DE69917959T2 - In Emulsion hergestellter Styrene-Butadien-Kautschuk - Google Patents
In Emulsion hergestellter Styrene-Butadien-Kautschuk Download PDFInfo
- Publication number
- DE69917959T2 DE69917959T2 DE69917959T DE69917959T DE69917959T2 DE 69917959 T2 DE69917959 T2 DE 69917959T2 DE 69917959 T DE69917959 T DE 69917959T DE 69917959 T DE69917959 T DE 69917959T DE 69917959 T2 DE69917959 T2 DE 69917959T2
- Authority
- DE
- Germany
- Prior art keywords
- styrene
- butadiene rubber
- molecular weight
- emulsion
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920003048 styrene butadiene rubber Polymers 0.000 title claims abstract description 374
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 192
- 239000002174 Styrene-butadiene Substances 0.000 claims abstract description 192
- 239000000203 mixture Substances 0.000 claims abstract description 189
- 239000000839 emulsion Substances 0.000 claims abstract description 103
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 95
- 238000000149 argon plasma sintering Methods 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 17
- 238000003860 storage Methods 0.000 claims abstract description 9
- 238000001495 thermal field-flow fractionation Methods 0.000 claims abstract description 9
- 229920001971 elastomer Polymers 0.000 claims description 127
- 239000005060 rubber Substances 0.000 claims description 124
- 238000006116 polymerization reaction Methods 0.000 claims description 70
- 239000000178 monomer Substances 0.000 claims description 57
- 229920000126 latex Polymers 0.000 claims description 54
- 239000004816 latex Substances 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 48
- 229920001195 polyisoprene Polymers 0.000 claims description 43
- 239000000344 soap Substances 0.000 claims description 39
- 238000006243 chemical reaction Methods 0.000 claims description 31
- 229920002857 polybutadiene Polymers 0.000 claims description 28
- 230000008569 process Effects 0.000 claims description 21
- 239000011324 bead Substances 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 19
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 claims description 18
- 229920001194 natural rubber Polymers 0.000 claims description 18
- 244000043261 Hevea brasiliensis Species 0.000 claims description 17
- 229920003052 natural elastomer Polymers 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000007334 copolymerization reaction Methods 0.000 claims description 11
- 239000005062 Polybutadiene Substances 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 5
- 239000011115 styrene butadiene Substances 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005065 High vinyl polybutadiene Substances 0.000 claims description 3
- 229920005683 SIBR Polymers 0.000 claims description 3
- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 claims description 3
- 229920003049 isoprene rubber Polymers 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229920003194 trans-1,4-polybutadiene polymer Polymers 0.000 claims description 2
- 239000005063 High cis polybutadiene Substances 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 43
- 238000005096 rolling process Methods 0.000 abstract description 14
- 238000009472 formulation Methods 0.000 abstract description 8
- 230000010355 oscillation Effects 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 59
- 239000000377 silicon dioxide Substances 0.000 description 29
- 239000000243 solution Substances 0.000 description 27
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 24
- 239000011593 sulfur Substances 0.000 description 24
- 229910052717 sulfur Inorganic materials 0.000 description 24
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 19
- 150000003254 radicals Chemical class 0.000 description 19
- 239000006229 carbon black Substances 0.000 description 17
- 239000003999 initiator Substances 0.000 description 16
- 238000007720 emulsion polymerization reaction Methods 0.000 description 14
- 239000004636 vulcanized rubber Substances 0.000 description 14
- 239000003963 antioxidant agent Substances 0.000 description 13
- 238000012545 processing Methods 0.000 description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 230000003078 antioxidant effect Effects 0.000 description 12
