DE69912161T2 - Uv-absorbierende partikel - Google Patents
Uv-absorbierende partikel Download PDFInfo
- Publication number
- DE69912161T2 DE69912161T2 DE69912161T DE69912161T DE69912161T2 DE 69912161 T2 DE69912161 T2 DE 69912161T2 DE 69912161 T DE69912161 T DE 69912161T DE 69912161 T DE69912161 T DE 69912161T DE 69912161 T2 DE69912161 T2 DE 69912161T2
- Authority
- DE
- Germany
- Prior art keywords
- core
- shell
- polymer
- monomers
- ethyl acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002245 particle Substances 0.000 title claims description 27
- 229920000642 polymer Polymers 0.000 claims description 55
- 239000000178 monomer Substances 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 32
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 25
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 25
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 15
- 239000006096 absorbing agent Substances 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 5
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims 2
- 239000011162 core material Substances 0.000 description 57
- 239000007771 core particle Substances 0.000 description 32
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 26
- 239000000126 substance Substances 0.000 description 20
- 239000010420 shell particle Substances 0.000 description 19
- 238000000034 method Methods 0.000 description 11
- 239000006185 dispersion Substances 0.000 description 9
- 230000005855 radiation Effects 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- IUNVCWLKOOCPIT-UHFFFAOYSA-N 6-methylheptylsulfanyl 2-hydroxyacetate Chemical compound CC(C)CCCCCSOC(=O)CO IUNVCWLKOOCPIT-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000004971 Cross linker Substances 0.000 description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 229920002313 fluoropolymer Polymers 0.000 description 5
- 239000004811 fluoropolymer Substances 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 5
- 230000002745 absorbent Effects 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- BEHACUVDSXWNGX-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CC(=C)C(=O)OCC1=CC=CC=C1 BEHACUVDSXWNGX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000176 photostabilization Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US371064 | 1999-08-09 | ||
| US09/371,064 US6312807B1 (en) | 1999-08-09 | 1999-08-09 | UV-absorbing core/shell particles |
| PCT/US1999/027507 WO2001010936A1 (en) | 1999-08-09 | 1999-11-19 | Uv-absorbing particles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69912161D1 DE69912161D1 (de) | 2003-11-20 |
| DE69912161T2 true DE69912161T2 (de) | 2004-06-09 |
Family
ID=23462321
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69912161T Expired - Fee Related DE69912161T2 (de) | 1999-08-09 | 1999-11-19 | Uv-absorbierende partikel |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6312807B1 (enExample) |
| EP (1) | EP1208137B1 (enExample) |
| JP (1) | JP2003506545A (enExample) |
| AU (1) | AU2706200A (enExample) |
| DE (1) | DE69912161T2 (enExample) |
| WO (1) | WO2001010936A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9919304D0 (en) | 1999-08-17 | 1999-10-20 | Ici Plc | Acrylic composition |
| US6610405B2 (en) * | 2000-05-12 | 2003-08-26 | Nippon Shokubai Co., Ltd. | Grain aggregate and producing method thereof, and light-diffusing agent |
| US6572969B1 (en) | 2002-05-16 | 2003-06-03 | Meadwestvaco Corporation | Core shell polymeric compositions |
| US6521343B1 (en) | 2002-05-16 | 2003-02-18 | Westvaco Corporation | Cationic core-shell particles with stabilizer-containing acid-swellable shells |
| US6767638B2 (en) * | 2002-05-16 | 2004-07-27 | Meadwestvaco Corporation | Core-shell polymeric compositions |
| US7622185B2 (en) * | 2005-04-15 | 2009-11-24 | Nitto Denko Corporation | Protective cover sheet comprising a UV-absorbing layer for a polarizer plate and method of making the same |
| DE102005023806A1 (de) * | 2005-05-19 | 2006-11-23 | Basf Ag | Farbiges Polymersystem mit verbesserter Farbbrillianz |
| US8039549B2 (en) | 2006-06-20 | 2011-10-18 | Basf Aktiengesellschaft | Method for producing aqueous polymer dispersions containing at least one lipophilic active substance and the use thereof |
| US7563508B2 (en) * | 2007-05-30 | 2009-07-21 | Chung Shan Institute Of Science And Technology, Armaments Bureau, M.N.D. | Diffusion beads with core-shell structure |
| EP2135598B1 (en) * | 2008-06-16 | 2011-08-03 | Rohm and Haas Company | Particle Containing Ultraviolet Absorber |
