DE820134C - Verfahren zur Entfernung von Wasserstoff und bzw. oder Sauerstoff aus Gasgemischen und Mittel hierzu - Google Patents
Verfahren zur Entfernung von Wasserstoff und bzw. oder Sauerstoff aus Gasgemischen und Mittel hierzuInfo
- Publication number
- DE820134C DE820134C DEB1108A DEB0001108A DE820134C DE 820134 C DE820134 C DE 820134C DE B1108 A DEB1108 A DE B1108A DE B0001108 A DEB0001108 A DE B0001108A DE 820134 C DE820134 C DE 820134C
- Authority
- DE
- Germany
- Prior art keywords
- oxygen
- hydrogen
- contact
- palladium
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 63
- 239000001301 oxygen Substances 0.000 title claims description 63
- 229910052760 oxygen Inorganic materials 0.000 title claims description 63
- 239000001257 hydrogen Substances 0.000 title claims description 46
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 46
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 43
- 239000007789 gas Substances 0.000 title claims description 35
- 238000000034 method Methods 0.000 title claims description 24
- 239000000203 mixture Substances 0.000 title claims description 17
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 40
- 229910052763 palladium Inorganic materials 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 230000003197 catalytic effect Effects 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 238000006555 catalytic reaction Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 238000000746 purification Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- MPCRDALPQLDDFX-UHFFFAOYSA-L Magnesium perchlorate Chemical compound [Mg+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O MPCRDALPQLDDFX-UHFFFAOYSA-L 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- -1 food Chemical compound 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
- C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/04—Purification or separation of nitrogen
- C01B21/0405—Purification or separation processes
- C01B21/0411—Chemical processing only
- C01B21/0416—Chemical processing only by oxidation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B23/00—Noble gases; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B5/00—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0045—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/005—Carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US259820XA | 1945-12-10 | 1945-12-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE820134C true DE820134C (de) | 1951-11-08 |
Family
ID=21829145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB1108A Expired DE820134C (de) | 1945-12-10 | 1949-12-15 | Verfahren zur Entfernung von Wasserstoff und bzw. oder Sauerstoff aus Gasgemischen und Mittel hierzu |
Country Status (4)
| Country | Link |
|---|---|
| CH (1) | CH259820A (enrdf_load_stackoverflow) |
| DE (1) | DE820134C (enrdf_load_stackoverflow) |
| FR (1) | FR943689A (enrdf_load_stackoverflow) |
| NL (1) | NL74835C (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1013636B (de) * | 1955-06-04 | 1957-08-14 | Degussa | Verfahren zur katalytischen Herstellung von Blausaeure und Wasserstoff aus Gemischenvon Kohlenwasserstoff und Ammoniak |
| DE1245336B (de) * | 1959-01-10 | 1967-07-27 | Engelhard Ind Inc | Verfahren zum Entfernen von Spuren von Wasserstoff und Sauerstoff aus Wasserdampf |
| DE1283805B (de) * | 1957-04-05 | 1968-11-28 | Engelhard Ind Inc | Verfahren zur Reinigung atmosphaerischer Luft, die verfluessigt werden soll, von kleinen Acetylenmengen |
| DE2411006A1 (de) * | 1973-03-12 | 1974-09-19 | Rockwell International Corp | Verfahren zur thermischen rekombination und vorrichtung zur durchfuehrung dieses verfahrens |
| DE3909540A1 (de) * | 1989-03-22 | 1990-09-27 | Nis Ingenieurgesellschaft Mbh | Vorrichtung zur rekombination von wasserstoff aus einem wasserstoffhaltigen gasgemisch |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3372356D1 (en) * | 1982-03-12 | 1987-08-13 | Cjb Developments Ltd | Process for the removal of hydrogen from gases |
-
0
- NL NL74835D patent/NL74835C/xx active
-
1946
- 1946-12-06 CH CH259820D patent/CH259820A/de unknown
- 1946-12-10 FR FR943689D patent/FR943689A/fr not_active Expired
-
1949
- 1949-12-15 DE DEB1108A patent/DE820134C/de not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1013636B (de) * | 1955-06-04 | 1957-08-14 | Degussa | Verfahren zur katalytischen Herstellung von Blausaeure und Wasserstoff aus Gemischenvon Kohlenwasserstoff und Ammoniak |
| DE1283805B (de) * | 1957-04-05 | 1968-11-28 | Engelhard Ind Inc | Verfahren zur Reinigung atmosphaerischer Luft, die verfluessigt werden soll, von kleinen Acetylenmengen |
| DE1245336B (de) * | 1959-01-10 | 1967-07-27 | Engelhard Ind Inc | Verfahren zum Entfernen von Spuren von Wasserstoff und Sauerstoff aus Wasserdampf |
| DE2411006A1 (de) * | 1973-03-12 | 1974-09-19 | Rockwell International Corp | Verfahren zur thermischen rekombination und vorrichtung zur durchfuehrung dieses verfahrens |
| DE3909540A1 (de) * | 1989-03-22 | 1990-09-27 | Nis Ingenieurgesellschaft Mbh | Vorrichtung zur rekombination von wasserstoff aus einem wasserstoffhaltigen gasgemisch |
Also Published As
| Publication number | Publication date |
|---|---|
| NL74835C (enrdf_load_stackoverflow) | |
| CH259820A (de) | 1949-02-15 |
| FR943689A (fr) | 1949-03-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1544130C2 (de) | Verfahren zum Reinigen von durch Quecksilber verunreinigten Gasen | |
| DE1249228C2 (de) | Hydrierungskatalysator | |
| DE2130983A1 (de) | Verfahren zur Reinigung von Gasgemischen,die als Verunreinigungen insbesondere Kohlenmonoxyd enthalten | |
| DE1493354B1 (de) | Entfernung von Wasser aus als Kaeltemittel dienenden halogenierten Methan- und AEthanderivaten | |
| DE820134C (de) | Verfahren zur Entfernung von Wasserstoff und bzw. oder Sauerstoff aus Gasgemischen und Mittel hierzu | |
| DE1277484B (de) | Verfahren zur Herstellung farbstabiler Schmieroele | |
| DE2118770A1 (de) | Verfahren zur Herstellung eines Katalysators für die Oxydation von Kohlenmonoxyd zu Kohlendioxyd | |
| DE1148982B (de) | Verfahren zur selektiven Entfernung von Oxyden des Stickstoffs aus sauerstoff-haltigen Gasgemischen | |
| DE2263152A1 (de) | Verfahren zur heterogenen katalyse einer chemischen reaktion in fluessiger phase | |
| DE2636877A1 (de) | Verfahren zur herstellung von gereinigter terephthalsaeure | |
| DE1290530B (de) | Kreislaufverfahren zur Herstellung von Wasserstoffsuperoxyd | |
| DE1299286B (de) | Verfahren zur Verminderung der Luftentzuendlichkeit eines pyrophoren Katalysators | |
| DE2121975B2 (de) | Verfahren zur Entfernung von Verun reinigungen in Kohlenstoffkorpern | |
| DE830785C (de) | Verfahren zur Herstellung von Platinkatalysatoren | |
| DE520793C (de) | Entfernung von Stickoxyden aus Gasen | |
| DE1263717B (de) | Verfahren zur Umsetzung von Wasserstoff und/oder Deuterium mit Sauerstoff | |
| AT266775B (de) | Verfahren zur Reinigung von wässerigen Wasserstoffperoxydlösungen | |
| DE1166164B (de) | Verfahren zur Behandlung von Bariumoxyd als Ausgangsmaterial zur Herstellung von Bariummethylat | |
| DD288055A7 (de) | Regenerierungsverfahren von silber-traegerkatalysatoren fuer die ethenoxidsynthese | |
| DE1567814C (de) | Verfahren zum Reinigen von wäßrigen Losungen von Wasserstoffperoxyd | |
| AT232973B (de) | Verfahren zur Entfernung von Acetylenen aus Gasgemischen | |
| DE1135428B (de) | Verfahren zur Gewinnung von praktisch stickstoffoxyd- und sauerstofffreiem Stickstoff | |
| DE1195726B (de) | Katalysator zur Herstellung von Chlor | |
| DE1017168B (de) | Verfahren zur Herstellung von Mononatriumacetylid | |
| DE619847C (de) | Verfahren zur Entfernung von Schwefelwasserstoff und anderen Schwefelverbindungen aus Kohlendestillationsgasen u. dgl. |