ES2179338T3 - Un sistema catalizador basado en rutenio para metatesis de olefina. - Google Patents

Un sistema catalizador basado en rutenio para metatesis de olefina.

Info

Publication number
ES2179338T3
ES2179338T3 ES97923458T ES97923458T ES2179338T3 ES 2179338 T3 ES2179338 T3 ES 2179338T3 ES 97923458 T ES97923458 T ES 97923458T ES 97923458 T ES97923458 T ES 97923458T ES 2179338 T3 ES2179338 T3 ES 2179338T3
Authority
ES
Spain
Prior art keywords
rutenium
compound
metatesis
olefine
system based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97923458T
Other languages
English (en)
Inventor
Philip O Nubel
Craig Lane Hunt
David S Choi
Tobin J Marks
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Corp North America Inc
Original Assignee
BP Corp North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Corp North America Inc filed Critical BP Corp North America Inc
Application granted granted Critical
Publication of ES2179338T3 publication Critical patent/ES2179338T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2286—Alkynes, e.g. acetylides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C07C6/06—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond at a cyclic carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

SE DESCRIBE UN SISTEMA CATALIZADOR DE METATESIS BASADO EN RUTENIO QUE CONTIENE UN COMPUESTO DE RUTENIO (A), UN COMPUESTO DE FOSFORO (B) Y UN COMPUESTO (C) QUE CONTIENE UN TRIPLE ENLACE CARBONO MENTE 1,0:0,01 NDO ANIONICO (X) Y OPCIONALMENTE UN LIGANDO DE ARENO Y OPCIONALMENTE UN LIGANDO DE COMPUESTO DE FOSFORO. EL COMPUESTO DE FOSFORO (B) ES OPCIONAL SI EL COMPUESTO DE RUTENIO (A) CONTIENE UN LIGANDO QUE CONTIENE FOSFORO.
ES97923458T 1996-04-30 1997-04-25 Un sistema catalizador basado en rutenio para metatesis de olefina. Expired - Lifetime ES2179338T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US1655496P 1996-04-30 1996-04-30
US3325796P 1996-12-06 1996-12-06
US08/842,251 US6156692A (en) 1996-04-30 1997-04-24 Ruthenium-containing catalyst composition for olefin metathesis

Publications (1)

Publication Number Publication Date
ES2179338T3 true ES2179338T3 (es) 2003-01-16

Family

ID=27360592

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97923458T Expired - Lifetime ES2179338T3 (es) 1996-04-30 1997-04-25 Un sistema catalizador basado en rutenio para metatesis de olefina.

Country Status (6)

Country Link
US (1) US6156692A (es)
EP (1) EP0841988B1 (es)
JP (1) JP2000500700A (es)
DE (1) DE69713472T2 (es)
ES (1) ES2179338T3 (es)
WO (1) WO1997040934A1 (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6156692A (en) * 1996-04-30 2000-12-05 Bp Amoco Corporation Ruthenium-containing catalyst composition for olefin metathesis
US6159890A (en) * 1996-04-30 2000-12-12 Bp Amoco Corporation Ruthenium-containing catalyst system for olefin metathesis
DE59709143D1 (de) * 1996-11-15 2003-02-20 Ciba Sc Holding Ag Katalysatorgemisch für die ringöffnende Metathesepolymerisation
US6175047B1 (en) * 1997-12-26 2001-01-16 Takasago International Corporation Ruthenium metathesis catalyst and method for producing olefin reaction product by metathesis reaction using the same
JP3650582B2 (ja) 1998-11-30 2005-05-18 ナノスフェアー インコーポレイテッド ポリマー−ナノ粒子ハイブリッド粒子
WO2001083097A2 (en) * 2000-05-04 2001-11-08 University Of Florida Metathesis of functionalized allylic olefins
RU2289568C2 (ru) * 2001-03-26 2006-12-20 Дау Глобал Текнолоджиз Инк. Способ метатезиса сложных эфиров ненасыщенных жирных кислот или ненасыщенных жирных кислот с низшими олефинами и композиция гетерогенного катализатора, предназначенная для способа метатезиса
US20050124839A1 (en) * 2001-06-13 2005-06-09 Gartside Robert J. Catalyst and process for the metathesis of ethylene and butene to produce propylene
US6683019B2 (en) 2001-06-13 2004-01-27 Abb Lummus Global Inc. Catalyst for the metathesis of olefin(s)
US6884859B2 (en) * 2001-08-29 2005-04-26 California Institute Of Technology Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms
WO2003026770A1 (en) * 2001-09-24 2003-04-03 Smithkline Beecham Corporation Method for removing metal from the products of olefin metathesis reactions
CN102936536B (zh) 2002-04-29 2014-01-29 陶氏环球技术有限责任公司 关于种子油工业应用的综合化学方法
DE10393514T5 (de) * 2002-10-24 2005-09-29 Dow Global Technologies, Inc., Midland Stabilisierung von Produktmischungen aus der Olefinmetathese
DE602004014958D1 (de) * 2003-10-09 2008-08-21 Dow Global Technologies Inc Verbessertes verfahren zur synthese ungesättigter alkohole
JP5191972B2 (ja) * 2008-10-30 2013-05-08 高砂香料工業株式会社 ルテニウム錯体の製造方法
EP2350159A1 (en) * 2008-10-31 2011-08-03 Dow Global Technologies LLC Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands
JP5536541B2 (ja) * 2009-07-13 2014-07-02 高砂香料工業株式会社 ルテニウム−ジアミン錯体および光学活性化合物の製造方法
FR2975310B1 (fr) 2011-05-19 2014-03-14 IFP Energies Nouvelles Composition catalytique a base de ruthenium comprenant un compose de type silane ou siloxane et procede de metathese des olefines utilisant ladite composition
EP3408273B1 (en) * 2016-01-27 2020-06-17 Basf Se Process for the generation of thin inorganic films
EP3546495A1 (de) * 2018-03-29 2019-10-02 Evonik Degussa GmbH Verfahren zur herstellung von temperaturstabilen polyalkenameren

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3117952A (en) * 1958-11-17 1964-01-14 American Cyanamid Co Method of improving certain catalysts
BE757752A (fr) * 1969-10-27 1971-04-01 Goodyear Tire & Rubber Nouveaux catalyseurs pour la polymerisation par ouverture du cycle de composes alicycliques insatures
DE2028935C3 (de) * 1970-06-12 1979-08-16 Chemische Werke Huels Ag, 4370 Marl Polyalkenamere und Verfahren zu deren Herstellung
US3855323A (en) * 1970-10-14 1974-12-17 Sun Ventures Inc Olefin isomerization catalysts and process
DE2157405C3 (de) * 1971-11-19 1975-10-16 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von polymeren Kohlenwasserstoffen mit reaktiven SiIyIe ndgruppen
US3962294A (en) * 1973-08-27 1976-06-08 Sun Ventures, Inc. Olefin isomerization catalysts and process
US3957827A (en) * 1974-10-17 1976-05-18 Sun Ventures, Inc. Hydrogenation of carboxylic acid anhydrides to lactones or esters by homogeneous catalysis
US4323508A (en) * 1978-01-03 1982-04-06 The Standard Oil Company Process for the manufacture of furan compounds
JPH0757758B2 (ja) * 1988-10-24 1995-06-21 高砂香料工業株式会社 ルテニウム―ホスフィン錯体
US5198561A (en) * 1989-06-22 1993-03-30 Monsanto Company Ruthenium-BINAP asymmetric hydrogenation catalyst
FR2651152B1 (fr) * 1989-08-23 1991-11-29 Elf Aquitaine Perfectionnement a la preparation de catalyseurs chiraux a base de complexes du ruthenium et du phosphore.
US5198511A (en) * 1991-12-20 1993-03-30 Minnesota Mining And Manufacturing Company Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor
US5324616A (en) * 1992-04-01 1994-06-28 Xerox Corporation Encapsulated toner compositions and processes thereof
US5710298A (en) * 1992-04-03 1998-01-20 California Institute Of Technology Method of preparing ruthenium and osmium carbene complexes
US5312940A (en) * 1992-04-03 1994-05-17 California Institute Of Technology Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
US5405924A (en) * 1993-07-22 1995-04-11 Shell Oil Company Imido transition metal complex metathesis catalysts
WO1996016100A1 (de) * 1994-11-17 1996-05-30 Ciba Specialty Chemicals Holding Inc. Thermisches metathesepolymerisationsverfahren und polymerisierbare zusammensetzung
JP3820471B2 (ja) * 1994-12-23 2006-09-13 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 重合可能な組成物および重合方法
US5559262A (en) * 1995-01-31 1996-09-24 E. I. Du Pont De Nemours And Company Process for the preparation of ruthenium complexes and their in situ use as hydrogenation catalysts
US5599962A (en) * 1995-01-31 1997-02-04 E. I. Du Pont De Nemours And Company Process for the preparation of ruthenium hydrogenation catalysts and products thereof
US5728785A (en) * 1995-07-07 1998-03-17 California Institute Of Technology Romp polymerization in the presence of peroxide crosslinking agents to form high-density crosslinked polymers
US5831108A (en) * 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
US5939504A (en) * 1995-12-07 1999-08-17 Advanced Polymer Technologies Method for extending the pot life of an olefin metathesis polymerization reaction
JP2000513393A (ja) * 1996-04-04 2000-10-10 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 触媒混合物及び重合性組成物
US6156692A (en) * 1996-04-30 2000-12-05 Bp Amoco Corporation Ruthenium-containing catalyst composition for olefin metathesis
US5753584A (en) * 1996-06-04 1998-05-19 Intevep, S.A. Catalyst system for selective hydrogenation of heteroaromatic sulfur-containing and nitrogen-containing compounds
ATE228140T1 (de) * 1996-11-01 2002-12-15 Ciba Sc Holding Ag Verfahren zur herstellung von katalysatoren
US5917071A (en) * 1996-11-15 1999-06-29 California Institute Of Technology Synthesis of ruthenium or osmium metathesis catalysts
WO1998039346A1 (en) * 1997-03-06 1998-09-11 Ciba Specialty Chemicals Holding Inc. New catalysts
US5998326A (en) * 1997-05-23 1999-12-07 Ciba Specialty Chemicals Corp. Two-component catalyst for ROMP
US5977393A (en) * 1997-11-21 1999-11-02 California Institute Of Technology Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts
EP0955303B1 (en) * 1998-05-08 2006-11-08 Takasago International Corporation Ruthenium-iodo-optically active phosphine complex

Also Published As

Publication number Publication date
EP0841988A1 (en) 1998-05-20
WO1997040934A1 (en) 1997-11-06
JP2000500700A (ja) 2000-01-25
EP0841988B1 (en) 2002-06-19
DE69713472D1 (de) 2002-07-25
US6156692A (en) 2000-12-05
MX9710359A (es) 1998-07-31
DE69713472T2 (de) 2003-02-20

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