EP0111897A1 - Procédé pour le traitement de surfaces métalliques, en particulier de celles en aluminium, en alliages d'aluminium et en acier, ainsi que solutions de bain aqueuses appropriées à cet effet - Google Patents
Procédé pour le traitement de surfaces métalliques, en particulier de celles en aluminium, en alliages d'aluminium et en acier, ainsi que solutions de bain aqueuses appropriées à cet effet Download PDFInfo
- Publication number
- EP0111897A1 EP0111897A1 EP83112610A EP83112610A EP0111897A1 EP 0111897 A1 EP0111897 A1 EP 0111897A1 EP 83112610 A EP83112610 A EP 83112610A EP 83112610 A EP83112610 A EP 83112610A EP 0111897 A1 EP0111897 A1 EP 0111897A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ions
- bath solution
- chromium
- water
- iii
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 40
- 239000002184 metal Substances 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 30
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 7
- 229910000831 Steel Inorganic materials 0.000 title claims abstract 4
- 239000010959 steel Substances 0.000 title claims abstract 4
- 239000004411 aluminium Substances 0.000 title 1
- -1 chromium (III) ions Chemical class 0.000 claims abstract description 29
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 14
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 4
- 229920001577 copolymer Polymers 0.000 claims abstract description 4
- 229920000642 polymer Polymers 0.000 claims abstract description 4
- 239000008199 coating composition Substances 0.000 claims abstract description 3
- 239000000470 constituent Substances 0.000 claims abstract description 3
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims description 12
- 229920002125 Sokalan® Polymers 0.000 claims description 7
- 229920001519 homopolymer Polymers 0.000 claims 1
- 239000000243 solution Substances 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000011651 chromium Substances 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000004584 polyacrylic acid Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000010960 cold rolled steel Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000008237 rinsing water Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910021564 Chromium(III) fluoride Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- UJRBOEBOIXOEQK-UHFFFAOYSA-N oxo(oxochromiooxy)chromium hydrate Chemical compound O.O=[Cr]O[Cr]=O UJRBOEBOIXOEQK-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- FTBATIJJKIIOTP-UHFFFAOYSA-K trifluorochromium Chemical compound F[Cr](F)F FTBATIJJKIIOTP-UHFFFAOYSA-K 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium
Definitions
- the invention relates to the preparation of cleaned metal surfaces, in particular of strips made of aluminum, aluminum alloys and cold-rolled steel - but also other metal surfaces - for a subsequent coating with organic coatings, with particular attention being paid to the production of metal goods for the food packaging sector.
- the metal surface is cleaned from vl, dirt and other residues in a first stage. Any residues of chemicals from this first stage are removed by rinsing with water.
- the clean metal surface is wetted with an aqueous bath solution which is no longer rinsed off, but on the contrary is dried in situ on the metal surface and converted there into a solid film of the bath components.
- Such coatings can substantially improve the surface quality, in particular with regard to corrosion protection and adhesion of subsequently applied corner layers.
- Treatment solutions containing hexavalent chromium were originally often proposed in the extensive pertinent printed prior art. Because of the toxic nature of this combination, these processes and the rinsing water that they require require elaborate wastewater treatment.
- treatment solutions which contain v-valent chromium and trivalent chromium salts together with film formers are described, for example, in DE-AS 17 69 582 and in DE-OS 29 03 311.
- aicalisate is to be used as the inorganic film former.
- the second reference uses polyacrylic acid as an organic film former. Due to the content of 6-valent chromium in the aqueous building fluids, these materials are not suitable for use in the food sector.
- the present invention is based on the object of creating a “ n o rinse” method of the type described at the outset or suitable treatment agents which do not have the disadvantages known hitherto for materials of this type and in particular for use in the sector of Food packaging are suitable.
- the process according to the invention is intended to produce a glossy, optically appealing finish layer on the metal surface which, for example in the subsequent overcoats with clear lacquers, meets the aesthetic requirements which are particularly desired in the field of food packaging.
- the invention relates in a first embodiment to a method for treating metal surfaces, in particular for a subsequent coating with organic-based coating compositions, this method being characterized in that the metal surface is wetted with an aqueous bath solution which contains chromium (III) Ions, fluoride ions and a water-soluble or homogeneously dispersible organic film former.
- the material applied to the metal surface is dried on the metal surface without an intermediate rinsing process and converted into a water-insoluble film by heating.
- the invention relates to the aqueous treatment solutions suitable for this process, which are described in detail below.
- the method according to the invention is suitable for the surface treatment of all metals relevant here, in particular therefore ferrous metals, aluminum or aluminum alloys, zinc and / or magnesium.