- 239000003921 oil Substances 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
- 239000000194 fatty acid Substances 0.000 description 11
- 229930195729 fatty acid Natural products 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 11
- 239000011787 zinc oxide Substances 0.000 description 10
- 230000006399 behavior Effects 0.000 description 9
- 239000000945 filler Substances 0.000 description 9
- 238000010058 rubber compounding Methods 0.000 description 9
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 8
- 229910052700 potassium Inorganic materials 0.000 description 8
- 239000011591 potassium Substances 0.000 description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000005345 coagulation Methods 0.000 description 7
- -1 dodecylmercaptan Chemical compound 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 238000005227 gel permeation chromatography Methods 0.000 description 7
- 150000003961 organosilicon compounds Chemical class 0.000 description 7
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 7
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 6
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 230000015271 coagulation Effects 0.000 description 6
- 239000004200 microcrystalline wax Substances 0.000 description 6
- 235000019808 microcrystalline wax Nutrition 0.000 description 6
- 239000012188 paraffin wax Substances 0.000 description 6
- 239000004071 soot Substances 0.000 description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 5
- 238000005194 fractionation Methods 0.000 description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 238000001256 steam distillation Methods 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 230000000930 thermomechanical effect Effects 0.000 description 5
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 4
- LIZVXGBYTGTTTI-UHFFFAOYSA-N 2-[(4-methylphenyl)sulfonylamino]-2-phenylacetic acid Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(C(O)=O)C1=CC=CC=C1 LIZVXGBYTGTTTI-UHFFFAOYSA-N 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 238000010924 continuous production Methods 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 4
- 239000008149 soap solution Substances 0.000 description 4
- 239000003784 tall oil Substances 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 241001441571 Hiodontidae Species 0.000 description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000012986 chain transfer agent Substances 0.000 description 3
- 230000001112 coagulating effect Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000002516 radical scavenger Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920003051 synthetic elastomer Polymers 0.000 description 3
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 3
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 3
- 229960002447 thiram Drugs 0.000 description 3
- 239000003981 vehicle Substances 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 238000010074 rubber mixing Methods 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- MKWYFZFMAMBPQK-UHFFFAOYSA-J sodium feredetate Chemical compound [Na+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O MKWYFZFMAMBPQK-UHFFFAOYSA-J 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 2
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
- SYXTYIFRUXOUQP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy butaneperoxoate Chemical compound CCCC(=O)OOOC(C)(C)C SYXTYIFRUXOUQP-UHFFFAOYSA-N 0.000 description 1
- BLKRGXCGFRXRNQ-SNAWJCMRSA-N (z)-3-carbonoperoxoyl-4,4-dimethylpent-2-enoic acid Chemical compound OC(=O)/C=C(C(C)(C)C)\C(=O)OO BLKRGXCGFRXRNQ-SNAWJCMRSA-N 0.000 description 1
- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 description 1
- CORMBJOFDGICKF-UHFFFAOYSA-N 1,3,5-trimethoxy 2-vinyl benzene Natural products COC1=CC(OC)=C(C=C)C(OC)=C1 CORMBJOFDGICKF-UHFFFAOYSA-N 0.000 description 1
- YOSRRIGSGJDAJR-UHFFFAOYSA-N 1-(2-dimethoxysilylpropyltrisulfanyl)propan-2-yl-dimethoxysilane Chemical compound CC(CSSSCC(C)[SiH](OC)OC)[SiH](OC)OC YOSRRIGSGJDAJR-UHFFFAOYSA-N 0.000 description 1
- LYPJSBQIFJESQY-UHFFFAOYSA-N 1-(3-diethoxysilylhexyldisulfanyl)hexan-3-yl-diethoxysilane Chemical compound C(CC)C(CCSSCCC(CCC)[SiH](OCC)OCC)[SiH](OCC)OCC LYPJSBQIFJESQY-UHFFFAOYSA-N 0.000 description 1
