kg Vorrichtung zum Abscheiden von Lack-Overspray
DE102009006528A1 (de) * 2009-01-28 2010-07-29 Eisenmann Anlagenbau Gmbh & Co. Kg Anlage zum Beschichten, insbesondere Lackieren, von Gegenständen, insbesondere Fahrzeugkarosserien
DE102011012011A1 (de) * 2011-02-22 2012-08-23 Eisenmann Ag Vorrichtung zum Abscheiden von Overspray

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5549795A (en) * 1994-08-25 1996-08-27 Hughes Aircraft Company Corona source for producing corona discharge and fluid waste treatment with corona discharge
AT406024B (de) * 1995-05-02 2000-01-25 Scheuch Alois Gmbh Anlage zur elektrostatischen reinigung von staubhaltigem abgas
LT4627B (lt) 1998-06-02 2000-02-25 Vilniaus Gedimino technikos universitetas Išcentrinis elektrostatinis filtras
US6398848B1 (en) 1999-04-26 2002-06-04 American Electric Power Service Method of separating a low density fly ash fraction from an overall group of fly ash
KR100389669B1 (ko) * 2000-07-11 2003-06-27 학교법인 유한학원 전계 인가형 수분 필터 장치
US6783575B2 (en) * 2002-05-09 2004-08-31 Ohio University Membrane laminar wet electrostatic precipitator
FI121410B (fi) * 2003-06-24 2010-11-15 Alstom Technology Ltd Menetelmä sähkösuodattimen puhdistamiseksi suodatustoiminnan aikana ja sähkösuodatin
US7132009B2 (en) * 2005-03-08 2006-11-07 Fancy Food Service Equipment Co., Ltd. Air filter device for air exhauster
SE530738C2 (sv) * 2006-06-07 2008-08-26 Alstom Technology Ltd Våtelfilter samt sätt att rengöra en utfällningselektrod
KR100812131B1 (ko) * 2006-08-19 2008-03-12 김재옥 공기 청정기용 필터
US7708803B2 (en) * 2006-11-03 2010-05-04 Electric Power Research Institute, Inc. Method and apparatus for the enhanced removal of aerosols from a gas stream
JP2008212846A (ja) * 2007-03-05 2008-09-18 Hitachi Plant Technologies Ltd 湿式電気集塵装置の流水機構
DE102007035639B3 (de) * 2007-07-27 2009-02-26 Outotec Oyj Anlage zum Verteilen einer Flüssigkeit
JPWO2009104411A1 (ja) * 2008-02-20 2011-06-23 ダイキン工業株式会社 集塵装置
DE102010007479B3 (de) 2010-02-09 2011-06-22 EISENMANN Anlagenbau GmbH & Co. KG, 71032 Anlage zum Beschichten von Gegenständen
US9993828B2 (en) 2010-03-05 2018-06-12 Garrett Thermal Systems Limited Particle precipitator
CN101890270A (zh) * 2010-07-16 2010-11-24 湖南湘达环保工程有限公司 一种电除尘和电布袋除尘的组合除尘器
AU2012272552A1 (en) 2011-06-22 2013-12-12 Garrett Thermal Systems Limited Particle detector with dust rejection
EP2620221A1 (fr) 2012-01-26 2013-07-31 Alstom Technology Ltd Ébranlage pour un précipitateur électrostatique
DE102012023554A1 (de) * 2012-12-01 2014-06-05 Eisenmann Ag Abscheideeinheit zur Verwendung in einer Abscheidevorrichtung für Overspray
CN103920588A (zh) * 2013-01-10 2014-07-16 陕西骏马环保工程有限公司 电气湿式除尘器
KR101460663B1 (ko) * 2013-10-21 2014-11-20 서울샤프중공업 주식회사 집진효율을 향상시킨 집진판 및 이를 사용하는 습식전기집진기
GB2520009A (en) * 2013-11-05 2015-05-13 Edwards Ltd Gas treatment apparatus
KR200479771Y1 (ko) * 2014-05-22 2016-03-07 오동진 집진 장치용 집진판
CN104043311A (zh) * 2014-06-20 2014-09-17 北京世纪清科环保设备有限责任公司 一种高压静电油烟净化设备
CN104174246B (zh) * 2014-08-25 2016-01-20 段洪池 利用液体还原剂的空气净化设备及其工作和应用方法
CN105013275B (zh) * 2015-05-22 2016-11-30 四川省宜宾惠美线业有限责任公司 一种锅炉烟气净化方法
JP6582293B2 (ja) * 2015-07-29 2019-10-02 群馬県 ネット式脱臭装置
CN105363560A (zh) * 2015-11-16 2016-03-02 艾尼科环保技术(安徽)有限公司 一种湿式静电除尘器极板清洗方法
CN105363558A (zh) * 2015-12-04 2016-03-02 艾尼科环保技术(安徽)有限公司 一种湿式静电除尘器极板
CN105797865A (zh) * 2016-05-10 2016-07-27 艾尼科环保技术(安徽)有限公司 一种湿式静电除尘器柔性极板
CN106731299B (zh) * 2016-12-02 2023-05-12 成都易态科技有限公司 气体过滤装置
CN110787583A (zh) * 2019-12-06 2020-02-14 徐州申恒环境科技有限公司 一种高效静电式车间油雾处理设备及其工作方式
CN112973354A (zh) * 2021-02-22 2021-06-18 广东紫科环保设备有限公司 一种静电除油净化器和病死畜禽废气处理组合装置及其工艺
KR102347101B1 (ko) * 2021-08-11 2022-01-06 주식회사 진에너텍 하이브리드 습식 전기 집진장치 및 그가 적용된 슬러지 연료화 시스템
KR102347105B1 (ko) * 2021-08-11 2022-01-05 주식회사 진에너텍 배출장치가 적용된 하이브리드 습식 전기 집진장치

