DE69819578T2 - Verfahren zur Herstellung von Antimonat-Katalysatoren zur (Amm)oxidation von Alkanen und Alkenen - Google Patents
Verfahren zur Herstellung von Antimonat-Katalysatoren zur (Amm)oxidation von Alkanen und Alkenen Download PDFInfo
- Publication number
- DE69819578T2 DE69819578T2 DE69819578T DE69819578T DE69819578T2 DE 69819578 T2 DE69819578 T2 DE 69819578T2 DE 69819578 T DE69819578 T DE 69819578T DE 69819578 T DE69819578 T DE 69819578T DE 69819578 T2 DE69819578 T2 DE 69819578T2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- promoter
- catalyst precursor
- added
- aqueous mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims description 62
- 238000000034 method Methods 0.000 title claims description 52
- 230000008569 process Effects 0.000 title claims description 15
- 238000002360 preparation method Methods 0.000 title description 5
- 150000001336 alkenes Chemical class 0.000 title description 4
- 230000003647 oxidation Effects 0.000 title description 4
- 238000007254 oxidation reaction Methods 0.000 title description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 75
- 239000012018 catalyst precursor Substances 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 21
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical class O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 21
- 229910001887 tin oxide Inorganic materials 0.000 claims description 21
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- 238000001354 calcination Methods 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 11
- 229910052718 tin Inorganic materials 0.000 claims description 10
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 5
- 229910052785 arsenic Inorganic materials 0.000 claims description 5
- 229910052788 barium Inorganic materials 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 229910052733 gallium Inorganic materials 0.000 claims description 5
- 229910052738 indium Inorganic materials 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- 229910052712 strontium Inorganic materials 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 239000011135 tin Substances 0.000 description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 34
- 239000010936 titanium Substances 0.000 description 33
- 239000002002 slurry Substances 0.000 description 27
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 26
- 229910004298 SiO 2 Inorganic materials 0.000 description 26
- 239000007787 solid Substances 0.000 description 18
- 238000001027 hydrothermal synthesis Methods 0.000 description 16
- 229910010413 TiO 2 Inorganic materials 0.000 description 13
- 239000001294 propane Substances 0.000 description 13
- 229910044991 metal oxide Inorganic materials 0.000 description 12
- 150000004706 metal oxides Chemical class 0.000 description 12
- 229910006404 SnO 2 Inorganic materials 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000010949 copper Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 238000010992 reflux Methods 0.000 description 10
- 239000002585 base Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 6
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 6
- 238000001694 spray drying Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000011651 chromium Substances 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000003837 high-temperature calcination Methods 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000000908 ammonium hydroxide Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- RJAAXVMENUVEAN-UHFFFAOYSA-N antimony vanadium Chemical compound [V].[Sb] RJAAXVMENUVEAN-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- -1 diethoxyethylamine Chemical class 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- HJKLEAOXCZIMPI-UHFFFAOYSA-N 2,2-diethoxyethanamine Chemical compound CCOC(CN)OCC HJKLEAOXCZIMPI-UHFFFAOYSA-N 0.000 description 1
