EP0329768B1 - Polymere intrinsequement conducteur sous forme de solide dispersible, sa fabrication et son emploi - Google Patents

Polymere intrinsequement conducteur sous forme de solide dispersible, sa fabrication et son emploi Download PDF

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EP0329768B1
EP0329768B1 EP88908186A EP88908186A EP0329768B1 EP 0329768 B1 EP0329768 B1 EP 0329768B1 EP 88908186 A EP88908186 A EP 88908186A EP 88908186 A EP88908186 A EP 88908186A EP 0329768 B1 EP0329768 B1 EP 0329768B1
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polymer
polymers
temperature
conductive
dispersion
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EP0329768A1 (fr
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Bernhard Wessling
Harald Volk
Susanne BLÄTTNER
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Zipperling Kessler GmbH and Co
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Zipperling Kessler GmbH and Co
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K9/00—Screening of apparatus or components against electric or magnetic fields
    • H05K9/0073—Shielding materials
    • H05K9/0081—Electromagnetic shielding materials, e.g. EMI, RFI shielding
    • H05K9/0083—Electromagnetic shielding materials, e.g. EMI, RFI shielding comprising electro-conductive non-fibrous particles embedded in an electrically insulating supporting structure, e.g. powder, flakes, whiskers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F38/00—Homopolymers and copolymers of compounds having one or more carbon-to-carbon triple bonds
    • C08F38/02—Acetylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/10—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0209—Polyarylenethioethers derived from monomers containing one aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0286—Chemical after-treatment
    • C08G75/0295—Modification with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/128—Intrinsically conductive polymers comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Definitions

  • This term refers to organic polymers which have (poly)-conjugated ⁇ -electron systems (e.g. double bonds, aromatic or heteroaromatic rings or triple bonds).
  • polymers are polydiacetylene, polyacetylene (PAc), polypyrrole (PPy), polyaniline (PAni), polythiophene (PTh), polyisothianaphthene (PITN), polyheteroarylenvinylene (PArV), in which the heteroarylene group can be e.g.
  • a polymer alloy is a single-phase mixture of compatible polymers
  • a composite is a composition, usually already a semi-finished or (almost) finished product, which constitutes a mixture of polymers with other polymers or other non-polymer substances which is macroscopically not homogeneous, but often a layered arrangement of the individual components
  • a compound is a macroscopically homogeneous compound of one or more polymers with one or more non-polymer and not necessarily organic substance(s).
  • the smallest morphological unit i.e. super-molecular structural unit, (here: of an ICP) that is recognisable in the scanning or transmission electron microscope.
  • the primary particles assemble to form higher structures (secondary and tertiary structures).
  • aggregate one understands the assemblage of primary particles brought about by growing together and stabilised by material bridges; by “agglomerate” one understands the assemblage of primary particles which only consists of point-like contacts. Agglomerates can be broken down again in a substrate and dispersed as primary particles, with aggregates this is not possible without breaking chemical bonds.
  • conventionally used in pigment technology cf. Herbst/Hunger, "Industrielle organische Pigmente", VCH 1987
  • ICPs conventionally used in pigment technology
  • a polymer is dissolved when its entire polymer chain is surrounded on all sides with molecules of the solvent, by which means the primary particles are usually swollen. There are then no short range interactions between chain segments of different polymer chains. A true polymer solution can no longer be separated from the solvent by a filter, however fine.
  • the soluble intrinsically conductive polymers which clearly also have a glass transition point
  • the soluble polythiophenes and their copolymers are listed (cf. R. Elsenbaumer et al, Synth. Met. 18 , 277 (1987)), the processability per se of which appears simplified in comparison with, e.g. a polypyrrole or polyaniline, these substances however exhibit very high percolation points in polymer blends (e.g. over 10 to 15% by weight) and to date can only be processed as pure substances or in polymer blends via solutions, and not by solvent-free processes, mainly in their non-complexed, neutral, non-conductive form,
  • the percolation point of this two phase system is around 60 to 65 parts [polypyrrole] to 30 to 35 parts [methylcellulose monomer units], and the saturation point of the conductivity not before 93 to 94 parts polypyrrole to 6 to 7 parts methylcellulose monomer units.