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1968334A (en) * 1932-07-13 1934-07-31 Research Corp Water film precipitator
GB609386A (en) * 1944-08-29 1948-09-30 Smidth & Co As F L Improvements in and relating to electrostatic dust-separating filters
US2708008A (en) * 1953-08-12 1955-05-10 Research Corp Mechanical and electrostatic gas cleaning mechanism
FR1139151A (fr) * 1955-12-29 1957-06-26 Cfcmug Perfectionnements aux précipitateurs électrostatiques humides
CH362682A (de) * 1958-10-04 1962-06-30 Gema Ag Apparatebau Und Stanze Elektrofilter, insbesondere zum Reinigen von Rauchgasen
DE1926752A1 (de) * 1968-07-15 1970-01-22 Metallgesellschaft Ag Vorrichtung zum Abreinigen von Spruehelektroden
US4308038A (en) * 1979-05-10 1981-12-29 Santek, Inc. Inertial-electrostatic wet precipitator
EP0076627A1 (fr) * 1981-10-07 1983-04-13 Dresser Industries,Inc. Précipitateurs électrostatiques humides

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2709497A (en) * 1954-02-04 1955-05-31 Research Corp Electrical precipitator
US3238702A (en) * 1962-09-07 1966-03-08 Electronatom Corp Self-decontaminating electrostatic precipitator structures
US3444668A (en) * 1964-03-06 1969-05-20 Onoda Cement Co Ltd Apparatus for electrostatic precipitation of dust
JPS54114874A (en) * 1978-02-27 1979-09-07 Hitachi Plant Eng & Constr Co Ltd Electric dust collector
JPS5561946A (en) * 1978-11-01 1980-05-10 Hitachi Ltd Anti-corrosive method for wet-type electric dust collector
US4529418A (en) * 1982-01-15 1985-07-16 Santek, Inc. Inlet section for inertial-electrostatic precipitator unit

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1968334A (en) * 1932-07-13 1934-07-31 Research Corp Water film precipitator
GB609386A (en) * 1944-08-29 1948-09-30 Smidth & Co As F L Improvements in and relating to electrostatic dust-separating filters
US2708008A (en) * 1953-08-12 1955-05-10 Research Corp Mechanical and electrostatic gas cleaning mechanism
FR1139151A (fr) * 1955-12-29 1957-06-26 Cfcmug Perfectionnements aux précipitateurs électrostatiques humides
CH362682A (de) * 1958-10-04 1962-06-30 Gema Ag Apparatebau Und Stanze Elektrofilter, insbesondere zum Reinigen von Rauchgasen
DE1926752A1 (de) * 1968-07-15 1970-01-22 Metallgesellschaft Ag Vorrichtung zum Abreinigen von Spruehelektroden
US4308038A (en) * 1979-05-10 1981-12-29 Santek, Inc. Inertial-electrostatic wet precipitator
EP0076627A1 (fr) * 1981-10-07 1983-04-13 Dresser Industries,Inc. Précipitateurs électrostatiques humides