- BULPGPDAJKQNHS-UHFFFAOYSA-N 1-(3-dimethoxysilylheptyltrisulfanyl)heptan-3-yl-dimethoxysilane Chemical compound C(CCC)C(CCSSSCCC(CCCC)[SiH](OC)OC)[SiH](OC)OC BULPGPDAJKQNHS-UHFFFAOYSA-N 0.000 description 1
- WJNKJKGZKFOLOJ-UHFFFAOYSA-N 1-dodecyl-4-ethenylbenzene Chemical compound CCCCCCCCCCCCC1=CC=C(C=C)C=C1 WJNKJKGZKFOLOJ-UHFFFAOYSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- YHOMZMOAUNOPCN-UHFFFAOYSA-N 1-ethenyl-2,3,4,5-tetraethylbenzene Chemical compound CCC1=CC(C=C)=C(CC)C(CC)=C1CC YHOMZMOAUNOPCN-UHFFFAOYSA-N 0.000 description 1
- HVOKBODBWQEEGI-UHFFFAOYSA-N 1-ethenyl-3,5-diethylbenzene Chemical compound CCC1=CC(CC)=CC(C=C)=C1 HVOKBODBWQEEGI-UHFFFAOYSA-N 0.000 description 1
- XSHXURIGVYRXAD-UHFFFAOYSA-N 1-ethenyl-3,5-diphenylbenzene Chemical compound C=1C(C=C)=CC(C=2C=CC=CC=2)=CC=1C1=CC=CC=C1 XSHXURIGVYRXAD-UHFFFAOYSA-N 0.000 description 1
- LFZRKMOWVSTEMD-UHFFFAOYSA-N 1-ethenyl-3-ethylnaphthalene Chemical compound C1=CC=CC2=CC(CC)=CC(C=C)=C21 LFZRKMOWVSTEMD-UHFFFAOYSA-N 0.000 description 1
- XTUJFEHBYGQMFD-UHFFFAOYSA-N 1-ethenyl-3-hexyl-5-methylbenzene Chemical compound CCCCCCC1=CC(C)=CC(C=C)=C1 XTUJFEHBYGQMFD-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- VVTGQMLRTKFKAM-UHFFFAOYSA-N 1-ethenyl-4-propylbenzene Chemical compound CCCC1=CC=C(C=C)C=C1 VVTGQMLRTKFKAM-UHFFFAOYSA-N 0.000 description 1
- ZUJBNWMWGTYWMW-UHFFFAOYSA-N 1-ethenyl-6-propan-2-ylnaphthalene Chemical compound C=CC1=CC=CC2=CC(C(C)C)=CC=C21 ZUJBNWMWGTYWMW-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- HQOVXPHOJANJBR-UHFFFAOYSA-N 2,2-bis(tert-butylperoxy)butane Chemical compound CC(C)(C)OOC(C)(CC)OOC(C)(C)C HQOVXPHOJANJBR-UHFFFAOYSA-N 0.000 description 1
- GSFSVEDCYBDIGW-UHFFFAOYSA-N 2-(1,3-benzothiazol-2-yl)-6-chlorophenol Chemical compound OC1=C(Cl)C=CC=C1C1=NC2=CC=CC=C2S1 GSFSVEDCYBDIGW-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- PYKCEDJHRUUDRK-UHFFFAOYSA-N 2-(tert-butyldiazenyl)-2-methylpropanenitrile Chemical compound CC(C)(C)N=NC(C)(C)C#N PYKCEDJHRUUDRK-UHFFFAOYSA-N 0.000 description 1
- WGUWOLAXPCRPKH-UHFFFAOYSA-N 2-(tert-butyldiazenyl)cyclohexane-1-carbonitrile Chemical compound CC(C)(C)N=NC1CCCCC1C#N WGUWOLAXPCRPKH-UHFFFAOYSA-N 0.000 description 1
- ABERXULXRGIGTD-UHFFFAOYSA-N 2-dodecyl-7-ethenylnaphthalene Chemical compound C1=CC(C=C)=CC2=CC(CCCCCCCCCCCC)=CC=C21 ABERXULXRGIGTD-UHFFFAOYSA-N 0.000 description 1
- PDELBHCVXBSVPJ-UHFFFAOYSA-N 2-ethenyl-1,3,5-trimethylbenzene Chemical compound CC1=CC(C)=C(C=C)C(C)=C1 PDELBHCVXBSVPJ-UHFFFAOYSA-N 0.000 description 1
- XYFRHHAYSXIKGH-UHFFFAOYSA-N 3-(5-methoxy-2-methoxycarbonyl-1h-indol-3-yl)prop-2-enoic acid Chemical compound C1=C(OC)C=C2C(C=CC(O)=O)=C(C(=O)OC)NC2=C1 XYFRHHAYSXIKGH-UHFFFAOYSA-N 0.000 description 1
- CSIPGRDAPMEMLW-UHFFFAOYSA-N 3-ethoxypropoxy-[1-[2-(3-ethoxypropoxysilyl)propyltetrasulfanyl]propan-2-yl]silane Chemical compound CC(CSSSSCC(C)[SiH2]OCCCOCC)[SiH2]OCCCOCC CSIPGRDAPMEMLW-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- DXFURPHVJQITAC-UHFFFAOYSA-N 4-benzyl-1-ethenyl-2-ethylbenzene Chemical compound C1=C(C=C)C(CC)=CC(CC=2C=CC=CC=2)=C1 DXFURPHVJQITAC-UHFFFAOYSA-N 0.000 description 1
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 1
- GYLGGODPGFTNRX-UHFFFAOYSA-N 6-cyclohexyl-1-ethenylnaphthalene Chemical compound C=1C=C2C(C=C)=CC=CC2=CC=1C1CCCCC1 GYLGGODPGFTNRX-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- JXWBEOBROLXBGC-UHFFFAOYSA-N CO[SiH2]C(C)(C)CSSCC(C)(C)[SiH2]OC Chemical compound CO[SiH2]C(C)(C)CSSCC(C)(C)[SiH2]OC JXWBEOBROLXBGC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- NVHLTUPSVCBIJJ-UHFFFAOYSA-N [1-[(1,2-dimethoxy-2-methyl-1-phenylsilylpropyl)disulfanyl]-1,2-dimethoxy-2-methylpropyl]-phenylsilane Chemical compound COC(C([SiH2]C1=CC=CC=C1)(OC)SSC(C(C)(OC)C)(OC)[SiH2]C1=CC=CC=C1)(C)C NVHLTUPSVCBIJJ-UHFFFAOYSA-N 0.000 description 1
- SKFWHOBZYWUYMC-UHFFFAOYSA-N [2-[(2-diethoxysilyl-2-methoxyethyl)tetrasulfanyl]-1-methoxyethyl]-diethoxysilane Chemical compound CCO[SiH](OCC)C(OC)CSSSSCC(OC)[SiH](OCC)OCC SKFWHOBZYWUYMC-UHFFFAOYSA-N 0.000 description 1
- PZZINDDYVJCEGV-UHFFFAOYSA-N [3,3,3-trimethoxy-2-methyl-1-[(3,3,3-trimethoxy-2-methyl-1-silylpropyl)tetrasulfanyl]propyl]silane Chemical compound COC(C(C([SiH3])SSSSC(C(C(OC)(OC)OC)C)[SiH3])C)(OC)OC PZZINDDYVJCEGV-UHFFFAOYSA-N 0.000 description 1
- PWRCPTKSXMCQLS-UHFFFAOYSA-N [3-[(3,3-diphenyl-3-propan-2-yloxysilylpropyl)tetrasulfanyl]-1,1-diphenylpropyl]-propan-2-yloxysilane Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)([SiH2]OC(C)C)CCSSSSCCC([SiH2]OC(C)C)(C=1C=CC=CC=1)C1=CC=CC=C1 PWRCPTKSXMCQLS-UHFFFAOYSA-N 0.000 description 1
- AIQUYWRDQFFHKH-UHFFFAOYSA-N [3-[(3-dimethoxysilyl-3-phenylpropyl)tetrasulfanyl]-1-phenylpropyl]-dimethoxysilane Chemical compound C1(=CC=CC=C1)C(CCSSSSCCC(C1=CC=CC=C1)[SiH](OC)OC)[SiH](OC)OC AIQUYWRDQFFHKH-UHFFFAOYSA-N 0.000 description 1
- WGVIKVJFYJSWDB-UHFFFAOYSA-N [3-[2-[(3-tert-butyl-3-methoxysilyl-4,4-dimethylpentyl)tetrasulfanyl]ethyl]-2,2,4,4-tetramethylpentan-3-yl]-methoxysilane Chemical compound C(C)(C)(C)C(CCSSSSCCC(C(C)(C)C)(C(C)(C)C)[SiH2]OC)([SiH2]OC)C(C)(C)C WGVIKVJFYJSWDB-UHFFFAOYSA-N 0.000 description 1
- UHBSMIYRAQANCI-UHFFFAOYSA-N [3-ethyl-1-[(3-ethyl-3-methoxysilylpentyl)tetrasulfanyl]pentan-3-yl]-methoxysilane Chemical compound C(C)C(CCSSSSCCC(CC)(CC)[SiH2]OC)([SiH2]OC)CC UHBSMIYRAQANCI-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Natural products CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GITLYQNXZPGJRU-UHFFFAOYSA-N butan-2-yloxy-[1-[(2-butan-2-yloxysilyl-2-methylpropyl)trisulfanyl]-2-methylpropan-2-yl]silane Chemical compound CC(CSSSCC([SiH2]OC(C)CC)(C)C)([SiH2]OC(C)CC)C GITLYQNXZPGJRU-UHFFFAOYSA-N 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000000000 cycloalkoxy group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- GPRMZRVUGCUUCQ-UHFFFAOYSA-N cyclohexyloxy-[3-[(3-cyclohexyloxysilyl-3,3-diphenylpropyl)disulfanyl]-1,1-diphenylpropyl]silane Chemical compound C1(=CC=CC=C1)C(CCSSCCC(C1=CC=CC=C1)(C1=CC=CC=C1)[SiH2]OC1CCCCC1)([SiH2]OC1CCCCC1)C1=CC=CC=C1 GPRMZRVUGCUUCQ-UHFFFAOYSA-N 0.000 description 1
- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 1
- 238000013480 data collection Methods 0.000 description 1
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- CVTGXJYPLFSIDQ-UHFFFAOYSA-N di(butan-2-yloxy)-[1-[3-di(butan-2-yloxy)silylpentyldisulfanyl]pentan-3-yl]silane Chemical compound C(C)C(CCSSCCC([SiH](OC(C)CC)OC(C)CC)CC)[SiH](OC(C)CC)OC(C)CC CVTGXJYPLFSIDQ-UHFFFAOYSA-N 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- LAQYGVFTFKGFLA-UHFFFAOYSA-N dimethoxymethyl-[5-[5-(dimethoxymethylsilyl)pentyltrisulfanyl]pentyl]silane Chemical compound COC(OC)[SiH2]CCCCCSSSCCCCC[SiH2]C(OC)OC LAQYGVFTFKGFLA-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- YGSXCBZAEOMZFW-UHFFFAOYSA-N ethoxy-[1-[(3-ethoxysilyl-3-methylheptyl)tetrasulfanyl]-3-methylheptan-3-yl]silane Chemical compound CCCCC(C)([SiH2]OCC)CCSSSSCCC(C)(CCCC)[SiH2]OCC YGSXCBZAEOMZFW-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- AWJOGEUUYZRGOU-UHFFFAOYSA-N ethylsulfanyl-[4-[(3-ethylsulfanylsilyl-3-methylbutyl)tetrasulfanyl]-2-methylbutan-2-yl]silane Chemical compound CC(CCSSSSCCC(C)(C)[SiH2]SCC)([SiH2]SCC)C AWJOGEUUYZRGOU-UHFFFAOYSA-N 0.000 description 1
- 238000007701 flash-distillation Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- QWVBGCWRHHXMRM-UHFFFAOYSA-N hexadecoxycarbonyloxy hexadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCCCCC QWVBGCWRHHXMRM-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- GZOUCNGRFRMHIZ-UHFFFAOYSA-N methoxy-[1-[(2-methoxysilyl-3-phenylpropyl)trisulfanyl]-3-phenylpropan-2-yl]silane Chemical compound C=1C=CC=CC=1CC([SiH2]OC)CSSSCC([SiH2]OC)CC1=CC=CC=C1 GZOUCNGRFRMHIZ-UHFFFAOYSA-N 0.000 description 1
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- HDBWAWNLGGMZRQ-UHFFFAOYSA-N p-Vinylbiphenyl Chemical compound C1=CC(C=C)=CC=C1C1=CC=CC=C1 HDBWAWNLGGMZRQ-UHFFFAOYSA-N 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 150000002978 peroxides Chemical group 0.000 description 1
- 125000005385 peroxodisulfate group Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- RHCICBOBTHGGEY-UHFFFAOYSA-N tri(propan-2-yloxy)-[12-[12-tri(propan-2-yloxy)silyldodecyldisulfanyl]dodecyl]silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)CCCCCCCCCCCCSSCCCCCCCCCCCC[Si](OC(C)C)(OC(C)C)OC(C)C RHCICBOBTHGGEY-UHFFFAOYSA-N 0.000 description 1
- ATYIZISYPACGCO-UHFFFAOYSA-N tributoxy-[3-(3-tributoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCCSSCCC[Si](OCCCC)(OCCCC)OCCCC ATYIZISYPACGCO-UHFFFAOYSA-N 0.000 description 1