  • the subject of the invention is a dispersible intrinsically conductive doped polymer (ICP) powder of primary particles having a specific surface area acccording to BET of > 15 m 2 /g, an average (weight) diameter of less than 500 nm, and exhibiting a percolation threshold concentration of ⁇ 7.5 Vol.% ICP (derived from an ICP volume concentration/conductivity curve measured in polycaprolactone as matrix polymer in the presence of a surface active agent), whereby said powder is obtainable through polymerization in a solvent, in which the appropriate monomer is present in solution or colloid dispersion but in which the polymer formed is insoluble and that the temperature of the reaction mixture is controlled by cooling and the rate of oxidant addition so that it will not rise to a value of more than 5°C over the starting temperature.
  • the polymer contains in the particle size range > 500 nm not more than 20% aggregates with an average size of > 0.5 ⁇ m.
  • the polymer contains more than 80% of dispersible primary particles with an average diameter of less than 500 nm, as shown in the appropriate tests.
  • unformed intrinsically conductive polymers are particularly well processable or shapable, when they consist of primary particles which are not connected with each other by material bridges (i.e. they are not assembled into aggregates) but exist as individual particles or as re-dispersible agglomerates.
  • the ICP raw materials are particularly well suited for further shaping processing
  • the intrinsically conductive polymer exists as a dispersible solid with a purity of more than 90%, i.e. it does not contain more than 10% by weight of impurities originating from the polymerisation, particularly polymerisation aids.
  • the shape of the primary particles is not important. Many of the ICPs according to the invention admittedly occur as spherical or near-spherical primary particles, but other shapes (rods, fibrils, angular shapes or asymmetric structures etc.) are suitable as long as the specific surface area, the particle size and the purity meet the given specifications.
  • All conductive polymers are suitable and their (reversibly) "doped” (in other words: complexed, oxidised or protonised or charged) conductive forms are preferred.
  • the polymers preferably contain counter ions with a molecular weight of not more than 1000, such as e.g. benzolsulphonate. ICPs are further preferred which are insoluble in organic solvents or only in very few solvents e.g. in those with a solubility parameter of 11 (cal/cm 3 ) 1/2 .
  • Suitable polymers are, e.g.
  • polydiacetylene polyacetylene
  • PAc polypyrrole
  • PAni polyaniline
  • PMS polyphenylensulphide
  • PPN polyperinaphthaline
  • Phc polyphthalocyanine
  • other conjugated polymers their derivatives (i.e. polymers of derivatives e.g. substituted with side-chains on the ring or on the heteroatom [these derivatives being] of the monomers forming the above mentioned polymers) and their copolymers and their physical mixtures with each other.
  • polymers are suitable that are convertible via a reversible oxidation or reduction and/or via reversible protonisation or other deriving reactions (which one can to some extent describe as a complexing or compensation reaction) into conjugated, positive or negative polymer chains (the charging of which is compensated by ions of the opposite charge), by which means the polymer can exist in states of different conductivity (which normally have a different chemical composition).
  • Polymers are preferred with a conductivity which can reach more than 10 -2 S/cm.
  • the intrinsically conductive polymers can depending on the application be obtained in neutral, reduced or oxidised form or in protonised/deprotonised form, then processed in the further procedures and used.
  • the ICP raw materials according to the invention have surprisingly proved to be more suitable than the raw materials used in these processes previously both for further processing as a pure substance in high pressure processes according to DE-PS 34 21 993 and for dispersion in polymer blends according to DE-PS 34 22 316. Additional advantages that were not foreseeable have also emerged, such as
  • the ICP raw materials according to the invention can be manufactured in various ways, e.g. electrochemically or chemically.
  • Chemical processes in which the "doped" (in other words: charged, oxidised, protonised) conductive polymer is formed directly and is not obtained in its uncharged forms and in which the formation of many centres of reaction is possible, have proved particularly suitable; a method in which the length of time that the reaction is being carried out is itself relatively long or the rate of reaction is reduced also appears advantageous.
  • the invention is directed to a process for the preparation of intrinsically conductive polymers in the form of dispersible solids with the specific surface area and the particle size range given above, in which process the polymerisation is carried out in a solvent in which the appropriate monomer is soluble or exists in a colloidal dispersion, but in which the polymer formed is insoluble, and in which process the temperature of the reaction mixture is controlled by cooling so that it will not rise to a value more than 5oC over the starting temperature.