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 5, no. 35 (C-46)(707) 05 März 1981, & JP-A-55 159857 (HITACHI) 12 Dezember 1980, *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008046410A1 (de) * 2008-09-04 2010-03-11 Eisenmann Anlagenbau Gmbh & Co. Kg Vorrichtung zum Abscheiden von Lack-Overspray
DE102008046414A1 (de) * 2008-09-04 2010-03-18 Eisenmann Anlagenbau Gmbh & Co. Kg Vorrichtung zum Abscheiden von Lack-Overspray
US8945288B2 (en) 2008-09-04 2015-02-03 Eisenmann Ag Device for separating paint overspray
DE102008046410B4 (de) * 2008-09-04 2016-03-17 Eisenmann Se Vorrichtung zum Abscheiden von Lack-Overspray
DE102009006528A1 (de) * 2009-01-28 2010-07-29 Eisenmann Anlagenbau Gmbh & Co. Kg Anlage zum Beschichten, insbesondere Lackieren, von Gegenständen, insbesondere Fahrzeugkarosserien
WO2010086093A1 (fr) * 2009-01-28 2010-08-05 Eisenmann Anlagenbau Gmbh & Co. Kg Installation de revêtement, notamment de peinture, d'objets, notamment de carrosseries de véhicule
DE102011012011A1 (de) * 2011-02-22 2012-08-23 Eisenmann Ag Vorrichtung zum Abscheiden von Overspray

Also Published As

Publication number Publication date
AU643794B2 (en) 1993-11-25
ATE118371T1 (de) 1995-03-15
DE59104573D1 (de) 1995-03-23
EP0461695B1 (fr) 1995-02-15
KR920000359A (ko) 1992-01-29
AU7823291A (en) 1991-12-12
JPH04227075A (ja) 1992-08-17
US5160510A (en) 1992-11-03

Similar Documents

Publication Publication Date Title
EP0461695B1 (fr) Procédé et appareil pour la purification d'effluents de gaz poussiéreux et nocifs
EP0415486B1 (fr) Procédé et appareil pour la purification électrostatique d'effluents de gaz nocifs et poussiéreux dans des séparateurs à plusieurs champs
DE3122515C2 (de) Elektrostatische Filteranordnung
DE1542314C3 (de) Verfahren und Vorrichtung zur Entfernung von Schwefeloxiden aus Abgasen
DE3927701A1 (de) Verfahren und anlage zur reinigung eines gases mit festen und gasfoermigen beimengungen
DE2626789A1 (de) Verfahren zur entfernung von partikeln aus einem gasstrom
DE2838159A1 (de) Verfahren und vorrichtung zum behandeln von mit schmutzpartikeln beladenen gasen
AT408843B (de) Staubfilter
DE1921949A1 (de) Staubabscheider
CH638107A5 (de) Vorrichtung und verfahren zum absorbieren von verunreinigungen in abgasen.
EP0014782A1 (fr) Dispositif de dépoussiérage
AT406024B (de) Anlage zur elektrostatischen reinigung von staubhaltigem abgas
DE4018488C1 (en) Removing dust and hazardous materials from waste gases - by sepg. dust in dry multi-cyclone stage, and wet electrostatic precipitator stage
DE2435864C2 (de) Verfahren und Vorrichtung zur Entfernung von Feststoffpartikeln aus einem Gasstrom
EP0274037A1 (fr) Procédé et dispositif pour la séparation des particules
DE3217146C2 (fr)
CH636778A5 (de) Verfahren und vorrichtung zur abscheidung von feinstaeuben und aerosolen aus einem gasstrom.
WO2000026141A1 (fr) Installation compacte pour l'epuration mecanique d'eaux usees
DE3928808C1 (en) Treating chemical pollutants - by passage of waste gas through multiple passages between collector plates
DE2522097A1 (de) Vorrichtung zum abscheiden von festen stoffen aus einem gasstrom
EP0545943B1 (fr) Procede et systeme de separation de particules solides et/ou liquides et/ou gaseaux contenus dans un courant de gas
DE3307999A1 (de) Verfahren und anlage zur verminderung von schadstoffen in gasen
DE2554096C3 (de) Filteranlage mit Sättigungskühler
DE19651857C1 (de) Vorrichtung zur Abscheidung von Feststoffen aus staubbeladenen Abgasen, insbesondere von Verbrennungsanlagen
DE4004357C1 (en) Gas electrostatic cleaning system - has linkage driven hammer operating against striker at bottom edge of screen

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT DE FR GB IT LU NL SE

17P Request for examination filed

Effective date: 19920207

17Q First examination report despatched

Effective date: 19930924

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT DE FR GB IT LU NL SE

REF Corresponds to:

Ref document number: 118371

Country of ref document: AT

Date of ref document: 19950315

Kind code of ref document: T

ET Fr: translation filed
REF Corresponds to:

Ref document number: 59104573

Country of ref document: DE

Date of ref document: 19950323

ITF It: translation for a ep patent filed

Owner name: STUDIO JAUMANN

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19950510

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19970410

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19970411

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19970422

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19970423

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19970428

Year of fee payment: 7

Ref country code: LU

Payment date: 19970428

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19980420

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980529

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980529

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980529

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980530

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF THE APPLICANT RENOUNCES

Effective date: 19980630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19981201

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19980529

EUG Se: european patent has lapsed

Ref document number: 91201274.7

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 19981201

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050529