EP0151402B1 - Spinnpräparation für das Schmelzspinnen von synthetischen Fasermaterialien - Google Patents

Spinnpräparation für das Schmelzspinnen von synthetischen Fasermaterialien Download PDF

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Publication number
EP0151402B1
EP0151402B1 EP85100312A EP85100312A EP0151402B1 EP 0151402 B1 EP0151402 B1 EP 0151402B1 EP 85100312 A EP85100312 A EP 85100312A EP 85100312 A EP85100312 A EP 85100312A EP 0151402 B1 EP0151402 B1 EP 0151402B1
Authority
EP
European Patent Office
Prior art keywords
weight
spinning
melt spinning
agents
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP85100312A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0151402A3 (en
EP0151402A2 (de
Inventor
Albert Dr. Löwenstein
Heidi Fiedler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AT85100312T priority Critical patent/ATE51651T1/de
Publication of EP0151402A2 publication Critical patent/EP0151402A2/de
Publication of EP0151402A3 publication Critical patent/EP0151402A3/de
Application granted granted Critical
Publication of EP0151402B1 publication Critical patent/EP0151402B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11—Compounds containing epoxy groups or precursors thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

  • the multifilament threads are wound onto the spinning bobbin without rotation.
  • the individual capillaries are present as a parallel bundle of threads, the cohesion of the individual capillaries only being brought about by the more or less pronounced adhesive effect of the spin preparation.
  • these yarns are usually given a protective twist of a few turns per meter.
  • this protective twist is not sufficient for many subsequent processing processes.
  • the spin finishes used hitherto contain additives such as sarcosides or higher-viscosity polymers such as polyisobutylene as thread-closing agents.
  • substances of this type are able to improve the thread-closing effect of spin finishes by increasing the adhesive forces between the individual capillaries.
  • this only conveys a temporary thread closure, because these substances in the first wet process - e.g. when dyeing - to be washed out again.
  • Another disadvantage that many of these thread closure agents have is their inadequate thermal stability. This severely limits their use for spin finishes intended for texturing or for technical yarns that have to go through a hot stretching process.
  • the invention relates to spin finishes for the melt spinning of synthetic fiber materials based on smoothing agents, emulsifiers, wetting agents, antistatic agents and optionally other additives, characterized by a content of 1-30, preferably 5-15% by weight, on a C O. - -C 24 epoxy alkyl compound.
  • the invention further relates to a method for achieving permanent thread closure during melt spinning of synthetic fiber materials, the claimed spin finish being applied to the fiber material in an amount of 0.3-2.0% by weight and then being heated to 150-250 ° degrees .
  • the Cg-C 24 -epoxyalkyl compounds mentioned are derived from unsaturated Cg-C 24 -alkyl radicals containing fatty acids, fatty alcohols, fatty acid esters or olefins.
  • the introduction of one or more epoxy groups is carried out according to known methods, for. B. by reacting the compounds containing at least one carbon double bond in the alkyl radical with hydrogen peroxide in the presence of formic acid.
  • Preferred products are the epoxidation products of unsaturated C 12 ⁇ C 18 .
  • Suitable products are the epoxidation products of oleic acid methyl ester, soybean oil fatty acid methyl ester, soybean oil, mixtures of unsaturated C 12 -C 18 fatty alcohols, 1,2-hexadecene, and the like.
  • Common smoothing agents are mineral oils, fatty acid esters and alkylene oxide adducts or polymers.
  • Suitable emulsifiers, wetting agents and antistatic agents are anionic and nonionic surfactants, such as ethylene oxide adducts with higher fatty alcohols, alkylphenols or other fatty substances, triethanolamine soaps, alkanesulfonates, phosphoric acid esters and the like.
  • the treated threads are subjected to heat treatment, using temperatures of 150-250 ° C., preferably 150-230 ° C. This thermal aftertreatment, which is a prerequisite for the occurrence of the thread closure effect, can be carried out immediately after application of the preparation or at a later point in time in a separate operation.
  • the preparations are sufficiently stable over longer periods.
  • the method is suitable for achieving a permanent, temperature- and wash-resistant thread closure effect in the production of textile yarns, technical yarns or BCF (bulked continuous filament) yarns made of polyamide (PA), polyester (PES) or polyolefin, e.g. B. Polypropylene (PP).
  • PA polyamide
  • PET polyester
  • PP polyolefin
  • changes in the usual course of the process are not necessary.
  • the spin finishes given below were applied as 10-25% aqueous emulsions immediately after the melt spinning process on various fiber materials.
  • the application was carried out by means of application rollers in an amount of 0.5-1.3% by weight, based on the anhydrous preparation. Following the order, thermal fixation was carried out by heating to 150-230 ° C.
  • the preparation of Example 7 contained no epoxy compound and served as a comparison substance.
  • the thread closure effect was tested in the following way: The thread to be tested is clamped vertically in a holding device. The total length of the thread is 50 cm. The lower end of the thread is loaded with a weight of 5.7 g / tex (5.6 CN / tex). The thread is cut at 40 cm thread length with sharp scissors.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
  • Artificial Filaments (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
EP85100312A 1984-01-23 1985-01-14 Spinnpräparation für das Schmelzspinnen von synthetischen Fasermaterialien Expired - Lifetime EP0151402B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT85100312T ATE51651T1 (de) 1984-01-23 1985-01-14 Spinnpraeparation fuer das schmelzspinnen von synthetischen fasermaterialien.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3402155 1984-01-23
DE19843402155 DE3402155A1 (de) 1984-01-23 1984-01-23 Spinnpraeparation fuer das schmelzspinnen von synthetischen fasermaterialien