  • This starting temperature is room temperature or below, i.e. normally will not exceed 20oC.
  • the temperature is not allowed to rise to a value more than 2oC above the starting temperature.
  • the polymerization is preferably carried out under an inert gas atmosphere, in particular under a nitrogen blanket. It is further preferred to control the reaction by keeping the electrochemical potential of the reaction mixture ⁇ 730 mV.
  • the viscosity of monomer solution or dispersion before the start of the polymerisation reaction is advantageously > 0.9 mPa.sec.
  • the viscosity of the monomer solution or dispersion is preferably adjusted by the addition of an organic substance which is soluble in the reaction medium and which increases the viscosity. These substances are not necessarily surface-active. They can have a macromolecular structure. The only restriction on the selection of these substances is that they should be able to be washed out easily in the reprocessing of the already polymerised ICP. Siloxane copolymers have, for example, proved useful for the synthesis of polyaniline.
  • the polymerisation is carried out at a temperature of ⁇ 20oC or 1 to 2oC above the temperature at which the dissolved monomer precipitates, the viscosity of the reaction medium will increase and the rate of reaction will decrease.
  • the order of addition of the reagents also appears to have a certain influence on the quality of the raw materials according to the invention.
  • the addition of the polymerisation reagent (oxidation agent) to the suspension or dispersion/solution of the monomer is preferably such that the heat effect of the reaction can be dissipated. As a rule this demands that the addition lasts more than 30 minutes with reaction mixtures with 100g of monomer. It is also advantageous to pre-mix the monomer solution or dispersion and the reagents at a temperature below that at which the polymerisation begins, and to slowly heat [the mixture] to the starting temperature after which the heat effect must be largely dissipated.
  • the monomer is preferably added in doses according to the progress of the polymerisation.
  • the polymerisation is generally carried out under strong mechanical agitation. If the monomer is not soluble in the dilution agent used, the usual emulsifiers and/or aids to dispersion are added to obtain a suitable monomer dispersion.
  • the suitable polymers were therefore usually polymerised at between 550 and 800 mV, and preferably at 600-700 mV vs Ag/AgCl.
  • reaction and shaping should also be implemented following the instructions in EP-OS 168 620 and 168 621 for the manufacture of purer and more homogeneous ICPs.
  • a reduction agent e.g. N 2 H 4 .
  • N 2 H 4 a reduction agent
  • Suitable here are ethanol and other water soluble alcohols, ketones such as acetone, THF, DMSO etc.
  • the freshly polymerised and washed ICP can thus first be compensated in water (discharged) and filtered, and then taken up with organic solvents, if necessary dispersed according to EP-OS 168 620 and then washed again and filtered, after which the further forming stages take place (with or without subsequent complexing/charging) for the preparation of the ICP.
  • the polymer powder is preferably reversibly converted by oxidation or reduction or by being treated with an acid or base into a conductive or non-conductive oxidation or protonisation state without the shape and size of the primary particles being significantly altered.
  • the raw material according to the invention is prepared, e.g. dried, for use in the subsequent processing procedures.
  • very well dried and de-gassed raw materials are preferably used for the processing of the pure ICP in the high pressure process. Only pre-dried raw materials according to the invention can be employed for use in polymer blends; the final drying can then take place during the manufacture of the polymer blend, especially as the majority of synthetics processing machines are equipped with de-gassing options.
  • the raw materials according to the invention can be characterised using the measurement of the specific surface area.
  • those according to the invention have a specific surface area (measured using the BET method) of more than 15 m 2 /g, and preferably more than 25 m 2 /g.
  • the raw materials according to the invention occur as powder with 80% by weight of the primary particles being smaller than 500 nm, and not more than 20% by weight of these being aggregated into aggregates of more than 1 um. This can be seen from scanning electron microscope photographs of the dried solid and using the light microscope from the SEM (electron microscope) examinations of the dispersions in polymer blends.
  • the light microscope examination is carried out with the solid according to the invention dispersed in a test polymer either directly or as a concentrate with the help of an internal mixer.
  • Suitable as test polymers are PCL or PVC.