- the invention is particularly suitable for the pretreatment of strips made of aluminum or aluminum alloys and cold-rolled steel for their subsequent use in the food packaging sector.
- the bath solution for surface treatment additionally contains phosphate ions.
- Aqueous bac solutions are suitable for the process according to the invention, the active ingredient components of which lie within the following concentration ranges: 0.5 to 10 g / l chromium (III) ions, 0.55 to 11 g / 1 fluoride ions, 0.6 to 12.5 g / l phosphate ions and 0.15 to 5 g / l of the organic film former.
- a conventionally cleaned and rinsed metal surface for example the surface of strips of the aforementioned metals, is squeezed in any way with the aqueous treatment solution after squeezing off the water film in such a way that expediently about 2 to 20 ml per square meter of the area , preferably about 3 to 7 ml of the aqueous treatment solution are applied.
- the content of the aforementioned active constituents of the aqueous treatment solution should continue to be per square meter of the metal surface within the following ranges: 5 to 100 mg of chromium (III) ions, 5.5 to 110 mg of fluoride ions and 6 to 125 mg of phosphate ions, and about 1 , 5 to 35 mg of the organic water-soluble or homogeneously water-dispersible film oil.
- the applied liquid film is allowed to act on the metal surface for a reaction time of about 1 to 10 seconds, whereupon the film is dried and thermally treated at an elevated temperature.
- a deformable water-insoluble solid film remains on the metal surface with a mass per unit area of about 18 to 370 mg / m 2 , preferably of about 50 to 250 mg / m 2, of the metal surface.
- the drying and / or the thermal treatment of the liquid liquid applied or the chemicals applied with it can be carried out in particular in the temperature range from about 50 to 300 ° C.
- Chromium (III) ions and fluorine ions are most easily introduced into the bath using chromium (III) fluoride, although the ratio of chromium (III) ions: fluoride ions is in the range from 1: 2.5 to 3.5 can fluctuate.
- the phosphate content is adjusted by adding phosphates or phosphoric acid with subsequent partial neutralization. It applies that the phosphate content based on 1 mol of chromium (III) ions is preferably in a molar ratio of 0.3 to 3.0.
- the organic film former is expediently a synthetic polymer with a sufficient content of free carboxyl groups which ensure its water solubility or homogeneous dispersibility in water.
- polymers of acrylic acid and / or methacrylic acid which may also contain limited amounts of copolymers and the corresponding ones May contain esters, nitriles and / or amides.
- Preferred organic film formers are clearly soluble polyacrylic acids, which retain their clear solubility, in particular in the pli range of the aqueous treatment baths - which is usually between about 2 and 3.
- these are polyacrylic acids of a molecular weight which is not too high, for example those with molecular weights of up to about 150,000, preferably up to about 100,000.
- aqueous treatment solutions according to the invention can be applied to the pre-cleaned metal strips in any type of application which is suitable for producing a uniform, defined liquid film in the specified quantity ranges on the metal surface.
- the roller application method with two or three rollers has proven successful, but also wetting of the strip by spraying or dipping with subsequent squeezing off of the excess liquid film by, for example, plastic-coated leveling rollers or adjustable air doctor blades can be used.
- Both acidic and alkaline cleaners are suitable for the cleaning pretreatment of the metal surfaces to be wetted according to the invention.
- the layers obtained with the aqueous treatment solution according to the invention provide a uniform, glossy finish without discoloration of the base material.
- suitable organic coatings applied below they meet the requirements for the food packaging sector.
- aluminum strip of the alloy AlMg 5 was first cleaned and degreased by spraying.
- an acidic solution was used with a content of 1 g / l H 2 SO 4 , 0.2 g / l HF and 1 g / l surfactant combination.
- the cleaning was conducted at a temperature-r ature of 60 ° C, 8 seconds, and performed at an injection pressure of 1.5 bar.
- the belt was then rinsed with warm demineralized water and the rinsing water squeezed out.
- a liquid film with a surface area of 5 ml / m 2 was then applied with the solution according to the invention by means of a roller application process, whereby the surface per m 2 is covered with a liquid film containing 25 mg Cr 3+ , 27.5 mg F, 31.3 mg PO 4 and 8.75 mg of polyacrylic acid ("Acrylsol A1" from Röhm & Haas, Philadelphia, USA).
- the water contained in the liquid film was dusted off in a floating dryer with a circulating air temperature of 100 ° C. and a metal object temperature of approx. 50 ° C., and a water-insoluble film of 92.5 mg / m 2 was obtained on the metal surface.
