DE69937957T2 - Silberfilm mit schützenden unlöslischen metallischen salzausscheidungen - Google Patents
Silberfilm mit schützenden unlöslischen metallischen salzausscheidungen Download PDFInfo
- Publication number
- DE69937957T2 DE69937957T2 DE69937957T DE69937957T DE69937957T2 DE 69937957 T2 DE69937957 T2 DE 69937957T2 DE 69937957 T DE69937957 T DE 69937957T DE 69937957 T DE69937957 T DE 69937957T DE 69937957 T2 DE69937957 T2 DE 69937957T2
- Authority
- DE
- Germany
- Prior art keywords
- solution
- silver
- specified
- mirror
- silver surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims description 103
- 229910052709 silver Inorganic materials 0.000 title claims description 100
- 239000004332 silver Substances 0.000 title claims description 99
- 230000001681 protective effect Effects 0.000 title description 3
- 238000000034 method Methods 0.000 claims description 48
- 239000011521 glass Substances 0.000 claims description 39
- 150000001768 cations Chemical class 0.000 claims description 34
- 239000002244 precipitate Substances 0.000 claims description 33
- 238000005260 corrosion Methods 0.000 claims description 30
- 230000007797 corrosion Effects 0.000 claims description 30
- 150000001450 anions Chemical class 0.000 claims description 27
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 229910052718 tin Inorganic materials 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 21
- -1 hydroxyl ions Chemical class 0.000 claims description 20
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- 238000005507 spraying Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 7
- 229910008449 SnF 2 Inorganic materials 0.000 claims description 3
- 206010070834 Sensitisation Diseases 0.000 claims 1
- 230000008313 sensitization Effects 0.000 claims 1
- 229910001432 tin ion Inorganic materials 0.000 claims 1
- 239000000243 solution Substances 0.000 description 78
- 239000010410 layer Substances 0.000 description 26
- 239000010949 copper Substances 0.000 description 23
- 229910052802 copper Inorganic materials 0.000 description 22
- 238000012360 testing method Methods 0.000 description 22
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 21
- 229910052751 metal Inorganic materials 0.000 description 21
- 239000002184 metal Substances 0.000 description 21
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 19
- 239000007795 chemical reaction product Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 9
- 239000003973 paint Substances 0.000 description 7
- 208000014451 palmoplantar keratoderma and congenital alopecia 2 Diseases 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 239000002923 metal particle Substances 0.000 description 4
- 230000001235 sensitizing effect Effects 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 125000000218 acetic acid group Chemical class C(C)(=O)* 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 235000011150 stannous chloride Nutrition 0.000 description 2
- ZSUXOVNWDZTCFN-UHFFFAOYSA-L tin(ii) bromide Chemical compound Br[Sn]Br ZSUXOVNWDZTCFN-UHFFFAOYSA-L 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- BHHYHSUAOQUXJK-UHFFFAOYSA-L zinc fluoride Chemical compound F[Zn]F BHHYHSUAOQUXJK-UHFFFAOYSA-L 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 229920004142 LEXAN™ Polymers 0.000 description 1
- 239000004418 Lexan Substances 0.000 description 1
- DAOANAATJZWTSJ-UHFFFAOYSA-N N-Decanoylmorpholine Chemical compound CCCCCCCCCC(=O)N1CCOCC1 DAOANAATJZWTSJ-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical class [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- JALQQBGHJJURDQ-UHFFFAOYSA-L bis(methylsulfonyloxy)tin Chemical compound [Sn+2].CS([O-])(=O)=O.CS([O-])(=O)=O JALQQBGHJJURDQ-UHFFFAOYSA-L 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000002443 hydroxylamines Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HAAYBYDROVFKPU-UHFFFAOYSA-N silver;azane;nitrate Chemical compound N.N.[Ag+].[O-][N+]([O-])=O HAAYBYDROVFKPU-UHFFFAOYSA-N 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- OBBXFSIWZVFYJR-UHFFFAOYSA-L tin(2+);sulfate Chemical compound [Sn+2].[O-]S([O-])(=O)=O OBBXFSIWZVFYJR-UHFFFAOYSA-L 0.000 description 1
- FACAOUDUXZBFBR-UHFFFAOYSA-N tin(4+) Chemical compound [Sn+4].[Sn+4] FACAOUDUXZBFBR-UHFFFAOYSA-N 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- 229910000375 tin(II) sulfate Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3605—Coatings of the type glass/metal/inorganic compound
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/3663—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties specially adapted for use as mirrors
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/38—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/08—Corrosion or deposition inhibiting
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemically Coating (AREA)
- Surface Treatment Of Glass (AREA)
- Mirrors, Picture Frames, Photograph Stands, And Related Fastening Devices (AREA)
- Optical Elements Other Than Lenses (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US143685 | 1998-08-28 | ||
| US09/143,685 US6017580A (en) | 1998-08-28 | 1998-08-28 | Silver film incorporating protective insoluble metallic salt precipitate |
| PCT/US1999/017663 WO2000012227A1 (en) | 1998-08-28 | 1999-08-03 | Silver film incorporating protective insoluble metallic salt precipitate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69937957D1 DE69937957D1 (de) | 2008-02-21 |
| DE69937957T2 true DE69937957T2 (de) | 2009-01-08 |
Family
ID=22505144
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69937957T Expired - Lifetime DE69937957T2 (de) | 1998-08-28 | 1999-08-03 | Silberfilm mit schützenden unlöslischen metallischen salzausscheidungen |
Country Status (18)
| Country | Link |
|---|---|
| US (3) | US6017580A (enExample) |
| EP (1) | EP1113886B1 (enExample) |
| JP (1) | JP4240816B2 (enExample) |
| KR (1) | KR100637616B1 (enExample) |
| CN (1) | CN1173784C (enExample) |
| AR (2) | AR019240A1 (enExample) |
| AT (1) | ATE383208T1 (enExample) |
| AU (1) | AU755529B2 (enExample) |
| BR (1) | BR9913265A (enExample) |
| CA (1) | CA2341985C (enExample) |
| CO (1) | CO5100955A1 (enExample) |
| DE (1) | DE69937957T2 (enExample) |
| ES (1) | ES2299255T3 (enExample) |
| ID (1) | ID28770A (enExample) |
| TR (1) | TR200100658T2 (enExample) |
| TW (1) | TW568957B (enExample) |
| WO (1) | WO2000012227A1 (enExample) |
| ZA (1) | ZA200101533B (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5933421A (en) * | 1997-02-06 | 1999-08-03 | At&T Wireless Services Inc. | Method for frequency division duplex communications |
| US6017580A (en) * | 1998-08-28 | 2000-01-25 | Lilly Industries, (Usa), Inc. | Silver film incorporating protective insoluble metallic salt precipitate |
| JP3352422B2 (ja) * | 1999-02-10 | 2002-12-03 | セントラル硝子株式会社 | 銀被膜形成用薬液および銀被膜形成方法 |
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| EP1727773A1 (en) * | 2004-03-18 | 2006-12-06 | Glaverbel | Mirror |
| JP4807957B2 (ja) * | 2005-02-10 | 2011-11-02 | セントラル硝子株式会社 | 水性の鏡用縁塗り液およびそれを用いた鏡 |
| WO2006121517A1 (en) * | 2005-05-06 | 2006-11-16 | Valspar Sourcing, Inc. | Adhesion promoter |
| US20090153988A1 (en) * | 2006-06-16 | 2009-06-18 | Agc Flat Glass Europe Sa | Mirror |
| US8481084B2 (en) | 2007-05-23 | 2013-07-09 | Amcol International Corporation | Cholesterol-interacting layered phyllosilicates and methods of reducing hypercholesteremia in a mammal |
| DE102007051684B4 (de) * | 2007-10-26 | 2009-11-05 | Dr.-Ing. Schmitt Gmbh | Verfahren und Mittel zur Herstellung von kupferlosen Spiegeln |
| CN101200350B (zh) * | 2007-12-18 | 2012-08-22 | 张家港雅博纳米材料科技有限公司 | 银镜镀层的加工方法 |
| AU2008340000B2 (en) * | 2007-12-21 | 2011-11-24 | Agc Glass Europe | Solar energy reflector |
| KR100862502B1 (ko) * | 2008-02-05 | 2008-10-08 | 삼화페인트 공업주식회사 | 은경액 조성물 및 이를 이용한 ｏｎｌｉｎｅ 방식의은경막 제조방법 |
| WO2009128988A1 (en) | 2008-04-15 | 2009-10-22 | Valspar Sourcing, Inc. | Articles having improved corrosion resistance |
| FR2943144B1 (fr) * | 2009-03-13 | 2012-12-14 | Jet Metal Technologies | Miroir anticorrosion, son procede de fabrication et ses applications dans la recuperation de l'energie solaire |
| BE1021679B1 (fr) * | 2012-09-17 | 2016-01-08 | Agc Glass Europe | Procede de fabrication d'un miroir sans couche de cuivre |
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| US2759845A (en) * | 1954-10-25 | 1956-08-21 | Metropolitan Mirror And Glass | Processes of precipitating copper from copper sulfate solutions and precipitating media for so doing |
| BE723176A (enExample) * | 1968-08-27 | 1969-04-01 | ||
| CA1188288A (en) * | 1983-03-02 | 1985-06-04 | Pierre Mathieu | Method for producing a catalyst for oxidizing carbon monoxide |
| IT1177081B (it) * | 1984-10-30 | 1987-08-26 | Vitreal Specchi Spa | Apparecchiatura per l'incisione in continuo all'acido su una faccia di lastre di vetro |
| US4707405A (en) * | 1985-01-02 | 1987-11-17 | Ppg Industries, Inc. | Cyanamide salts of non-lead metals as corrosion inhibitive pigments in mirror back coatings |
| US5292354A (en) * | 1986-12-04 | 1994-03-08 | Glaverbel, Societe Anonyme | Method of producing dealkalized sheet glass |
| US4737188A (en) * | 1987-05-18 | 1988-04-12 | London Laboratories Limited | Reducing agent and method for the electroless deposition of silver |
| IL86366A0 (en) * | 1988-05-12 | 1988-11-15 | Luz Ind Israel Ltd | Protected silvered substrates and mirrors containing the same |
| US5156917A (en) * | 1990-01-11 | 1992-10-20 | Lilly Industries, Inc. | Mirrorback coating |
| BE1005463A3 (fr) * | 1990-11-03 | 1993-08-03 | Glaverbel | Fabrication d'objets reflechissants. |
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| US6017580A (en) * | 1998-08-28 | 2000-01-25 | Lilly Industries, (Usa), Inc. | Silver film incorporating protective insoluble metallic salt precipitate |
| JP6425120B2 (ja) * | 2014-09-30 | 2018-11-21 | 株式会社リコー | 画像形成装置 |
-
1998
- 1998-08-28 US US09/143,685 patent/US6017580A/en not_active Expired - Lifetime
-
1999
- 1999-07-19 TW TW088112219A patent/TW568957B/zh not_active IP Right Cessation
- 1999-07-21 AR ARP990103574A patent/AR019240A1/es active IP Right Grant
- 1999-08-03 WO PCT/US1999/017663 patent/WO2000012227A1/en not_active Ceased
- 1999-08-03 ID IDW20010462A patent/ID28770A/id unknown
- 1999-08-03 CA CA002341985A patent/CA2341985C/en not_active Expired - Fee Related
- 1999-08-03 EP EP99938991A patent/EP1113886B1/en not_active Expired - Lifetime
- 1999-08-03 BR BR9913265-6A patent/BR9913265A/pt not_active IP Right Cessation
- 1999-08-03 CN CNB998127051A patent/CN1173784C/zh not_active Expired - Lifetime
- 1999-08-03 TR TR2001/00658T patent/TR200100658T2/xx unknown
- 1999-08-03 KR KR1020017002425A patent/KR100637616B1/ko not_active Expired - Lifetime
- 1999-08-03 DE DE69937957T patent/DE69937957T2/de not_active Expired - Lifetime
- 1999-08-03 ES ES99938991T patent/ES2299255T3/es not_active Expired - Lifetime
- 1999-08-03 AU AU53360/99A patent/AU755529B2/en not_active Ceased
- 1999-08-03 AT AT99938991T patent/ATE383208T1/de not_active IP Right Cessation
- 1999-08-03 JP JP2000567315A patent/JP4240816B2/ja not_active Expired - Lifetime
- 1999-08-25 CO CO99053807A patent/CO5100955A1/es unknown
- 1999-10-18 US US09/420,100 patent/US6218019B1/en not_active Expired - Lifetime
-
2000
- 2000-11-29 US US09/724,467 patent/US6432200B2/en not_active Expired - Lifetime
-
2001
- 2001-02-23 ZA ZA200101533A patent/ZA200101533B/en unknown
-
2002
- 2002-07-02 AR ARP020102487A patent/AR034684A2/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| TR200100658T2 (tr) | 2001-06-21 |
| TW568957B (en) | 2004-01-01 |
| KR100637616B1 (ko) | 2006-10-24 |
| AR034684A2 (es) | 2004-03-03 |
| HK1040657A1 (en) | 2002-06-21 |
| WO2000012227A1 (en) | 2000-03-09 |
| AR019240A1 (es) | 2001-12-26 |
| AU5336099A (en) | 2000-03-21 |
| AU755529B2 (en) | 2002-12-12 |
| CA2341985A1 (en) | 2000-03-09 |
| DE69937957D1 (de) | 2008-02-21 |
| EP1113886A4 (en) | 2003-05-14 |
| US6017580A (en) | 2000-01-25 |
| JP4240816B2 (ja) | 2009-03-18 |
| CO5100955A1 (es) | 2001-11-27 |
| ID28770A (id) | 2001-06-28 |
| ZA200101533B (en) | 2002-02-25 |
| CA2341985C (en) | 2008-02-19 |
| EP1113886B1 (en) | 2008-01-09 |
| ATE383208T1 (de) | 2008-01-15 |
| CN1324275A (zh) | 2001-11-28 |
| US6432200B2 (en) | 2002-08-13 |
| KR20010072978A (ko) | 2001-07-31 |
| ES2299255T3 (es) | 2008-05-16 |
| US20010000332A1 (en) | 2001-04-19 |
| JP2002523628A (ja) | 2002-07-30 |
| CN1173784C (zh) | 2004-11-03 |
| BR9913265A (pt) | 2002-01-15 |
| US6218019B1 (en) | 2001-04-17 |
| EP1113886A1 (en) | 2001-07-11 |
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