DE69713472D1 - Katalysatorzusammensetzung auf rutheniumbasis zur olefinmetathese - Google Patents

Katalysatorzusammensetzung auf rutheniumbasis zur olefinmetathese

Info

Publication number
DE69713472D1
DE69713472D1 DE69713472T DE69713472T DE69713472D1 DE 69713472 D1 DE69713472 D1 DE 69713472D1 DE 69713472 T DE69713472 T DE 69713472T DE 69713472 T DE69713472 T DE 69713472T DE 69713472 D1 DE69713472 D1 DE 69713472D1
Authority
DE
Germany
Prior art keywords
metethesis
ruthenium
olefin
catalyst composition
based catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69713472T
Other languages
English (en)
Other versions
DE69713472T2 (de
Inventor
O Nubel
Lane Hunt
S Choi
J Marks
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Corp North America Inc
Original Assignee
BP Corp North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Corp North America Inc filed Critical BP Corp North America Inc
Publication of DE69713472D1 publication Critical patent/DE69713472D1/de
Application granted granted Critical
Publication of DE69713472T2 publication Critical patent/DE69713472T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2286Alkynes, e.g. acetylides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C07C6/06Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond at a cyclic carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14Other (co) polymerisation, e.g. of lactides, epoxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE69713472T 1996-04-30 1997-04-25 Katalysatorzusammensetzung auf rutheniumbasis zur olefinmetathese Expired - Fee Related DE69713472T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US1655496P 1996-04-30 1996-04-30
US3325796P 1996-12-06 1996-12-06
US08/842,251 US6156692A (en) 1996-04-30 1997-04-24 Ruthenium-containing catalyst composition for olefin metathesis
PCT/US1997/006937 WO1997040934A1 (en) 1996-04-30 1997-04-25 A ruthenium-based catalyst system for olefin metathesis

Publications (2)

Publication Number Publication Date
DE69713472D1 true DE69713472D1 (de) 2002-07-25
DE69713472T2 DE69713472T2 (de) 2003-02-20

Family

ID=27360592

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69713472T Expired - Fee Related DE69713472T2 (de) 1996-04-30 1997-04-25 Katalysatorzusammensetzung auf rutheniumbasis zur olefinmetathese

Country Status (6)

Country Link
US (1) US6156692A (de)
EP (1) EP0841988B1 (de)
JP (1) JP2000500700A (de)
DE (1) DE69713472T2 (de)
ES (1) ES2179338T3 (de)
WO (1) WO1997040934A1 (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6156692A (en) * 1996-04-30 2000-12-05 Bp Amoco Corporation Ruthenium-containing catalyst composition for olefin metathesis
US6159890A (en) * 1996-04-30 2000-12-12 Bp Amoco Corporation Ruthenium-containing catalyst system for olefin metathesis
DE59709143D1 (de) * 1996-11-15 2003-02-20 Ciba Sc Holding Ag Katalysatorgemisch für die ringöffnende Metathesepolymerisation
US6175047B1 (en) * 1997-12-26 2001-01-16 Takasago International Corporation Ruthenium metathesis catalyst and method for producing olefin reaction product by metathesis reaction using the same
CA2352362C (en) 1998-11-30 2009-02-17 Nanosphere, Inc. Nanoparticles with polymer shells
WO2001083097A2 (en) * 2000-05-04 2001-11-08 University Of Florida Metathesis of functionalized allylic olefins
CN100509155C (zh) * 2001-03-26 2009-07-08 陶氏环球技术公司 多相催化剂组合物
US20050124839A1 (en) * 2001-06-13 2005-06-09 Gartside Robert J. Catalyst and process for the metathesis of ethylene and butene to produce propylene
US6683019B2 (en) 2001-06-13 2004-01-27 Abb Lummus Global Inc. Catalyst for the metathesis of olefin(s)
EP2251360B1 (de) * 2001-08-29 2013-07-31 California Institute of Technology Ringöffnungsmetathesepolymerisation von verbrückten bicyclischen und polycyclischen olefinen mit zwei oder mehr heteroatomen
WO2003026770A1 (en) * 2001-09-24 2003-04-03 Smithkline Beecham Corporation Method for removing metal from the products of olefin metathesis reactions
WO2003093215A1 (en) 2002-04-29 2003-11-13 Dow Global Technologies Inc. Intergrated chemical processes for industrial utilization of seed oils
DE10393514T5 (de) * 2002-10-24 2005-09-29 Dow Global Technologies, Inc., Midland Stabilisierung von Produktmischungen aus der Olefinmetathese
EP1673328B1 (de) * 2003-10-09 2008-07-09 Dow Global Technologies Inc. Verbessertes verfahren zur synthese ungesättigter alkohole
JP5191972B2 (ja) * 2008-10-30 2013-05-08 高砂香料工業株式会社 ルテニウム錯体の製造方法
WO2010051268A1 (en) * 2008-10-31 2010-05-06 Dow Global Technologies Inc. Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands
JP5536541B2 (ja) * 2009-07-13 2014-07-02 高砂香料工業株式会社 ルテニウム−ジアミン錯体および光学活性化合物の製造方法
FR2975310B1 (fr) 2011-05-19 2014-03-14 IFP Energies Nouvelles Composition catalytique a base de ruthenium comprenant un compose de type silane ou siloxane et procede de metathese des olefines utilisant ladite composition
EP3408273B1 (de) * 2016-01-27 2020-06-17 Basf Se Verfahren zur erzeugung von dünnen anorganischen filmen
EP3546495A1 (de) * 2018-03-29 2019-10-02 Evonik Degussa GmbH Verfahren zur herstellung von temperaturstabilen polyalkenameren

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Publication number Priority date Publication date Assignee Title
US3117952A (en) * 1958-11-17 1964-01-14 American Cyanamid Co Method of improving certain catalysts
BE757752A (fr) * 1969-10-27 1971-04-01 Goodyear Tire & Rubber Nouveaux catalyseurs pour la polymerisation par ouverture du cycle de composes alicycliques insatures
DE2028935C3 (de) * 1970-06-12 1979-08-16 Chemische Werke Huels Ag, 4370 Marl Polyalkenamere und Verfahren zu deren Herstellung
US3855323A (en) * 1970-10-14 1974-12-17 Sun Ventures Inc Olefin isomerization catalysts and process
DE2157405C3 (de) * 1971-11-19 1975-10-16 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von polymeren Kohlenwasserstoffen mit reaktiven SiIyIe ndgruppen
US3962294A (en) * 1973-08-27 1976-06-08 Sun Ventures, Inc. Olefin isomerization catalysts and process
US3957827A (en) * 1974-10-17 1976-05-18 Sun Ventures, Inc. Hydrogenation of carboxylic acid anhydrides to lactones or esters by homogeneous catalysis
US4323508A (en) * 1978-01-03 1982-04-06 The Standard Oil Company Process for the manufacture of furan compounds
JPH0757758B2 (ja) * 1988-10-24 1995-06-21 高砂香料工業株式会社 ルテニウム―ホスフィン錯体
US5198561A (en) * 1989-06-22 1993-03-30 Monsanto Company Ruthenium-BINAP asymmetric hydrogenation catalyst
FR2651152B1 (fr) * 1989-08-23 1991-11-29 Elf Aquitaine Perfectionnement a la preparation de catalyseurs chiraux a base de complexes du ruthenium et du phosphore.
US5198511A (en) * 1991-12-20 1993-03-30 Minnesota Mining And Manufacturing Company Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor
US5324616A (en) * 1992-04-01 1994-06-28 Xerox Corporation Encapsulated toner compositions and processes thereof
US5312940A (en) * 1992-04-03 1994-05-17 California Institute Of Technology Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
US5710298A (en) * 1992-04-03 1998-01-20 California Institute Of Technology Method of preparing ruthenium and osmium carbene complexes
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
US5405924A (en) * 1993-07-22 1995-04-11 Shell Oil Company Imido transition metal complex metathesis catalysts
WO1996016100A1 (de) * 1994-11-17 1996-05-30 Ciba Specialty Chemicals Holding Inc. Thermisches metathesepolymerisationsverfahren und polymerisierbare zusammensetzung
ATE180001T1 (de) * 1994-12-23 1999-05-15 Ciba Geigy Ag Polymerisierbare zusammensetzung und polymerisationsverfahren
US5599962A (en) * 1995-01-31 1997-02-04 E. I. Du Pont De Nemours And Company Process for the preparation of ruthenium hydrogenation catalysts and products thereof
US5559262A (en) * 1995-01-31 1996-09-24 E. I. Du Pont De Nemours And Company Process for the preparation of ruthenium complexes and their in situ use as hydrogenation catalysts
US5728785A (en) * 1995-07-07 1998-03-17 California Institute Of Technology Romp polymerization in the presence of peroxide crosslinking agents to form high-density crosslinked polymers
US5831108A (en) * 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
US5939504A (en) * 1995-12-07 1999-08-17 Advanced Polymer Technologies Method for extending the pot life of an olefin metathesis polymerization reaction
EP0891384A1 (de) * 1996-04-04 1999-01-20 Ciba SC Holding AG Katalysatormischung und polymerisierbare zusammensetzung
US6156692A (en) * 1996-04-30 2000-12-05 Bp Amoco Corporation Ruthenium-containing catalyst composition for olefin metathesis
US5753584A (en) * 1996-06-04 1998-05-19 Intevep, S.A. Catalyst system for selective hydrogenation of heteroaromatic sulfur-containing and nitrogen-containing compounds
ATE228140T1 (de) * 1996-11-01 2002-12-15 Ciba Sc Holding Ag Verfahren zur herstellung von katalysatoren
US5917071A (en) * 1996-11-15 1999-06-29 California Institute Of Technology Synthesis of ruthenium or osmium metathesis catalysts
DE69818240T2 (de) * 1997-03-06 2004-07-01 Ciba Speciality Chemicals Holding Inc. Neue katalysatoren
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US5977393A (en) * 1997-11-21 1999-11-02 California Institute Of Technology Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts
DE69933904T2 (de) * 1998-05-08 2007-09-06 Takasago International Corp. Ruthenium-iodo optisch aktiver Phosphinkomplex

Also Published As

Publication number Publication date
DE69713472T2 (de) 2003-02-20
EP0841988A1 (de) 1998-05-20
MX9710359A (es) 1998-07-31
US6156692A (en) 2000-12-05
ES2179338T3 (es) 2003-01-16
EP0841988B1 (de) 2002-06-19
JP2000500700A (ja) 2000-01-25
WO1997040934A1 (en) 1997-11-06

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee