CN1196973A - 烷烃和烯烃的(氨)氧化锑酸盐催化剂的制备方法 - Google Patents
烷烃和烯烃的(氨)氧化锑酸盐催化剂的制备方法 Download PDFInfo
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- CN1196973A CN1196973A CN98107866A CN98107866A CN1196973A CN 1196973 A CN1196973 A CN 1196973A CN 98107866 A CN98107866 A CN 98107866A CN 98107866 A CN98107866 A CN 98107866A CN 1196973 A CN1196973 A CN 1196973A
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- catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
- B01J23/8472—Vanadium
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
温度 | CT | %C3 = | %AN | 丙烯转化的选择性% | |||||||
实例 | ℃ | Sec | 转化塞 | 产率 | AN | HCN | Aceto | Acrol | AcryAc | CO | CO2 |
1 | 465 | 0.91 | 97.91 | 78.88 | 80.56 | 3.92 | 1.80 | 0.81 | 0.41 | 5.25 | 7.25 |
2 | 462 | 1.09 | 97.43 | 75.67 | 77.66 | 4.07 | 2.10 | 3.00 | 0.32 | 6.15 | 8.74 |
3 | 458 | 0.55 | 97.76 | 75.54 | 77.28 | 5.03 | 1.88 | 0.32 | 0.57 | 7.22 | 7.70 |
4 | 460 | 0.57 | 97.27 | 78.02 | 80.21 | 4.28 | 1.95 | 0.75 | 0.98 | 4.92 | 6.92 |
5 | 460 | 0.68 | 97.98 | 77.29 | 78.88 | 4.42 | 1.98 | 0.68 | 0.87 | 5.45 | 7.71 |
6 | 460 | 0.78 | 98.13 | 77.85 | 79.34 | 4.20 | 2.06 | 0.82 | 0.62 | 5.10 | 7.86 |
7 | 458 | 0.61 | 97.67 | 77.73 | 79.59 | 4.39 | 1.97 | 0.59 | 0.72 | 5.46 | 7.28 |
8 | 458 | 0.61 | 98.47 | 78.59 | 79.82 | 4.27 | 1.97 | 0.71 | 0.71 | 5.22 | 7.31 |
9 | 458 | 0.61 | 98.42 | 77.86 | 79.11 | 4.57 | 1.81 | 0.54 | 0.62 | 5.81 | 7.54 |
10 | 458 | 0.60 | 97.88 | 77.71 | 79.40 | 4.34 | 1.70 | 0.58 | 0.79 | 5.75 | 7.45 |
11 | 460 | 1.02 | 98.82 | 75.46 | 76.36 | 4.62 | 1.96 | 0.46 | 0.28 | 7.05 | 9.28 |
12 | 463 | 1.19 | 97.60 | 77.14 | 79.03 | 4.19 | 2.06 | 0.52 | 0.23 | 5.26 | 8.70 |
13 | 460 | 0.79 | 98.44 | 78.68 | 79.93 | 4.43 | 1.93 | 0.48 | 0.45 | 5.61 | 7.18 |
14 | 460 | 0.60 | 97.88 | 79.03 | 80.74 | 4.49 | 1.25 | 0.56 | 0.60 | 5.37 | 6.99 |
15 | 460 | 0.61 | 98.76 | 79.25 | 80.25 | 4.48 | 1.31 | 0.20 | 0.40 | 5.66 | 7.71 |
温度 | CT | %C3 = | %AN | 丙烯转化的选择性% | ||||||||
实例 | ℃ | Sec | wwh | 转化率 | 产率 | AN | HCN | Aceto | Acrol | AcryAc | CO | CO2 |
1 | 450 | 1.01 | 0.23 | 98.47 | 80.94 | 82.20 | 5.07 | 1.13 | 0.20 | 0.24 | 4.01 | 6.88 |
2 | 450 | 0.83 | 0.26 | 98.51 | 80.90 | 82.12 | 5.05 | 1.06 | 0.18 | 0.15 | 4.05 | 7.13 |
温度 | CT | %C3 = | %AN | 丙烯转化的选择性% | 进料比 | ||||||||
实例 | ℃ | Sec | wwh | 转化率 | 产率 | AN | HCN | Ace-to | AcryAc | CO | CO2 | C3 = | C3 =/NH3/O2/N2/H2O |
1 | 470 | 1.89 | 0.03 | 20.56 | 12.15 | 59.05 | 13.52 | 1.74 | 1.30 | 13.76 | 10.04 | 0.54 | 1/1.34/3.51/11.7/3.7 |
2 | 470 | 1.89 | 0.04 | 22.83 | 11.78 | 51.58 | 11.17 | 1.11 | 0.44 | 19.11 | 16.26 | 0.33 | 1/1.24/3.33/11.0/3.5 |
3 | 470 | 2.27 | 0.04 | 19.50 | 10.99 | 56.38 | 11.47 | 1.19 | 0.00 | 17.04 | 13.61 | 0.31 | 1/1.24/3.33/11.0/3.5 |
4 | 470 | 2.27 | 0.04 | 20.61 | 12.37 | 60.04 | 7.48 | 0.93 | 0.00 | 17.79 | 13.35 | 0.41 | 1/1.24/3.33/11.0/3.5 |
5 | 480 | 2.08 | 0.11 | 20.17 | 12.86 | 63.75 | 8.86 | 1.56 | 0.04 | 13.15 | 11.85 | 0.48 | 1/1.20/.98/3.27/2 |
6 | 480 | 1.66 | 0.13 | 21.89 | 13.70 | 62.59 | 9.22 | 1.62 | 0.04 | 13.81 | 11.74 | 0.56 | 1/1.2/.99/3.3/2 |
7 | 480 | 1.88 | 0.15 | 21.61 | 13.35 | 61.80 | 9.38 | 1.55 | 0.03 | 14.16 | 12.19 | 0.47 | 1/1.2/.99/3.29/2 |
8 | 470 | 2.42 | 0.04 | 20.61 | 11.29 | 54.58 | 9.27 | 1.16 | 0.52 | 18.70 | 15.31 | 0.46 | 1/1.52/3.0/10.6/3.5 |
Claims (19)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US835,042 | 1997-03-27 | ||
US08/835,042 US5866502A (en) | 1997-03-27 | 1997-03-27 | Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes |
US835042 | 1997-03-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1196973A true CN1196973A (zh) | 1998-10-28 |
CN1129473C CN1129473C (zh) | 2003-12-03 |
Family
ID=25268429
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN98107866A Expired - Fee Related CN1129473C (zh) | 1997-03-27 | 1998-03-27 | 烷烃和烯烃的(氨)氧化锑酸盐催化剂的制备方法 |
Country Status (16)
Country | Link |
---|---|
US (1) | US5866502A (zh) |
EP (1) | EP0867221B1 (zh) |
JP (2) | JP4002660B2 (zh) |
KR (1) | KR100526283B1 (zh) |
CN (1) | CN1129473C (zh) |
BG (1) | BG64191B1 (zh) |
BR (1) | BR9800979A (zh) |
DE (1) | DE69819578T2 (zh) |
ES (1) | ES2212222T3 (zh) |
MY (1) | MY118711A (zh) |
RO (1) | RO120460B1 (zh) |
RU (1) | RU2200061C2 (zh) |
SG (1) | SG80585A1 (zh) |
TR (1) | TR199800494A1 (zh) |
TW (1) | TW442510B (zh) |
ZA (1) | ZA981676B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105618078A (zh) * | 2015-12-07 | 2016-06-01 | 沧州临港亚诺化工有限公司 | 一种用于氨氧化烷基吡啶的催化剂 |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5854172A (en) * | 1997-01-17 | 1998-12-29 | The Standard Oil Company | Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O |
US6037304A (en) * | 1999-01-11 | 2000-03-14 | Saudi Basic Industries Corporation | Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same |
US6017846A (en) * | 1999-01-11 | 2000-01-25 | Saudi Basic Industries Corporation | Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same |
US6486091B1 (en) | 2000-03-14 | 2002-11-26 | Saudi Basic Industries Corporation | Process for making highly active and selective catalysts for the production of unsaturated nitriles |
US6864384B2 (en) * | 2002-11-27 | 2005-03-08 | The Standard Oil Company | Preparation of vanadium antimony oxide based catalysts using nano-scale iron |
US6887825B2 (en) * | 2002-11-27 | 2005-05-03 | The Standard Oil Company | Method for the preparation of vanadium-antimony-oxide based oxidation and ammoxidation catalysts using non-aqueous media |
US20040102318A1 (en) * | 2002-11-27 | 2004-05-27 | Brazdil James F. | Method for enhancing the productivity of vanadium antimony oxide catalysts |
US6916763B2 (en) * | 2002-11-27 | 2005-07-12 | Solutia Inc. | Process for preparing a catalyst for the oxidation and ammoxidation of olefins |
US20080004462A1 (en) * | 2004-11-22 | 2008-01-03 | Peters Alexander V | Catalyst for the Preparation of Fumaronitrile and/or Maleonitrile |
US20080103325A1 (en) * | 2006-10-31 | 2008-05-01 | Claus Lugmair | Mixed metal oxide catalysts for the ammoxidation of propane and isobutane |
US20080103326A1 (en) * | 2006-10-31 | 2008-05-01 | Bruce Irwin Rosen | Lithium containing mixed metal oxide catalysts for ammoxidation of propane and isobutane |
US20080248947A1 (en) * | 2007-04-03 | 2008-10-09 | Zajac Gerry W | Mixed metal oxide catalysts and catalytic processes for conversions of lower alkane hydrocarbons |
US8697596B2 (en) * | 2007-04-03 | 2014-04-15 | Ineos Usa Llc | Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons |
US20090005586A1 (en) * | 2007-06-29 | 2009-01-01 | Brazdil Jr James F | Mixed metal oxide catalysts for the ammoxidation of propane and isobutane |
KR101524392B1 (ko) * | 2011-03-02 | 2015-05-29 | 아사히 가세이 케미칼즈 가부시키가이샤 | 불포화 니트릴의 제조 방법 |
US9409156B2 (en) * | 2012-10-19 | 2016-08-09 | Instituto Mexicano Del Petroleo | Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE741001A (zh) * | 1968-11-02 | 1970-04-01 | ||
US3860534A (en) * | 1971-03-24 | 1975-01-14 | Power Gas Ltd | Method of making an antimony-vanadium catalyst |
US4788317A (en) * | 1984-08-22 | 1988-11-29 | Standard Oil Company | Ammoxidation of paraffins and catalysts therefor |
US4746641A (en) * | 1984-08-22 | 1988-05-24 | Standard Oil Company | Ammoxidation of paraffins and catalysts therefor |
US4879264A (en) * | 1988-11-14 | 1989-11-07 | The Standard Oil Company | Method of making catalyst and catalyst precursor containing vanadium and antimony |
US5008427A (en) * | 1988-12-23 | 1991-04-16 | The Standard Oil Company | Ammoxidation of paraffins |
US5214016A (en) * | 1992-04-02 | 1993-05-25 | The Standard Oil Company | Method of making catalysts containing vanadium, antimony and tin |
US5258543A (en) * | 1992-06-26 | 1993-11-02 | The Standard Oil Company | Method for ammoxidation of olefins |
ES2133599T3 (es) * | 1994-02-22 | 1999-09-16 | Basf Ag | Masas de oxidos multimetalicos. |
FR2721598B1 (fr) * | 1994-06-23 | 1996-08-23 | Rhone Poulenc Chimie | Procédé de préparation de catalyseurs d'ammoxydation. |
US5498588A (en) * | 1994-09-09 | 1996-03-12 | The Standard Oil Company | Surface modification and promotion of vanadium antimony oxide catalysts |
-
1997
- 1997-03-27 US US08/835,042 patent/US5866502A/en not_active Expired - Fee Related
-
1998
- 1998-02-17 SG SG9800344A patent/SG80585A1/en unknown
- 1998-02-26 BG BG102281A patent/BG64191B1/bg unknown
- 1998-02-27 ZA ZA981676A patent/ZA981676B/xx unknown
- 1998-02-27 KR KR1019980006460A patent/KR100526283B1/ko not_active IP Right Cessation
- 1998-03-05 DE DE69819578T patent/DE69819578T2/de not_active Expired - Fee Related
- 1998-03-05 EP EP98301629A patent/EP0867221B1/en not_active Expired - Lifetime
- 1998-03-05 ES ES98301629T patent/ES2212222T3/es not_active Expired - Lifetime
- 1998-03-18 TR TR1998/00494A patent/TR199800494A1/xx unknown
- 1998-03-25 TW TW087104497A patent/TW442510B/zh not_active IP Right Cessation
- 1998-03-26 BR BR9800979-6A patent/BR9800979A/pt active Search and Examination
- 1998-03-26 RO RO98-00789A patent/RO120460B1/ro unknown
- 1998-03-26 RU RU98105630/04A patent/RU2200061C2/ru not_active IP Right Cessation
- 1998-03-26 MY MYPI98001320A patent/MY118711A/en unknown
- 1998-03-27 CN CN98107866A patent/CN1129473C/zh not_active Expired - Fee Related
- 1998-03-27 JP JP08179798A patent/JP4002660B2/ja not_active Expired - Fee Related
-
2006
- 2006-10-26 JP JP2006291651A patent/JP2007038224A/ja not_active Withdrawn
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105618078A (zh) * | 2015-12-07 | 2016-06-01 | 沧州临港亚诺化工有限公司 | 一种用于氨氧化烷基吡啶的催化剂 |
CN105618078B (zh) * | 2015-12-07 | 2018-05-22 | 沧州临港亚诺化工有限公司 | 一种用于氨氧化烷基吡啶的催化剂 |
Also Published As
Publication number | Publication date |
---|---|
ZA981676B (en) | 1999-02-19 |
BR9800979A (pt) | 1999-10-05 |
DE69819578T2 (de) | 2004-06-03 |
JPH10272362A (ja) | 1998-10-13 |
DE69819578D1 (de) | 2003-12-18 |
KR100526283B1 (ko) | 2006-01-27 |
EP0867221A3 (en) | 1999-06-23 |
RU2200061C2 (ru) | 2003-03-10 |
JP2007038224A (ja) | 2007-02-15 |
JP4002660B2 (ja) | 2007-11-07 |
BG64191B1 (bg) | 2004-04-30 |
MY118711A (en) | 2005-01-31 |
EP0867221A2 (en) | 1998-09-30 |
BG102281A (en) | 1998-12-30 |
TR199800494A1 (xx) | 2000-05-22 |
US5866502A (en) | 1999-02-02 |
SG80585A1 (en) | 2001-05-22 |
EP0867221B1 (en) | 2003-11-12 |
KR19980079784A (ko) | 1998-11-25 |
TW442510B (en) | 2001-06-23 |
CN1129473C (zh) | 2003-12-03 |
RO120460B1 (ro) | 2006-02-28 |
ES2212222T3 (es) | 2004-07-16 |
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