JP4264852B2 - アルミナ押出し物、その調製方法および触媒または触媒担体としてのその使用 - Google Patents

アルミナ押出し物、その調製方法および触媒または触媒担体としてのその使用 Download PDF

Info

Publication number
JP4264852B2
JP4264852B2 JP50177499A JP50177499A JP4264852B2 JP 4264852 B2 JP4264852 B2 JP 4264852B2 JP 50177499 A JP50177499 A JP 50177499A JP 50177499 A JP50177499 A JP 50177499A JP 4264852 B2 JP4264852 B2 JP 4264852B2
Authority
JP
Japan
Prior art keywords
alumina
extrudate
produced
acid
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP50177499A
Other languages
English (en)
Japanese (ja)
Other versions
JP2002510242A5 (https=
JP2002510242A (ja
Inventor
ロレ ジャン リュック ル
ユベール ニィスボー
ドゥニ ボルメイエ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of JP2002510242A publication Critical patent/JP2002510242A/ja
Publication of JP2002510242A5 publication Critical patent/JP2002510242A5/ja
Application granted granted Critical
Publication of JP4264852B2 publication Critical patent/JP4264852B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/44—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water
    • C01F7/447—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes
    • C01F7/448—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes using superatmospheric pressure, e.g. hydrothermal conversion of gibbsite into boehmite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/04—Compounds with a limited amount of crystallinty, e.g. as indicated by a crystallinity index
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Analytical Chemistry (AREA)
  • Catalysts (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
JP50177499A 1997-06-10 1998-06-10 アルミナ押出し物、その調製方法および触媒または触媒担体としてのその使用 Expired - Fee Related JP4264852B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9707146A FR2764208B1 (fr) 1997-06-10 1997-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs
FR97/07146 1997-06-10
PCT/FR1998/001186 WO1998056499A1 (fr) 1997-06-10 1998-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs

Publications (3)

Publication Number Publication Date
JP2002510242A JP2002510242A (ja) 2002-04-02
JP2002510242A5 JP2002510242A5 (https=) 2005-12-22
JP4264852B2 true JP4264852B2 (ja) 2009-05-20

Family

ID=9507787

Family Applications (1)

Application Number Title Priority Date Filing Date
JP50177499A Expired - Fee Related JP4264852B2 (ja) 1997-06-10 1998-06-10 アルミナ押出し物、その調製方法および触媒または触媒担体としてのその使用

Country Status (7)

Country Link
US (1) US6656875B1 (https=)
EP (1) EP0991466B1 (https=)
JP (1) JP4264852B2 (https=)
AU (1) AU7925498A (https=)
DE (1) DE69827255T2 (https=)
FR (1) FR2764208B1 (https=)
WO (1) WO1998056499A1 (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2787041B1 (fr) * 1998-12-10 2001-01-19 Inst Francais Du Petrole Catalyseur d'hydrotraitement de charges hydrocarbonees dans un reacteur a lit fixe
CN1119208C (zh) * 1999-08-04 2003-08-27 中国石化集团齐鲁石化公司 一种大孔的耐硫变换催化剂及其制备方法
FR2797639B1 (fr) * 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
CN1102444C (zh) * 1999-09-29 2003-03-05 中国石油化工集团公司 一种氧化铝载体的制备方法
CN1102443C (zh) * 1999-09-29 2003-03-05 中国石油化工集团公司 具有集中孔分布的氧化铝载体的制备方法
AUPQ665000A0 (en) * 2000-04-03 2000-05-04 University Of Queensland, The Improved catalyst
FR2823193B1 (fr) * 2001-04-04 2004-02-13 Pro Catalyse Agglomeres d'alumine, leur procede de preparation, et leurs utilisations comme support de catalyseur, catalyseur ou absorbant
FR2823194B1 (fr) * 2001-04-10 2004-02-13 Pro Catalyse Agglomeres d'alumine utilisables, notamment, comme supports de catalyseur, catalyseurs ou adsorbants, et leurs procedes de preparation
US20090166260A1 (en) * 2005-12-22 2009-07-02 Stephane Kressmann Irregularly shaped non-spherical supported catalyst, and a process for hydroconverting heavy oil fractions
DE102007011471B4 (de) * 2006-03-09 2021-09-30 Shell Internationale Research Maatschappij B.V. Katalysatorkombination für die hydrierende Verarbeitung von Vakuumgasölen und/oder Visbreakergasölen
JP2008012527A (ja) * 2006-06-06 2008-01-24 Denso Corp 触媒担持粒子およびそれを用いた触媒体の製造方法
FR2927267B1 (fr) * 2008-02-07 2010-04-16 Inst Francais Du Petrole Catalyseur d'hydrogenation selective et son procede de preparation
RU2711605C1 (ru) * 2019-07-03 2020-01-17 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Способ получения алюмооксидных катализаторов процесса Клауса и применение их на установках получения серы
CN118847134A (zh) * 2023-04-26 2024-10-29 中国石油化工股份有限公司 一种重质油加氢脱氮、脱残炭催化剂的制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE273780C (https=) *
US3856708A (en) * 1972-04-10 1974-12-24 Reynolds Metals Co Alumina catalyst support
FR2299911A1 (fr) * 1975-02-04 1976-09-03 Kali Chemie Ag Procede de fabrication de particules spheriques contenant de l'alumine et produits obtenus
DE2758945A1 (de) * 1977-12-30 1979-07-05 American Cyanamid Co Verfahren zur herstellung von formteilchen aus aluminiumoxid
FR2449474A1 (fr) * 1979-02-26 1980-09-19 Rhone Poulenc Ind Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs
FR2449650A1 (fr) * 1979-02-26 1980-09-19 Rhone Poulenc Ind Procede de preparation d'alumine au moins partiellement sous forme de boehmite ultra-fine
FR2528721B1 (fr) * 1982-06-17 1986-02-28 Pro Catalyse Ste Fse Prod Cata Catalyseur supporte presentant une resistance accrue aux poisons et son utilisation en particulier pour l'hydrotraitement de fractions petrolieres contenant des metaux
FR2537889B1 (fr) * 1982-12-20 1992-10-09 Pro Catalyse Procede de traitement d'hydrocarbures en presence d'un catalyseur a base de billes d'alumine mises en forme par coagulation en gouttes
FR2556235A1 (fr) * 1983-12-09 1985-06-14 Pro Catalyse Procede de fabrication d'un catalyseur a base d'alumine
US4579728A (en) * 1985-04-24 1986-04-01 Shell Oil Company Wide pore alumina supports
FR2634757B1 (fr) * 1988-07-29 1992-09-18 Rhone Poulenc Chimie Procede de fabrication d'agglomeres d'alumine et agglomeres obtenus
GB9010075D0 (en) * 1990-05-04 1990-06-27 Shell Int Research Process for the preparation of alumina based extrudates
DE4311650C2 (de) * 1993-04-08 1996-06-05 Sued Chemie Ag Hochporöse Formlinge auf der Basis von Aluminiumoxid und deren Verwendung
FR2736281B1 (fr) * 1995-07-07 1997-08-01 Rhone Poulenc Chimie Procede pour l'adsorption de composes organometalliques chelates et adsorbants a base d'alumine comprenant un compose organometallique chelate

