MX2012006595A - Sistema catalizador y procesos para la (co-) trimerizacion de olefinas y la (co-) polimerizacion de oligomeros de olefina. - Google Patents

Sistema catalizador y procesos para la (co-) trimerizacion de olefinas y la (co-) polimerizacion de oligomeros de olefina.

Info

Publication number
MX2012006595A
MX2012006595A MX2012006595A MX2012006595A MX2012006595A MX 2012006595 A MX2012006595 A MX 2012006595A MX 2012006595 A MX2012006595 A MX 2012006595A MX 2012006595 A MX2012006595 A MX 2012006595A MX 2012006595 A MX2012006595 A MX 2012006595A
Authority
MX
Mexico
Prior art keywords
olefin oligomers
catalyst system
trimerization
olefin
polymerization
Prior art date
Application number
MX2012006595A
Other languages
English (en)
Other versions
MX339766B (es
Inventor
Timur Mikhailovich Zilbershtein
Maxim Vladimirovich Lipskikh
Alexei Alexandrovich Nosikov
Georgy Viktorovich Nesyn
Original Assignee
Closed Joint Stock Company Sibur Holding
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Closed Joint Stock Company Sibur Holding filed Critical Closed Joint Stock Company Sibur Holding
Publication of MX2012006595A publication Critical patent/MX2012006595A/es
Publication of MX339766B publication Critical patent/MX339766B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La invención se refiere al campo de la producción de polímeros y copolímeros de oligómeros de olefina producidos mediante una reacción de trimerización de monómeros de olefina. Se describe un proceso que comprende la producción de oligómeros de olefina con la ayuda de un sistema catalizador de trimerización preparado usando irradiación UHF para activar componentes individuales del sistema catalizador de trimerización. El uso del sistema catalizador de trimerización así es mejorado y tiene actividad incrementada que proporciona efectividad incrementada en la producción de los oligómeros de olefina a partir de etileno u otros monómeros de olefina, inter alia, a una presión baja de etileno. Los oligómeros de olefina así producidos enseguida son polimerizados o copolimerizados usando procesos conocidos en el arte. El efecto técnico consiste en incrementar la efectividad de la producción de oligómeros de olefina que enseguida son usados en una reacción de polimerización o copolimerización.
MX2012006595A 2010-01-29 2011-01-28 Sistema catalizador y procesos para la (co-) trimerizacion de olefinas y la (co-) polimerizacion de oligomeros de olefina. MX339766B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2010103074/04A RU2430116C1 (ru) 2010-01-29 2010-01-29 Способ полимеризации и сополимеризации олефиновых олигомеров
PCT/RU2011/000049 WO2011093748A1 (ru) 2010-01-29 2011-01-28 Каталитическая система и способы (со-)-тримеризации олефинов и (со-)-полимеризации олефиновых олигомеров

Publications (2)

Publication Number Publication Date
MX2012006595A true MX2012006595A (es) 2012-08-17
MX339766B MX339766B (es) 2016-06-08

Family

ID=44319560

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012006595A MX339766B (es) 2010-01-29 2011-01-28 Sistema catalizador y procesos para la (co-) trimerizacion de olefinas y la (co-) polimerizacion de oligomeros de olefina.

Country Status (12)

Country Link
US (1) US8921251B2 (es)
EP (1) EP2529832B1 (es)
JP (1) JP5485415B2 (es)
KR (1) KR101449636B1 (es)
CN (1) CN102596408B (es)
CA (1) CA2770520C (es)
EA (1) EA020804B1 (es)
IN (1) IN2012DN01854A (es)
MX (1) MX339766B (es)
RU (1) RU2430116C1 (es)
WO (1) WO2011093748A1 (es)
ZA (1) ZA201201223B (es)

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US9550841B2 (en) * 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
RU2471762C1 (ru) * 2011-06-22 2013-01-10 Открытое акционерное общество "СИБУР Холдинг" (ОАО "СИБУР Холдинг") Способ выделения продуктов олигомеризации олефинов и разложения остатков катализатора олигомеризации
CN103102237B (zh) * 2011-11-09 2015-02-11 中国石油化工股份有限公司 一种提高乙烯三聚催化剂性能的方法
KR101482962B1 (ko) * 2014-03-05 2015-01-15 아주대학교산학협력단 크롬 화합물, 이를 포함하는 촉매 시스템 및 이를 이용한 올레핀 중합방법
EP2918705B1 (en) 2014-03-12 2017-05-03 Rolls-Royce Corporation Coating including diffusion barrier layer including iridium and oxide layer and method of coating
WO2016105227A1 (en) * 2014-12-23 2016-06-30 Public Joint Stock Company "Sibur Holding" Methods of preparing oligomers of an olefin
WO2016105226A1 (en) 2014-12-23 2016-06-30 Public Joint Stock Company "Sibur Holding" Methods of precipitating polymer and deactivated organometallic catalyst in an olefin oligomerization reaction
US10099970B2 (en) 2014-12-23 2018-10-16 Public Joint Stock Company “SIBUR Holding” Methods of preparing oligomers of an olefin
BR112017020721B1 (pt) * 2015-03-27 2022-08-30 Mitsubishi Chemical Corporation Método para produzir oligômero de a-olefina
EA201990746A1 (ru) * 2016-11-14 2019-10-31 Каталитическая система, используемая в процессе олигомеризации олефинов и способ олигомеризации олефинов
JP7447015B2 (ja) 2018-04-27 2024-03-11 中国石油化工股▲ふん▼有限公司 極性モノマーグラフト化ポリプロピレン樹脂、およびその製造方法と応用
CN110498873A (zh) * 2018-05-17 2019-11-26 中国石油天然气股份有限公司 一种烷基铝氧烷的预处理方法、茂金属催化剂的制备方法及烯烃聚合方法
WO2020263113A1 (en) * 2019-06-26 2020-12-30 Public Joint Stock Company "Sibur Holding" The method of reducing polymer deposits on the surfaces of the reactor equipment in the olefin oligomerization process
WO2021133202A1 (en) * 2019-12-27 2021-07-01 Public Joint Stock Company "Sibur Holding" Transition metal oxocarboxylate composition and method for preparing thereof
RU2749903C1 (ru) * 2020-09-24 2021-06-18 Общество с ограниченной ответственностью "Транснефть-Синтез" (ООО "Транснефть-Синтез") Способ получения основ полиолефиновых противотурбулентных присадок

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Also Published As

Publication number Publication date
US8921251B2 (en) 2014-12-30
RU2430116C1 (ru) 2011-09-27
CN102596408B (zh) 2015-03-11
US20120302715A1 (en) 2012-11-29
EA201290604A1 (ru) 2013-01-30
WO2011093748A4 (ru) 2011-09-22
KR20120132626A (ko) 2012-12-06
EP2529832A4 (en) 2013-07-24
EP2529832B1 (en) 2017-09-13
KR101449636B1 (ko) 2014-10-13
WO2011093748A1 (ru) 2011-08-04
ZA201201223B (en) 2013-01-30
JP2013517938A (ja) 2013-05-20
EP2529832A1 (en) 2012-12-05
IN2012DN01854A (es) 2015-08-21
CA2770520C (en) 2015-10-27
CA2770520A1 (en) 2011-08-04
RU2010103074A (ru) 2011-08-10
MX339766B (es) 2016-06-08
JP5485415B2 (ja) 2014-05-07
EA020804B1 (ru) 2015-01-30
CN102596408A (zh) 2012-07-18

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Owner name: AO&G HOLDING B.V.

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Owner name: AO&G HOLDING B.V.

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