FR2764208B1 - Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs - Google Patents

Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs

Info

Publication number
FR2764208B1
FR2764208B1 FR9707146A FR9707146A FR2764208B1 FR 2764208 B1 FR2764208 B1 FR 2764208B1 FR 9707146 A FR9707146 A FR 9707146A FR 9707146 A FR9707146 A FR 9707146A FR 2764208 B1 FR2764208 B1 FR 2764208B1
Authority
FR
France
Prior art keywords
extrudes
catalysts
alumina
processes
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9707146A
Other languages
English (en)
French (fr)
Other versions
FR2764208A1 (fr
Inventor
Loarer Jean Luc Le
Hubert Nussbaum
Denis Bortzmeyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR9707146A priority Critical patent/FR2764208B1/fr
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Priority to PCT/FR1998/001186 priority patent/WO1998056499A1/fr
Priority to EP98929535A priority patent/EP0991466B1/fr
Priority to JP50177499A priority patent/JP4264852B2/ja
Priority to DE69827255T priority patent/DE69827255T2/de
Priority to AU79254/98A priority patent/AU7925498A/en
Priority to US09/445,753 priority patent/US6656875B1/en
Publication of FR2764208A1 publication Critical patent/FR2764208A1/fr
Application granted granted Critical
Publication of FR2764208B1 publication Critical patent/FR2764208B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/44—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water
    • C01F7/447—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes
    • C01F7/448—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes using superatmospheric pressure, e.g. hydrothermal conversion of gibbsite into boehmite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/04—Compounds with a limited amount of crystallinty, e.g. as indicated by a crystallinity index
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Analytical Chemistry (AREA)
  • Catalysts (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
FR9707146A 1997-06-10 1997-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs Expired - Fee Related FR2764208B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR9707146A FR2764208B1 (fr) 1997-06-10 1997-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs
EP98929535A EP0991466B1 (fr) 1997-06-10 1998-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs
JP50177499A JP4264852B2 (ja) 1997-06-10 1998-06-10 アルミナ押出し物、その調製方法および触媒または触媒担体としてのその使用
DE69827255T DE69827255T2 (de) 1997-06-10 1998-06-10 Aluminiumoxidextrudate, ihre herstellungsverfahren und verwendung dieser, als katalysatoren oder katalysatorträger
PCT/FR1998/001186 WO1998056499A1 (fr) 1997-06-10 1998-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs
AU79254/98A AU7925498A (en) 1997-06-10 1998-06-10 Alumina extrudates, methods for preparing and use as catalysts or cataly st supports
US09/445,753 US6656875B1 (en) 1997-06-10 1998-06-10 Alumina extrudates, methods for preparing and use as catalysts supports

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9707146A FR2764208B1 (fr) 1997-06-10 1997-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs

Publications (2)

Publication Number Publication Date
FR2764208A1 FR2764208A1 (fr) 1998-12-11
FR2764208B1 true FR2764208B1 (fr) 1999-07-16

Family

ID=9507787

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9707146A Expired - Fee Related FR2764208B1 (fr) 1997-06-10 1997-06-10 Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs

Country Status (7)

Country Link
US (1) US6656875B1 (https=)
EP (1) EP0991466B1 (https=)
JP (1) JP4264852B2 (https=)
AU (1) AU7925498A (https=)
DE (1) DE69827255T2 (https=)
FR (1) FR2764208B1 (https=)
WO (1) WO1998056499A1 (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2787041B1 (fr) * 1998-12-10 2001-01-19 Inst Francais Du Petrole Catalyseur d'hydrotraitement de charges hydrocarbonees dans un reacteur a lit fixe
CN1119208C (zh) * 1999-08-04 2003-08-27 中国石化集团齐鲁石化公司 一种大孔的耐硫变换催化剂及其制备方法
FR2797639B1 (fr) * 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
CN1102444C (zh) * 1999-09-29 2003-03-05 中国石油化工集团公司 一种氧化铝载体的制备方法
CN1102443C (zh) * 1999-09-29 2003-03-05 中国石油化工集团公司 具有集中孔分布的氧化铝载体的制备方法
AUPQ665000A0 (en) * 2000-04-03 2000-05-04 University Of Queensland, The Improved catalyst
FR2823193B1 (fr) * 2001-04-04 2004-02-13 Pro Catalyse Agglomeres d'alumine, leur procede de preparation, et leurs utilisations comme support de catalyseur, catalyseur ou absorbant
FR2823194B1 (fr) * 2001-04-10 2004-02-13 Pro Catalyse Agglomeres d'alumine utilisables, notamment, comme supports de catalyseur, catalyseurs ou adsorbants, et leurs procedes de preparation
US20090166260A1 (en) * 2005-12-22 2009-07-02 Stephane Kressmann Irregularly shaped non-spherical supported catalyst, and a process for hydroconverting heavy oil fractions
DE102007011471B4 (de) * 2006-03-09 2021-09-30 Shell Internationale Research Maatschappij B.V. Katalysatorkombination für die hydrierende Verarbeitung von Vakuumgasölen und/oder Visbreakergasölen
JP2008012527A (ja) * 2006-06-06 2008-01-24 Denso Corp 触媒担持粒子およびそれを用いた触媒体の製造方法
FR2927267B1 (fr) * 2008-02-07 2010-04-16 Inst Francais Du Petrole Catalyseur d'hydrogenation selective et son procede de preparation
RU2711605C1 (ru) * 2019-07-03 2020-01-17 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Способ получения алюмооксидных катализаторов процесса Клауса и применение их на установках получения серы
CN118847134A (zh) * 2023-04-26 2024-10-29 中国石油化工股份有限公司 一种重质油加氢脱氮、脱残炭催化剂的制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE273780C (https=) *
US3856708A (en) * 1972-04-10 1974-12-24 Reynolds Metals Co Alumina catalyst support
FR2299911A1 (fr) * 1975-02-04 1976-09-03 Kali Chemie Ag Procede de fabrication de particules spheriques contenant de l'alumine et produits obtenus
DE2758945A1 (de) * 1977-12-30 1979-07-05 American Cyanamid Co Verfahren zur herstellung von formteilchen aus aluminiumoxid
FR2449474A1 (fr) * 1979-02-26 1980-09-19 Rhone Poulenc Ind Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs
FR2449650A1 (fr) * 1979-02-26 1980-09-19 Rhone Poulenc Ind Procede de preparation d'alumine au moins partiellement sous forme de boehmite ultra-fine
FR2528721B1 (fr) * 1982-06-17 1986-02-28 Pro Catalyse Ste Fse Prod Cata Catalyseur supporte presentant une resistance accrue aux poisons et son utilisation en particulier pour l'hydrotraitement de fractions petrolieres contenant des metaux
FR2537889B1 (fr) * 1982-12-20 1992-10-09 Pro Catalyse Procede de traitement d'hydrocarbures en presence d'un catalyseur a base de billes d'alumine mises en forme par coagulation en gouttes
FR2556235A1 (fr) * 1983-12-09 1985-06-14 Pro Catalyse Procede de fabrication d'un catalyseur a base d'alumine
US4579728A (en) * 1985-04-24 1986-04-01 Shell Oil Company Wide pore alumina supports
FR2634757B1 (fr) * 1988-07-29 1992-09-18 Rhone Poulenc Chimie Procede de fabrication d'agglomeres d'alumine et agglomeres obtenus
GB9010075D0 (en) * 1990-05-04 1990-06-27 Shell Int Research Process for the preparation of alumina based extrudates
DE4311650C2 (de) * 1993-04-08 1996-06-05 Sued Chemie Ag Hochporöse Formlinge auf der Basis von Aluminiumoxid und deren Verwendung
FR2736281B1 (fr) * 1995-07-07 1997-08-01 Rhone Poulenc Chimie Procede pour l'adsorption de composes organometalliques chelates et adsorbants a base d'alumine comprenant un compose organometallique chelate

Also Published As

Publication number Publication date
US6656875B1 (en) 2003-12-02
EP0991466B1 (fr) 2004-10-27
JP4264852B2 (ja) 2009-05-20
EP0991466A1 (fr) 2000-04-12
AU7925498A (en) 1998-12-30
FR2764208A1 (fr) 1998-12-11
WO1998056499A1 (fr) 1998-12-17
JP2002510242A (ja) 2002-04-02
DE69827255T2 (de) 2005-03-10
DE69827255D1 (de) 2004-12-02

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PLFP Fee payment

Year of fee payment: 19

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Effective date: 20170228