EA022667B1 - Способ получения цеолитов ts-1 - Google Patents

Способ получения цеолитов ts-1 Download PDF

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Publication number
EA022667B1
EA022667B1 EA201000989A EA201000989A EA022667B1 EA 022667 B1 EA022667 B1 EA 022667B1 EA 201000989 A EA201000989 A EA 201000989A EA 201000989 A EA201000989 A EA 201000989A EA 022667 B1 EA022667 B1 EA 022667B1
Authority
EA
Eurasian Patent Office
Prior art keywords
zeolite
source
hours
silicon dioxide
temperature
Prior art date
Application number
EA201000989A
Other languages
English (en)
Russian (ru)
Other versions
EA201000989A1 (ru
Inventor
Анджела Карати
Донателла Берти
Роберто Миллини
Франко Риветти
Мария Анджела Мантегацца
Джанни Джиротти
Original Assignee
ВЕРСАЛИС С.п.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ВЕРСАЛИС С.п.А. filed Critical ВЕРСАЛИС С.п.А.
Publication of EA201000989A1 publication Critical patent/EA201000989A1/ru
Publication of EA022667B1 publication Critical patent/EA022667B1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
EA201000989A 2007-12-14 2008-12-03 Способ получения цеолитов ts-1 EA022667B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT002342A ITMI20072342A1 (it) 2007-12-14 2007-12-14 Processo per preparare zeoliti ts-1
PCT/EP2008/010290 WO2009077086A1 (en) 2007-12-14 2008-12-03 Process for the preparation of ts-1 zeolites

Publications (2)

Publication Number Publication Date
EA201000989A1 EA201000989A1 (ru) 2011-02-28
EA022667B1 true EA022667B1 (ru) 2016-02-29

Family

ID=40315583

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201000989A EA022667B1 (ru) 2007-12-14 2008-12-03 Способ получения цеолитов ts-1

Country Status (19)

Country Link
US (1) US9358531B2 (enExample)
EP (1) EP2222601B1 (enExample)
JP (1) JP5619617B2 (enExample)
KR (1) KR101501798B1 (enExample)
CN (1) CN101918315B (enExample)
BR (1) BRPI0820994B1 (enExample)
CA (1) CA2708787C (enExample)
DK (1) DK2222601T3 (enExample)
EA (1) EA022667B1 (enExample)
EG (1) EG25949A (enExample)
ES (1) ES2443030T3 (enExample)
IL (1) IL206285A (enExample)
IT (1) ITMI20072342A1 (enExample)
MX (1) MX2010006545A (enExample)
MY (1) MY155562A (enExample)
TN (1) TN2010000271A1 (enExample)
TW (1) TWI432379B (enExample)
UA (1) UA103757C2 (enExample)
WO (1) WO2009077086A1 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI399242B (zh) * 2009-12-11 2013-06-21 China Petrochemical Dev Corp Taipei Taiwan Method for preparing large-diameter titanium-silicon molecular sieve and method for producing cyclohexanone oxime using the molecular sieve
TWI426050B (zh) * 2011-04-19 2014-02-11 China Petrochemical Dev Corp Taipei Taiwan A method for preparing titanium-silicon molecular sieve and method for producing cyclohexanone oxime using the molecular sieve
TWI480100B (zh) * 2011-04-27 2015-04-11 China Petrochemical Dev Corp Taipei Taiwan Titanium-silicon molecular sieve and its preparation method and method for producing cyclohexanone oxime using the molecular sieve
TWI508935B (zh) * 2011-08-11 2015-11-21 China Petrochemical Dev Corp Taipei Taiwan Titanium-silicon molecular sieve and its preparation method and method for producing cyclohexanone oxime using the molecular sieve
CN102502690A (zh) 2011-10-31 2012-06-20 大连理工大学 一种基于季铵盐和无机碱混合液的ts-1改性方法
CN103360344B (zh) * 2012-04-01 2016-01-20 中国石油化工股份有限公司 一种催化丙烯环氧化的方法
CN104174341B (zh) * 2013-05-27 2017-09-26 乌鲁木齐益好天成新型节能材料有限公司 一种固相硅凝胶的制备方法
CN104944441B (zh) * 2014-03-31 2017-05-24 中国石油化工股份有限公司 一种合成钛硅分子筛的方法
CN104528760B (zh) * 2014-12-25 2016-12-07 中国天辰工程有限公司 一种纳米级钛硅分子筛的制备方法
CN107986293B (zh) * 2016-10-27 2020-03-24 中国石油化工股份有限公司 一种钛硅分子筛及其合成方法和应用
CN109721070B (zh) * 2017-10-31 2020-12-04 中国石油化工股份有限公司 钛硅分子筛的生产方法以及由该方法生产的钛硅分子筛和氨肟化反应方法
WO2020097876A1 (zh) 2018-11-15 2020-05-22 中国科学院大连化学物理研究所 一种多级孔ts-1分子筛的制备方法
US12383891B2 (en) 2018-11-15 2025-08-12 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Method for preparation of hierarchical TS-1 molecular sieve
US11655158B2 (en) 2019-10-14 2023-05-23 Totalenergies Onetech Isomorphous substitution of metals during the synthesis of a zeolite framework
US12478959B2 (en) 2019-12-19 2025-11-25 Basf Se Continuous synthesis of a titanosilicate zeolitic material, said zeolitic material, molding prepared thereof, and their use
CN112624143B (zh) * 2020-12-11 2022-05-03 北京科技大学 一种以MOFs为钛源制备TS-1分子筛催化剂的方法
CN114669287B (zh) * 2022-04-26 2024-09-24 西安科技大学 一种有序介孔钛铝复合氧化物包覆ts-1分子筛材料及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2471950A1 (fr) * 1979-12-21 1981-06-26 Snam Progetti Matiere synthetique cristalline poreuse constituee par des oxydes de silicium et de titane, son procede de preparation et ses applications
JPH08253314A (ja) * 1995-01-19 1996-10-01 Tosoh Corp 高結晶性チタノシリケートの製造方法
US5958369A (en) * 1997-05-30 1999-09-28 Director-General Of Agency Of Industrial Science And Technology Titanium-containing porous silica and process of preparing same
JP2000185912A (ja) * 1998-12-22 2000-07-04 Tosoh Corp 結晶性チタノシリケートゼオライトおよびその製造方法
EP1106576A1 (en) * 1999-12-03 2001-06-13 Enichem S.p.A. Process for the preparation of zeolitic catalysts
US20070059237A1 (en) * 2005-09-13 2007-03-15 Chevron U.S.A. Inc. Preparation of titanosilicate zeolite TS-1
JP2007145687A (ja) * 2005-10-26 2007-06-14 Tohoku Univ チタノシリケートの製造方法及びチタノシリケート

