CN105542651B - 聚氨酯丙烯酸酯分散体及其制备方法和紫外光固化导电涂料及其制备方法 - Google Patents
聚氨酯丙烯酸酯分散体及其制备方法和紫外光固化导电涂料及其制备方法 Download PDFInfo
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- CN105542651B CN105542651B CN201511026065.4A CN201511026065A CN105542651B CN 105542651 B CN105542651 B CN 105542651B CN 201511026065 A CN201511026065 A CN 201511026065A CN 105542651 B CN105542651 B CN 105542651B
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- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical group C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
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- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
- C08G18/348—Hydroxycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/40—High-molecular-weight compounds
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- C—CHEMISTRY; METALLURGY
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C—CHEMISTRY; METALLURGY
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
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- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
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CN105949989A (zh) * | 2016-06-20 | 2016-09-21 | 中物功能材料研究院有限公司 | 水性uv抗菌涂料及其制备方法 |
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CN107254251B (zh) * | 2017-07-10 | 2019-11-05 | 湖南邦弗特新材料技术有限公司 | 一种具有自引发功能的水性uv聚氨酯丙烯酸酯分散体及其制备方法 |
CN107930690B (zh) * | 2017-10-25 | 2020-04-21 | 中国科学院宁波材料技术与工程研究所 | 一种超细纤维状高分子固载型催化剂及其制备方法和应用 |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0014921A1 (en) * | 1979-02-16 | 1980-09-03 | EASTMAN KODAK COMPANY (a New Jersey corporation) | Coating compositions and processes |
US5322861A (en) * | 1991-10-01 | 1994-06-21 | Mitsubishi Kasei Corporation | Ultraviolet-hardening urethane acrylate oligomer |
CN103570911A (zh) * | 2013-11-06 | 2014-02-12 | 中国科学院长春应用化学研究所 | 水性聚氨酯丙烯酸酯、水性聚氨酯紫外光固化涂料及其制备方法 |
CN104387957A (zh) * | 2014-11-13 | 2015-03-04 | 山东华亚环保科技有限公司 | 一种抗静电涂料及其制备方法 |
CN104629611A (zh) * | 2013-11-14 | 2015-05-20 | 江南大学 | 一种光固化导电涂料的制备方法 |
CN105001396A (zh) * | 2015-07-08 | 2015-10-28 | 华南理工大学 | 一种80-95%固含量水性光固化聚氨酯丙烯酸酯及制备方法 |
-
2015
- 2015-12-30 CN CN201511026065.4A patent/CN105542651B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0014921A1 (en) * | 1979-02-16 | 1980-09-03 | EASTMAN KODAK COMPANY (a New Jersey corporation) | Coating compositions and processes |
US5322861A (en) * | 1991-10-01 | 1994-06-21 | Mitsubishi Kasei Corporation | Ultraviolet-hardening urethane acrylate oligomer |
CN103570911A (zh) * | 2013-11-06 | 2014-02-12 | 中国科学院长春应用化学研究所 | 水性聚氨酯丙烯酸酯、水性聚氨酯紫外光固化涂料及其制备方法 |
CN104629611A (zh) * | 2013-11-14 | 2015-05-20 | 江南大学 | 一种光固化导电涂料的制备方法 |
CN104387957A (zh) * | 2014-11-13 | 2015-03-04 | 山东华亚环保科技有限公司 | 一种抗静电涂料及其制备方法 |
CN105001396A (zh) * | 2015-07-08 | 2015-10-28 | 华南理工大学 | 一种80-95%固含量水性光固化聚氨酯丙烯酸酯及制备方法 |
Non-Patent Citations (1)
Title |
---|
UV固化聚氨酯-丙烯酸酯水性上光油的合成;黄怡 等;《化工新型材料》;20120531;第40卷(第5期);第65-67、77页 * |
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