  • the concentration of the substance to be dispersed is usually 0.5% by weight.
  • the mixture is pressed out to a thin film.
  • Using the raw materials according to the invention one can see an evenly highly coloured semi-transparent substance; the colouring is due to the dispersed primary particles. In addition one can see in some circumstances undispersed particles of 0.5-1 ⁇ m and single coarse particles.
  • the raw materials according to the invention can be formed following the instructions in EP-OS 168 621.
  • An improved embodiment of EP-OS 168 621 consists in allowing the necessary pressure to act isostatically on the ICP. It was found thereby that manufacturing formed parts from conductive polymers under pressure and under an inert atmosphere leads to particularly homogeneous formed parts. Preforms can initially be manufactured under conditions of procedure which are subject to no particular restriction. It has emerged however that the use of formed parts according to DE-PS 34 21 993 gives better results.
  • the application of isostatic pressure is successful when known hot-isostatic presses are used in which both the pressure and the inert atmosphere are provided by noble gases such as helium or argon.
  • any apparatus is in principle suitable which can produce isostatic pressure under an inert atmosphere and using which one can simultaneously bring the material to be formed or the preformed blank to the desired temperature, this being above the ambient temperature and below the decomposition temperature of the substance concerned.
  • Oils are also suitable as the pressure transfer medium, preferred however is apparatus in which inert gases, e.g. noble gases such as helium or argon, serve both to supply the inert atmosphere and as the pressure transfer medium.
  • a particularly suitable embodiment of the process consists in a preformed blank which, for example, has been manufactured according to the instructions in DE-PS 34 21 993, being introduced under an inert atmosphere into a vacuum-tight or pressure-tight casing, known as a capsule and the capsule being sealed so that it is pressure and vacuum-tight, e.g. by welding or soldering.
  • the capsule is preferably made of metal, e.g. Cu or steel sheet.
  • the capsule with the preformed blank is transferred into a suitable plant, e.g. into a apparatus for carrying out the so-called hot-isostatic techniques or for carrying out hot and isostatic pressing, such as used in powder metallurgy for the production of high-quality mouldings ("Hot isostatic pressing").
  • the desired pressure is set, this pressure should be above 50 bar and preferably above 200 bar, and the desired temperature, which should be above 35oC and must be below the decomposition temperature at the chosen conditions.
  • the pressure is then maintained longer than 10 minutes, after which the temperature drops first and then the pressure is regulated down to normal pressure. Then the appararus and the capsule can be opened. Very homogeneous mouldings result, which depending on the chosen conditions of the process and the raw materials are extraordinarily rigid and break-proof.
  • Formed parts of almost any geometry and size desired can therefore be made now from ICPs.
  • the new high quality of the formed ICP according to the invention permits, e.g. mechanical after-treatment.
  • Formed parts can therefore be manufactured from ICP raw materials according to the invention of the most varied chemical composition which are brought to their final form by further processing such as, for example, cutting, boring, milling, machining, ultrasonic processing, spark erosion etc.
  • One can therefore obtain, e.g. very thin ( ⁇ 100 ⁇ m e.g. to 0.5 ⁇ m) plates, or other components in any form desired.
  • the (electro)chemical properties of these substances which do not change during the forming and further processing operations, additionally allow the manufacture of formed parts of a complicated structure, because by (electro)chemical aftertreatment various layers (insulating, semi-conductive, conductive) or structures (e.g. conductor channels or paths) and boundary layers (e.g. p-n-bridges) can be produced in or on a formed part.
  • the various oxidation and protonisation states for example, of e.g. polyaniline, make it possible to adjust the electrical properties of a finished product according to the requirements of the desired application almost at will.
  • ICP raw materials according to the invention are in their dispersal in polymers that are not electrically conductive. Processes suitable per se are described in EP-OS 168620, EP-OS 168 621 and EP 181 587.
  • the raw materials according to the invention create considerable additional advantages compared with the prior art in the application of analogous dispersion processes:
  • the polymer blends have advantageous antistatic properties depending on the concentration of ICP, which distinguish them from known forming materials that contain carbon black because of their low content and the non-black optical effect. Moreover they have the same properties as self-supporting films of PAc, PPy or PAni, e.g. as regards the temperature dependency of the conductivity, the (electro-)chemical reactivity of the interactions with electromagnetic waves of all types or the thermoelectric power, which cannot be achieved by compounds filled with conductive carbon black.
  • the raw materials according to the invention are preferably used after the after-treatment stages have been carried out (forming or polymer blend manufacture) e.g. in the following areas (this list being only by way of example and not limiting):
  • Example 1 Various monomers and opposite charged ions (complexing agents or protonisation agents or “doping agents”) can be used as in Example 1 and different oxidation agents can be employed for the polymerisation, e.g.:
  • an Ag/AgCl electrode is immersed in the reaction vessel, the measured quantity outlet [of this electrode] being linked to a dosing pump via a redox-potential control device.
  • the redox-potential desired can be set on the control device. It has proved beneficial not to polymerise above 730 mV.
  • the raw, washed polyaniline from Example 1 or the raw polymers from Example 2 are suspended in water and ammonia solution is added until the suspension reacts strongly alkaline. Then the process is carried out as described in EP-OS 0168620 and the compensated (neutralised or discharged) raw polymer is obtained. This is washed with water and filtered after every washing operation until the water used for washing only reacts slightly alkaline. The last filter cake is taken up in dimethyl sulphoxide and dispersed, e.g. using ultrasonics. To eliminate the remaining aggregates [the dispersion] is filtered through a black-band filter and then double the quantity of isopropanol is added to the filtrate. After two days the precipitated compensated polymer is filtered off and washed several times with isopropanol. Specific surface (BET): 26 m 2 /g (polyaniline from Example 1)
  • the raw materials according to the invention obtained as in Examples 1 to 3 are dried and examined in a scanning electron microscope. Primary particles are found of ⁇ 250 nm, these are very easily distinguishable from one other, some isolated and some in agglomerates. The smallest recognisable primary particles have a diameter of 10 to 20 nm. The proportion of larger aggregates is less than 20%.
  • the compensated, intrinsically conductive polymer obtained according to Example 3 is dispersed following the instructions of EP-OS 168 620 in polyethylene glycol (PEG) at a concentration of 40 %.
  • PEG polyethylene glycol
  • the PEG-PAni concentrate is dried and then diluted in polymethylmethacrylate (PMMA) or polycarbonate (PC) in an extruder in the concentration suitable for non-linear optical uses.
  • PMMA polymethylmethacrylate
  • PC polycarbonate
  • the intrinsically conductive polymers obtained according to the Examples 1 to 3 are washed after the last washing operation with acetone, methanol or iso-propanol to simplify the subsequent drying, and then dispersed in polycaprolactone (PCL), polyethylene oxide, ethylene acrylic acid copolymers or polyvinlypyrrolidone following the instructions in EP-OS 168 620 in a concentration of 50 to 75% by volume and intensively dried during or after the manufacture of the dispersion.
  • PCL polycaprolactone
  • the concentrates of the intrinsically conductive polymers are then diluted in the desired concentration in the polymers to be used for the further applications, these [polymers] may or may not be thermoplastic.
  • ABIL B 9950 a siloxane copolymer from Th. Goldschmidt AG
  • 200 ml of 28% hydrochloric acid and 120 ml of aniline are dissolved in 500 ml of H 2 O and cooled to -5oC.
  • a solution of 180 g of peroxydisulphate in 400 ml of H 2 is added slowly drop by drop.
  • the precipitated polyaniline is filtered off and cleaned four times as in Example 1 with 1.5M hydrochloric acid.
  • Example 1 The product of Example 1 or the re-complexed product of Example 3 is intensively dried to a residual solvent content of ⁇ 0.5% and then combined in a ball mill or a high-speed mixer with Polysurf CG6 in the ratio 3:1 (ICP:CG6). This product is dispersed in the concentration desired in the polymers required for the further applications (cf. Example 7 and 11).
  • the following table contains the measured values for the conductivity when different quantities are dispersed in PCL.
  • a polyaniline obtained as in the Examples 1 to 4 and treated as in Example 7 which can be processed to polymer blends shows the following dependency of the conductivity on the volume concentration after dispersion in PCL; Test 1 is shown in graph form in Figure 1.