Also Published As

Publication number Publication date
US6656875B1 (en) 2003-12-02
EP0991466B1 (fr) 2004-10-27
EP0991466A1 (fr) 2000-04-12
AU7925498A (en) 1998-12-30
FR2764208A1 (fr) 1998-12-11
FR2764208B1 (fr) 1999-07-16
WO1998056499A1 (fr) 1998-12-17
JP2002510242A (ja) 2002-04-02
DE69827255T2 (de) 2005-03-10
DE69827255D1 (de) 2004-12-02

Similar Documents

Publication Publication Date Title
KR101108408B1 (ko) 도핑된 구체 형상의 지지된 촉매 및 금속 함유 석유유분의 수소화처리 및 수소화전환 방법
CN101255360B (zh) 使用担载催化剂的重质烃原料和/或煤浆料相加氢转化方法
JP4264852B2 (ja) アルミナ押出し物、その調製方法および触媒または触媒担体としてのその使用
US7666296B2 (en) Process for the hydroconversion in a slurry of heavy hydrocarbonaceous feedstocks in the presence of a dispersed phase and an alumina-based oxide
JP4501195B2 (ja) 固定床反応器内での炭化水素仕込原料の水素化処理触媒
KR102041652B1 (ko) 실리카-함유 알루미나 지지체, 이로부터 제조된 촉매, 및 이를 사용하는 공정
JP6432086B2 (ja) 重質炭化水素油の水素化処理触媒、重質炭化水素油の水素化処理触媒の製造方法、及び重質炭化水素油の水素化処理方法
JP4818163B2 (ja) アルミナ担体及びそれを用いた水素化脱金属触媒並びにそれらの製造方法
US6303531B1 (en) Hydrothermally stable high pore volume aluminum oxide/swellable clay composites and methods of their preparation and use
TWI666310B (zh) 觸媒組成物、加氫處理重烴類部分之方法及製備沉澱氧化鋁組成物的方法
AU778286B2 (en) Hydrothermally stable high pore volume aluminum oxide/swellable clay composites and methods of their preparation and use
JPH119996A (ja) 固定床反応器における炭化水素仕込原料の水素化処理触媒
JP6553030B2 (ja) 重質炭化水素原料のミクロ残留炭素分の接触転化のための方法及び前記方法において使用するための低表面積触媒
JP4537713B2 (ja) 水素化精製触媒の製造方法
WO2001094012A1 (fr) Catalyseur et procede d'hydrodesulfuration
CN116528978B (zh) 包含1-30重量%结晶碱式碳酸铝铵的二氧化硅-氧化铝组合物及其制备方法
JP5502192B2 (ja) 水素化変換多金属触媒及びその作製方法
GB2150852A (en) Hydrocarbon hydrotreatment process
JP2556341B2 (ja) ヒドロゲルから作成した水添処理触媒の製造方法および製造された触媒
JP2556343B2 (ja) ヒドロゲルからの水添処理触媒の製造方法
CN115702040A (zh) 烃油的加氢处理催化剂、烃油的加氢处理催化剂的制造方法、以及烃油的加氢处理方法
RU2836692C1 (ru) Катализатор гидрирования и способ его получения и применение
JP2021531962A (ja) ヘテロポリアニオンを含有している溶液から生じた共混合型触媒、その製造のための方法、および重質炭化水素供給原料の水素化転化における同触媒の使用
CN112547079A (zh) 一种重油加氢处理催化剂及其应用
JPH0813329B2 (ja) 炭化水素油の水素化脱硫触媒組成物の製造方法

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050607

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20050607

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080701

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20081001

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20090106

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20090205

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120227

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120227

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130227

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees