DE69827255T2 - Aluminiumoxidextrudate, ihre herstellungsverfahren und verwendung dieser, als katalysatoren oder katalysatorträger - Google Patents

Aluminiumoxidextrudate, ihre herstellungsverfahren und verwendung dieser, als katalysatoren oder katalysatorträger Download PDF

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Publication number
DE69827255T2
DE69827255T2 DE69827255T DE69827255T DE69827255T2 DE 69827255 T2 DE69827255 T2 DE 69827255T2 DE 69827255 T DE69827255 T DE 69827255T DE 69827255 T DE69827255 T DE 69827255T DE 69827255 T2 DE69827255 T2 DE 69827255T2
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DE
Germany
Prior art keywords
alumina
extrudates
rehydrated
stage
boehmite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69827255T
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German (de)
English (en)
Other versions
DE69827255D1 (de
Inventor
Jean-Luc Le Loarer
Hubert Nussbaum
Denis Bortzmeyer
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Publication of DE69827255D1 publication Critical patent/DE69827255D1/de
Publication of DE69827255T2 publication Critical patent/DE69827255T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/44—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water
    • C01F7/447—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes
    • C01F7/448—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes using superatmospheric pressure, e.g. hydrothermal conversion of gibbsite into boehmite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/04—Compounds with a limited amount of crystallinty, e.g. as indicated by a crystallinity index
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Analytical Chemistry (AREA)
  • Catalysts (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE69827255T 1997-06-10 1998-06-10 Aluminiumoxidextrudate, ihre herstellungsverfahren und verwendung dieser, als katalysatoren oder katalysatorträger Expired - Lifetime DE69827255T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9707146A FR2764208B1 (fr) 1997-06-10 1997-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs
FR9707146 1997-06-10
PCT/FR1998/001186 WO1998056499A1 (fr) 1997-06-10 1998-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs

Publications (2)

Publication Number Publication Date
DE69827255D1 DE69827255D1 (de) 2004-12-02
DE69827255T2 true DE69827255T2 (de) 2005-03-10

Family

ID=9507787

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69827255T Expired - Lifetime DE69827255T2 (de) 1997-06-10 1998-06-10 Aluminiumoxidextrudate, ihre herstellungsverfahren und verwendung dieser, als katalysatoren oder katalysatorträger

Country Status (7)