- NMPPNPIZYXDMMY-UHFFFAOYSA-N tricyclohexyloxy-[3-(3-tricyclohexyloxysilylpropyltetrasulfanyl)propyl]silane Chemical compound C1CCCCC1O[Si](OC1CCCCC1)(OC1CCCCC1)CCCSSSSCCC[Si](OC1CCCCC1)(OC1CCCCC1)OC1CCCCC1 NMPPNPIZYXDMMY-UHFFFAOYSA-N 0.000 description 1
- RLQRJIRGQDCNKY-UHFFFAOYSA-N tricyclopentyloxy-[3-(3-tricyclopentyloxysilylpropyltrisulfanyl)propyl]silane Chemical compound C1CCCC1O[Si](OC1CCCC1)(OC1CCCC1)CCCSSSCCC[Si](OC1CCCC1)(OC1CCCC1)OC1CCCC1 RLQRJIRGQDCNKY-UHFFFAOYSA-N 0.000 description 1
- ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 description 1
- KORAJTACFWEGPU-UHFFFAOYSA-N triethoxy-[6-(6-triethoxysilylhexyltetrasulfanyl)hexyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCCCCSSSSCCCCCC[Si](OCC)(OCC)OCC KORAJTACFWEGPU-UHFFFAOYSA-N 0.000 description 1
- XGVRSFOOQXXSDO-UHFFFAOYSA-N trihexoxy-[3-(3-trihexoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCCCCCO[Si](OCCCCCC)(OCCCCCC)CCCSSCCC[Si](OCCCCCC)(OCCCCCC)OCCCCCC XGVRSFOOQXXSDO-UHFFFAOYSA-N 0.000 description 1
- XQCNPXMIHJAHGO-UHFFFAOYSA-N trimethoxy-[(trimethoxysilylmethyltetrasulfanyl)methyl]silane Chemical compound CO[Si](OC)(OC)CSSSSC[Si](OC)(OC)OC XQCNPXMIHJAHGO-UHFFFAOYSA-N 0.000 description 1
- SVNJQEIWNMNTBW-UHFFFAOYSA-N trimethoxy-[18-(18-trimethoxysilyloctadecyltetrasulfanyl)octadecyl]silane Chemical compound CO[Si](OC)(OC)CCCCCCCCCCCCCCCCCCSSSSCCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC SVNJQEIWNMNTBW-UHFFFAOYSA-N 0.000 description 1
- NQRACKNXKKOCJY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSCCC[Si](OC)(OC)OC NQRACKNXKKOCJY-UHFFFAOYSA-N 0.000 description 1
- YGLOWFUKVQMIQC-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropylhexasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSSSCCC[Si](OC)(OC)OC YGLOWFUKVQMIQC-UHFFFAOYSA-N 0.000 description 1
- JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 description 1
- KOFGNZOFJYBHIN-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltrisulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSCCC[Si](OC)(OC)OC KOFGNZOFJYBHIN-UHFFFAOYSA-N 0.000 description 1
- BPBNXPYFZUPVRY-UHFFFAOYSA-N trimethoxy-[3-(4-trimethoxysilylbut-1-en-2-yltetrasulfanyl)but-3-enyl]silane Chemical compound CO[Si](OC)(OC)CCC(=C)SSSSC(=C)CC[Si](OC)(OC)OC BPBNXPYFZUPVRY-UHFFFAOYSA-N 0.000 description 1
- WUMASLCNJBRHDA-UHFFFAOYSA-N trimethoxy-[4-(4-trimethoxysilylbutyltetrasulfanyl)butyl]silane Chemical compound CO[Si](OC)(OC)CCCCSSSSCCCC[Si](OC)(OC)OC WUMASLCNJBRHDA-UHFFFAOYSA-N 0.000 description 1
- ORMMMPDHLQZPEB-UHFFFAOYSA-N trioctoxy-[3-(3-trioctoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCCCCCCCO[Si](OCCCCCCCC)(OCCCCCCCC)CCCSSSSCCC[Si](OCCCCCCCC)(OCCCCCCCC)OCCCCCCCC ORMMMPDHLQZPEB-UHFFFAOYSA-N 0.000 description 1
- VKJFZCCNSAEGRS-UHFFFAOYSA-N tripropoxy-[18-(18-tripropoxysilyloctadec-1-enyltetrasulfanyl)octadec-17-enyl]silane Chemical compound CCCO[Si](OCCC)(OCCC)CCCCCCCCCCCCCCCCC=CSSSSC=CCCCCCCCCCCCCCCCC[Si](OCCC)(OCCC)OCCC VKJFZCCNSAEGRS-UHFFFAOYSA-N 0.000 description 1
- HRAOIWWIABULSC-UHFFFAOYSA-N tripropoxy-[2-(2-tripropoxysilylethylpentasulfanyl)ethyl]silane Chemical compound CCCO[Si](OCCC)(OCCC)CCSSSSSCC[Si](OCCC)(OCCC)OCCC HRAOIWWIABULSC-UHFFFAOYSA-N 0.000 description 1
- IRNPVNAUHNTHDI-UHFFFAOYSA-N tris(6-methylheptoxy)-[3-[3-[tris(6-methylheptoxy)silyl]propyltetrasulfanyl]propyl]silane Chemical compound CC(C)CCCCCO[Si](OCCCCCC(C)C)(OCCCCCC(C)C)CCCSSSSCCC[Si](OCCCCCC(C)C)(OCCCCCC(C)C)OCCCCCC(C)C IRNPVNAUHNTHDI-UHFFFAOYSA-N 0.000 description 1
- CONCKWGHNZAEBO-UHFFFAOYSA-N tris[(2-methylpropan-2-yl)oxy]-[3-[3-[tris[(2-methylpropan-2-yl)oxy]silyl]propyldisulfanyl]propyl]silane Chemical compound CC(C)(C)O[Si](OC(C)(C)C)(OC(C)(C)C)CCCSSCCC[Si](OC(C)(C)C)(OC(C)(C)C)OC(C)(C)C CONCKWGHNZAEBO-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/22—Coagulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/16—Powdering or granulating by coagulating dispersions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2030/00—Pneumatic or solid tyres or parts thereof
- B29L2030/002—Treads
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10495—Pneumatic tire or inner tube
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Tires In General (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11366398P | 1998-03-11 | 1998-03-11 | |
| US113663P | 1998-03-11 | ||
| US7978998P | 1998-03-28 | 1998-03-28 | |
| US79789P | 1998-03-28 | ||
| US10475598P | 1998-10-19 | 1998-10-19 | |
| US104755P | 1998-10-19 | ||
| US10953098P | 1998-11-23 | 1998-11-23 | |
| US109530P | 1998-11-23 | ||
| US11730599P | 1999-01-26 | 1999-01-26 | |
| US117305P | 1999-01-26 | ||
| US12002499P | 1999-02-13 | 1999-02-13 | |
| US120024P | 1999-02-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69917959D1 DE69917959D1 (de) | 2004-07-22 |
| DE69917959T2 true DE69917959T2 (de) | 2005-06-30 |
Family
ID=27557201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69917959T Expired - Fee Related DE69917959T2 (de) | 1998-03-11 | 1999-03-10 | In Emulsion hergestellter Styrene-Butadien-Kautschuk |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US6469104B1 (enExample) |
| EP (1) | EP0942042B1 (enExample) |
| JP (1) | JP2000017021A (enExample) |
| KR (1) | KR100597804B1 (enExample) |
| CN (1) | CN1230564A (enExample) |
| AT (1) | ATE269376T1 (enExample) |
| AU (1) | AU1862899A (enExample) |
| BR (1) | BR9915758A (enExample) |
| CA (1) | CA2265153A1 (enExample) |
| CO (1) | CO5060538A1 (enExample) |
| DE (1) | DE69917959T2 (enExample) |
| ES (1) | ES2222004T3 (enExample) |
| HU (1) | HUP9900785A3 (enExample) |
| ID (1) | ID22093A (enExample) |
| NZ (1) | NZ334587A (enExample) |
| PE (1) | PE20000344A1 (enExample) |
| SG (1) | SG165133A1 (enExample) |
| SK (1) | SK31299A3 (enExample) |
| TR (1) | TR199900530A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010061469A1 (de) * | 2010-12-22 | 2012-06-28 | Continental Reifen Deutschland Gmbh | Kautschukmischung mit verbessertem Rollwiderstandsverhalten |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030050370A1 (en) | 2001-03-16 | 2003-03-13 | Victor Thielen Georges Marcel | Silica filled multi-viscoelastic response rubber |
| DE19963781A1 (de) * | 1998-12-31 | 2000-07-06 | Goodyear Tire & Rubber | Reifenlaufflächen-Compound |
| CA2301788A1 (en) * | 1999-05-12 | 2000-11-12 | The Goodyear Tire & Rubber Company | Endless rubber track and vehicle containing such track |
| CA2368002A1 (fr) * | 2000-02-02 | 2001-08-09 | Michelin Recherche Et Technique S.A. | Bande de roulement de pneumatique comprenant un copolymere styrene/butadiene prepare en emulsion |
| CA2368003A1 (fr) * | 2000-02-02 | 2001-08-09 | Roland Rauline | Bande de roulement de pneumatique comprenant un copolymere styrene/butadiene prepare en emulsion |
| DE60118364T8 (de) * | 2000-06-07 | 2007-05-10 | Zeon Corp. | Konjugiertes dienkautschukgel, kautschukzusammensetzungen die dieses enthalten und verfahren zur herstellung von konjugiertem dienkautschuk |
| US6455655B1 (en) * | 2000-09-28 | 2002-09-24 | The Goodyear Tire & Rubber Company | Emulsion styrene-butadiene rubber |
| EP1385708B1 (en) * | 2001-04-13 | 2004-10-13 | PIRELLI PNEUMATICI Società per Azioni | Tyre with high roadholding, tread band and elastomeric composition used therein |
| US8800615B2 (en) | 2005-03-14 | 2014-08-12 | Bridgestone Corporation | Rubber composition and pneumatic tire using the same |
| US20060266454A1 (en) * | 2005-05-27 | 2006-11-30 | Sandstrom Paul H | Tire with tread comprised of natural rubber and specialized emulsion prepared styrene/butadiene elastomer |
| EP1887037A1 (en) * | 2006-08-10 | 2008-02-13 | PolymerLatex GmbH | Latex with reduced odour |
| BRPI0603376A (pt) * | 2006-08-17 | 2008-04-08 | Petroflex Ind E Com S A | processo para a obtenção de copolìmeros de butadieno e estireno, através da polimerização em emulsão, agente modificador da reologia do copolìmero, composição de borracha, goma base, goma de mascar e goma para chicle de bola |
| US8136562B2 (en) * | 2006-12-29 | 2012-03-20 | Bridgestone Firestone North American Tire, Llc | Tire bead insulation |
| US7594528B2 (en) | 2007-03-08 | 2009-09-29 | The Goodyear Tire & Rubber Company | Tire with sidewall comprised of emulsion styrene/butadiene rubber, cis 1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber |
| JP5259332B2 (ja) * | 2007-10-25 | 2013-08-07 | 東洋ゴム工業株式会社 | 空気入りタイヤ |
| JP5259337B2 (ja) * | 2007-11-19 | 2013-08-07 | 東洋ゴム工業株式会社 | 空気入りタイヤ |