  • Polyaniline and polypyrrole that do not correspond to the instructions in the invention exhibit a percolation curve as shown in the diagram of Fig. 2.
  • a concentrate of polyaniline hydrochloride in PCL produced as in the previous Examples is mixed with 7% conductive carbon black. (Ketjenblack EC) and with 2% chlorinated polyethylene pre-stabilised with barium cadmium stearate in melt and extruded or pressed into electrode strips. The electrodes are placed in glass beakers which are connected via a salt bridge. Hydrogen peroxide in 1-N hydrochloric acid is added to one of the two glass beakers while hydrazine in 1-N ammoniac solution is added in the other beaker. A potential of 800 mV (without current) results and a maximum initial current of 2.1 mA.
  • Example 10 The product from Example 10 is dispersed in a concentration of 1% in a polyurethane matrix. After leaving in normal climate (20oC, 55% relative air humidity) for 24h the transparent film is antistatic (10 8 to 10 10 ⁇ surface and volume resistivity).
  • a product manufactured as in the Examples 1 to 4 is incapsulated under an inert atmosphere, and the capsule is placed in a hot-isostat press.
  • the press is heated to 220oC and the pressure is brought to 1100 bar.
  • the pressure is maintained for 60 min, the capsule is cooled first and then the pressure is slowly released.
  • a compact moulding can be taken from the case which is mechanically very strong, the conductivity and elementary analysis of which corresponds with that of the starting product.
  • Raw conductive polymer from one of the Examples 1 - 4 or 7 - 10 is dispersed in a ball mill into a solvent containing clear lacquer on a basis of chlorinated rubber or on a basis of a VC-copolymer. It is best to use a concentration of between 20 and 25% in relation to 100% of the lacquer containing the solvent.
  • Fig. 5 shows the dependence of the conductivity of the dry lacquer on the concentration of PAni.
  • the lacquer In its undiluted state the lacquer is only just brushable, it can however if required be diluted with MEK [methylethylketone] to obtain better flow properties.
  • the lacquer can be used depending on the concentration as an antistatic coating or for applications according to Example 17 or 18.
  • the conductive lacquer from Example 16 is applied to an aluminium foil which is either - as is usual in the manufacture of electrolytic capacitors - formed, or not formed. After a drying period of 12 to 24 hours the conductive lacquer coating is touched with conductive silver lacquer, so that it is possible to attach a connecting electrode. After a further drying period of approx. 30 minutes the measuring electrodes are attached to the aluminium foil and to the conductive silver coating.
  • the following readings result (LCR bridge from Hewlitt-Packard):
  • the lacquer from Example 16 is applied to a non-corroded, smooth and polished steel plate. After drying the adhesion is relatively good. After a few days a section of the lacquer coating is scratched off with a spatula as a control and it is established that the iron has taken on a red-brown colour. The discolouration indicates that an iron oxide has been formed. The thin red-brown layer adheres firmly to the iron (on the steel plate) and does not have the porous, voluminous and poor adhesive character of normal rust.
  • Thermoplastic polymer blends of conductive polymers e.g. PAni(-MeSO 3 blends as in Example 10 or 11 (“A") are worked into plates of differing thickness and conductivity.
  • electrode substances filled with carbon black (“B") are manufactured as in DE-PS 36 19 094 and the shielding of electromagnetic waves of different frequencies by all the plates is measured.

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Claims (26)

  1. Poudre dispersible de polymère intrinsèquement conducteur (PIC) dopé constituée de particules primaires ayant une aire de surface spécifique selon la méthode BET > 15 m2/g, un diamètre moyen (en poids) de moins de 500 nm, et présentant une concentration au seuil de percolation < 7,5 % de PIC en volume (tiré d'une courbe de conductivité du PIC exprimant la conductivité en fonction de la concentration, mesurée en présence d'un agent tensioactif, dans une matrice polymère de polycaprolactone), ladite poudre pouvant être obtenue par polymérisation dans un solvant, dans lequel le monomère approprié est présent en solution ou sous forme de dispersion colloïdale, mais dans lequel le polymère formé est insoluble, et la temperature du mélange réactionnel étant contrôlée par refroidissement et par la vitesse d'ajout de l'oxydant, de manière à ce qu'elle n'atteigne pas une valeur supérieure de plus de 5°C à la température initiale.