Publications (3)

Publication Number Publication Date
EP0151402A2 EP0151402A2 (de) 1985-08-14
EP0151402A3 EP0151402A3 (en) 1988-03-23
EP0151402B1 true EP0151402B1 (de) 1990-04-04

Family

ID=6225637

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85100312A Expired - Lifetime EP0151402B1 (de) 1984-01-23 1985-01-14 Spinnpräparation für das Schmelzspinnen von synthetischen Fasermaterialien

Country Status (10)

Country Link
US (2) US4654153A (xx)
EP (1) EP0151402B1 (xx)
JP (1) JPS60155774A (xx)
AT (1) ATE51651T1 (xx)
BR (1) BR8500268A (xx)
DE (2) DE3402155A1 (xx)
ES (1) ES8605874A1 (xx)
MX (1) MX161543A (xx)
TR (1) TR22796A (xx)
ZA (1) ZA85503B (xx)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3830468A1 (de) * 1988-09-08 1990-03-15 Henkel Kgaa Polyurethanhaltige spinnpraeparationen
US5263308A (en) * 1992-02-28 1993-11-23 E. I. Du Pont De Nemours And Company Method for ply-twisting yarns having low levels of finish
JP2882718B2 (ja) * 1992-07-30 1999-04-12 旭化成工業株式会社 合成繊維の製造方法
US5464546A (en) * 1994-06-16 1995-11-07 Henkel Kommanditgesellschaft Auf Aktien Thermally stable textile lubricants
US5478485A (en) * 1994-06-16 1995-12-26 Henkel Kommanditgesellschaft Auf Aktien Thermally stable textile lubricants
US5840280A (en) * 1996-05-30 1998-11-24 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Silicone copolyol formulated hairspray compositions
CN101307564B (zh) * 2008-04-09 2011-04-20 张金惠 涤纶短纤维双组份组合油剂及制备方法
CN103174021B (zh) * 2013-03-20 2014-11-19 常州市灵达化学品有限公司 一种环境友好型腈纶油剂

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2774774A (en) * 1954-03-26 1956-12-18 Fmc Corp In situ epoxidation of oleic acid using formic acid
JPS5025893A (xx) * 1973-07-16 1975-03-18
JPS5234100A (en) * 1975-09-08 1977-03-15 Unitika Ltd Production of nonconductile canvas
JPS5331898A (en) * 1976-08-31 1978-03-25 Toyo Boseki Oil agent for processing polyester fiber
JPS5413527A (en) * 1977-07-02 1979-02-01 Naoyuki Koga Method of making tokobashira piller
JPS5430997A (en) * 1977-08-12 1979-03-07 Kao Corp Lubricating composition for treating synthetic fiber
US4199647A (en) * 1977-11-30 1980-04-22 Basf Wyandotte Corporation Fiber lubricants derived from polyethoxylated and polyoxyalkylated reaction products of an alpha-olefin epoxide and a fatty alcohol
US4371658A (en) * 1980-05-05 1983-02-01 Allied Corporation Polyamide yarn spin finish containing a glyceride and oxidized polyethylene
DD150913A1 (de) * 1980-05-22 1981-09-23 Juergen Peschel Gleitmittel
JPS5789668A (en) * 1980-11-19 1982-06-04 Unitika Ltd Production of polyester fiber having good adhesiveness with rubbers
US4356219A (en) * 1980-12-03 1982-10-26 The Goodyear Tire & Rubber Company Treated yarn, method of preparation and rubber/cord composite
US4348517A (en) * 1980-12-09 1982-09-07 Allied Chemical Corporation Process and finish composition for producing adhesive active polyester yarn
JPS57128271A (en) * 1981-01-29 1982-08-09 Unitika Ltd Production of polyester fiber with good adhesiveness with rubbers
JPS57171714A (en) * 1981-04-16 1982-10-22 Teijin Ltd Surface modified synthetic fiber having low friction
JPS5865067A (ja) * 1981-10-08 1983-04-18 東レ株式会社 繊維処理剤
US4517245A (en) * 1984-01-26 1985-05-14 Hitco Non-ionic epoxy resin emulsion finishes for carbon fibers

Also Published As

Publication number Publication date
ES8605874A1 (es) 1986-04-01
DE3576974D1 (de) 1990-05-10
DE3402155A1 (de) 1985-07-25
EP0151402A3 (en) 1988-03-23
US4871592A (en) 1989-10-03
ATE51651T1 (de) 1990-04-15
US4654153A (en) 1987-03-31
MX161543A (es) 1990-10-25
BR8500268A (pt) 1985-09-03
JPS60155774A (ja) 1985-08-15
ZA85503B (en) 1985-09-25
ES539729A0 (es) 1986-04-01
EP0151402A2 (de) 1985-08-14
TR22796A (tr) 1988-07-19

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