CN104387957B - 一种抗静电涂料及其制备方法 - Google Patents
一种抗静电涂料及其制备方法 Download PDFInfo
- Publication number
- CN104387957B CN104387957B CN201410635558.7A CN201410635558A CN104387957B CN 104387957 B CN104387957 B CN 104387957B CN 201410635558 A CN201410635558 A CN 201410635558A CN 104387957 B CN104387957 B CN 104387957B
- Authority
- CN
- China
- Prior art keywords
- antistatic coating
- coating
- powder
- polypyrrole
- conducting polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 46
- 238000000576 coating method Methods 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 229920000128 polypyrrole Polymers 0.000 claims abstract description 24
- 239000002322 conducting polymer Substances 0.000 claims abstract description 19
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 14
- 239000004816 latex Substances 0.000 claims abstract description 8
- 229920000126 latex Polymers 0.000 claims abstract description 8
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 6
- 239000004917 carbon fiber Substances 0.000 claims abstract description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 12
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 8
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 238000003786 synthesis reaction Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 1
- 238000000227 grinding Methods 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 239000003643 water by type Substances 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 10
- 239000006185 dispersion Substances 0.000 abstract description 3
- 239000003973 paint Substances 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 239000011256 inorganic filler Substances 0.000 abstract description 2
- 229910003475 inorganic filler Inorganic materials 0.000 abstract description 2
- 238000000593 microemulsion method Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 229940008099 dimethicone Drugs 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000011231 conductive filler Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
一种抗静电涂料及其制备方法，属于涂料领域。本发明抗静电涂料利用微乳液法合成聚吡咯导电聚合物胶乳，所合成的聚吡咯具有粒径小、分散性好、稳定性好等优点，有利于涂料的涂覆；添加碳纤维粉的使用可以增强涂料的强度和耐磨性；添加无机填料可以增加涂料的硬度和附着力；本发明抗静电涂料制备工艺简单，操作方便。
Description
技术领域
本发明涉及一种涂料的制备方法，具体地涉及一种抗静电涂料及其制备方法。
背景技术
抗静电涂料由于含有导电成分，电阻率低，所以具有传导电流、排除物体积累的静电荷的作用。同时它又具备涂料的防护功能。抗静电涂料是一组体积电阻率在105-109Ω范围内的特种功能涂料，它最早的研究记载实在美国公布的导电胶专利。日本在20世纪50年代就研究出银系和炭系为主的抗静电涂料，并应用于电子工业和军事领域，而对石油工业领域静电危害的认识到80年代才完全成熟。我国在这方面的研究起步较晚，但发展较快，尤其是自1992年国家强制性要求石油罐采用抗静电涂料以来，这类涂料在石油罐方面的应用迅速发展起来。随着现代科技的发展，一些有洁净要求和抗静电要求的墙面和地面的场所，如在电子电器厂房、计算机房、印刷厂、纺织厂及制药厂等的应用也多了起来，抗静电涂料受到越来越广泛而深入的重视。
抗静电涂料应用最多的是石油储罐，石油储罐的设计寿命通常在10-15年，基于储罐如此长的寿命，高造价和储存物质的重要性及特殊性，对石油储罐进行防护极为必要。根据所储存油品的不同，分为原油储罐、中间产品罐和成品罐。所有储罐在使用过程中，均存在两个共同的问题，即静电和腐蚀。过去的一些应用中，由于对这两个问题的认识不足，因而油罐爆炸、泄露核穿孔的事故屡有发生。近年来，我国在这方面的研究较多，加之国家和行业的重视，在石油罐的防护和使用上也相继采用了抗静电涂料、防腐涂料及牺牲阳极保护等一系列措施。
目前，常用的抗静电涂料多为添加型，是导电填料、绝缘性成膜物，助剂和溶剂的混合物，利用导电填料的导电作用产生防静电效果，比如加入石墨、炭黑、炭纤维、银、镍、铜等填料，但这种抗静电涂料性能不稳定，填料分散不均匀便会影响抗静电效果。
为解决现有技术不足，本发明提出一种由具有导电性的聚合物为主要成分的抗静电涂料，具有施工方便，性能稳定等优点。
发明内容
本发明为解决上述问题，本发明提供了一种抗静电涂料及其制备方法，本发明实现上述目的所采用的技术如下：
一种抗静电涂料及其制备方法，由以下重量份的组分组成：
聚吡咯导电聚合物 30-40份；
流平剂 5-10份；
钛白粉 12-16份；
滑石粉 8-10份；
炭纤维粉末 2-7份。
其中所述的聚吡咯的合成工艺如下：
分别将3.6-4.7g十二烷基苯磺酸钠、8.9-9.6g异丙醇、22.9-27.0g去离子水加入聚合釜，搅拌均匀后，加入1.2-2.3g的过硫酸铵，然后通入10.9-13.8g吡咯单体，80-100℃下反应4-10h后，加0.7-1.3g对苯二酚终止剂，冷却后出料，即得聚吡咯导电聚合物胶乳。
其中所述的流平剂由以下份数的组份组成，所述份数均为重量份：
甲基硅油 2-5份；
二甲基硅油 3-5份。
所述钛白粉的目数为200-300目。
所述滑石粉的目数为100-200目。
其中所述的碳纤维粉是将碳纤维长丝经研磨、高温烘干后而获得的碳纤维微小圆柱体粉末，可以增加涂料的强度和耐磨性。
本发明抗静电涂料的制备工艺如下：
将各组份按照聚吡咯导电聚合物、流平剂、钛白粉、滑石粉、炭纤维粉末的顺序分别加入混料器，以80-150r/min的转速，40-60℃下，搅拌1-2h即可施工使用。
本发明所具有的有益效果是：
1、利用微乳液法合成聚吡咯导电聚合物胶乳，所合成的聚吡咯具有粒径小、分散性好、稳定性好等优点，有利于涂料的涂覆；
2、碳纤维粉的使用可以增强涂料的强度和耐磨性；
3、添加无机填料可以增加涂料的硬度和附着力；
4、本发明抗静电涂料制备工艺简单，操作方便。
具体实施方式
下面将结合具体实施例对本发明做进一步说明，具体实施例不限制本发明。
实施例1：本发明提供了一种抗静电涂料及其制备方法，由以下重量份的组分组成：
聚吡咯导电聚合物 30份；
甲基硅油 2份；
二甲基硅油 3份；
钛白粉 12份；
滑石粉 8份；
炭纤维粉末 2份。
本发明抗静电涂料的制备工艺如下：
（1）聚吡咯导电聚合物合成：分别将3.6g十二烷基苯磺酸钠、8.9g异丙醇、22.9g去离子水加入聚合釜，搅拌均匀后，加入1.2g的过硫酸铵，然后通入10.9g吡咯单体，80℃下反应4h后，加0.7g对苯二酚终止剂，冷却后出料，即得聚吡咯导电聚合物胶乳。
（2）将上述各组分分别加入混料器，以80r/min的转速，40℃下，搅拌1h即可施工使用。
实施例2：本发明提供了一种抗静电涂料及其制备方法，由以下重量份的组分组成：
聚吡咯导电聚合物 32份；
甲基硅油 35份；
二甲基硅油 4份；
钛白粉 13份；
滑石粉 9份；
炭纤维粉末 4份。
本发明抗静电涂料的制备工艺如下：
（1）聚吡咯导电聚合物合成：分别将3.9g十二烷基苯磺酸钠、9.0g异丙醇、23.6g去离子水加入聚合釜，搅拌均匀后，加入1.9g的过硫酸铵，然后通入11.9g吡咯单体，85℃下反应4-10h后，加0.8g对苯二酚终止剂，冷却后出料，即得聚吡咯导电聚合物胶乳。
（2）将上述各组分分别加入混料器，以90r/min的转速，45℃下，搅拌1.5h即可施工使用。
实施例3：本发明提供了一种抗静电涂料及其制备方法，由以下重量份的组分组成：
聚吡咯导电聚合物 38份；
甲基硅油 4份；
二甲基硅油 4份；
钛白粉 15份；
滑石粉 9份；
炭纤维粉末 6份。
本发明抗静电涂料的制备工艺如下：
（1）聚吡咯导电聚合物合成：分别将4.5g十二烷基苯磺酸钠、9.1g异丙醇、26.3g去离子水加入聚合釜，搅拌均匀后，加入2.2g的过硫酸铵，然后通入12.6g吡咯单体，90℃下反应9h后，加1.2g对苯二酚终止剂，冷却后出料，即得聚吡咯导电聚合物胶乳。
（2）将上述各组分分别加入混料器，以120r/min的转速，50℃下，搅拌2h即可施工使用。
实施例4：本发明提供了一种抗静电涂料及其制备方法，由以下重量份的组分组成：
聚吡咯导电聚合物 40份；
甲基硅油 5份；
二甲基硅油 5份；
钛白粉 16份；
滑石粉 10份；
炭纤维粉末 7份。
本发明抗静电涂料的制备工艺如下：
（1）聚吡咯导电聚合物合成：分别将4.7g十二烷基苯磺酸钠、9.6g异丙醇、27.0g去离子水加入聚合釜，搅拌均匀后，加入2.3g的过硫酸铵，然后通入13.8g吡咯单体，100℃下反应10h后，加1.3g对苯二酚终止剂，冷却后出料，即得聚吡咯导电聚合物胶乳。
（2）将上述各组分分别加入混料器，以150r/min的转速，60℃下，搅拌2h即可施工使用。
Claims (6)
1.一种抗静电涂料，由下述原料构成，所述份数均为重量份：
聚吡咯导电聚合物 30-40份；
流平剂 5-10份；
钛白粉 12-16份；
滑石粉 8-10份；
炭纤维粉末 2-7份；
其中所述的聚吡咯的合成工艺如下：分别将3. 6-4. 7g十二烷基苯磺酸钠、8.9-9. 6g异丙醇、22. 9-27. 0g去离子水加入聚合釜，搅拌均匀后，加入1. 2-2. 3g的过硫酸铵，然后通入10. 9-13. 8g吡咯单体，反应4-10h后，加0. 7-1. 3g对苯二酚终止剂，冷却后出料，即得聚吡咯导电聚合物胶乳。
2.权利要求1的一种抗静电涂料，其特征在于：反应温度为80-100℃。
3.权利要求1的一种抗静电涂料，其特征在于：所述钛白粉的目数为200-300目。
4.权利要求1的一种抗静电涂料，其特征在于：所述滑石粉的目数为100-200目。
5.权利要求1的一种抗静电涂料，其特征在于：其中所述的炭纤维粉是将炭纤维长丝经研磨、高温烘干后而获得的炭纤维微小圆柱体粉末。
6.权利要求1所述的一种抗静电涂料的制备方法，其特征在于：将各组份按照聚吡咯导电聚合物、流平剂、钛白粉、滑石粉、炭纤维粉末的顺序分别加入混料器，以80-150r/min的转速，40-60℃下，搅拌1-2h即可。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410635558.7A CN104387957B (zh) | 2014-11-13 | 2014-11-13 | 一种抗静电涂料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410635558.7A CN104387957B (zh) | 2014-11-13 | 2014-11-13 | 一种抗静电涂料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104387957A CN104387957A (zh) | 2015-03-04 |
| CN104387957B true CN104387957B (zh) | 2016-08-24 |
Family
ID=52605923
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410635558.7A Expired - Fee Related CN104387957B (zh) | 2014-11-13 | 2014-11-13 | 一种抗静电涂料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104387957B (zh) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542651B (zh) * | 2015-12-30 | 2018-03-23 | 砺剑防务技术集团有限公司 | 聚氨酯丙烯酸酯分散体及其制备方法和紫外光固化导电涂料及其制备方法 |
| CN106479280A (zh) * | 2016-11-10 | 2017-03-08 | 无锡市明盛强力风机有限公司 | 一种汽车底盘碳纤维防腐方法 |
| CN109880474A (zh) * | 2019-03-07 | 2019-06-14 | 徐克军 | 一种固体浮力材料基体表面用抗静电涂料 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3729566A1 (de) * | 1987-09-04 | 1989-03-16 | Zipperling Kessler & Co | Intrinsisch leitfaehiges polymer in form eines dispergierbaren feststoffes, dessen herstellung und dessen verwendung |
| CN1262575C (zh) * | 2003-09-15 | 2006-07-05 | 北京大学 | 导电聚吡咯纳米线的制备方法 |
| DE102004003784B4 (de) * | 2004-01-23 | 2011-01-13 | Ormecon Gmbh | Dispersion intrinsisch leitfähigen Polyanilins und deren Verwendung |
| DE102004013634A1 (de) * | 2004-03-18 | 2005-10-06 | Ormecon Gmbh | Zusammensetzung, enthaltend leitfähiges Polymer in kolloidaler Form und Kohlenstoff, Verfahren zur Herstellung und Verwendung |
| CN102532538A (zh) * | 2011-12-29 | 2012-07-04 | 上海理工大学 | 一种尺寸可控聚吡咯纳米颗粒及其制备方法 |
-
2014
- 2014-11-13 CN CN201410635558.7A patent/CN104387957B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN104387957A (zh) | 2015-03-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105001759B (zh) | 钼酸盐掺杂聚吡咯/环氧树脂自修复涂料及其制备和应用 | |
| CN105355968B (zh) | 电解液以及包括该电解液的锂离子电池 | |
