EP0183908B1 - Verfahren zur Verringerung des NOx-Gehaltes im Rauchgas bei der Beheizung von Verkokungsöfen und Verkokungsofen zur Durchführung des Verfahrens - Google Patents
Verfahren zur Verringerung des NOx-Gehaltes im Rauchgas bei der Beheizung von Verkokungsöfen und Verkokungsofen zur Durchführung des Verfahrens Download PDFInfo
- Publication number
- EP0183908B1 EP0183908B1 EP85108019A EP85108019A EP0183908B1 EP 0183908 B1 EP0183908 B1 EP 0183908B1 EP 85108019 A EP85108019 A EP 85108019A EP 85108019 A EP85108019 A EP 85108019A EP 0183908 B1 EP0183908 B1 EP 0183908B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heating
- gas
- flue
- volumetric
- level
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000010438 heat treatment Methods 0.000 title claims description 42
- 239000003546 flue gas Substances 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 10
- 239000000571 coke Substances 0.000 title claims 4
- 239000007789 gas Substances 0.000 claims description 32
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 15
- 238000002485 combustion reaction Methods 0.000 claims description 15
- 239000011230 binding agent Substances 0.000 claims description 5
- 206010022000 influenza Diseases 0.000 claims 2
- 238000004939 coking Methods 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B21/00—Heating of coke ovens with combustible gases
- C10B21/10—Regulating and controlling the combustion
- C10B21/18—Recirculating the flue gases
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B21/00—Heating of coke ovens with combustible gases
- C10B21/20—Methods of heating ovens of the chamber oven type
Definitions
- the invention relates to a method for reducing the NO x content in the flue gas when heating coking ovens with paired heating trains, high and low combustion stages and a flue gas recirculation at the level of the heating flue (circulating current).
- the invention further relates to a coking oven for performing this method.
- the known measures for reducing the formation of No x are aimed at reducing the flame temperature through flue gas recirculation or at reducing the oxygen and nitrogen concentrations through partial combustion.
- Flue gas is mixed into the air and heating gas flow through one or two openings in every second truss wall at the level of the heating mantle, primarily by reducing the maximum flame temperature, but also by reducing the O Z and N 2 concentration the NO x production rates.
- the NO x reduction principle of partial combustion is used in coking ovens in the form of step heating.
- a preferred combination with regard to minimal NO x emission provides that the circulating current rate is set between 35% and 45% and the step ratio between 50% and 65% and that the second combustion stage is arranged between 40% and 50% of the heating draft.
- a coking furnace which is characterized in that the secondary air supply and the secondary lean gas supply to the second, high-lying combustion stages are arranged exclusively within the binder walls delimiting the heating train pairs, the secondary air supply and the secondary lean gas supply open into the neighboring heating trains on both sides of the truss walls and at the same height.
- the path of the flue gases leads from the flamed heating cable 2 via the reversal point 15 (part via the differential channel 16) into the non-flaming heating cable 2a and via the nozzles and channels 4a, 3a, 6a, 5a, 1 Oa, 9a, 12a, 11 a in the exhaust gas regenerators (not shown).
- FIGS. 1 and 2 the direction of flow of the media is indicated by arrows for both low and high gas operation. In the case of lean gas operation, however, no heavy gas flows, while in the case of heavy gas operation the lean gas ducts carry combustion air.
- a heater pair 1 is laterally delimited by the rotor walls 17 and the binder walls 18 passing through the channels 9 and 11.
- the heating pair 1 is divided into the heating trains 2 and 2a by the binder wall 19 which is penetrated by the reversal point 15 and the circulating current opening 13 becomes.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3443976 | 1984-12-01 | ||
DE19843443976 DE3443976A1 (de) | 1984-12-01 | 1984-12-01 | Verfahren zur verringerung des no(pfeil abwaerts)x(pfeil abwaerts)-gehaltes im rauchgas bei der beheizung von verkokungsoefen und verkokungsofen zur durchfuehrung des verfahrens |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0183908A1 EP0183908A1 (de) | 1986-06-11 |
EP0183908B1 true EP0183908B1 (de) | 1988-08-03 |
Family
ID=6251728
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85108019A Expired EP0183908B1 (de) | 1984-12-01 | 1985-06-28 | Verfahren zur Verringerung des NOx-Gehaltes im Rauchgas bei der Beheizung von Verkokungsöfen und Verkokungsofen zur Durchführung des Verfahrens |
Country Status (4)
Country | Link |
---|---|
US (1) | US4704195A (enrdf_load_stackoverflow) |
EP (1) | EP0183908B1 (enrdf_load_stackoverflow) |
JP (1) | JPH0778220B2 (enrdf_load_stackoverflow) |
DE (2) | DE3443976A1 (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10222973B2 (en) | 2014-05-30 | 2019-03-05 | Sonova Ag | Method for controlling a hearing device via touch gestures, a touch gesture controllable hearing device and a method for fitting a touch gesture controllable hearing device |
Families Citing this family (61)
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DE3807926A1 (de) * | 1988-03-10 | 1989-09-21 | Hoelter Heinz | Verfahren zur schadstoffarmen beheizung von koksoefen und koksofen zur durchfuehrung des verfahrens |
DE3812558C2 (de) * | 1988-04-15 | 2001-02-22 | Krupp Koppers Gmbh | Verfahren zur Verringerung des NO¶x¶-Gehaltes im Rauchgas bei der Beheizung von Verkokungsöfen |
DE3822029A1 (de) * | 1988-06-30 | 1990-01-04 | Still Otto Gmbh | Gaszufuehrung in verkokungsoefen |
DE3841630A1 (de) * | 1988-12-10 | 1990-06-13 | Krupp Koppers Gmbh | Verfahren zur verringerung des no(pfeil abwaerts)x(pfeil abwaerts)-gehaltes im abgas bei der beheizung von starkgas- oder verbundkoksoefen und koksofenbatterie zur durchfuehrung des verfahrens |
US5259932A (en) * | 1989-05-26 | 1993-11-09 | Didier Ofu Engineering Gmbh | Heating system for regenerative coke ovens |
DE4006217A1 (de) * | 1989-05-26 | 1990-11-29 | Didier Ofu Eng | Beheizungssystem fuer regenerativverkokungsoefen |
DE60014213T2 (de) | 1999-03-04 | 2006-03-02 | The Japan Iron And Steel Federation | Koksofen und Verfahren zum Betrieb desselben |
US6596128B2 (en) | 2001-02-14 | 2003-07-22 | Sun Coke Company | Coke oven flue gas sharing |
JP4767730B2 (ja) * | 2006-03-22 | 2011-09-07 | 新日本製鐵株式会社 | コークス炉の操業方法 |
KR101259185B1 (ko) * | 2006-12-19 | 2013-04-29 | 주식회사 포스코 | 연료가스 우회로가 구비된 코크스 오븐의 연소실 |
KR101259216B1 (ko) | 2006-12-19 | 2013-04-29 | 주식회사 포스코 | 일체형 연료가스 우회로가 구비된 코크스 오븐의 연소실 |
US7998316B2 (en) | 2009-03-17 | 2011-08-16 | Suncoke Technology And Development Corp. | Flat push coke wet quenching apparatus and process |
US9200225B2 (en) | 2010-08-03 | 2015-12-01 | Suncoke Technology And Development Llc. | Method and apparatus for compacting coal for a coal coking process |
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US9169439B2 (en) | 2012-08-29 | 2015-10-27 | Suncoke Technology And Development Llc | Method and apparatus for testing coal coking properties |
WO2014046701A1 (en) | 2012-09-21 | 2014-03-27 | Suncoke Technology And Development Llc. | Reduced output rate coke oven operation with gas sharing providing extended process cycle |
