DE69830222D1 - Reformer und Methode zu dessen Betreiben - Google Patents

Reformer und Methode zu dessen Betreiben

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Publication number
DE69830222D1
DE69830222D1 DE69830222T DE69830222T DE69830222D1 DE 69830222 D1 DE69830222 D1 DE 69830222D1 DE 69830222 T DE69830222 T DE 69830222T DE 69830222 T DE69830222 T DE 69830222T DE 69830222 D1 DE69830222 D1 DE 69830222D1
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DE
Germany
Prior art keywords
reformer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69830222T
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English (en)
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DE69830222T2 (de
Inventor
Fumio Abe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NGK Insulators Ltd
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NGK Insulators Ltd
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Filing date
Publication date
Application filed by NGK Insulators Ltd filed Critical NGK Insulators Ltd
Publication of DE69830222D1 publication Critical patent/DE69830222D1/de
Application granted granted Critical
Publication of DE69830222T2 publication Critical patent/DE69830222T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H01M8/0631Reactor construction specially adapted for combination reactor/fuel cell
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/007Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/0013Controlling the temperature of the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/248Reactors comprising multiple separated flow channels
    • B01J19/2485Monolithic reactors
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00054Controlling or regulating the heat exchange system
    • B01J2219/00056Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00058Temperature measurement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00132Controlling the temperature using electric heating or cooling elements
    • B01J2219/00135Electric resistance heaters
    • CCHEMISTRY; METALLURGY
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0266Processes for making hydrogen or synthesis gas containing a decomposition step
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435Catalytic purification
    • C01B2203/044Selective oxidation of carbon monoxide
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0833Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/085Methods of heating the process for making hydrogen or synthesis gas by electric heating
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    • C01B2203/08Methods of heating or cooling
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    • C01B2203/0866Methods of heating the process for making hydrogen or synthesis gas by combination of different heating methods
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    • C01B2203/0872Methods of cooling
    • C01B2203/0888Methods of cooling by evaporation of a fluid
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1011Packed bed of catalytic structures, e.g. particles, packing elements
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    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1023Catalysts in the form of a monolith or honeycomb
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    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
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    • C01B2203/1047Group VIII metal catalysts
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    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
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    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288Evaporation of one or more of the different feed components
    • C01B2203/1294Evaporation by heat exchange with hot process stream
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    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
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    • C01B2203/146At least two purification steps in series
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    • C01B2203/16Controlling the process
    • C01B2203/1604Starting up the process
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    • C01B2203/16Controlling the process
    • C01B2203/1614Controlling the temperature
    • C01B2203/1619Measuring the temperature
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1614Controlling the temperature
    • C01B2203/1623Adjusting the temperature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/30Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a fuel reformer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)
  • Catalysts (AREA)
  • Resistance Heating (AREA)
DE69830222T 1997-10-28 1998-10-27 Reformer und Methode zu dessen Betreiben Expired - Fee Related DE69830222T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP9296004A JPH11130405A (ja) 1997-10-28 1997-10-28 改質反応装置、触媒装置、それらに用いる発熱・触媒体、及び改質反応装置の運転方法
JP29600497 1997-10-28

Publications (2)

Publication Number Publication Date
DE69830222D1 true DE69830222D1 (de) 2005-06-23
DE69830222T2 DE69830222T2 (de) 2006-02-02

Family

ID=17827893

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69830222T Expired - Fee Related DE69830222T2 (de) 1997-10-28 1998-10-27 Reformer und Methode zu dessen Betreiben

Country Status (5)

Country Link
US (1) US6641795B2 (de)
EP (1) EP0913357B1 (de)
JP (1) JPH11130405A (de)
CA (1) CA2252073C (de)
DE (1) DE69830222T2 (de)

Families Citing this family (121)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10213326A1 (de) * 2002-03-25 2003-10-16 Viessmann Werke Kg Apparat zur Erzeugung von Wasserstoff
US6156084A (en) * 1998-06-24 2000-12-05 International Fuel Cells, Llc System for desulfurizing a fuel for use in a fuel cell power plant
JP2000007301A (ja) 1998-06-29 2000-01-11 Ngk Insulators Ltd 改質反応装置
US6203587B1 (en) 1999-01-19 2001-03-20 International Fuel Cells Llc Compact fuel gas reformer assemblage
US6140266A (en) * 1999-02-18 2000-10-31 International Fuel Cells, Co., Llc Compact and light weight catalyst bed for use in a fuel cell power plant and method for forming the same
US6284206B1 (en) 1999-03-22 2001-09-04 International Fuel Cells, Llc Compact selective oxidizer assemblage for a fuel cell power plant
US6797244B1 (en) 1999-05-27 2004-09-28 Dtc Fuel Cells Llc Compact light weight autothermal reformer assembly
US6746650B1 (en) 1999-06-14 2004-06-08 Utc Fuel Cells, Llc Compact, light weight methanol fuel gas autothermal reformer assembly
JP2001023671A (ja) * 1999-07-02 2001-01-26 Ishikawajima Harima Heavy Ind Co Ltd 燃料電池用触媒反応器および燃料電池システム、並びに坦体
JP2001080906A (ja) * 1999-09-10 2001-03-27 Daikin Ind Ltd 水素ガス生成装置
EP1148024A4 (de) * 1999-09-10 2009-03-11 Daikin Ind Ltd Vorrichtung zur herstellung von wasserstoffgas und verwendung dieses gases in einem brennstoffzellensystem
DE19944187A1 (de) * 1999-09-15 2001-03-29 Xcellsis Gmbh Gaserzeugungssystem
DE19944540B4 (de) 1999-09-17 2005-01-13 Daimlerchrysler Ag Reaktorsystem mit elektrischen Heizmitteln
JP4534277B2 (ja) * 1999-10-06 2010-09-01 トヨタ自動車株式会社 改質装置
JP4644892B2 (ja) * 1999-12-16 2011-03-09 ダイキン工業株式会社 改質装置
US6902717B2 (en) * 1999-12-21 2005-06-07 Shell Oil Company Process for the catalytic partial oxidation of a hydrocarbonaceous feedstock
JP3921910B2 (ja) 2000-02-18 2007-05-30 日産自動車株式会社 燃料電池システム
DE10013687B4 (de) 2000-03-21 2007-06-28 Nucellsys Gmbh Brennstoffzellensystem und Verfahren zum Betreiben desselben
JP2001279276A (ja) * 2000-03-29 2001-10-10 Idemitsu Kosan Co Ltd 燃料電池用燃料油及び燃料電池用水素の製造方法
FR2807746B1 (fr) * 2000-04-13 2002-12-13 Air Liquide Procede de production d'un melange comportant de l'hydrogene et du co
JP2001302202A (ja) * 2000-04-18 2001-10-31 Nippon Telegr & Teleph Corp <Ntt> メタノール改質器
ES2208490T3 (es) * 2000-04-27 2004-06-16 Haldor Topsoe A/S Procedimiento de produccion de un gas rico en hidrogeno.
DE10023410A1 (de) * 2000-05-12 2001-11-15 Linde Gas Ag Verfahren zur Erzeugung eines CO- und H2-haltigen Behandlungsgases für die Wärmebehandlung von metallischem Gut, Gasgenerator und Wärmebehandlungsanlage
JP5024717B2 (ja) * 2000-10-20 2012-09-12 株式会社Ihi 固体高分子型燃料電池のco除去方法及び装置
DE10053597A1 (de) * 2000-10-28 2002-08-08 Xcellsis Gmbh Gaserzeugungssystem für ein Brennstoffzellensystem und Verfahren zur Bereitstellung wasserstoffhaltigen Brennstoffs
DE10056536C2 (de) * 2000-11-15 2002-10-10 Mtu Friedrichshafen Gmbh Brennstoffzellenanordnung
DE10057418A1 (de) * 2000-11-20 2002-06-20 Emitec Emissionstechnologie Reaktoreinheit und Reformeranlage
DE10057420A1 (de) * 2000-11-20 2002-06-06 Emitec Emissionstechnologie Mehrstufiger Shiftreaktor und Reformeranlage
BR0115948B1 (pt) * 2000-12-05 2010-05-18 método para aquecer um leito de catalisador, e, módulo de reator para uso em um processador de combustìvel compacto.
AU2002234574A1 (en) * 2000-12-15 2002-06-24 Shell Internationale Research Maatschappij B.V. Catalytic partial oxidation process using a catalyst system having an upstream and a downstream part
JP4590730B2 (ja) * 2000-12-27 2010-12-01 トヨタ自動車株式会社 改質器の起動制御
US6929785B2 (en) * 2001-02-13 2005-08-16 Delphi Technologies, Inc. Method and apparatus for preheating of a fuel cell micro-reformer
DE10122016A1 (de) * 2001-05-07 2002-11-28 Viessmann Werke Kg Apparat zur Erzeugung von Wasserstoff und Verfahren zur allothermen Dampfreformierung
JP4045755B2 (ja) * 2001-05-23 2008-02-13 日産自動車株式会社 燃料電池システム
JP3659204B2 (ja) 2001-08-30 2005-06-15 日産自動車株式会社 移動体用燃料電池パワープラント
US7082753B2 (en) * 2001-12-03 2006-08-01 Catalytica Energy Systems, Inc. System and methods for improved emission control of internal combustion engines using pulsed fuel flow
BR0214668A2 (pt) * 2001-12-03 2011-07-05 Catalytica Energy Sys Inc sistema e métodos para um controle de emissão melhorado de motores de combustão interna
JP4136396B2 (ja) * 2002-02-22 2008-08-20 株式会社フレイン・エナジー 水素発生・貯蔵装置用の有機ハイドライド又は芳香族炭化水素の気化・凝縮装置
ATE342227T1 (de) * 2002-03-25 2006-11-15 Viessmann Werke Kg Vorrichtung zur erzeugung von wasserstoff
JP2003306307A (ja) * 2002-04-09 2003-10-28 Nissan Motor Co Ltd 燃料改質装置
FR2840110B1 (fr) * 2002-05-27 2004-08-20 Renault Sa Systeme de traction a pile a combustible pour vehicule
US6918941B2 (en) * 2002-08-05 2005-07-19 Battelle Energy Alliance, Llc Cermet materials, self-cleaning cermet filters, apparatus and systems employing same
US7022647B2 (en) * 2002-08-05 2006-04-04 Battelle Energy Alliance, Llc Methods of fabricating cermet materials and methods of utilizing same
US7347978B2 (en) * 2002-08-09 2008-03-25 H2Gen Innovations, Inc. Electrically heated catalyst support plate and method for starting up water gas shift reactors
US7468089B2 (en) * 2002-11-04 2008-12-23 Battelle Energy Alliance, Llc Cermet materials
US7181906B2 (en) * 2002-11-15 2007-02-27 Catalytica Energy Systems, Inc. Devices and methods for reduction of NOx emissions from lean burn engines
US20040097371A1 (en) * 2002-11-19 2004-05-20 Juzer Jangbarwala Application of conductive adsorbents, activated carbon granules and carbon fibers as substrates in catalysis
DE10253930A1 (de) * 2002-11-19 2004-06-09 Umicore Ag & Co.Kg Verfahren zur Erzeugung eines wasserstoffhaltigen Brenngases für Brennstoffzellen sowie Vorrichtung dafür
JP4251321B2 (ja) 2003-01-28 2009-04-08 トヨタ自動車株式会社 内燃機関および内燃機関の運転方法
US7131264B2 (en) * 2003-01-29 2006-11-07 Delphi Technologies, Inc. Method of operating a reformer and a vehicle
US7862631B2 (en) * 2003-02-07 2011-01-04 Gm Global Technology Operations, Inc. Fuel processor primary reactor and combustor startup via electrically-heated catalyst
US7101175B2 (en) 2003-04-04 2006-09-05 Texaco Inc. Anode tailgas oxidizer
DE10317197A1 (de) * 2003-04-15 2004-11-04 Degussa Ag Elektrisch beheizter Reaktor und Verfahren zur Durchführung von Gasreaktionen bei hoher Temperatur unter Verwendung dieses Reaktors
CN1274051C (zh) * 2003-04-24 2006-09-06 松下电器产业株式会社 氢生成装置及具备该装置的燃料电池系统
GB0317573D0 (en) 2003-07-26 2003-08-27 Rolls Royce Fuel Cell Systems A pre-reformer
JP2005071970A (ja) * 2003-08-27 2005-03-17 Setec:Kk メタノール利用燃料電池
JP4039383B2 (ja) * 2003-10-21 2008-01-30 トヨタ自動車株式会社 水素利用内燃機関
JP2005216615A (ja) * 2004-01-28 2005-08-11 Ebara Ballard Corp 燃料処理装置及び燃料電池発電システム
US20050188617A1 (en) * 2004-02-26 2005-09-01 Casio Computer Co., Ltd. Reactor and power generator
JP4051569B2 (ja) 2004-03-22 2008-02-27 修 山田 金属間化合物系多孔質材料の製造方法
US8617265B2 (en) * 2004-04-12 2013-12-31 Intelligent Energy, Inc. Hydrogen generation apparatus incorporating a staged catalyst and method for using same
US7306781B2 (en) * 2004-07-09 2007-12-11 Catacel Corp. Hydrogen generator