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1050584C (zh) * 1996-06-05 2000-03-22 中国石油化工总公司 一种钛硅分子筛(ts-1)的制备方法
IT1295267B1 (it) * 1997-10-03 1999-05-04 Enichem Spa Processo per preparare zeoliti legate
IT1314001B1 (it) * 1999-11-19 2002-12-03 Enichem Spa Metodo per la rimozione del templante da zeoliti sintetiche
EP1129991A1 (de) * 2000-03-02 2001-09-05 Degussa AG Verfahren zur Herstellung eines titanhaltigen Zeolithen
WO2003043937A2 (en) * 2001-11-15 2003-05-30 Pq Holding, Inc. Method for controlling synthesis conditions during molecular sieve synthesis using combinations of quaternary ammonium hydroxides and halides

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2471950A1 (fr) * 1979-12-21 1981-06-26 Snam Progetti Matiere synthetique cristalline poreuse constituee par des oxydes de silicium et de titane, son procede de preparation et ses applications
JPH08253314A (ja) * 1995-01-19 1996-10-01 Tosoh Corp 高結晶性チタノシリケートの製造方法
US5958369A (en) * 1997-05-30 1999-09-28 Director-General Of Agency Of Industrial Science And Technology Titanium-containing porous silica and process of preparing same
JP2000185912A (ja) * 1998-12-22 2000-07-04 Tosoh Corp 結晶性チタノシリケートゼオライトおよびその製造方法
EP1106576A1 (en) * 1999-12-03 2001-06-13 Enichem S.p.A. Process for the preparation of zeolitic catalysts
US20070059237A1 (en) * 2005-09-13 2007-03-15 Chevron U.S.A. Inc. Preparation of titanosilicate zeolite TS-1
JP2007145687A (ja) * 2005-10-26 2007-06-14 Tohoku Univ チタノシリケートの製造方法及びチタノシリケート

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ZHANG G. ET AL.: "PREPARATION OF COLLOIDAL SUSPENSIONS OF DISCRETE TS-1 CRYSTALS". CHEMISTRY OF MATERIALS, AMERICAN CHEMICAL SOCIETY, WASHINGTON, US, vol. 9, no. 1, 1 January 1997 (1997-01-01), pages 210-217, XP000683976, ISSN: 0897-4756, the whole document *

Also Published As

Publication number Publication date
KR20100103545A (ko) 2010-09-27
US9358531B2 (en) 2016-06-07
EP2222601A1 (en) 2010-09-01
TN2010000271A1 (en) 2011-11-11
DK2222601T3 (da) 2013-12-09
BRPI0820994B1 (pt) 2019-11-05
EA201000989A1 (ru) 2011-02-28
WO2009077086A1 (en) 2009-06-25
ES2443030T3 (es) 2014-02-17
TWI432379B (zh) 2014-04-01
CA2708787A1 (en) 2009-06-25
IL206285A (en) 2014-01-30
JP5619617B2 (ja) 2014-11-05
UA103757C2 (ru) 2013-11-25
HK1142872A1 (en) 2010-12-17
CA2708787C (en) 2013-07-16
US20100331576A1 (en) 2010-12-30
MX2010006545A (es) 2010-08-31
BRPI0820994A2 (pt) 2015-06-16
EG25949A (en) 2012-11-12
JP2011506241A (ja) 2011-03-03
CN101918315B (zh) 2013-04-24
WO2009077086A8 (en) 2009-10-15
IL206285A0 (en) 2010-12-30
TW200934728A (en) 2009-08-16
EP2222601B1 (en) 2013-09-25
KR101501798B1 (ko) 2015-03-11
ITMI20072342A1 (it) 2009-06-15
CN101918315A (zh) 2010-12-15
MY155562A (en) 2015-10-30

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): MD