- JUWSCPBRVFRPFT-UHFFFAOYSA-N 2-methylpropan-2-amine;hydrate Chemical compound O.CC(C)(C)N JUWSCPBRVFRPFT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- DOSKSMLJRWKRKF-UHFFFAOYSA-N [V+5].[V+5].[V+5].[O-][Sb]([O-])([O-])=O.[O-][Sb]([O-])([O-])=O.[O-][Sb]([O-])([O-])=O.[O-][Sb]([O-])([O-])=O.[O-][Sb]([O-])([O-])=O Chemical compound [V+5].[V+5].[V+5].[O-][Sb]([O-])([O-])=O.[O-][Sb]([O-])([O-])=O.[O-][Sb]([O-])([O-])=O.[O-][Sb]([O-])([O-])=O.[O-][Sb]([O-])([O-])=O DOSKSMLJRWKRKF-UHFFFAOYSA-N 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- UMEAURNTRYCPNR-UHFFFAOYSA-N azane;iron(2+) Chemical class N.[Fe+2] UMEAURNTRYCPNR-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
- B01J23/8472—Vanadium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US835042 | 1997-03-27 | ||
| US08/835,042 US5866502A (en) | 1997-03-27 | 1997-03-27 | Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69819578D1 DE69819578D1 (de) | 2003-12-18 |
| DE69819578T2 true DE69819578T2 (de) | 2004-06-03 |
Family
ID=25268429
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69819578T Expired - Fee Related DE69819578T2 (de) | 1997-03-27 | 1998-03-05 | Verfahren zur Herstellung von Antimonat-Katalysatoren zur (Amm)oxidation von Alkanen und Alkenen |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5866502A (enExample) |
| EP (1) | EP0867221B1 (enExample) |
| JP (2) | JP4002660B2 (enExample) |
| KR (1) | KR100526283B1 (enExample) |
| CN (1) | CN1129473C (enExample) |
| BG (1) | BG64191B1 (enExample) |
| BR (1) | BR9800979A (enExample) |
| DE (1) | DE69819578T2 (enExample) |
| ES (1) | ES2212222T3 (enExample) |
| MY (1) | MY118711A (enExample) |
| RO (1) | RO120460B1 (enExample) |
| RU (1) | RU2200061C2 (enExample) |
| SG (1) | SG80585A1 (enExample) |
| TR (1) | TR199800494A1 (enExample) |
| TW (1) | TW442510B (enExample) |
| ZA (1) | ZA981676B (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5854172A (en) * | 1997-01-17 | 1998-12-29 | The Standard Oil Company | Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O |
| US6037304A (en) * | 1999-01-11 | 2000-03-14 | Saudi Basic Industries Corporation | Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same |
| US6017846A (en) * | 1999-01-11 | 2000-01-25 | Saudi Basic Industries Corporation | Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same |
| US6486091B1 (en) | 2000-03-14 | 2002-11-26 | Saudi Basic Industries Corporation | Process for making highly active and selective catalysts for the production of unsaturated nitriles |
| US6864384B2 (en) * | 2002-11-27 | 2005-03-08 | The Standard Oil Company | Preparation of vanadium antimony oxide based catalysts using nano-scale iron |
| US6916763B2 (en) * | 2002-11-27 | 2005-07-12 | Solutia Inc. | Process for preparing a catalyst for the oxidation and ammoxidation of olefins |
| US6887825B2 (en) * | 2002-11-27 | 2005-05-03 | The Standard Oil Company | Method for the preparation of vanadium-antimony-oxide based oxidation and ammoxidation catalysts using non-aqueous media |
| US20040102318A1 (en) * | 2002-11-27 | 2004-05-27 | Brazdil James F. | Method for enhancing the productivity of vanadium antimony oxide catalysts |
| US20050054869A1 (en) * | 2003-06-06 | 2005-03-10 | Lugmair Claus G. | Mixed metal oxide catalysts for propane and isobutane oxidation and ammoxidation, and methods of preparing same |
| CN101060925B (zh) * | 2004-11-22 | 2010-09-08 | 帝斯曼知识产权资产管理有限公司 | 制备反丁烯二腈和/或顺丁烯二腈的催化剂 |
| US20080103325A1 (en) * | 2006-10-31 | 2008-05-01 | Claus Lugmair | Mixed metal oxide catalysts for the ammoxidation of propane and isobutane |
| US20080103326A1 (en) * | 2006-10-31 | 2008-05-01 | Bruce Irwin Rosen | Lithium containing mixed metal oxide catalysts for ammoxidation of propane and isobutane |
| US20080248947A1 (en) * | 2007-04-03 | 2008-10-09 | Zajac Gerry W | Mixed metal oxide catalysts and catalytic processes for conversions of lower alkane hydrocarbons |
| US8697596B2 (en) * | 2007-04-03 | 2014-04-15 | Ineos Usa Llc | Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons |
| US20090005586A1 (en) * | 2007-06-29 | 2009-01-01 | Brazdil Jr James F | Mixed metal oxide catalysts for the ammoxidation of propane and isobutane |
| RU2558146C2 (ru) * | 2011-03-02 | 2015-07-27 | Асахи Касеи Кемикалз Корпорейшн | Способ производства ненасыщенного нитрила |
| US9409156B2 (en) * | 2012-10-19 | 2016-08-09 | Instituto Mexicano Del Petroleo | Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process |
| CN105618078B (zh) * | 2015-12-07 | 2018-05-22 | 沧州临港亚诺化工有限公司 | 一种用于氨氧化烷基吡啶的催化剂 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE741001A (enExample) * | 1968-11-02 | 1970-04-01 | ||
| US3860534A (en) * | 1971-03-24 | 1975-01-14 | Power Gas Ltd | Method of making an antimony-vanadium catalyst |
| US4746641A (en) * | 1984-08-22 | 1988-05-24 | Standard Oil Company | Ammoxidation of paraffins and catalysts therefor |
| US4788317A (en) * | 1984-08-22 | 1988-11-29 | Standard Oil Company | Ammoxidation of paraffins and catalysts therefor |
| US4879264A (en) * | 1988-11-14 | 1989-11-07 | The Standard Oil Company | Method of making catalyst and catalyst precursor containing vanadium and antimony |
| US5008427A (en) * | 1988-12-23 | 1991-04-16 | The Standard Oil Company | Ammoxidation of paraffins |
| US5214016A (en) * | 1992-04-02 | 1993-05-25 | The Standard Oil Company | Method of making catalysts containing vanadium, antimony and tin |
| US5258543A (en) * | 1992-06-26 | 1993-11-02 | The Standard Oil Company | Method for ammoxidation of olefins |
| RU2105757C1 (ru) * | 1993-09-02 | 1998-02-27 | Стандарт Ойл Компани | Способ парофазного аммоксидирования с3 - с5-моноолефинов |
| DE59505944D1 (de) * | 1994-02-22 | 1999-06-24 | Basf Ag | Multimetalloxidmassen. |
| FR2721598B1 (fr) * | 1994-06-23 | 1996-08-23 | Rhone Poulenc Chimie | Procédé de préparation de catalyseurs d'ammoxydation. |
| US5498588A (en) * | 1994-09-09 | 1996-03-12 | The Standard Oil Company | Surface modification and promotion of vanadium antimony oxide catalysts |
-
1997
- 1997-03-27 US US08/835,042 patent/US5866502A/en not_active Expired - Fee Related
-
1998
- 1998-02-17 SG SG9800344A patent/SG80585A1/en unknown
- 1998-02-26 BG BG102281A patent/BG64191B1/bg unknown
- 1998-02-27 KR KR1019980006460A patent/KR100526283B1/ko not_active Expired - Fee Related
- 1998-02-27 ZA ZA981676A patent/ZA981676B/xx unknown
- 1998-03-05 ES ES98301629T patent/ES2212222T3/es not_active Expired - Lifetime
- 1998-03-05 DE DE69819578T patent/DE69819578T2/de not_active Expired - Fee Related
- 1998-03-05 EP EP98301629A patent/EP0867221B1/en not_active Expired - Lifetime
- 1998-03-18 TR TR1998/00494A patent/TR199800494A1/xx unknown
- 1998-03-25 TW TW087104497A patent/TW442510B/zh not_active IP Right Cessation
- 1998-03-26 MY MYPI98001320A patent/MY118711A/en unknown
- 1998-03-26 BR BR9800979-6A patent/BR9800979A/pt active Search and Examination
- 1998-03-26 RU RU98105630/04A patent/RU2200061C2/ru not_active IP Right Cessation
- 1998-03-26 RO RO98-00789A patent/RO120460B1/ro unknown
- 1998-03-27 CN CN98107866A patent/CN1129473C/zh not_active Expired - Fee Related
- 1998-03-27 JP JP08179798A patent/JP4002660B2/ja not_active Expired - Fee Related
-
2006
- 2006-10-26 JP JP2006291651A patent/JP2007038224A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| KR19980079784A (ko) | 1998-11-25 |
| ES2212222T3 (es) | 2004-07-16 |
| BG102281A (en) | 1998-12-30 |
| TR199800494A1 (xx) | 2000-05-22 |
| US5866502A (en) | 1999-02-02 |
| JPH10272362A (ja) | 1998-10-13 |
| RU2200061C2 (ru) | 2003-03-10 |
| RO120460B1 (ro) | 2006-02-28 |
| TW442510B (en) | 2001-06-23 |
| SG80585A1 (en) | 2001-05-22 |
| EP0867221B1 (en) | 2003-11-12 |
| EP0867221A3 (en) | 1999-06-23 |
| JP2007038224A (ja) | 2007-02-15 |
| BR9800979A (pt) | 1999-10-05 |
| EP0867221A2 (en) | 1998-09-30 |
| KR100526283B1 (ko) | 2006-01-27 |
| CN1129473C (zh) | 2003-12-03 |
| JP4002660B2 (ja) | 2007-11-07 |
| CN1196973A (zh) | 1998-10-28 |
| DE69819578D1 (de) | 2003-12-18 |
| BG64191B1 (bg) | 2004-04-30 |
| MY118711A (en) | 2005-01-31 |
| ZA981676B (en) | 1999-02-19 |
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