US9238778B2 (en) | 2012-12-28 | 2016-01-19 | Suncoke Technology And Development Llc. | Systems and methods for improving quenched coke recovery |
US9476547B2 (en) | 2012-12-28 | 2016-10-25 | Suncoke Technology And Development Llc | Exhaust flow modifier, duct intersection incorporating the same, and methods therefor |
US10760002B2 (en) | 2012-12-28 | 2020-09-01 | Suncoke Technology And Development Llc | Systems and methods for maintaining a hot car in a coke plant |
US10047295B2 (en) | 2012-12-28 | 2018-08-14 | Suncoke Technology And Development Llc | Non-perpendicular connections between coke oven uptakes and a hot common tunnel, and associated systems and methods |
US9273249B2 (en) | 2012-12-28 | 2016-03-01 | Suncoke Technology And Development Llc. | Systems and methods for controlling air distribution in a coke oven |
US10016714B2 (en) | 2012-12-28 | 2018-07-10 | Suncoke Technology And Development Llc | Systems and methods for removing mercury from emissions |
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US10883051B2 (en) | 2012-12-28 | 2021-01-05 | Suncoke Technology And Development Llc | Methods and systems for improved coke quenching |
US9193915B2 (en) | 2013-03-14 | 2015-11-24 | Suncoke Technology And Development Llc. | Horizontal heat recovery coke ovens having monolith crowns |
US9273250B2 (en) | 2013-03-15 | 2016-03-01 | Suncoke Technology And Development Llc. | Methods and systems for improved quench tower design |
US10619101B2 (en) | 2013-12-31 | 2020-04-14 | Suncoke Technology And Development Llc | Methods for decarbonizing coking ovens, and associated systems and devices |
CN106661456A (zh) | 2014-06-30 | 2017-05-10 | 太阳焦炭科技和发展有限责任公司 | 具有整体式冠的水平热回收焦炉 |
CA2959367C (en) | 2014-08-28 | 2018-02-20 | John Francis Quanci | Coke oven charging system |
JP2017526798A (ja) | 2014-09-15 | 2017-09-14 | サンコーク テクノロジー アンド ディベロップメント リミテッド ライアビリティ カンパニー | モノリス構成要素構造を有するコークス炉 |
US10968395B2 (en) | 2014-12-31 | 2021-04-06 | Suncoke Technology And Development Llc | Multi-modal beds of coking material |
US11060032B2 (en) | 2015-01-02 | 2021-07-13 | Suncoke Technology And Development Llc | Integrated coke plant automation and optimization using advanced control and optimization techniques |
KR102531894B1 (ko) | 2015-01-02 | 2023-05-11 | 선코크 테크놀러지 앤드 디벨로프먼트 엘엘씨 | 고급 제어 및 최적화 기술을 이용한 통합형 코크스 플랜트 자동화 및 최적화 |
UA125640C2 (uk) | 2015-12-28 | 2022-05-11 | Санкоук Текнолоджі Енд Дівелепмент Ллк | Спосіб і система динамічного завантаження коксової печі |
CN105885876B (zh) * | 2016-05-09 | 2018-11-02 | 大连迈泰克科技开发有限公司 | 前端治理的低nox排放浓度的节能环保型炼焦工艺方法 |
CN105802639A (zh) * | 2016-05-10 | 2016-07-27 | 中冶焦耐工程技术有限公司 | 一种干熄炉放散气处理方法 |
MX387575B (es) | 2016-06-03 | 2025-03-18 | Suncoke Tech & Development Llc | Métodos y sistemas para generar automaticamente una acción correctiva en una instalación industrial. |
CN110832055B (zh) | 2017-05-23 | 2023-02-03 | 太阳焦炭科技和发展有限责任公司 | 用于修补炼焦炉的系统和方法 |
DE102017216437A1 (de) | 2017-09-15 | 2019-03-21 | Thyssenkrupp Ag | Koksofenvorrichtung mit exzentrischen Einlässen zum Herstellen von Koks und Verfahren zum Betreiben der Koksofenvorrichtung sowie Steuerungseinrichtung und Verwendung |
DE102017216439A1 (de) | 2017-09-15 | 2019-03-21 | Thyssenkrupp Ag | Koksofenvorrichtung mit umströmtem Kreisstrompfad zum Herstellen von Koks und Verfahren zum Betreiben der Koksofenvorrichtung sowie Steuerungseinrichtung und Verwendung |