- This tape which was chemically pretreated and lacquered using no-rinse technology, was processed into lids for beverage sockets and, in comparison with lids with conversion layers that were customary to date, was subjected to the tests specific to beverage cans.
- the speeds of rotation of the chemcoater rolls were adjusted so that a liquid film of 8 ml / m 2 of belt surface was applied to a cleaned and water-rinsed aluminum belt at a belt speed of 100 m / minute by means of the application rollers of the chemcoater.
- the tape was wetted with a liquid film, which contains 40 mg Cr 3+ , 44 mg F - , 50 mg PO 4 and 14 mg ' polyacrylic acid 100% strength per m 2 of surface and, after drying, a mass per unit area of 148 mg / m 2 on the aluminum.
- the W was as- se ranteil of the liquid withdrawn from the film by means of hot air dryer and then heated the BAHD to an object temperature of 200 C. After cooling, the film obtained on the tape was wetted with 8 to 10 mg of dioctyl sebacate to improve the sliding property.
- the chemically pretreated aluminum surface thus obtained was coated with varnishes suitable for the food sector and tested for its resistance to filling goods and forming behavior. In all tests, technological values were found which, in comparison to conventional solutions and methods, achieved results which were at least equivalent, and in some cases even better, with the methods according to the invention.
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coating With Molten Metal (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Manufacturing Of Steel Electrode Plates (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT83112610T ATE23573T1 (de) | 1982-12-23 | 1983-12-15 | Verfahren zur behandlung von metalloberflaechen, insbesondere solchen von aluminium, aluminiumlegierungen und stahl, sowie hierfuer geeignete waessrige badloesungen. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3247729 | 1982-12-23 | ||
| DE19823247729 DE3247729A1 (de) | 1982-12-23 | 1982-12-23 | Verfahren zur behandlung von metalloberflaechen, insbesondere solchen von aluminium, aluminiumlegierungen und stahl, sowie hierfuer geeignete waessrige badloesungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0111897A1 true EP0111897A1 (fr) | 1984-06-27 |
| EP0111897B1 EP0111897B1 (fr) | 1986-11-12 |
Family
ID=6181576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP83112610A Expired EP0111897B1 (fr) | 1982-12-23 | 1983-12-15 | Procédé pour le traitement de surfaces métalliques, en particulier de celles en aluminium, en alliages d'aluminium et en acier, ainsi que solutions de bain aqueuses appropriées à cet effet |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4761189A (fr) |
| EP (1) | EP0111897B1 (fr) |
| JP (1) | JPH076071B2 (fr) |
| AT (1) | ATE23573T1 (fr) |
| AU (1) | AU557724B2 (fr) |
| BR (1) | BR8306981A (fr) |
| CA (1) | CA1219790A (fr) |
| DE (2) | DE3247729A1 (fr) |
| ES (1) | ES528361A0 (fr) |
| GR (1) | GR79449B (fr) |
| MX (1) | MX7298E (fr) |
| NO (1) | NO162623C (fr) |
| ZA (1) | ZA839574B (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996017977A1 (fr) * | 1994-12-09 | 1996-06-13 | Metallgesellschaft Aktiengesellschaft | Procede d'application de revetements de phosphate sur des surfaces metalliques |
| EP3290543A1 (fr) * | 2016-08-31 | 2018-03-07 | AD Productions B.V. | Procé?dé? de traitement de surfaces mé?talliques au moyen d'une composition aqueuse et composition aqueuse |
| WO2021233715A1 (fr) * | 2020-05-19 | 2021-11-25 | Rhodia Operations | Polymères pour traitement de surface métallique |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6096772A (ja) * | 1983-10-31 | 1985-05-30 | Nippon Parkerizing Co Ltd | アルミニウム合金における化成処理の前処理方法 |