US8133622B2 (en) 2004-09-08 2012-03-13 Samsung Sdi Co., Ltd. Heated reformer and fuel cell system having the same
US7943547B2 (en) * 2005-09-14 2011-05-17 Hamilton Sundstrand Space Systems International, Inc. Selective catalytic oxidation of ammonia to water and nitrogen
JP2007099596A (ja) * 2005-10-07 2007-04-19 Ishikawajima Shibaura Mach Co Ltd 燃料改質装置
US7682577B2 (en) 2005-11-07 2010-03-23 Geo2 Technologies, Inc. Catalytic exhaust device for simplified installation or replacement
US7682578B2 (en) 2005-11-07 2010-03-23 Geo2 Technologies, Inc. Device for catalytically reducing exhaust
JP2007177672A (ja) * 2005-12-27 2007-07-12 Hino Motors Ltd 排気浄化装置
US7722828B2 (en) 2005-12-30 2010-05-25 Geo2 Technologies, Inc. Catalytic fibrous exhaust system and method for catalyzing an exhaust gas
JP4751734B2 (ja) * 2006-02-14 2011-08-17 アイシン精機株式会社 改質装置
US7939051B2 (en) 2006-05-23 2011-05-10 Idatech, Llc Hydrogen-producing fuel processing assemblies, heating assemblies, and methods of operating the same
DE102007005154B4 (de) * 2007-01-29 2009-04-09 Thyssenkrupp Vdm Gmbh Verwendung einer Eisen-Chrom-Aluminium-Legierung mit hoher Lebensdauer und geringen Änderungen im Warmwiderstand
JP5164441B2 (ja) * 2007-06-13 2013-03-21 Jx日鉱日石エネルギー株式会社 燃料電池システムの起動方法
JP4483901B2 (ja) * 2007-06-29 2010-06-16 株式会社日立製作所 エンジンシステム
US8268289B2 (en) * 2007-07-19 2012-09-18 Toda Kogyo Corporation Hydrocarbon-decomposing catalyst, process for decomposing hydrocarbons and process for producing hydrogen using the catalyst, and power generation system
EP2244830A2 (de) * 2008-01-14 2010-11-03 Hydrogen Catalyst Ltd. Monolithischer katalysator und verfahren dafür
US8882863B2 (en) * 2008-05-14 2014-11-11 Alliant Techsystems Inc. Fuel reformulation systems
DE102008034221A1 (de) * 2008-07-23 2010-01-28 Bayerische Motoren Werke Aktiengesellschaft Kraftstoffversorgungseinrichtung für ein mit Wasserstoff betreibbares Kraftfahrzeug
JP5353133B2 (ja) * 2008-09-11 2013-11-27 カシオ計算機株式会社 発電システム
US20100068130A1 (en) * 2008-09-17 2010-03-18 Frederick Carl Wilhelm Process for the Production of Hydrogen Gas Employing a Thermally Stable Catalyst
DE102008050817A1 (de) 2008-10-08 2010-04-15 Karl-Heinz Tetzlaff Abgasfreie allotherme Dampfreformierung
JP2010195642A (ja) * 2009-02-26 2010-09-09 Tama Tlo Ltd 水素生成装置
JP2010235406A (ja) * 2009-03-31 2010-10-21 Toyota Industries Corp 改質器
JP5717993B2 (ja) * 2010-07-12 2015-05-13 本田技研工業株式会社 改質装置及びその製造方法
US8697451B2 (en) * 2010-11-22 2014-04-15 Fuelcell Energy, Inc. Sulfur breakthrough detection assembly for use in a fuel utilization system and sulfur breakthrough detection method
WO2013135707A1 (de) * 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Verfahren zur herstellung eines kohlenmonoxid enthaltenden gasgemisches bei hohen temperaturen an mischmetalloxidkatalysatoren umfassend edelmetalle
WO2013135668A1 (de) * 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Chemisches reaktorsystem, umfassend einen axialen strömungsreaktor mit heiz- und zwischenebenen
WO2013135666A1 (de) * 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Axialer strömungsreaktor auf der basis einer fe-cr-al-legierung
WO2013135660A1 (de) * 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Axialer strömungsreaktor mit heiz- und zwischenebenen
WO2013135657A1 (de) * 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Verfahren für die synthesegasherstellung im wechselbetrieb zwischen zwei betriebsarten
US9115913B1 (en) 2012-03-14 2015-08-25 Leonardo Corporation Fluid heater
IL220629A0 (en) * 2012-06-25 2017-01-31 Yeda Res & Dev Device and apparatus for performing chemical decomposition reactions at high temperatures
CA2929546C (en) 2013-11-06 2019-03-05 Watt Fuel Cell Corp. Gaseous fuel cpox reformers and methods of cpox reforming
WO2015069621A2 (en) 2013-11-06 2015-05-14 Watt Fuel Cell Corp. Reformer with perovskite as structural component thereof
MX2016004622A (es) 2013-11-06 2016-08-01 WATT Fuel Cell Corp Reformador de cpox de combustible gaseoso integrado y sistemas de celda de combustible, y metodos para producir electricidad.
JP6231697B2 (ja) 2013-11-06 2017-11-15 ワット・フューエル・セル・コーポレイションWatt Fuel Cell Corp. 液体燃料cpox改質器及びcpox改質の方法
CN105705227B (zh) 2013-11-06 2018-09-25 瓦特燃料电池公司 液体燃料催化部分氧化重整器和燃料电池系统、以及产生电力的方法
WO2015069762A2 (en) 2013-11-06 2015-05-14 Watt Fuel Cell Corp. Chemical reactor with manifold for management of a flow of gaseous reaction medium thereto
KR102320128B1 (ko) 2014-10-07 2021-11-02 프로토넥스 테크놀로지 코퍼레이션 Sofc-전도
WO2016056488A1 (ja) * 2014-10-09 2016-04-14 株式会社豊田自動織機 化学蓄熱装置
DE102016213322B4 (de) 2015-08-05 2023-07-20 Ford Global Technologies, Llc Duales Katalysator-Heizsystem
US10790523B2 (en) * 2015-10-20 2020-09-29 Upstart Power, Inc. CPOX reactor control system and method
DE102016213612B3 (de) * 2016-07-25 2017-12-28 Continental Automotive Gmbh Elektrischer Abgaskatalysator, Fahrzeug und Verfahren zum Betreiben eines elektrischen Abgaskatalysators
US11108072B2 (en) 2016-08-11 2021-08-31 Upstart Power, Inc. Planar solid oxide fuel unit cell and stack
US10428713B2 (en) 2017-09-07 2019-10-01 Denso International America, Inc. Systems and methods for exhaust heat recovery and heat storage
WO2019104204A1 (en) * 2017-11-25 2019-05-31 Starfire Energy Chemical reactor with integrated heat exchanger
WO2019110268A1 (en) 2017-12-08 2019-06-13 Haldor Topsøe A/S A plant and process for producing synthesis gas
CN111247091B (zh) 2017-12-08 2023-05-30 托普索公司 用于生产合成气的方法和系统
US11932538B2 (en) * 2017-12-08 2024-03-19 Haldor Topsøe A/S Process and system for reforming a hydrocarbon gas
EP3574991A1 (de) 2018-05-31 2019-12-04 Haldor Topsøe A/S Durch widerstandsheizung erhitzte dampfreformierung
US11591215B2 (en) 2018-05-31 2023-02-28 Haldor Topsøe A/S Hydrogen production by steam methane reforming
ES2914044T3 (es) 2018-06-29 2022-06-07 Shell Int Research Reactor calentado eléctricamente y un proceso de conversión de gas mediante el uso de dicho reactor
DE102018217174B4 (de) * 2018-10-08 2020-07-09 Vitesco Technologies GmbH Elektrisch beheizter Abgaskatalysator und Verfahren zum Betreiben eines elektrisch beheizten Abgaskatalysators
CN113167475B (zh) * 2018-11-13 2022-11-29 庄信万丰股份有限公司 电加热的催化燃烧器
NO20190635A1 (en) * 2019-05-21 2020-11-23 Vestlandets Innovasjonsselskap As A catalytic converter module and a method of enhancing the efficiency of a catalytic converter
DE102019209304B4 (de) * 2019-06-26 2021-03-25 Vitesco Technologies GmbH Vorrichtung zur Abgasnachbehandlung
FR3101075B1 (fr) * 2019-09-19 2022-07-29 Commissariat Energie Atomique : Réacteur à lit fixe catalytique intégrant un élément chauffant électrique, Unité de production d’hydrogène par vaporeformage comprenant un tel réacteur et un générateur de vapeur électrique, procédé de fonctionnement associé.
KR20220104735A (ko) * 2019-12-04 2022-07-26 토프쉐 에이/에스 저항 가열에 의해 가열된 원료 가스의 흡열 반응
US11578019B2 (en) * 2020-06-22 2023-02-14 Purdue Research Foundation Electrically heated dehydrogenation process
CN117480009A (zh) * 2021-05-28 2024-01-30 托普索公司 具有催化活性的电加热器
CN114797684A (zh) * 2022-04-01 2022-07-29 众立能源装备(陕西)有限公司 一种氨气低温催化分解的制氢装置

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL62754C (de) * 1941-01-27
CH645318A5 (de) * 1978-11-21 1984-09-28 Silberring Ludwig Verfahren und vorrichtung zur herstellung von wasserstoff.
US4522802A (en) * 1982-04-26 1985-06-11 United Technologies Corporation Steam reforming utilizing iron oxide catalyst
US4451578A (en) * 1982-04-26 1984-05-29 United Technologies Corporation Iron oxide catalyst for steam reforming
JPS58219945A (ja) * 1982-06-15 1983-12-21 Matsushita Electric Ind Co Ltd 炭化水素改質用触媒
DE3521766A1 (de) * 1985-06-19 1987-01-02 Basf Ag Wabenfoermiger katalysator, seiner herstellung und seine verwendung
US5149508A (en) * 1989-03-06 1992-09-22 W. R. Grace & Co.-Conn. Parallel path catalytic converter
US5281462A (en) 1989-11-01 1994-01-25 Corning Incorporated Material, structure, filter and catalytic converter
JPH03247501A (ja) * 1990-02-27 1991-11-05 Mitsubishi Heavy Ind Ltd メタノール改質装置のシャットダウン方法
JPH0474701A (ja) * 1990-07-12 1992-03-10 Fuji Electric Co Ltd 一酸化炭素転化反応器
DE4035971A1 (de) * 1990-11-12 1992-05-14 Emitec Emissionstechnologie Beheizbare katalysatoranordnung fuer die abgasreinigung von verbrennungsmotoren
KR0140505B1 (ko) 1991-01-31 1998-06-01 볼프강 마우스, 지그프리트 나스 불균일하게 전기 가열되는 벌집형 본체
FR2684313B1 (fr) * 1991-12-03 1994-01-28 Institut Francais Petrole Procede et dispositif pour la fabrication de gaz de synthese et application.
JPH05147903A (ja) * 1991-12-03 1993-06-15 Fuji Electric Co Ltd 改質装置
JPH06389A (ja) 1992-03-02 1994-01-11 Nippon Steel Corp 自動車触媒用高耐熱型メタル担体
GB2268694A (en) * 1992-07-14 1994-01-19 Rolls Royce Plc A catalytic combustion chamber
JPH0648701A (ja) 1992-07-24 1994-02-22 Mitsubishi Heavy Ind Ltd 水蒸気改質反応器
US5856263A (en) 1992-08-28 1999-01-05 Union Carbide Chemicals & Plastics Technology Corporation Catalysts comprising substantially pure alpha-alumina carrier for treating exhaust gases
US5866498A (en) 1992-09-28 1999-02-02 Ford Global Technologies, Inc. Composite catalysts for hydrocarbon oxidation
GB9225188D0 (en) * 1992-12-02 1993-01-20 Rolls Royce & Ass Combined reformer and shift reactor
US5741440A (en) * 1994-02-28 1998-04-21 Eastman Chemical Company Production of hydrogen and carbon monoxide
JP3403494B2 (ja) 1994-05-23 2003-05-06 日本碍子株式会社 改質反応器
CA2188653A1 (en) * 1995-02-27 1996-09-06 Akira Matsuoka Hydrogen generator
US5939025A (en) * 1995-08-23 1999-08-17 The University Of Chicago Methanol partial oxidation reformer
US5883138A (en) * 1997-04-25 1999-03-16 Exxon Research And Engineering Company Rapid injection catalytic partial oxidation process and apparatus for producing synthesis gas (law 562)

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US6641795B2 (en) 2003-11-04
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CA2252073C (en) 2003-05-13
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CA2252073A1 (en) 1999-04-28
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