  2. Poudre de polymère selon la revendication 1 comprenant un polymère organique ayant un système d'électrons π (poly)-conjugués ou un dérivé de celui-ci.
  3. Poudre de polymère selon la revendication 2, le polymère étant sélectionné parmi le groupe constitué par le polydiacétylène, le polyacétylène , le polypyrrole , la polyaniline, le polythiophène, le polyisothianaphtène, le polyhétéroarylène vinylène (dans lequel le groupe hétéoarylène peut être un groupe thiophène, ou pyrrole), le poly-p-phénylène, le polysulfure de phénylène , le polypérinaphtalène , et la polyphtalocyanine.
  4. Poudre de polymère selon l'une des revendications 1 à 3, caractérisée en ce que, à l'état sec, elle ne contient pas plus de 10% en poids d'impuretés provenant de la polymérisation.
  5. Poudre de polymère selon l'une des revendications 1 à 4, caractérisée en ce que, le polymère conducteur est sous une forme qui est dopée réversiblement par oxydation ou protonation.
  6. Poudre de polymère selon l'une des revendications 1 à 5, caractérisée en ce qu'elle ne contient pas de contre ions ayant un poids moléculaire supérieur à 1000.
  7. Procédé de préparation de la poudre de polymère intrinsèquement conducteur selon les revendications 1 à 6, caractérisé en ce que l'on effectue la polymérisation dans un solvant, dans lequel le monomère approprié est présent en solution ou sous forme de dispersion colloïdale, mais dans lequel le polymère formé est insoluble, et la température du mélange réactionnel est contrôlée par refroidissement et par la vitesse d'ajout de l'oxydant, de manière à ce qu'elle n'atteigne pas une valeur supérieure de plus de 5°C à la température initiale.
  8. Procédé selon la revendication 7, caractérisé en ce que l'on ne laisse pas la température monter à une valeur supérieure de 2°C à la température initiale.
  9. Procédé selon les revendications 7 ou 8, caractérisé en ce que l'on effectue la polymérisation à une température ≤ 5°C.
  10. Procédé selon l'une quelconque des revendications 7 à 9, caractérisé en ce que l'on effectue la polymérisation de manière à ce que la concentration du monomère dans la solution ou la dispersion ne dépasse à aucun moment 20% en poids.
  11. Procédé selon l'une quelconque des revendications 7 à 10, caractérisé en ce que l'on effectue la polymérisation sous une atmosphère de gaz inerte.
  12. Procédé selon l'une quelconque des revendications 7 à 11, caractérisé en ce que l'on maintient le potentiel électrochimique du mélange réactionnel < 730 mV.
  13. Procédé selon l'un quelconque des revendications 7 à 12, caractérisé en ce que l'on ajoute des émulsifiants et/ou des agents dispersants pour la formation d'une dispersion du monomère.
  14. Procédé selon l'un quelconque des revendications 7 à 13, caractérisé en ce que la viscosité de la solution ou de la dispersion monomère est > 0,9 mPa.s avant le début de la réaction de polymérisation.
  15. Procédé selon la revendication 14, caractérisé en ce que la viscosité de la solution ou de la dispersion monomère est ajustée par l'addition d'une substance organique augmentant la viscosité, qui est soluble dans le milieu réactionnel.
  16. Procédé selon les revendications 14 ou 15, caractérisé en ce que la viscosité du milieu réactionnel est contrôlée en ajustant sa température à une valeur suffisamment basse.
  17. Procédé selon l'un quelconque des revendications 7 à 16, caractérisé en ce l'on chauffe après la fin de réaction de polymérisation la suspension ou la dispersion de polymère à une température supérieure à 100°C, ce post-traitement étant effectué dans un récipient fermé en augmentant la pression si nécessaire.
  18. Procédé selon l'un quelconque des revendications 7 à 16, caractérisé en ce l'on convertit la poudre de polymère de manière réversible par oxydation ou réduction ou par traitement avec un acide ou une base à un état d'oxydation conducteur ou non conducteur ou de protonation, sans altérer de manière significative la forme et la taille des particules primaires.
  19. Utilisation de la poudre de polymère selon les revendications 1 à 6 pour la fabrication de pièces électriquement conductrices mises en forme par pressage de la poudre à des températures élevées en l'absence d'air.
  20. Utilisation selon la revendication 19, caractérisée en ce que l'on expose la poudre ou le matériau vierge préformé à une pression isostatique.
  21. Utilisation de la poudre de polymère selon les revendications 1 à 6 pour la fabrication de mélanges de polymères en mélangeant la poudre de polymère intrinsèquement conducteur avec une matrice de polymères et/ou avec des monomères et/ou des prépolymères non-conducteurs, à partir desquels on produit la matrice polymère par polymérisation.
  22. Utilisation selon la revendication 21, caractérisée en ce que l'on utilise une matrice de polymères thermoplastiques.
  23. Utilisation selon la revendication 21, caractérisée en ce que l'on convertit le mélange de la poudre de polymère intrinsèquement conductrice et des monomères et/ou des prépolymères polymérisables directement par polymérisation, en le solide désiré mis en forme.
  24. Utilisation selon la revendication 23, caractérisée en ce que la matrice de polymères n'est pas thermoplastique.
  25. Utilisation selon la revendication 23 ou 24, caractérisée en ce que le mélange de la poudre de polymère intrinsèquement conductrice et des monomères et/ou des prépolymères polymérisables est sous la forme d'un vernis qui peut contenir de manière facultative un solvant.
  26. Utilisation de la poudre de polymère selon l'une quelconque des revendications 1 à 6 ou des solides mis en forme ou des vernis obtenus à partir de ceux-ci selon les revendications 19 à 25
    Figure imgb0003
    comme conducteurs électriques ou semiconducteurs,
    Figure imgb0003
    comme protection contre les charges statiques,
    Figure imgb0003
    comme blindage contre les ondes électromagnétiques (blindage EMI)
    Figure imgb0003
    comme condensateurs ou comme substituts de l'électrolyte dans un condensateur électrolytique,
    Figure imgb0003
    pour la fabrication de composants semiconducteurs, en particulier des diodes ou des transistors,
    Figure imgb0003
    comme photoconducteurs ou dans la conversion d'énergie photovoltaïque,
    Figure imgb0003
    en combinaison avec des métaux ou des semi-métaux ou en combinaison avec différents polymères conducteurs variés en utilisant l'effet thermoélectrique comme capteur de température (absorption IR) ou dans la conversion d'énergie photovoltaïque,
    Figure imgb0003
    comme capteurs,
    Figure imgb0003
    comme indicateurs(par effet électrochrome),
    Figure imgb0003
    dans des procédés d'électrolyse ou d'électrosynthèse comme électrodes électrocatalytiques, en particulier dans les piles à combustible,
    Figure imgb0003
    dans la catalyse ou la synthèse photoélectrique,
    Figure imgb0003
    dans la protection contre la corrosion,
    Figure imgb0003
    comme électrodes dans les accumulateurs.
EP88908186A 1987-09-04 1988-09-02 Polymere intrinsequement conducteur sous forme de solide dispersible, sa fabrication et son emploi Expired - Lifetime EP0329768B1 (fr)

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DE3729566 1987-09-04
DE19873729566 DE3729566A1 (de) 1987-09-04 1987-09-04 Intrinsisch leitfaehiges polymer in form eines dispergierbaren feststoffes, dessen herstellung und dessen verwendung
PCT/EP1988/000798 WO1989002155A1 (fr) 1987-09-04 1988-09-02 Polymere intrinsequement conducteur sous forme de solide dispersible, sa fabrication et son emploi

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EP0329768A1 EP0329768A1 (fr) 1989-08-30
EP0329768B1 true EP0329768B1 (fr) 1996-11-20

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WO1989002155A1 (fr) 1989-03-09
JPH0819336B2 (ja) 1996-02-28
DE3855678T2 (de) 1997-03-13
DE3855678D1 (de) 1997-01-02
KR0136280B1 (ko) 1998-06-15
US5567355A (en) 1996-10-22
KR890702215A (ko) 1989-12-23
ATE145493T1 (de) 1996-12-15
JPH02500918A (ja) 1990-03-29
DE3729566A1 (de) 1989-03-16
EP0329768A1 (fr) 1989-08-30

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