EA201290297A1 - Способ полимеризации олефина - Google Patents

Способ полимеризации олефина

Info

Publication number
EA201290297A1
EA201290297A1 EA201290297A EA201290297A EA201290297A1 EA 201290297 A1 EA201290297 A1 EA 201290297A1 EA 201290297 A EA201290297 A EA 201290297A EA 201290297 A EA201290297 A EA 201290297A EA 201290297 A1 EA201290297 A1 EA 201290297A1
Authority
EA
Eurasian Patent Office
Prior art keywords
polymerization
catalyst
directing
emulsion
solidification
Prior art date
Application number
EA201290297A
Other languages
English (en)
Other versions
EA021843B1 (ru
Inventor
Жаннетт Аумо
Паси Матикайнен
Михаэль Бартке
Том Эловирта
Самир Виджай
Микко Люлюкангас
Пертти Эло
Лаури Хухтанен
Original Assignee
Бореалис Аг
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бореалис Аг filed Critical Бореалис Аг
Publication of EA201290297A1 publication Critical patent/EA201290297A1/ru
Publication of EA021843B1 publication Critical patent/EA021843B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Способ полимеризации олефинов в присутствии катализатора полимеризации, в котором образующие катализатор компоненты не переходят в раствор из твердых частиц в течение полимеризации и в котором твердые частицы не распадаются в течение полимеризации, включающий стадии образования эмульсии, включающей компоненты катализатора; затвердевание эмульсии; направление твердого компонента - катализатора полимеризации из указанной стадии затвердевания на первую и вторую стадии предварительной полимеризации, а затем направление предварительно полимеризованного катализатора на стадию полимеризации. Полимер получают с высоким выходом, хорошей морфологией и низким количеством мелких частиц, и способ можно осуществлять стабильно в течение длительного периода времени.
EA201290297A 2009-11-13 2010-11-11 Способ полимеризации олефина EA021843B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09175891 2009-11-13
PCT/EP2010/067268 WO2011058091A1 (en) 2009-11-13 2010-11-11 Process for olefin polymerization

Publications (2)

Publication Number Publication Date
EA201290297A1 true EA201290297A1 (ru) 2013-04-30
EA021843B1 EA021843B1 (ru) 2015-09-30

Family

ID=41581472

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201290297A EA021843B1 (ru) 2009-11-13 2010-11-11 Способ полимеризации олефина

Country Status (6)

Country Link
US (1) US8501881B2 (ru)
EP (1) EP2499173B1 (ru)
CN (1) CN102666601B (ru)
EA (1) EA021843B1 (ru)
ES (1) ES2424958T3 (ru)
WO (1) WO2011058091A1 (ru)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013106706A1 (de) 2013-06-26 2014-12-31 Rational Ag Verfahren zum Betrieb eines Gargeräts
EP2868375A1 (en) * 2013-10-31 2015-05-06 Borealis AG A method for producing an olefin polymerization catalyst
US9688543B2 (en) * 2013-12-09 2017-06-27 Lanxess Solutions Us, Inc. Method for making bromides
DE102014102471A1 (de) 2014-02-25 2015-08-27 Rational Ag Verfahren zum Betreiben eines Gargeräts und Gargerät
BR112017006060B1 (pt) 2014-09-30 2021-09-08 Borealis Ag Processo para a polimerização de etileno na presença de um catalisador de polimerização de olefinas
SG10202102810RA (en) * 2016-08-10 2021-05-28 Exxonmobil Chemical Patents Inc Methods for supplying solid catalysts to a solution polymerization reactor
US20220177613A1 (en) * 2018-11-30 2022-06-09 Borealis Ag Washing process