DE102017216436A1 (de) | 2017-09-15 | 2019-03-21 | Thyssenkrupp Ag | Koksofenvorrichtung mit zentrischer Rezirkulation zum Herstellen von Koks und Verfahren zum Betreiben der Koksofenvorrichtung sowie Steuerungseinrichtung und Verwendung |
TWI681048B (zh) * | 2017-09-15 | 2020-01-01 | 德商蒂森克虜伯工業解決方案股份有限公司 | 用於生產焦炭的包含具圍繞其之環繞流動之環形流動路徑的焦爐裝置、焦爐裝置的操作方法及其控制裝置與用途 |
US11760937B2 (en) | 2018-12-28 | 2023-09-19 | Suncoke Technology And Development Llc | Oven uptakes |
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CA3211286A1 (en) | 2021-11-04 | 2023-05-11 | John Francis Quanci | Foundry coke products, and associated systems, devices, and methods |
US11946108B2 (en) | 2021-11-04 | 2024-04-02 | Suncoke Technology And Development Llc | Foundry coke products and associated processing methods via cupolas |
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Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2746913A (en) * | 1954-09-01 | 1956-05-22 | Koppers Co Inc | Rich gas nozzle for regenerative coke oven with recirculation heating |
DE1147559B (de) * | 1956-07-02 | 1963-04-25 | Otto & Co Gmbh Dr C | Waagerechter Kammerofen zur Erzeugung von Koks und Gas |
US3192127A (en) * | 1961-04-13 | 1965-06-29 | Koppers Co Inc | Coking retort oven firing method |
DE1571657B2 (de) * | 1966-09-13 | 1973-04-26 | Heinrich Koppers Gmbh, 4300 Essen | Regenerativkoksofenbatterie |
DE1671311A1 (de) * | 1966-12-17 | 1969-12-04 | Gvi Projektirowaniju Predprija | Koksofenbatterie |
DE1936023A1 (de) * | 1969-07-16 | 1971-02-04 | Koppers Gmbh Heinrich | Vorrichtung zum vollstaendigen oder teilweisen Schliessen der Gasdurchtrittsoeffnungen in den Heizwaenden von Verkokungskammeroefen |
BE790985A (fr) * | 1971-12-11 | 1973-03-01 | Koppers Gmbh Heinrich | Procede pour l'uniformisation du chauffage des fours a coke a chambre horizontale et installation pour la pratique du |
DE2420121B2 (de) * | 1974-04-25 | 1976-04-22 | Rohrbach, Rudolf, 7461 Dotternhausen | Verfahren und anlage zur herstellung von zementklinker |
DE2427032B2 (de) * | 1974-06-05 | 1978-06-29 | Dr. C. Otto & Co Gmbh, 4630 Bochum | Batterieweise angeordneter, regenerativ mit Schwachgas beheizbarer Verkokungsofen |
CA1097487A (en) * | 1976-04-20 | 1981-03-17 | David W. Turner | Method and apparatus for reducing no.sub.x emission to the atmosphere |
US4216060A (en) * | 1978-05-10 | 1980-08-05 | Mitsubishi Kasei Kogyo Kabushiki Kaisha | Horizontal type coke ovens |
IN154973B (enrdf_load_stackoverflow) * | 1981-04-09 | 1984-12-22 | Otto & Co Gmbh Dr C | |
US4405587A (en) * | 1982-02-16 | 1983-09-20 | Mcgill Incorporated | Process for reduction of oxides of nitrogen |
-
1984
- 1984-12-01 DE DE19843443976 patent/DE3443976A1/de active Granted
-
1985
- 1985-06-28 EP EP85108019A patent/EP0183908B1/de not_active Expired
- 1985-06-28 DE DE8585108019T patent/DE3564130D1/de not_active Expired
- 1985-11-08 US US06/796,582 patent/US4704195A/en not_active Expired - Lifetime
- 1985-11-29 JP JP60267628A patent/JPH0778220B2/ja not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10222973B2 (en) | 2014-05-30 | 2019-03-05 | Sonova Ag | Method for controlling a hearing device via touch gestures, a touch gesture controllable hearing device and a method for fitting a touch gesture controllable hearing device |
Also Published As
Publication number | Publication date |
---|---|
US4704195A (en) | 1987-11-03 |
EP0183908A1 (de) | 1986-06-11 |
JPS61133286A (ja) | 1986-06-20 |
DE3443976C2 (enrdf_load_stackoverflow) | 1993-04-22 |
JPH0778220B2 (ja) | 1995-08-23 |
DE3443976A1 (de) | 1986-06-12 |
DE3564130D1 (en) | 1988-09-08 |
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