| CN102618107B (zh) | 导电石墨乳及其制备方法 | |
| Wang et al. | Synthesis and characterization of MnO2 nanosheets based multilayer coating and applications as a flame retardant for flexible polyurethane foam | |
| CN102627903B (zh) | 一种环保型水性防腐导静电涂料及其制备方法 | |
| CN104387957B (zh) | 一种抗静电涂料及其制备方法 | |
| CN105440879A (zh) | 一种导静电涂料 | |
| CN103319689A (zh) | 一种高泳透力阴极电泳涂料用乳液树脂及其制备方法 | |
| CN105623473A (zh) | 一种基于石墨烯分散体的含锌石墨烯防腐底漆及其制备方法 | |
| CN1693392A (zh) | 一种导静电防腐蚀涂料及其制备方法 | |
| CN103031039B (zh) | 一种碳纳米管环氧树脂导静电涂层材料及其制备方法 | |
| CN102952439A (zh) | 一种复合炭导电涂料及其制备方法 | |
| CN101633809A (zh) | 水溶性导电聚苯胺防静电阻尼涂料及其制备方法 | |
| CN1664034A (zh) | 一种碳纤维导静电涂料及其制备方法 | |
| CN103224747B (zh) | 一种纳米浓缩浆改性防腐导电涂料及其制备方法 | |
| CN103205150B (zh) | 聚苯胺包覆微米二氧化硅的防腐涂料及其制备方法 | |
| CN103555137B (zh) | 掺杂态聚苯胺-环氧-锌粉复合涂料及其制备方法 | |
| CN102070960B (zh) | 一种含导电聚合物的水性防腐导电涂料及其制备方法 | |
| CN105990583B (zh) | 一种铅酸蓄电池高性能耐腐蚀复合涂层板栅及其制备方法 | |
| CN101260277A (zh) | 丙烯酸聚氨酯防静电涂料及制备方法 | |
| CN103409032A (zh) | 一种无溶剂导静电漆及制造方法 | |
| CN101921510B (zh) | 含氟烯烃-乙烯基醚共聚物的油墨组合物及光伏组件边框 | |
| CN1935911A (zh) | 一种底面合一的氟碳磁漆及其制备方法 | |
| CN103642365A (zh) | 一种船用铝合金腐蚀自修复智能涂层及其制备方法 | |
| CN108587288A (zh) | 一种导电防腐涂料及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Dong Na Inventor after: Wang Weimin Inventor after: Gao Xiaogang Inventor after: Ji Lihong Inventor before: Mou Junping Inventor before: Zhu Na Inventor before: Liu Xiao Inventor before: Yu Chunguang |
|
| COR | Change of bibliographic data | ||
| GR01 | Patent grant | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160802 Address after: 750002 the Ningxia Hui Autonomous Region Jinfeng District of Yinchuan city Ning Street No. 490 Yinchuan IBI incubation center two building 6 room 1401 Applicant after: NINGXIA CN-SC LIGHTING PROTECTION Co.,Ltd. Address before: 250199 Shandong Province, Licheng District, Ji'nan Huaxin Road, building 389, No. 601 Applicant before: SHANDONG HWAYA ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181127 Address after: 523000 AB District, 7th Floor, Kanglianda Industrial and Trade Center, Yanwo Village, Shipai Town, Dongguan City, Guangdong Province Patentee after: Dongguan Wantian New Material Technology Co.,Ltd. Address before: 750002 Yinchuan, the Ningxia Hui Autonomous Region, Jinfeng District, Ning'an Street 490, Yinchuan IBI breeding center two phase 6 Building 1401 room. Patentee before: NINGXIA CN-SC LIGHTING PROTECTION Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160824 Termination date: 20211113 |