Family Cites Families (82)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3405109A (en) 1960-10-03 1968-10-08 Phillips Petroleum Co Polymerization process
US3324093A (en) 1963-10-21 1967-06-06 Phillips Petroleum Co Loop reactor
US3374211A (en) 1964-07-27 1968-03-19 Phillips Petroleum Co Solids recovery from a flowing stream
US4532311A (en) 1981-03-26 1985-07-30 Union Carbide Corporation Process for reducing sheeting during polymerization of alpha-olefins
US4621952A (en) 1981-07-28 1986-11-11 Union Carbide Corporation Fluidized bed discharge process
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4632311A (en) 1982-12-20 1986-12-30 Matsushita Electric Industrial Co., Ltd. Atomizing apparatus employing a capacitive piezoelectric transducer
JPS6079540U (ja) 1983-11-08 1985-06-03 三井造船株式会社 気相流動層反応器のガス分散板支持装置
US4933149A (en) 1984-08-24 1990-06-12 Union Carbide Chemicals And Plastics Company Inc. Fluidized bed polymerization reactors
AU576409B2 (en) 1984-12-31 1988-08-25 Mobil Oil Corporation Fluidized bed olefin polymerization process
US4582816A (en) 1985-02-21 1986-04-15 Phillips Petroleum Company Catalysts, method of preparation and polymerization processes therewith
FR2599991B1 (fr) 1986-06-16 1993-04-02 Bp Chimie Sa Evacuation de produits presents dans un reacteur de polymerisation d'alpha-olefines en lit fluidise
US4855370A (en) 1986-10-01 1989-08-08 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
US5026795A (en) 1987-02-24 1991-06-25 Phillips Petroleum Co Process for preventing fouling in a gas phase polymerization reactor
US4803251A (en) 1987-11-04 1989-02-07 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
US5047468A (en) 1988-11-16 1991-09-10 Union Carbide Chemicals And Plastics Technology Corporation Process for the in situ blending of polymers
US5565175A (en) 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
FI89929C (fi) 1990-12-28 1993-12-10 Neste Oy Foerfarande foer homo- eller sampolymerisering av eten
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
ES2145357T3 (es) 1991-03-06 2000-07-01 Mobil Oil Corp Polimeros de etileno bimodales producidos en reactores en tandem.
IT1262933B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Processo per la polimerizzazione in fase gas di alfa-olefine
EP0579426B1 (en) 1992-07-16 1998-03-18 BP Chemicals Limited Polymerization process
US5381827A (en) 1992-11-30 1995-01-17 Sumitomo Chemical Company, Limited Gas distributor for use in gas phase polymerization apparatus
CA2161448C (en) 1993-04-26 2003-10-14 Marc Louis Dechellis Process for polymerizing monomers in fluidized beds
JP3077940B2 (ja) 1993-04-26 2000-08-21 エクソン・ケミカル・パテンツ・インク 流動層重合法のための安定な操作条件を決定する方法
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
EP1070729B1 (en) 1993-06-07 2011-09-28 Mitsui Chemicals, Inc. Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said component, process for olefin polymerization using said catalyst, propylene homopolymer, propylene copolymer and propylene elastomer
CA2125246C (en) 1993-06-07 2001-07-03 Junichi Imuta Transition metal compound and olefin polymerization catalyst using the same
FI96745C (fi) 1993-07-05 1996-08-26 Borealis Polymers Oy Menetelmä olefiinien polymeroimiseksi leijupetipolymerointireaktorissa
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
FI96867C (fi) 1993-12-27 1996-09-10 Borealis Polymers Oy Leijupetireaktori
US6143686A (en) 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
FI96216C (fi) 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi
JP3497029B2 (ja) 1994-12-28 2004-02-16 三井化学株式会社 気相重合装置用ガス分散板
FI104975B (fi) 1995-04-12 2000-05-15 Borealis As Menetelmä katalyyttikomponenttien valmistamiseksi
US5632596A (en) 1995-07-19 1997-05-27 Charles Ross & Son Co. Low profile rotors and stators for mixers and emulsifiers
US6403772B1 (en) 1995-09-11 2002-06-11 Montell Technology Company, Bv Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
FI104826B (fi) 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
FI105818B (fi) 1996-03-13 2000-10-13 Borealis Tech Oy Prosessi olefiinimonomeerien polymeroimiseksi
FI972230A (fi) 1997-01-28 1998-07-29 Borealis As Uusi homogeeninen olefiinien polymerointikatalysaattorikoostumus
DE69831139T2 (de) 1997-03-07 2006-06-01 Basell Polyolefine Gmbh Verfahren zur herstellung substituierter indanone, die substituierte indanone und daraus hergestelle metallocene
EP0881237A1 (en) 1997-05-26 1998-12-02 Fina Research S.A. Process to produce bimodal polyolefins with metallocene catalysts using two reaction zones
FI111846B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi
WO1998058976A1 (en) 1997-06-24 1998-12-30 Borealis A/S Process for preparing propylene polymers
FI111847B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä propeenin kopolymeerien valmistamiseksi
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
FI973451A0 (fi) 1997-08-22 1997-08-22 Borealis As Ny organometalfoerening och metod foer polymerisation av olefiner med hjaelp av en katalytkomposition som innehaoller denna organometalfoerening
DE19739946A1 (de) 1997-09-11 1999-03-18 Targor Gmbh Verfahren zur Herstellung von Metallocenen
US6677265B1 (en) 1997-12-08 2004-01-13 Albemarle Corporation Process of producing self-supported catalysts
US6000840A (en) 1997-12-17 1999-12-14 Charles Ross & Son Company Rotors and stators for mixers and emulsifiers
AU2566399A (en) 1998-02-12 1999-08-30 University Of Delaware Catalyst compounds with beta-diiminate anionic ligands and processes for polymerizing olefins
DE19806918A1 (de) 1998-02-19 1999-08-26 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
FI981148A (fi) 1998-05-25 1999-11-26 Borealis As Uusia aktivaattorijärjestelmä metalloseeniyhdisteitä varten
FI111953B (fi) 1998-11-12 2003-10-15 Borealis Tech Oy Menetelmä ja laite polymerointireaktoreiden tyhjentämiseksi
EP1074557A3 (de) 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
DE10009308A1 (de) 2000-02-26 2001-08-30 Moeller Gmbh Befestigungsadapter für Befehls- bzw. Meldegeräte
GB0007002D0 (en) 2000-03-22 2000-05-10 Borealis Polymers Oy Catalysts
EP1632506A1 (en) 2000-06-30 2006-03-08 ExxonMobil Chemical Patents Inc. Propylene polymer
DE60102156T8 (de) 2000-06-30 2005-06-23 Exxonmobil Chemical Patents Inc., Baytown Verbrückte Bisindenyl Substituierte Metallocen-Verbindungen
WO2002048208A1 (en) 2000-12-15 2002-06-20 Basell Poliolefine Italia S.P.A. Continuous process for the preparation of solid catalyst components for the polymerisation of alpha-olefins
GB0102440D0 (en) 2001-01-31 2001-03-14 Borealis Tech Oy Catalyst
US6534609B2 (en) * 2001-03-13 2003-03-18 Chevron Phillips Chemical Company Lp Method for making and using a metallocene catalyst system
GB0118010D0 (en) 2001-07-24 2001-09-19 Borealis Tech Oy Catalysts
ATE367198T1 (de) 2001-10-30 2007-08-15 Borealis Tech Oy Polymerisationsreaktor
DE60137638D1 (de) 2001-12-19 2009-03-26 Borealis Tech Oy Herstellung von geträgerten Katalysatoren für die Olefinpolymerisation
EP1323747A1 (en) * 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
DE60223926T2 (de) 2002-10-30 2008-11-13 Borealis Technology Oy Verfahren und Vorrichtung zur Herstellung von Olefinpolymeren
EP1462464A1 (en) 2003-03-25 2004-09-29 Borealis Technology Oy Metallocene catalysts and preparation of polyolefins therewith
EP1577003A1 (en) 2004-03-15 2005-09-21 Borealis Technology Oy Method and apparatus for producing polymers
ES2267026T3 (es) 2004-04-29 2007-03-01 Borealis Technology Oy Proceso de produccion de polietileno.
AU2005321510B2 (en) 2004-12-31 2009-03-26 Borealis Technology Oy Process
EP1739103A1 (en) 2005-06-30 2007-01-03 Borealis Technology Oy Catalyst
EP1741725B1 (en) * 2005-07-08 2014-04-09 Borealis Technology Oy Propylene polymer composition
DE602005013376D1 (de) 2005-08-09 2009-04-30 Borealis Tech Oy Siloxy substituierte Metallocenkatalysatoren
CN1923861B (zh) 2005-09-02 2012-01-18 北方技术股份有限公司 在烯烃聚合催化剂存在下的烯烃聚合方法
EP1860125B1 (en) 2006-05-22 2011-05-11 Borealis Technology Oy A process to produce polyolefins with extra low impurity content
EP1939226B1 (en) 2006-12-28 2013-07-17 Borealis Technology Oy Process for producing a polymer, a process for producing a prepolymerized catalyst, such prepolymerized catalyst and its use
ATE509967T1 (de) * 2007-06-14 2011-06-15 Borealis Tech Oy Verfahren zur herstellung von propylen- copolymeren mit hilfe eines vorpolymerisierten katalysators
EP2042552A1 (en) 2007-09-27 2009-04-01 Borealis Technology Oy Polyolefin compositions having improved optical and mechanical properties
ES2377204T3 (es) 2007-11-30 2012-03-23 Borealis Technology Oy Proceso para la fabricación de copolímero de propileno heterofásico