| JP2013227266A (ja) * | 2011-05-18 | 2013-11-07 | Sumitomo Osaka Cement Co Ltd | 紫外線遮蔽剤と紫外線遮蔽剤含有分散液及び化粧料並びに紫外線遮蔽剤の製造方法 |
| JP5970956B2 (ja) * | 2011-05-18 | 2016-08-17 | 住友大阪セメント株式会社 | 紫外線遮蔽剤と紫外線遮蔽剤含有分散液及び化粧料並びに紫外線遮蔽剤の製造方法 |
| CN103547649B (zh) * | 2011-05-18 | 2017-04-26 | 住友大阪水泥股份有限公司 | 紫外线遮蔽剂及其制造方法、含有紫外线遮蔽剂的分散液、以及化妆料 |
| US9549891B2 (en) | 2012-03-19 | 2017-01-24 | The Procter & Gamble Company | Superabsorbent polymers and sunscreen actives for use in skin care compositions |
| US20150166795A1 (en) * | 2013-12-17 | 2015-06-18 | Intermolecular Inc. | Anti-Glare Coatings with Ultraviolet-Absorbing Particles and Methods for Forming the Same |
| CN107787222B (zh) | 2015-06-29 | 2020-12-04 | 宝洁公司 | 用于护肤组合物中的超吸收聚合物和淀粉粉末 |
| US20190106520A1 (en) * | 2016-03-28 | 2019-04-11 | Bar-Ilan Research & Development Company Ltd | Uv-absorbing polymeric particles |
| EP3708625A1 (en) | 2016-08-08 | 2020-09-16 | Asahi Kasei Kabushiki Kaisha | Process for producing aqueous composite-particle dispersion |
| US11820844B2 (en) * | 2018-03-22 | 2023-11-21 | 3M Innovative Properties Company | Charge-modified particles and methods of making the same |
| CN114507320B (zh) * | 2022-03-17 | 2022-08-23 | 嘉兴金门量子材料科技有限公司 | 丙烯酸酯预聚体及制备方法和应用 |
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| JPS543129A (en) | 1977-06-09 | 1979-01-11 | Mitsui Toatsu Chem Inc | Coating powder composition |
| US4419471A (en) | 1981-09-04 | 1983-12-06 | Gaf Corporation | Core-shell polymers |
| US4528311A (en) | 1983-07-11 | 1985-07-09 | Iolab Corporation | Ultraviolet absorbing polymers comprising 2-hydroxy-5-acrylyloxyphenyl-2H-benzotriazoles |
| NZ208751A (en) | 1983-07-11 | 1987-04-30 | Iolab Corp | 2-hydroxy-5-acrylyloxyalkylphenyl-2h-benzotriazole derivatives and polymers and copolymers thereof and use as uv absorbing additives in polymer compositions |
| JPS6028463A (ja) * | 1983-07-26 | 1985-02-13 | Nippon Paint Co Ltd | 水性塗料組成物 |
| JPS6293220A (ja) | 1985-10-21 | 1987-04-28 | Dainippon Ink & Chem Inc | 化粧品用紫外線吸収剤封入型非造膜性樹脂エマルジヨンの製法及びその粉末化法 |
| JPS6295301A (ja) | 1985-10-21 | 1987-05-01 | Dainippon Ink & Chem Inc | 化粧品以外に用いられる非造膜性樹脂エマルジヨンの製法及びその粉末化法 |
| CA1337104C (en) * | 1986-11-18 | 1995-09-26 | William James Work | Light-scattering thermoplastic polymers |
| US5237004A (en) | 1986-11-18 | 1993-08-17 | Rohm And Haas Company | Thermoplastic and thermoset polymer compositions |
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| GB8728884D0 (en) | 1987-12-10 | 1988-01-27 | Ici Plc | Aqueous-based fluoropolymer compositions |
| DE3837589A1 (de) * | 1988-11-05 | 1990-05-10 | Roehm Gmbh | Uv-absorber-haltige methacrylatschutzschicht fuer polycarbonat |
| DE3837588A1 (de) | 1988-11-05 | 1990-05-10 | Roehm Gmbh | Schlagzaehe, uv-absorber-haltige methacrylatschutzschicht fuer polycarbonat |
| US5207954A (en) | 1989-09-25 | 1993-05-04 | Union Carbide Chemicals & Plastics Technology Corporation | Method of making coreactable powdered coatings |
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| JP3304788B2 (ja) | 1996-10-22 | 2002-07-22 | ダイキン工業株式会社 | 含フッ素樹脂水性分散体 |
| US5827608A (en) | 1996-10-28 | 1998-10-27 | Minnesota Mining And Manufacturing Company | Method of forming a thermoplastic layer on a flexible two-dimensional substrate and powder for preparing same |
| EP0875544B1 (en) | 1997-04-28 | 2002-12-11 | Seiko Epson Corporation | Ink composition capable of realizing light fast image |
| JP4168477B2 (ja) * | 1997-04-28 | 2008-10-22 | セイコーエプソン株式会社 | 耐光性に優れた画像を実現するインク組成物 |
| CN1137150C (zh) | 1997-07-17 | 2004-02-04 | 北美埃尔夫爱托化学股份有限公司 | 用于粉末涂料的共混物的制备方法 |
| US6251521B1 (en) * | 1999-08-09 | 2001-06-26 | 3M Innovative Properties Company | Polymeric compositions |
-
1999
- 1999-08-09 US US09/371,064 patent/US6312807B1/en not_active Expired - Fee Related
- 1999-11-19 DE DE69912161T patent/DE69912161T2/de not_active Expired - Fee Related
- 1999-11-19 JP JP2001515739A patent/JP2003506545A/ja active Pending
- 1999-11-19 EP EP99968853A patent/EP1208137B1/en not_active Expired - Lifetime
- 1999-11-19 AU AU27062/00A patent/AU2706200A/en not_active Abandoned
- 1999-11-19 WO PCT/US1999/027507 patent/WO2001010936A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US6312807B1 (en) | 2001-11-06 |
| EP1208137A1 (en) | 2002-05-29 |
| AU2706200A (en) | 2001-03-05 |
| DE69912161D1 (de) | 2003-11-20 |
| WO2001010936A1 (en) | 2001-02-15 |
| EP1208137B1 (en) | 2003-10-15 |
| JP2003506545A (ja) | 2003-02-18 |
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