| JPS61136685A (ja) * | 1984-12-07 | 1986-06-24 | Nippon Light Metal Co Ltd | 親水性耐食皮膜を形成する方法 |
| NO168953C (no) * | 1986-08-27 | 1992-04-22 | Elektro Brite Gmbh | Surt kromholdig passiveringsbad for sink- eller kadmiumoverflater |
| JP3239312B2 (ja) * | 1994-03-31 | 2001-12-17 | 川崎製鉄株式会社 | 耐食性に優れた電気絶縁被膜を有する電磁鋼板 |
| DE4412138A1 (de) * | 1994-04-08 | 1995-10-12 | Henkel Kgaa | Chromfreies Verfahren zur No-Rinse Behandlung von Aluminium und seinen Legierungen sowie hierfür geeignete wäßrige Badlösungen |
| ES2102313B1 (es) * | 1994-07-29 | 1998-04-01 | Procoat S L | Composicion anticorrosiva exenta de cromo hexavalente. |
| US6224657B1 (en) | 1998-10-13 | 2001-05-01 | Sermatech International, Inc. | Hexavalent chromium-free phosphate-bonded coatings |
| JP2003147544A (ja) * | 2001-11-07 | 2003-05-21 | Nippon Parkerizing Co Ltd | 亜鉛系メッキ膜の表面処理膜、亜鉛系メッキ膜の表面処理液、及び表面処理方法 |
| PL1984536T3 (pl) * | 2006-02-14 | 2012-09-28 | Henkel Ag & Co Kgaa | Kompozycje i sposoby odpornej na korozję powłoki trójwartościowego chromu do suszenia na miejscu do stosowania na powierzchniach metalicznych |
| JP5690485B2 (ja) * | 2006-05-10 | 2015-03-25 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンＨｅｎｋｅｌ ＡＧ ＆ Ｃｏ．ＫＧａＡ | 金属表面に耐食被膜として用いられる改良された三価クロム含有組成物 |
| US10156016B2 (en) | 2013-03-15 | 2018-12-18 | Henkel Ag & Co. Kgaa | Trivalent chromium-containing composition for aluminum and aluminum alloys |
| DE102014222024A1 (de) | 2014-10-29 | 2016-06-16 | MTU Aero Engines AG | Schlicker und Verfahren zur Herstellung einer Oxidations- und Korrosionsbeständigen Diffusionschicht |
| EP3659716A1 (fr) * | 2018-11-27 | 2020-06-03 | Rhodia Operations | Polymères pour le traitement de surface métallique |
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| DE2903311A1 (de) * | 1978-01-30 | 1979-08-02 | Amchem Prod | Stabile, waessrige zusammensetzungen zur beschichtung von metalloberflaechen und ihre verwendung |
| US4171231A (en) * | 1978-04-27 | 1979-10-16 | R. O. Hull & Company, Inc. | Coating solutions of trivalent chromium for coating zinc surfaces |
| DE3038699A1 (de) * | 1979-12-21 | 1981-07-02 | Rohco Inc., Cleveland, Ohio | Waessrige saure chromatbeschichtungsloesung, verfahren zu ihrer herstellung und ihre verwendung zum beschichten von zink-, zinklegierungs- und cadimiumoberflaechen |
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| DE1769582C3 (de) * | 1967-06-14 | 1979-12-13 | British Chrome & Chemicals Ltd., Stockton-On-Tees (Grossbritannien) | Oberflächenbehandlungsmittel für Metalle, Verfahren zu ihrer Herstellung und ihre Verwendung zum Herstellen korrosionsfester und elektrisch widerstandsfähiger Überzüge |
| JPS5145604A (en) * | 1974-10-17 | 1976-04-19 | Nippon Steel Corp | Seikorono uchibarihoshuji niokeru ronaikankihoho |
| US3989550A (en) * | 1975-04-21 | 1976-11-02 | Amchem Products, Inc. | Method of forming a hydrophilic coating on an aluminum surface |
| JPS5337550A (en) * | 1976-09-20 | 1978-04-06 | Nippon Paint Co Ltd | Surface treating agents for aluminum or aluminum alloy and surface treating process |
| ES452499A1 (es) * | 1976-10-05 | 1978-04-01 | Brugarolas Sa | Procedimiento para colmatar peliculas obtenidas por oxida- cion anodica sobre el aluminio y sus aleaciones. |
| US4131489A (en) * | 1978-03-31 | 1978-12-26 | Amchem Products, Inc. | Chromate conversion composition and method for coating aluminum using low concentrations of chromate, phosphate and fluoride ions |
| US4191596A (en) * | 1978-09-06 | 1980-03-04 | Union Carbide Corporation | Method and compositions for coating aluminum |
| US4349392A (en) * | 1981-05-20 | 1982-09-14 | Occidental Chemical Corporation | Trivalent chromium passivate solution and process |
| US4359345A (en) * | 1981-04-16 | 1982-11-16 | Occidental Chemical Corporation | Trivalent chromium passivate solution and process |