Also Published As

Publication number Publication date
ES2424958T3 (es) 2013-10-10
CN102666601B (zh) 2014-04-23
EP2499173B1 (en) 2013-07-17
US8501881B2 (en) 2013-08-06
CN102666601A (zh) 2012-09-12
EA021843B1 (ru) 2015-09-30
WO2011058091A1 (en) 2011-05-19
US20120259076A1 (en) 2012-10-11
EP2499173A1 (en) 2012-09-19

Similar Documents

Publication Publication Date Title
EA201290297A1 (ru) Способ полимеризации олефина
ATE528322T1 (de) Verfahren zur initiierung von radikalischen polymerisationen
ATE491729T1 (de) Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung
EA201290604A1 (ru) Каталитическая система для (со-)тримеризации олефинов, способ (со-)тримеризации олефинов и способ (со-)полимеризации олефиновых олигомеров
EA200601924A1 (ru) СПОСОБ ПОЛУЧЕНИЯ ГЕТЕРОФАЗНЫХ α-ОЛЕФИНОВЫХ ПОЛИМЕРОВ
WO2008023040A3 (de) Auf nachwachsenden rohstoffen basierende acrylsäure und wasserabsorbierende polymergebilde sowie verfahren zu deren herstellung mittels dehydratisierung
WO2011111979A3 (en) Method for preparing supported metallocene catalyst and method for preparing polyolefin using the same
MY170957A (en) Method for producing lignin degradation product
EA201070301A1 (ru) Мягкая щелочная предварительная обработка и одновременное сахарообразование и ферментирование лигноцеллюлозной биомассы с получением органических кислот
ATE517190T1 (de) Verfahren zur fermentativen herstellung von 1,5- diaminopentan
WO2011129593A3 (ko) 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법
EA201201511A1 (ru) Получение твердой каталитической системы
WO2008153179A1 (ja) 脂肪組織由来多系統前駆細胞
EA201291225A1 (ru) Улучшенные способы получения сквалена
EP1854815A4 (en) HYBRID POLYMER AND MANUFACTURING METHOD THEREFOR
RU2012121998A (ru) Способ получения (1-алкокси-2-метил-1-оксопропан-2-ил) -(мет) акрилата
WO2013017942A3 (en) Improved process of dehydration reactions
CN102649831A (zh) 一种非离子氟碳改性聚丙烯酰胺的制备方法
WO2009131304A3 (ko) 목질계 바이오매스 전처리 방법 및 이를 이용한 바이오 연료의 제조 방법
CR20130456A (es) Aparato y proceso para la producción de un producto de células encapsuladas
BRPI0910037A2 (pt) método para fabricar polilactídeo estável
EA201591151A1 (ru) Способ получения полимера
IN2014DN10494A (ru)
EA201691522A1 (ru) Многостадийное измельчение при получении водоабсорбирующих полимерных частиц
EP1712569A4 (en) PROCESS FOR PREPARING ISOBUTYLENE RESIN POWDER

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU