KR100637616B1 - 거울의 제조방법 및 이의 제조장치 - Google Patents
거울의 제조방법 및 이의 제조장치 Download PDFInfo
- Publication number
- KR100637616B1 KR100637616B1 KR1020017002425A KR20017002425A KR100637616B1 KR 100637616 B1 KR100637616 B1 KR 100637616B1 KR 1020017002425 A KR1020017002425 A KR 1020017002425A KR 20017002425 A KR20017002425 A KR 20017002425A KR 100637616 B1 KR100637616 B1 KR 100637616B1
- Authority
- KR
- South Korea
- Prior art keywords
- silver
- mirror
- solution
- specific
- cation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 25
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 111
- 229910052709 silver Inorganic materials 0.000 claims abstract description 108
- 239000004332 silver Substances 0.000 claims abstract description 108
- 238000000034 method Methods 0.000 claims abstract description 46
- 150000001768 cations Chemical class 0.000 claims abstract description 36
- 230000007797 corrosion Effects 0.000 claims abstract description 34
- 238000005260 corrosion Methods 0.000 claims abstract description 34
- 150000001450 anions Chemical class 0.000 claims abstract description 32
- 239000002244 precipitate Substances 0.000 claims abstract description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 27
- -1 hydroxyl ions Chemical class 0.000 claims abstract description 23
- 239000000126 substance Substances 0.000 claims abstract description 15
- 239000011521 glass Substances 0.000 claims description 48
- 239000010410 layer Substances 0.000 claims description 36
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- 239000000758 substrate Substances 0.000 claims description 20
- 239000000047 product Substances 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000001556 precipitation Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 8
- 230000001235 sensitizing effect Effects 0.000 claims description 7
- 239000011241 protective layer Substances 0.000 claims description 5
- 229910008449 SnF 2 Inorganic materials 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 230000002708 enhancing effect Effects 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 3
- 229910001432 tin ion Inorganic materials 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000010949 copper Substances 0.000 abstract description 25
- 229910052802 copper Inorganic materials 0.000 abstract description 24
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 23
- 229910052718 tin Inorganic materials 0.000 abstract description 22
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- 239000000243 solution Substances 0.000 description 79
- 238000012360 testing method Methods 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 16
- 239000011734 sodium Substances 0.000 description 12
- 239000003973 paint Substances 0.000 description 11
- 230000008569 process Effects 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 8
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 7
- GSJBKPNSLRKRNR-UHFFFAOYSA-N $l^{2}-stannanylidenetin Chemical compound [Sn].[Sn] GSJBKPNSLRKRNR-UHFFFAOYSA-N 0.000 description 6
- 230000007547 defect Effects 0.000 description 6
- 208000014451 palmoplantar keratoderma and congenital alopecia 2 Diseases 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002923 metal particle Substances 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 239000011630 iodine Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000007323 disproportionation reaction Methods 0.000 description 2
- 150000002443 hydroxylamines Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- YMPYFFXCTQBDLV-UHFFFAOYSA-F [Sn+4].[Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O Chemical compound [Sn+4].[Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O YMPYFFXCTQBDLV-UHFFFAOYSA-F 0.000 description 1
- QKNALXSEDPJVFW-UHFFFAOYSA-J [Sn].[Sn](Cl)(Cl)(Cl)Cl Chemical compound [Sn].[Sn](Cl)(Cl)(Cl)Cl QKNALXSEDPJVFW-UHFFFAOYSA-J 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229940045803 cuprous chloride Drugs 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- AICMYQIGFPHNCY-UHFFFAOYSA-J methanesulfonate;tin(4+) Chemical compound [Sn+4].CS([O-])(=O)=O.CS([O-])(=O)=O.CS([O-])(=O)=O.CS([O-])(=O)=O AICMYQIGFPHNCY-UHFFFAOYSA-J 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- NGBNXJUWQPLNGM-UHFFFAOYSA-N silver;azane Chemical compound N.[Ag+] NGBNXJUWQPLNGM-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- LTSUHJWLSNQKIP-UHFFFAOYSA-J tin(iv) bromide Chemical compound Br[Sn](Br)(Br)Br LTSUHJWLSNQKIP-UHFFFAOYSA-J 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- YUOWTJMRMWQJDA-UHFFFAOYSA-J tin(iv) fluoride Chemical compound [F-].[F-].[F-].[F-].[Sn+4] YUOWTJMRMWQJDA-UHFFFAOYSA-J 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3605—Coatings of the type glass/metal/inorganic compound
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/3663—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties specially adapted for use as mirrors
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/38—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/08—Corrosion or deposition inhibiting
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemically Coating (AREA)
- Surface Treatment Of Glass (AREA)
- Mirrors, Picture Frames, Photograph Stands, And Related Fastening Devices (AREA)
- Optical Elements Other Than Lenses (AREA)
- Laminated Bodies (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/143,685 US6017580A (en) | 1998-08-28 | 1998-08-28 | Silver film incorporating protective insoluble metallic salt precipitate |
| US09/143,685 | 1998-08-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20010072978A KR20010072978A (ko) | 2001-07-31 |
| KR100637616B1 true KR100637616B1 (ko) | 2006-10-24 |
Family
ID=22505144
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020017002425A Expired - Lifetime KR100637616B1 (ko) | 1998-08-28 | 1999-08-03 | 거울의 제조방법 및 이의 제조장치 |
Country Status (18)
| Country | Link |
|---|---|
| US (3) | US6017580A (enExample) |
| EP (1) | EP1113886B1 (enExample) |
| JP (1) | JP4240816B2 (enExample) |
| KR (1) | KR100637616B1 (enExample) |
| CN (1) | CN1173784C (enExample) |
| AR (2) | AR019240A1 (enExample) |
| AT (1) | ATE383208T1 (enExample) |
| AU (1) | AU755529B2 (enExample) |
| BR (1) | BR9913265A (enExample) |
| CA (1) | CA2341985C (enExample) |
| CO (1) | CO5100955A1 (enExample) |
| DE (1) | DE69937957T2 (enExample) |
| ES (1) | ES2299255T3 (enExample) |
| ID (1) | ID28770A (enExample) |
| TR (1) | TR200100658T2 (enExample) |
| TW (1) | TW568957B (enExample) |
| WO (1) | WO2000012227A1 (enExample) |
| ZA (1) | ZA200101533B (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5933421A (en) * | 1997-02-06 | 1999-08-03 | At&T Wireless Services Inc. | Method for frequency division duplex communications |
| US6017580A (en) * | 1998-08-28 | 2000-01-25 | Lilly Industries, (Usa), Inc. | Silver film incorporating protective insoluble metallic salt precipitate |
| JP3352422B2 (ja) * | 1999-02-10 | 2002-12-03 | セントラル硝子株式会社 | 銀被膜形成用薬液および銀被膜形成方法 |
| DE10009598A1 (de) * | 2000-02-29 | 2001-09-06 | Bosch Gmbh Robert | Verfahren und Vorrichtung zur Abscheidung einer Beschichtung auf einem Substrat durch Versprühen einer Flüssigkeit |
| JP3455912B2 (ja) | 2001-10-22 | 2003-10-14 | 株式会社金属化工技術研究所 | 銀鏡用活性化処理剤 |
| US6979478B1 (en) | 2002-08-01 | 2005-12-27 | Hilemn, Llc | Paint for silver film protection and method |
| EP1570080A4 (en) | 2002-11-15 | 2006-03-01 | Genomic Health Inc | GENE EXPRESSION PROFILING OF EGFR-POSITIVE CANCER DISEASE |
| US7758966B2 (en) * | 2004-03-18 | 2010-07-20 | Agc Glass Europe | Mirror |
| JP4807957B2 (ja) * | 2005-02-10 | 2011-11-02 | セントラル硝子株式会社 | 水性の鏡用縁塗り液およびそれを用いた鏡 |
| EP1883610B1 (en) * | 2005-05-06 | 2015-07-15 | Valspar Sourcing, Inc. | Activation method to enhance adhesion of a metal coating on a substrate |
| WO2007144311A1 (en) * | 2006-06-16 | 2007-12-21 | Agc Flat Glass Europe Sa | Mirror |
| EP2167069B1 (en) | 2007-05-23 | 2011-10-26 | Amcol International Corporation | Cholesterol-interacting layered phyllosilicates and methods of reducing hypercholesteremia in a mammal |
| DE102007051684B4 (de) * | 2007-10-26 | 2009-11-05 | Dr.-Ing. Schmitt Gmbh | Verfahren und Mittel zur Herstellung von kupferlosen Spiegeln |
| CN101200350B (zh) * | 2007-12-18 | 2012-08-22 | 张家港雅博纳米材料科技有限公司 | 银镜镀层的加工方法 |
| EP2271879B1 (en) * | 2007-12-21 | 2018-02-21 | AGC Glass Europe | Solar energy reflector |
| KR100862502B1 (ko) * | 2008-02-05 | 2008-10-08 | 삼화페인트 공업주식회사 | 은경액 조성물 및 이를 이용한 online 방식의은경막 제조방법 |
| US20110261473A1 (en) | 2008-04-15 | 2011-10-27 | Valspar Sourcing, Inc. | Articles Having Improved Corrosion Resistance |
| FR2943144B1 (fr) * | 2009-03-13 | 2012-12-14 | Jet Metal Technologies | Miroir anticorrosion, son procede de fabrication et ses applications dans la recuperation de l'energie solaire |
| BE1021679B1 (fr) * | 2012-09-17 | 2016-01-08 | Agc Glass Europe | Procede de fabrication d'un miroir sans couche de cuivre |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5240776A (en) * | 1990-11-03 | 1993-08-31 | Glaverbel | Corrosion resistant reflective articles |
| WO1996021752A1 (en) * | 1995-01-10 | 1996-07-18 | Circle-Prosco, Inc. | A process of coating metal surfaces to produce a highly hydrophilic, highly corrosion resistant surface with bioresistance and low odor impact characteristics |
| US9621752B2 (en) * | 2014-09-30 | 2017-04-11 | Ricoh Company, Ltd. | Image forming apparatus incorporating information detector |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2759845A (en) * | 1954-10-25 | 1956-08-21 | Metropolitan Mirror And Glass | Processes of precipitating copper from copper sulfate solutions and precipitating media for so doing |
| BE723176A (enExample) * | 1968-08-27 | 1969-04-01 | ||
| CA1188288A (en) * | 1983-03-02 | 1985-06-04 | Pierre Mathieu | Method for producing a catalyst for oxidizing carbon monoxide |
| IT1177081B (it) * | 1984-10-30 | 1987-08-26 | Vitreal Specchi Spa | Apparecchiatura per l'incisione in continuo all'acido su una faccia di lastre di vetro |
| US4707405A (en) * | 1985-01-02 | 1987-11-17 | Ppg Industries, Inc. | Cyanamide salts of non-lead metals as corrosion inhibitive pigments in mirror back coatings |
| US5292354A (en) * | 1986-12-04 | 1994-03-08 | Glaverbel, Societe Anonyme | Method of producing dealkalized sheet glass |
| US4737188A (en) * | 1987-05-18 | 1988-04-12 | London Laboratories Limited | Reducing agent and method for the electroless deposition of silver |
| IL86366A0 (en) * | 1988-05-12 | 1988-11-15 | Luz Ind Israel Ltd | Protected silvered substrates and mirrors containing the same |
| US5156917A (en) * | 1990-01-11 | 1992-10-20 | Lilly Industries, Inc. | Mirrorback coating |
| US5487779A (en) * | 1993-11-19 | 1996-01-30 | Wayne Pigment Corp. | Corrosion inhibiting pigment composition and method |
| US5419926A (en) * | 1993-11-22 | 1995-05-30 | Lilly London, Inc. | Ammonia-free deposition of copper by disproportionation |
| US5487482A (en) | 1994-01-14 | 1996-01-30 | Rocheleau; Lawrence W. | Handled closure device |
| KR0180850B1 (ko) * | 1996-06-26 | 1999-03-20 | 구자홍 | 유리기판 에칭장치 |
| US6017580A (en) * | 1998-08-28 | 2000-01-25 | Lilly Industries, (Usa), Inc. | Silver film incorporating protective insoluble metallic salt precipitate |
-
1998
- 1998-08-28 US US09/143,685 patent/US6017580A/en not_active Expired - Lifetime
-
1999
- 1999-07-19 TW TW088112219A patent/TW568957B/zh not_active IP Right Cessation
- 1999-07-21 AR ARP990103574A patent/AR019240A1/es active IP Right Grant
- 1999-08-03 TR TR2001/00658T patent/TR200100658T2/xx unknown
- 1999-08-03 AU AU53360/99A patent/AU755529B2/en not_active Ceased
- 1999-08-03 BR BR9913265-6A patent/BR9913265A/pt not_active IP Right Cessation
- 1999-08-03 WO PCT/US1999/017663 patent/WO2000012227A1/en not_active Ceased
- 1999-08-03 CN CNB998127051A patent/CN1173784C/zh not_active Expired - Lifetime
- 1999-08-03 CA CA002341985A patent/CA2341985C/en not_active Expired - Fee Related
- 1999-08-03 AT AT99938991T patent/ATE383208T1/de not_active IP Right Cessation
- 1999-08-03 ES ES99938991T patent/ES2299255T3/es not_active Expired - Lifetime
- 1999-08-03 JP JP2000567315A patent/JP4240816B2/ja not_active Expired - Lifetime
- 1999-08-03 KR KR1020017002425A patent/KR100637616B1/ko not_active Expired - Lifetime
- 1999-08-03 ID IDW20010462A patent/ID28770A/id unknown
- 1999-08-03 EP EP99938991A patent/EP1113886B1/en not_active Expired - Lifetime
- 1999-08-03 DE DE69937957T patent/DE69937957T2/de not_active Expired - Lifetime
- 1999-08-25 CO CO99053807A patent/CO5100955A1/es unknown
- 1999-10-18 US US09/420,100 patent/US6218019B1/en not_active Expired - Lifetime
-
2000
- 2000-11-29 US US09/724,467 patent/US6432200B2/en not_active Expired - Lifetime
-
2001
- 2001-02-23 ZA ZA200101533A patent/ZA200101533B/en unknown
-
2002
- 2002-07-02 AR ARP020102487A patent/AR034684A2/es active IP Right Grant
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5240776A (en) * | 1990-11-03 | 1993-08-31 | Glaverbel | Corrosion resistant reflective articles |
| WO1996021752A1 (en) * | 1995-01-10 | 1996-07-18 | Circle-Prosco, Inc. | A process of coating metal surfaces to produce a highly hydrophilic, highly corrosion resistant surface with bioresistance and low odor impact characteristics |
| US9621752B2 (en) * | 2014-09-30 | 2017-04-11 | Ricoh Company, Ltd. | Image forming apparatus incorporating information detector |
Non-Patent Citations (2)
| Title |
|---|
| 국제특허 제9621752호 |
| 미국특허 제5,240,776호 |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA200101533B (en) | 2002-02-25 |
| AU5336099A (en) | 2000-03-21 |
| AR019240A1 (es) | 2001-12-26 |
| WO2000012227A1 (en) | 2000-03-09 |
| CA2341985A1 (en) | 2000-03-09 |
| TW568957B (en) | 2004-01-01 |
| AR034684A2 (es) | 2004-03-03 |
| ATE383208T1 (de) | 2008-01-15 |
| DE69937957T2 (de) | 2009-01-08 |
| EP1113886A4 (en) | 2003-05-14 |
| TR200100658T2 (tr) | 2001-06-21 |
| EP1113886B1 (en) | 2008-01-09 |
| US6218019B1 (en) | 2001-04-17 |
| HK1040657A1 (en) | 2002-06-21 |
| CN1324275A (zh) | 2001-11-28 |
| DE69937957D1 (de) | 2008-02-21 |
| ID28770A (id) | 2001-06-28 |
| CO5100955A1 (es) | 2001-11-27 |
| US20010000332A1 (en) | 2001-04-19 |
| US6017580A (en) | 2000-01-25 |
| ES2299255T3 (es) | 2008-05-16 |
| EP1113886A1 (en) | 2001-07-11 |
| JP2002523628A (ja) | 2002-07-30 |
| CA2341985C (en) | 2008-02-19 |
| JP4240816B2 (ja) | 2009-03-18 |
| CN1173784C (zh) | 2004-11-03 |
| BR9913265A (pt) | 2002-01-15 |
| KR20010072978A (ko) | 2001-07-31 |
| AU755529B2 (en) | 2002-12-12 |
| US6432200B2 (en) | 2002-08-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100637616B1 (ko) | 거울의 제조방법 및 이의 제조장치 | |
| JP3029187B2 (ja) | ガラス質基体上に銀被覆を形成する方法 | |
| US5006418A (en) | Decorative mirror | |
| JPH04292441A (ja) | 反射性物品の製造 | |
| JP3352422B2 (ja) | 銀被膜形成用薬液および銀被膜形成方法 | |
| US20150056459A1 (en) | Articles Having Improved Corrosion Resistance | |
| US3404046A (en) | Chromating of zinc and aluminum and composition therefor | |
| EP1883610B1 (en) | Activation method to enhance adhesion of a metal coating on a substrate | |
| AT397817B (de) | Verfahren zur herstellung eines kupferspiegels | |
| JP6286431B2 (ja) | 銅層を有さない鏡の製造方法 | |
| MXPA01002027A (en) | Silver film incorporating protective insoluble metallic salt precipitate | |
| US20040115448A1 (en) | Corrosion resistant magnesium and magnesium alloy and method of producing same | |
| HK1040657B (en) | A mirror having enhanced corrosion resistance of a silver surface, the method for making it and the apparatus used | |
| US3644152A (en) | Method and composition for producing a black matte finish on ferrous metals | |
| EP1860076B1 (en) | Mirror |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20010226 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20040729 Comment text: Request for Examination of Application |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20051221 Patent event code: PE09021S01D |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 20060721 |
|
| GRNT | Written decision to grant | ||
| PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 20061017 Patent event code: PR07011E01D |
|
| PR1002 | Payment of registration fee |
Payment date: 20061018 End annual number: 3 Start annual number: 1 |
|
| PG1601 | Publication of registration | ||
| PR1001 | Payment of annual fee |
Payment date: 20091014 Start annual number: 4 End annual number: 4 |
|
| PR1001 | Payment of annual fee |
Payment date: 20101014 Start annual number: 5 End annual number: 5 |
|
| PR1001 | Payment of annual fee |
Payment date: 20111007 Start annual number: 6 End annual number: 6 |
|
| FPAY | Annual fee payment |
Payment date: 20121008 Year of fee payment: 7 |
|
| PR1001 | Payment of annual fee |
Payment date: 20121008 Start annual number: 7 End annual number: 7 |
|
| FPAY | Annual fee payment |
Payment date: 20131008 Year of fee payment: 8 |
|
| PR1001 | Payment of annual fee |
Payment date: 20131008 Start annual number: 8 End annual number: 8 |
|
| FPAY | Annual fee payment |
Payment date: 20141007 Year of fee payment: 9 |
|
| PR1001 | Payment of annual fee |
Payment date: 20141007 Start annual number: 9 End annual number: 9 |
|
| FPAY | Annual fee payment |
Payment date: 20151006 Year of fee payment: 10 |
|
| PR1001 | Payment of annual fee |
Payment date: 20151006 Start annual number: 10 End annual number: 10 |
|
| FPAY | Annual fee payment |
Payment date: 20161011 Year of fee payment: 11 |
|
| PR1001 | Payment of annual fee |
Payment date: 20161011 Start annual number: 11 End annual number: 11 |
|
| FPAY | Annual fee payment |
Payment date: 20171012 Year of fee payment: 12 |
|
| PR1001 | Payment of annual fee |
Payment date: 20171012 Start annual number: 12 End annual number: 12 |
|
| FPAY | Annual fee payment |
Payment date: 20181010 Year of fee payment: 13 |
|
| PR1001 | Payment of annual fee |
Payment date: 20181010 Start annual number: 13 End annual number: 13 |
|
| EXPY | Expiration of term | ||
| PC1801 | Expiration of term |
Termination date: 20200203 Termination category: Expiration of duration |