Country Link
US (1) US6656875B1 (https=)
EP (1) EP0991466B1 (https=)
JP (1) JP4264852B2 (https=)
AU (1) AU7925498A (https=)
DE (1) DE69827255T2 (https=)
FR (1) FR2764208B1 (https=)
WO (1) WO1998056499A1 (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2787041B1 (fr) * 1998-12-10 2001-01-19 Inst Francais Du Petrole Catalyseur d'hydrotraitement de charges hydrocarbonees dans un reacteur a lit fixe
CN1119208C (zh) * 1999-08-04 2003-08-27 中国石化集团齐鲁石化公司 一种大孔的耐硫变换催化剂及其制备方法
FR2797639B1 (fr) * 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
CN1102444C (zh) * 1999-09-29 2003-03-05 中国石油化工集团公司 一种氧化铝载体的制备方法
CN1102443C (zh) * 1999-09-29 2003-03-05 中国石油化工集团公司 具有集中孔分布的氧化铝载体的制备方法
AUPQ665000A0 (en) * 2000-04-03 2000-05-04 University Of Queensland, The Improved catalyst
FR2823193B1 (fr) * 2001-04-04 2004-02-13 Pro Catalyse Agglomeres d'alumine, leur procede de preparation, et leurs utilisations comme support de catalyseur, catalyseur ou absorbant
FR2823194B1 (fr) * 2001-04-10 2004-02-13 Pro Catalyse Agglomeres d'alumine utilisables, notamment, comme supports de catalyseur, catalyseurs ou adsorbants, et leurs procedes de preparation
US20090166260A1 (en) * 2005-12-22 2009-07-02 Stephane Kressmann Irregularly shaped non-spherical supported catalyst, and a process for hydroconverting heavy oil fractions
DE102007011471B4 (de) * 2006-03-09 2021-09-30 Shell Internationale Research Maatschappij B.V. Katalysatorkombination für die hydrierende Verarbeitung von Vakuumgasölen und/oder Visbreakergasölen
JP2008012527A (ja) * 2006-06-06 2008-01-24 Denso Corp 触媒担持粒子およびそれを用いた触媒体の製造方法
FR2927267B1 (fr) * 2008-02-07 2010-04-16 Inst Francais Du Petrole Catalyseur d'hydrogenation selective et son procede de preparation
RU2711605C1 (ru) * 2019-07-03 2020-01-17 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Способ получения алюмооксидных катализаторов процесса Клауса и применение их на установках получения серы
CN118847134A (zh) * 2023-04-26 2024-10-29 中国石油化工股份有限公司 一种重质油加氢脱氮、脱残炭催化剂的制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE273780C (https=) *
US3856708A (en) * 1972-04-10 1974-12-24 Reynolds Metals Co Alumina catalyst support
FR2299911A1 (fr) * 1975-02-04 1976-09-03 Kali Chemie Ag Procede de fabrication de particules spheriques contenant de l'alumine et produits obtenus
DE2758945A1 (de) * 1977-12-30 1979-07-05 American Cyanamid Co Verfahren zur herstellung von formteilchen aus aluminiumoxid
FR2449474A1 (fr) * 1979-02-26 1980-09-19 Rhone Poulenc Ind Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs
FR2449650A1 (fr) * 1979-02-26 1980-09-19 Rhone Poulenc Ind Procede de preparation d'alumine au moins partiellement sous forme de boehmite ultra-fine
FR2528721B1 (fr) * 1982-06-17 1986-02-28 Pro Catalyse Ste Fse Prod Cata Catalyseur supporte presentant une resistance accrue aux poisons et son utilisation en particulier pour l'hydrotraitement de fractions petrolieres contenant des metaux
FR2537889B1 (fr) * 1982-12-20 1992-10-09 Pro Catalyse Procede de traitement d'hydrocarbures en presence d'un catalyseur a base de billes d'alumine mises en forme par coagulation en gouttes
FR2556235A1 (fr) * 1983-12-09 1985-06-14 Pro Catalyse Procede de fabrication d'un catalyseur a base d'alumine
US4579728A (en) * 1985-04-24 1986-04-01 Shell Oil Company Wide pore alumina supports
FR2634757B1 (fr) * 1988-07-29 1992-09-18 Rhone Poulenc Chimie Procede de fabrication d'agglomeres d'alumine et agglomeres obtenus
GB9010075D0 (en) * 1990-05-04 1990-06-27 Shell Int Research Process for the preparation of alumina based extrudates
DE4311650C2 (de) * 1993-04-08 1996-06-05 Sued Chemie Ag Hochporöse Formlinge auf der Basis von Aluminiumoxid und deren Verwendung
FR2736281B1 (fr) * 1995-07-07 1997-08-01 Rhone Poulenc Chimie Procede pour l'adsorption de composes organometalliques chelates et adsorbants a base d'alumine comprenant un compose organometallique chelate

Also Published As

Publication number Publication date
US6656875B1 (en) 2003-12-02
EP0991466B1 (fr) 2004-10-27
JP4264852B2 (ja) 2009-05-20
EP0991466A1 (fr) 2000-04-12
AU7925498A (en) 1998-12-30
FR2764208A1 (fr) 1998-12-11
FR2764208B1 (fr) 1999-07-16
WO1998056499A1 (fr) 1998-12-17
JP2002510242A (ja) 2002-04-02
DE69827255D1 (de) 2004-12-02

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8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: IFP ENERGIES NOUVELLES, RUEIL-MALMAISON, FR

8328 Change in the person/name/address of the agent

Representative=s name: VONNEMANN, KLOIBER & KOLLEGEN, 81667 MUENCHEN