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1982
- 1982-12-23 DE DE19823247729 patent/DE3247729A1/de not_active Withdrawn
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1983
- 1983-11-18 NO NO834243A patent/NO162623C/no unknown
- 1983-11-29 CA CA000442149A patent/CA1219790A/fr not_active Expired
- 1983-12-15 EP EP83112610A patent/EP0111897B1/fr not_active Expired
- 1983-12-15 DE DE8383112610T patent/DE3367629D1/de not_active Expired
- 1983-12-15 AT AT83112610T patent/ATE23573T1/de active
- 1983-12-19 GR GR73277A patent/GR79449B/el unknown
- 1983-12-20 BR BR8306981A patent/BR8306981A/pt not_active IP Right Cessation
- 1983-12-21 AU AU22729/83A patent/AU557724B2/en not_active Ceased
- 1983-12-21 MX MX8310946U patent/MX7298E/es unknown
- 1983-12-22 ZA ZA839574A patent/ZA839574B/xx unknown
- 1983-12-23 JP JP58252417A patent/JPH076071B2/ja not_active Expired - Lifetime
- 1983-12-23 ES ES528361A patent/ES528361A0/es active Granted
-
1987
- 1987-05-20 US US07/053,598 patent/US4761189A/en not_active Expired - Lifetime
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| DE2903311A1 (de) * | 1978-01-30 | 1979-08-02 | Amchem Prod | Stabile, waessrige zusammensetzungen zur beschichtung von metalloberflaechen und ihre verwendung |
| US4171231A (en) * | 1978-04-27 | 1979-10-16 | R. O. Hull & Company, Inc. | Coating solutions of trivalent chromium for coating zinc surfaces |
| DE3038699A1 (de) * | 1979-12-21 | 1981-07-02 | Rohco Inc., Cleveland, Ohio | Waessrige saure chromatbeschichtungsloesung, verfahren zu ihrer herstellung und ihre verwendung zum beschichten von zink-, zinklegierungs- und cadimiumoberflaechen |
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| PATENT ABSTRACTS OF JAPAN, unexamined applications, C Field, Vol. 7, No. 19, 25. Janner 1983 THE PATENT OFFICE JAPANESE GOVERNMENT, Seite 64 C 147 & JP-A-57 174 469 (NITSUSHIN SEIKOU K.K. )(27-10-1982) * |
| PATENT ABSTRACTS OF JAPAN, unexamined applications, C Fields, Vol. 5, No. 180, 19. November 1981 THE PATENT OFFICE JAPANESE GOVERNMENT, Seite 130 C 79 & JP-A-56 105 486 (NIPPON PAINT K.K.) * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996017977A1 (fr) * | 1994-12-09 | 1996-06-13 | Metallgesellschaft Aktiengesellschaft | Procede d'application de revetements de phosphate sur des surfaces metalliques |
| US5904786A (en) * | 1994-12-09 | 1999-05-18 | Metallgesellschaft Aktiengesellschaft | Method of applying phosphate coatings to metal surfaces |
| CN1066207C (zh) * | 1994-12-09 | 2001-05-23 | 金属股份有限公司 | 在金属表面涂覆磷酸盐涂层的方法 |
| EP3290543A1 (fr) * | 2016-08-31 | 2018-03-07 | AD Productions B.V. | Procé?dé? de traitement de surfaces mé?talliques au moyen d'une composition aqueuse et composition aqueuse |
| NL2017398B1 (en) * | 2016-08-31 | 2018-03-08 | Ad Productions B V | Method of treating metal surfaces with an aqueous composition and aqueous composition |
| WO2021233715A1 (fr) * | 2020-05-19 | 2021-11-25 | Rhodia Operations | Polymères pour traitement de surface métallique |
Also Published As
| Publication number | Publication date |
|---|---|
| NO834243L (no) | 1984-06-25 |
| JPS59133373A (ja) | 1984-07-31 |
| DE3247729A1 (de) | 1984-07-05 |
| GR79449B (fr) | 1984-10-30 |
| MX7298E (es) | 1988-04-26 |
| NO162623C (no) | 1990-01-24 |
| CA1219790A (fr) | 1987-03-31 |
| ZA839574B (en) | 1984-08-29 |
| NO162623B (no) | 1989-10-16 |
| BR8306981A (pt) | 1984-07-31 |
| AU2272983A (en) | 1984-06-28 |
| ES8406563A1 (es) | 1984-08-01 |
| ES528361A0 (es) | 1984-08-01 |
| JPH076071B2 (ja) | 1995-01-25 |
| EP0111897B1 (fr) | 1986-11-12 |
| AU557724B2 (en) | 1987-01-08 |
| ATE23573T1 (de) | 1986-11-15 |
| DE3367629D1 (en) | 1987-01-02 |
| US4761189A (en) | 1988-08-02 |
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