EA201290604A1 - Каталитическая система для (со-)тримеризации олефинов, способ (со-)тримеризации олефинов и способ (со-)полимеризации олефиновых олигомеров - Google Patents

Каталитическая система для (со-)тримеризации олефинов, способ (со-)тримеризации олефинов и способ (со-)полимеризации олефиновых олигомеров

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Publication number
EA201290604A1
EA201290604A1 EA201290604A EA201290604A EA201290604A1 EA 201290604 A1 EA201290604 A1 EA 201290604A1 EA 201290604 A EA201290604 A EA 201290604A EA 201290604 A EA201290604 A EA 201290604A EA 201290604 A1 EA201290604 A1 EA 201290604A1
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EA
Eurasian Patent Office
Prior art keywords
trimerization
olefin oligomers
olefins
olefin
polymerization
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EA201290604A
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English (en)
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EA020804B1 (ru
Inventor
Тимур Михайлович ЗИЛЬБЕРШТЕЙН
Максим Владимирович ЛИПСКИХ
Алексей Александрович НОСИКОВ
Георгий Викторович Несын
Original Assignee
ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг"
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Publication of EA201290604A1 publication Critical patent/EA201290604A1/ru
Publication of EA020804B1 publication Critical patent/EA020804B1/ru

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Изобретение относится к области получения полимеров и сополимеров олефиновых олигомеров, полученных по реакции тримеризации олефиновых мономеров. Описан способ, включающий в себя получение олефиновых олигомеров с помощью каталитической системы тримеризации, приготовленной с использованием СВЧ-облучения для активации отдельных компонентов каталитической системы тримеризации. Использование улучшенной таким образом каталитической системы тримеризации с повышенной активностью обеспечивает повышенную эффективность получения олефиновых олигомеров из этилена или других олефиновых мономеров, в том числе при низком давлении этилена. Полученные таким образом олефиновые олигомеры далее полимеризуются или сополимеризуются принятыми в данной области техники способами. Технический эффект - повышение эффективности получения олефиновых олигомеров, используемых затем в реакции полимеризации или сополимеризации.
EA201290604A 2010-01-29 2011-01-28 Каталитическая система для (со)тримеризации олефинов, способ (со)тримеризации олефинов и способ (со)полимеризации олефиновых олигомеров EA020804B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2010103074/04A RU2430116C1 (ru) 2010-01-29 2010-01-29 Способ полимеризации и сополимеризации олефиновых олигомеров
PCT/RU2011/000049 WO2011093748A1 (ru) 2010-01-29 2011-01-28 Каталитическая система и способы (со-)-тримеризации олефинов и (со-)-полимеризации олефиновых олигомеров

Publications (2)

Publication Number Publication Date
EA201290604A1 true EA201290604A1 (ru) 2013-01-30
EA020804B1 EA020804B1 (ru) 2015-01-30

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EA201290604A EA020804B1 (ru) 2010-01-29 2011-01-28 Каталитическая система для (со)тримеризации олефинов, способ (со)тримеризации олефинов и способ (со)полимеризации олефиновых олигомеров

Country Status (12)

Country Link
US (1) US8921251B2 (ru)
EP (1) EP2529832B1 (ru)
JP (1) JP5485415B2 (ru)
KR (1) KR101449636B1 (ru)
CN (1) CN102596408B (ru)
CA (1) CA2770520C (ru)
EA (1) EA020804B1 (ru)
IN (1) IN2012DN01854A (ru)
MX (1) MX339766B (ru)
RU (1) RU2430116C1 (ru)
WO (1) WO2011093748A1 (ru)
ZA (1) ZA201201223B (ru)

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WO2016105227A1 (en) * 2014-12-23 2016-06-30 Public Joint Stock Company "Sibur Holding" Methods of preparing oligomers of an olefin
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BR112017020721B1 (pt) * 2015-03-27 2022-08-30 Mitsubishi Chemical Corporation Método para produzir oligômero de a-olefina
EA201990746A1 (ru) * 2016-11-14 2019-10-31 Каталитическая система, используемая в процессе олигомеризации олефинов и способ олигомеризации олефинов
JP7447015B2 (ja) 2018-04-27 2024-03-11 中国石油化工股▲ふん▼有限公司 極性モノマーグラフト化ポリプロピレン樹脂、およびその製造方法と応用
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WO2020263113A1 (en) * 2019-06-26 2020-12-30 Public Joint Stock Company "Sibur Holding" The method of reducing polymer deposits on the surfaces of the reactor equipment in the olefin oligomerization process
WO2021133202A1 (en) * 2019-12-27 2021-07-01 Public Joint Stock Company "Sibur Holding" Transition metal oxocarboxylate composition and method for preparing thereof
RU2749903C1 (ru) * 2020-09-24 2021-06-18 Общество с ограниченной ответственностью "Транснефть-Синтез" (ООО "Транснефть-Синтез") Способ получения основ полиолефиновых противотурбулентных присадок

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Also Published As

Publication number Publication date
US8921251B2 (en) 2014-12-30
RU2430116C1 (ru) 2011-09-27
CN102596408B (zh) 2015-03-11
US20120302715A1 (en) 2012-11-29
WO2011093748A4 (ru) 2011-09-22
KR20120132626A (ko) 2012-12-06
EP2529832A4 (en) 2013-07-24
EP2529832B1 (en) 2017-09-13
KR101449636B1 (ko) 2014-10-13
WO2011093748A1 (ru) 2011-08-04
ZA201201223B (en) 2013-01-30
JP2013517938A (ja) 2013-05-20
EP2529832A1 (en) 2012-12-05
IN2012DN01854A (ru) 2015-08-21
CA2770520C (en) 2015-10-27
CA2770520A1 (en) 2011-08-04
RU2010103074A (ru) 2011-08-10
MX339766B (es) 2016-06-08
MX2012006595A (es) 2012-08-17
JP5485415B2 (ja) 2014-05-07
EA020804B1 (ru) 2015-01-30
CN102596408A (zh) 2012-07-18

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