| WO2010078248A2 (en) | 2008-12-31 | 2010-07-08 | Bridgestone Corporation | Rubber compositions including a polymeric component having a multi-modal molecular weight distribution |
| RU2571135C2 (ru) * | 2011-06-03 | 2015-12-20 | Бриджстоун Корпорейшн | Резиновая смесь и шина, изготовляемая с ее использованием |
| NL2007262C2 (en) | 2011-08-12 | 2013-02-13 | Kraton Polymers Us Llc | A process for preparing articles from a latex comprising water and a styrenic block copolymer and such a latex. |
| EP2771397A4 (en) | 2011-10-24 | 2015-06-10 | Bridgestone Americas Tire | SILICA-CHARGED RUBBER COMPOSITION AND METHOD FOR MANUFACTURING THE SAME |
| CN102585316B (zh) * | 2012-04-20 | 2013-12-25 | 贵州轮胎股份有限公司 | 耐切割斜交轮胎胎面胶料及其制备方法 |
| JP6061919B2 (ja) * | 2012-05-09 | 2017-01-18 | 株式会社ブリヂストン | 天然ゴム、天然ゴムを含むゴム組成物及びその製造方法、及びタイヤ |
| CN103421144B (zh) * | 2012-05-16 | 2016-03-30 | 中国石油化工股份有限公司 | 一种母炼胶及其制备方法和硫化橡胶及其应用 |
| CN103450396B (zh) * | 2012-06-01 | 2015-05-27 | 中国石油天然气股份有限公司 | 一种乳液聚合法制备易加工型丁苯橡胶的方法 |
| US20140256858A1 (en) | 2013-03-11 | 2014-09-11 | Robert Anthony Bethea | Solution polymerization prepared styrene/butadiene elastomer containing liquid styrene/butadiene polymer and tire with component |
| CN104693455B (zh) * | 2015-02-15 | 2017-10-10 | 北京化工大学 | 一种溶聚丁苯橡胶乳液的制备方法 |
| KR101950705B1 (ko) | 2015-11-30 | 2019-02-21 | 주식회사 엘지화학 | 결합 스티렌 함량이 낮은 스티렌-부타디엔 고무의 제조방법 |
| CN107849195B (zh) | 2015-12-28 | 2020-10-23 | 株式会社Lg化学 | 丁苯橡胶的制备方法和丁苯橡胶 |
| CN105838879B (zh) * | 2016-03-29 | 2019-02-12 | 云南华联锌铟股份有限公司 | 从锌冶炼的沉铟后液中去除钙镁的方法和装置 |
| KR101950707B1 (ko) | 2016-11-10 | 2019-02-21 | 주식회사 엘지화학 | 스티렌-부타디엔 고무 컴파운드 및 이를 포함하는 타이어 비드 필러용 고무 조성물 |
| US10427463B2 (en) | 2016-11-16 | 2019-10-01 | The Goodyear Tire & Rubber Company | Pneumatic tire having a dual layer tread |
| CN106519119B (zh) * | 2016-11-30 | 2019-10-11 | 黄河三角洲京博化工研究院有限公司 | 一种丁苯胶乳的制备方法 |
| CN106519118A (zh) * | 2016-11-30 | 2017-03-22 | 黄河三角洲京博化工研究院有限公司 | 一种改性乳化沥青用丁苯胶乳的制备方法 |
| JP6922391B2 (ja) * | 2017-05-01 | 2021-08-18 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| CN109776726B (zh) * | 2017-11-15 | 2021-11-02 | 中国石油天然气股份有限公司 | 丁苯橡胶的制备方法及丁苯橡胶 |
| WO2019133365A1 (en) * | 2017-12-26 | 2019-07-04 | Bridgestone Corporation | Synthesis of low molecular weight tapered styrene-butadiene copolymer and its use in tires |
| KR102648095B1 (ko) * | 2019-05-20 | 2024-03-18 | 주식회사 엘지화학 | 방사원액의 응고현상 분석방법 |
| EP4015238A1 (en) * | 2020-12-18 | 2022-06-22 | The Goodyear Tire & Rubber Company | Rubber composition, tire comprising such a rubber composition and its method of manufacturing |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4110240A (en) * | 1977-07-29 | 1978-08-29 | Wyrough And Loser, Inc. | Coprecipitation process |
| CA1196139A (en) * | 1982-02-26 | 1985-10-29 | Hiroshi Furukawa | Elastomer composition |
| JPS60192739A (ja) * | 1984-03-15 | 1985-10-01 | Japan Synthetic Rubber Co Ltd | ブロック共重合体 |
| JPH0637578B2 (ja) * | 1988-02-01 | 1994-05-18 | 日本合成ゴム株式会社 | ゴム組成物 |
| US5202387A (en) | 1992-05-08 | 1993-04-13 | The Goodyear Tire & Rubber Company | Elastomer with outstanding characteristics for use in making tire tread compounds |
| JP3290469B2 (ja) * | 1992-08-17 | 2002-06-10 | ジェイエスアール株式会社 | ゴム組成物 |
| JPH07188462A (ja) * | 1993-12-27 | 1995-07-25 | Bridgestone Corp | タイヤトレッド用ゴム組成物 |
| US5583173A (en) * | 1995-04-10 | 1996-12-10 | The Goodyear Tire & Rubber Company | Process for preparing styrene-butadiene rubber |
| DE69612912T2 (de) * | 1995-06-30 | 2001-10-18 | Bridgestone Corp., Tokio/Tokyo | Kautschukmischung und daraus hergestellter Reifen |
| US5837756A (en) | 1997-05-28 | 1998-11-17 | The Goodyear Tire & Rubber Company | Polymer for asphalt cement modification |
| US6136899A (en) * | 1999-09-14 | 2000-10-24 | The Goodyear Tire & Rubber Company | SBR for asphalt cement modification |
-
1999
- 1999-03-08 SG SG9901075-3A patent/SG165133A1/en unknown
- 1999-03-08 AU AU18628/99A patent/AU1862899A/en not_active Abandoned
- 1999-03-09 SK SK312-99A patent/SK31299A3/sk unknown
- 1999-03-09 US US09/264,937 patent/US6469104B1/en not_active Expired - Fee Related
- 1999-03-10 NZ NZ334587A patent/NZ334587A/en unknown
- 1999-03-10 ES ES99104756T patent/ES2222004T3/es not_active Expired - Lifetime
- 1999-03-10 EP EP99104756A patent/EP0942042B1/en not_active Expired - Lifetime
- 1999-03-10 CO CO99014708A patent/CO5060538A1/es unknown
- 1999-03-10 ID IDP990204D patent/ID22093A/id unknown
- 1999-03-10 CA CA002265153A patent/CA2265153A1/en not_active Abandoned
- 1999-03-10 AT AT99104756T patent/ATE269376T1/de not_active IP Right Cessation
- 1999-03-10 BR BR9915758-6A patent/BR9915758A/pt not_active Application Discontinuation
- 1999-03-10 DE DE69917959T patent/DE69917959T2/de not_active Expired - Fee Related
- 1999-03-10 KR KR1019990007948A patent/KR100597804B1/ko not_active Expired - Fee Related
- 1999-03-11 JP JP11064663A patent/JP2000017021A/ja not_active Withdrawn
- 1999-03-11 TR TR1999/00530A patent/TR199900530A2/xx unknown
- 1999-03-11 PE PE1999000194A patent/PE20000344A1/es not_active Application Discontinuation
- 1999-03-11 CN CN99105530A patent/CN1230564A/zh active Pending
- 1999-03-26 HU HU9900785A patent/HUP9900785A3/hu unknown
-
2000
- 2000-10-17 US US09/690,555 patent/US6458884B1/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010061469A1 (de) * | 2010-12-22 | 2012-06-28 | Continental Reifen Deutschland Gmbh | Kautschukmischung mit verbessertem Rollwiderstandsverhalten |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0942042B1 (en) | 2004-06-16 |
| AU1862899A (en) | 1999-09-23 |
| SG165133A1 (en) | 2010-10-28 |
| BR9915758A (pt) | 2001-07-24 |
| HUP9900785A2 (hu) | 1999-08-30 |
| KR100597804B1 (ko) | 2006-07-10 |
| SK31299A3 (en) | 2000-10-09 |
| HUP9900785A3 (en) | 1999-11-29 |
| PE20000344A1 (es) | 2000-04-20 |
| DE69917959D1 (de) | 2004-07-22 |
| NZ334587A (en) | 2000-06-23 |
| ES2222004T3 (es) | 2005-01-16 |
| TR199900530A2 (xx) | 1999-10-21 |
| JP2000017021A (ja) | 2000-01-18 |
| ID22093A (id) | 1999-09-02 |
| KR19990077755A (ko) | 1999-10-25 |
| US6469104B1 (en) | 2002-10-22 |
| CA2265153A1 (en) | 1999-09-11 |
| US6458884B1 (en) | 2002-10-01 |
| HU9900785D0 (en) | 1999-05-28 |
| ATE269376T1 (de) | 2004-07-15 |
| EP0942042A3 (en) | 2001-11-07 |
| CN1230564A (zh) | 1999-10-06 |
| EP0942042A2 (en) | 1999-09-15 |
| CO5060538A1 (es) | 2001-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69917959T2 (de) | In Emulsion hergestellter Styrene-Butadien-Kautschuk | |
| DE60204072T2 (de) | Druckluftreifen aufgebaut aus einer Kautschukkomponente enthaltend ein Kautschukgel, syndiotaktisches 1,2-Polybutadien und olefinisch ungesättigten Kautschuk | |
| DE69721151T2 (de) | Kieselsäuregefüllte Kautschukzusammensetzungen und ihre Herstellung | |
| DE69606746T2 (de) | Hochleistungsmischung für Reifenlaufflächen | |
| EP0854170B1 (de) | SBR-Kautschukgele enthaltende Kautschukmischungen | |
| DE69914033T2 (de) | Reifen mit durch Kieselsäure verstärkter Lauffläche oder Seitenwandkomponente | |
| DE69630646T2 (de) | Natriumthiosulfat-Pentahydrat enthaltender, mit Schwefel vulkanisierbarer Kautschuk | |
| DE60027704T2 (de) | Kautschukmischung | |
| DE69218694T2 (de) | Kautschukmischung für Laufflächen | |
| US6512053B1 (en) | Emulsion styrene-butadiene rubber | |
| DE69605861T2 (de) | Reifen mit Kieselsäure verstärkter Laufflächenmischung | |
| DE60012825T2 (de) | Harzartige Polymere aus Limonen, Dimethyldicyclopentadien, Inden und Vinyltoluol | |
| DE10021070A1 (de) | Gelhaltige Kautschukmischungen für dynamisch belastete Reifenbauteile | |
| DE3311449A1 (de) | Kautschukmischung fuer kraftfahrzeugreifen | |
| EP0575851A1 (de) | Kautschukmischungen enthaltend Polybutadien-Gel | |
| EP2363303A1 (de) | Bimodales NdBR | |
| DE69905817T2 (de) | Kautschukzusammensetzung die ein reversionsverhinderndes Mittel enthält und Reifen mit daraus hergestellter Komponente | |
| DE69931367T2 (de) | Konjugierter dien-kautschuk, verfahren zu dessen herstellung und kautschukzusammensetzung | |
| DE19701487A1 (de) | NBR-Kautschuke enthaltende Kautschukmischungen | |
| DE69619902T2 (de) | Katalysatorsystem zur Herstellung von Kautschukpolymeren | |
| DE69915757T2 (de) | Kautschukmischung für Hochbelastungsreifen | |
| DE69030467T2 (de) | Kautschukmischung | |
| DE60211982T2 (de) | Mit visco-elastischen Verhalten Kieselsäure gefüllter Kautschuk | |
| DE112021002538T5 (de) | Polybutadienzusammensetzung, Herstellungsverfahren dafür, Kautschukzusammensetzung, Reifen und Gummiriemen | |
| DE69908039T2 (de) | Kautschukmischung für Lauffläche von Hochleistungsreifen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |