CN1129473C - 烷烃和烯烃的(氨)氧化锑酸盐催化剂的制备方法 - Google Patents
烷烃和烯烃的(氨)氧化锑酸盐催化剂的制备方法 Download PDFInfo
- Publication number
- CN1129473C CN1129473C CN98107866A CN98107866A CN1129473C CN 1129473 C CN1129473 C CN 1129473C CN 98107866 A CN98107866 A CN 98107866A CN 98107866 A CN98107866 A CN 98107866A CN 1129473 C CN1129473 C CN 1129473C
- Authority
- CN
- China
- Prior art keywords
- catalyst precursor
- aqueous mixture
- promotor
- mixture
- catalyzer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 72
- 239000003054 catalyst Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 40
- 230000008569 process Effects 0.000 title description 10
- 150000001335 aliphatic alkanes Chemical class 0.000 title description 5
- 150000001336 alkenes Chemical class 0.000 title description 5
- 230000003647 oxidation Effects 0.000 title description 5
- 238000007254 oxidation reaction Methods 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims abstract description 42
- 239000012018 catalyst precursor Substances 0.000 claims abstract description 20
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 23
- 229910001887 tin oxide Inorganic materials 0.000 claims description 19
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 17
- 239000003513 alkali Substances 0.000 claims description 15
- 229910052718 tin Inorganic materials 0.000 claims description 13
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 229910052733 gallium Inorganic materials 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- 229910052712 strontium Inorganic materials 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 230000002269 spontaneous effect Effects 0.000 claims description 3
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims 3
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- 229910052738 indium Inorganic materials 0.000 claims 2
- 238000001354 calcination Methods 0.000 abstract description 23
- 238000001035 drying Methods 0.000 abstract description 9
- 150000002825 nitriles Chemical class 0.000 abstract description 4
- 238000013019 agitation Methods 0.000 abstract description 3
- 229930195733 hydrocarbon Natural products 0.000 abstract description 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 1
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 abstract 1
- 239000011135 tin Substances 0.000 description 35
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 34
- 239000010936 titanium Substances 0.000 description 33
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 28
- 229910004298 SiO 2 Inorganic materials 0.000 description 27
- 239000002002 slurry Substances 0.000 description 26
- 239000007787 solid Substances 0.000 description 16
- 238000001027 hydrothermal synthesis Methods 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 239000001294 propane Substances 0.000 description 14
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 229910044991 metal oxide Inorganic materials 0.000 description 12
- 150000004706 metal oxides Chemical class 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 238000001704 evaporation Methods 0.000 description 8
- 230000008020 evaporation Effects 0.000 description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- 238000005507 spraying Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229910006404 SnO 2 Inorganic materials 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- RJAAXVMENUVEAN-UHFFFAOYSA-N antimony vanadium Chemical compound [V].[Sb] RJAAXVMENUVEAN-UHFFFAOYSA-N 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000003837 high-temperature calcination Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000000908 ammonium hydroxide Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- -1 metal oxide compound Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- KQEIJFWAXDQUPR-UHFFFAOYSA-N 2,4-diaminophenol;hydron;dichloride Chemical compound Cl.Cl.NC1=CC=C(O)C(N)=C1 KQEIJFWAXDQUPR-UHFFFAOYSA-N 0.000 description 1
- JUWSCPBRVFRPFT-UHFFFAOYSA-N 2-methylpropan-2-amine;hydrate Chemical compound O.CC(C)(C)N JUWSCPBRVFRPFT-UHFFFAOYSA-N 0.000 description 1
- CYJRNFFLTBEQSQ-UHFFFAOYSA-N 8-(3-methyl-1-benzothiophen-5-yl)-N-(4-methylsulfonylpyridin-3-yl)quinoxalin-6-amine Chemical compound CS(=O)(=O)C1=C(C=NC=C1)NC=1C=C2N=CC=NC2=C(C=1)C=1C=CC2=C(C(=CS2)C)C=1 CYJRNFFLTBEQSQ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 238000005915 ammonolysis reaction Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
- B01J23/8472—Vanadium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US835042 | 1997-03-27 | ||
| US08/835,042 US5866502A (en) | 1997-03-27 | 1997-03-27 | Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes |
| US835,042 | 1997-03-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1196973A CN1196973A (zh) | 1998-10-28 |
| CN1129473C true CN1129473C (zh) | 2003-12-03 |
Family
ID=25268429
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98107866A Expired - Fee Related CN1129473C (zh) | 1997-03-27 | 1998-03-27 | 烷烃和烯烃的(氨)氧化锑酸盐催化剂的制备方法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5866502A (enExample) |
| EP (1) | EP0867221B1 (enExample) |
| JP (2) | JP4002660B2 (enExample) |
| KR (1) | KR100526283B1 (enExample) |
| CN (1) | CN1129473C (enExample) |
| BG (1) | BG64191B1 (enExample) |
| BR (1) | BR9800979A (enExample) |
| DE (1) | DE69819578T2 (enExample) |
| ES (1) | ES2212222T3 (enExample) |
| MY (1) | MY118711A (enExample) |
| RO (1) | RO120460B1 (enExample) |
| RU (1) | RU2200061C2 (enExample) |
| SG (1) | SG80585A1 (enExample) |
| TR (1) | TR199800494A1 (enExample) |
| TW (1) | TW442510B (enExample) |
| ZA (1) | ZA981676B (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5854172A (en) * | 1997-01-17 | 1998-12-29 | The Standard Oil Company | Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O |
| US6037304A (en) * | 1999-01-11 | 2000-03-14 | Saudi Basic Industries Corporation | Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same |
| US6017846A (en) * | 1999-01-11 | 2000-01-25 | Saudi Basic Industries Corporation | Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same |
| US6486091B1 (en) | 2000-03-14 | 2002-11-26 | Saudi Basic Industries Corporation | Process for making highly active and selective catalysts for the production of unsaturated nitriles |
| US6864384B2 (en) * | 2002-11-27 | 2005-03-08 | The Standard Oil Company | Preparation of vanadium antimony oxide based catalysts using nano-scale iron |
| US6916763B2 (en) * | 2002-11-27 | 2005-07-12 | Solutia Inc. | Process for preparing a catalyst for the oxidation and ammoxidation of olefins |
| US6887825B2 (en) * | 2002-11-27 | 2005-05-03 | The Standard Oil Company | Method for the preparation of vanadium-antimony-oxide based oxidation and ammoxidation catalysts using non-aqueous media |
| US20040102318A1 (en) * | 2002-11-27 | 2004-05-27 | Brazdil James F. | Method for enhancing the productivity of vanadium antimony oxide catalysts |
| US20050054869A1 (en) * | 2003-06-06 | 2005-03-10 | Lugmair Claus G. | Mixed metal oxide catalysts for propane and isobutane oxidation and ammoxidation, and methods of preparing same |
| CN101060925B (zh) * | 2004-11-22 | 2010-09-08 | 帝斯曼知识产权资产管理有限公司 | 制备反丁烯二腈和/或顺丁烯二腈的催化剂 |
| US20080103325A1 (en) * | 2006-10-31 | 2008-05-01 | Claus Lugmair | Mixed metal oxide catalysts for the ammoxidation of propane and isobutane |
| US20080103326A1 (en) * | 2006-10-31 | 2008-05-01 | Bruce Irwin Rosen | Lithium containing mixed metal oxide catalysts for ammoxidation of propane and isobutane |
| US20080248947A1 (en) * | 2007-04-03 | 2008-10-09 | Zajac Gerry W | Mixed metal oxide catalysts and catalytic processes for conversions of lower alkane hydrocarbons |
| US8697596B2 (en) * | 2007-04-03 | 2014-04-15 | Ineos Usa Llc | Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons |
| US20090005586A1 (en) * | 2007-06-29 | 2009-01-01 | Brazdil Jr James F | Mixed metal oxide catalysts for the ammoxidation of propane and isobutane |
| RU2558146C2 (ru) * | 2011-03-02 | 2015-07-27 | Асахи Касеи Кемикалз Корпорейшн | Способ производства ненасыщенного нитрила |
| US9409156B2 (en) * | 2012-10-19 | 2016-08-09 | Instituto Mexicano Del Petroleo | Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process |
| CN105618078B (zh) * | 2015-12-07 | 2018-05-22 | 沧州临港亚诺化工有限公司 | 一种用于氨氧化烷基吡啶的催化剂 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042669A (zh) * | 1988-11-14 | 1990-06-06 | 标准石油公司 | 含钒和锑的催化剂和催化剂前体 |
| US5008427A (en) * | 1988-12-23 | 1991-04-16 | The Standard Oil Company | Ammoxidation of paraffins |
| US5214016A (en) * | 1992-04-02 | 1993-05-25 | The Standard Oil Company | Method of making catalysts containing vanadium, antimony and tin |
| US5258543A (en) * | 1992-06-26 | 1993-11-02 | The Standard Oil Company | Method for ammoxidation of olefins |
| CN1120973A (zh) * | 1994-06-23 | 1996-04-24 | 罗纳·布朗克化学公司 | 制备氨氧化反应催化剂的方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE741001A (enExample) * | 1968-11-02 | 1970-04-01 | ||
| US3860534A (en) * | 1971-03-24 | 1975-01-14 | Power Gas Ltd | Method of making an antimony-vanadium catalyst |
| US4746641A (en) * | 1984-08-22 | 1988-05-24 | Standard Oil Company | Ammoxidation of paraffins and catalysts therefor |
| US4788317A (en) * | 1984-08-22 | 1988-11-29 | Standard Oil Company | Ammoxidation of paraffins and catalysts therefor |
| RU2105757C1 (ru) * | 1993-09-02 | 1998-02-27 | Стандарт Ойл Компани | Способ парофазного аммоксидирования с3 - с5-моноолефинов |
| DE59505944D1 (de) * | 1994-02-22 | 1999-06-24 | Basf Ag | Multimetalloxidmassen. |
| US5498588A (en) * | 1994-09-09 | 1996-03-12 | The Standard Oil Company | Surface modification and promotion of vanadium antimony oxide catalysts |
-
1997
- 1997-03-27 US US08/835,042 patent/US5866502A/en not_active Expired - Fee Related
-
1998
- 1998-02-17 SG SG9800344A patent/SG80585A1/en unknown
- 1998-02-26 BG BG102281A patent/BG64191B1/bg unknown
- 1998-02-27 KR KR1019980006460A patent/KR100526283B1/ko not_active Expired - Fee Related
- 1998-02-27 ZA ZA981676A patent/ZA981676B/xx unknown
- 1998-03-05 ES ES98301629T patent/ES2212222T3/es not_active Expired - Lifetime
- 1998-03-05 DE DE69819578T patent/DE69819578T2/de not_active Expired - Fee Related
- 1998-03-05 EP EP98301629A patent/EP0867221B1/en not_active Expired - Lifetime
- 1998-03-18 TR TR1998/00494A patent/TR199800494A1/xx unknown
- 1998-03-25 TW TW087104497A patent/TW442510B/zh not_active IP Right Cessation
- 1998-03-26 MY MYPI98001320A patent/MY118711A/en unknown
- 1998-03-26 BR BR9800979-6A patent/BR9800979A/pt active Search and Examination
- 1998-03-26 RU RU98105630/04A patent/RU2200061C2/ru not_active IP Right Cessation
- 1998-03-26 RO RO98-00789A patent/RO120460B1/ro unknown
- 1998-03-27 CN CN98107866A patent/CN1129473C/zh not_active Expired - Fee Related
- 1998-03-27 JP JP08179798A patent/JP4002660B2/ja not_active Expired - Fee Related
-
2006
- 2006-10-26 JP JP2006291651A patent/JP2007038224A/ja not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042669A (zh) * | 1988-11-14 | 1990-06-06 | 标准石油公司 | 含钒和锑的催化剂和催化剂前体 |
| US5008427A (en) * | 1988-12-23 | 1991-04-16 | The Standard Oil Company | Ammoxidation of paraffins |
| US5214016A (en) * | 1992-04-02 | 1993-05-25 | The Standard Oil Company | Method of making catalysts containing vanadium, antimony and tin |
| US5258543A (en) * | 1992-06-26 | 1993-11-02 | The Standard Oil Company | Method for ammoxidation of olefins |
| CN1120973A (zh) * | 1994-06-23 | 1996-04-24 | 罗纳·布朗克化学公司 | 制备氨氧化反应催化剂的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR19980079784A (ko) | 1998-11-25 |
| ES2212222T3 (es) | 2004-07-16 |
| BG102281A (en) | 1998-12-30 |
| TR199800494A1 (xx) | 2000-05-22 |
| US5866502A (en) | 1999-02-02 |
| JPH10272362A (ja) | 1998-10-13 |
| RU2200061C2 (ru) | 2003-03-10 |
| RO120460B1 (ro) | 2006-02-28 |
| TW442510B (en) | 2001-06-23 |
| SG80585A1 (en) | 2001-05-22 |
| EP0867221B1 (en) | 2003-11-12 |
| EP0867221A3 (en) | 1999-06-23 |
| JP2007038224A (ja) | 2007-02-15 |
| BR9800979A (pt) | 1999-10-05 |
| EP0867221A2 (en) | 1998-09-30 |
| KR100526283B1 (ko) | 2006-01-27 |
| JP4002660B2 (ja) | 2007-11-07 |
| CN1196973A (zh) | 1998-10-28 |
| DE69819578D1 (de) | 2003-12-18 |
| BG64191B1 (bg) | 2004-04-30 |
| MY118711A (en) | 2005-01-31 |
| ZA981676B (en) | 1999-02-19 |
| DE69819578T2 (de) | 2004-06-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1129473C (zh) | 烷烃和烯烃的(氨)氧化锑酸盐催化剂的制备方法 | |
| CN1178903C (zh) | 用于选择性链烷烃氨氧化反应的钼助催化的钒-锑氧化物基底催化剂 | |
| EP2922633B1 (en) | Process for the preparation of mixed metal oxide ammoxidation catalysts | |
| CN103816908A (zh) | 一种用于醋酸酯加氢制乙醇的催化剂及其制备方法 | |
| US20110237820A1 (en) | Process for preparing improved mixed metal oxide ammoxidation catalysts | |
| US8420566B2 (en) | High efficiency ammoxidation process and mixed metal oxide catalysts | |
| CN1241164A (zh) | 烃转化方法和催化剂及其催化剂前体 | |
| CN1073051C (zh) | 制造马来酐的方法 | |
| CN1009339B (zh) | 含钼-铋的复合氧化物催化剂的制备方法 | |
| CN110022979A (zh) | 具有选择性共产物hcn生产的氨氧化催化剂 | |
| CN1205245A (zh) | 生产丙烯醛的方法和一种用于反应中的氧化还原系统的固体混合氧化物组合物 | |
| CN88102108A (zh) | 烷烃的氨氧化方法及其催化剂体系 | |
| CN117884194B (zh) | 一种丙烯氨氧化反应催化剂的制备方法、催化剂及其应用 | |
| CN1929918A (zh) | 用于从烯烃制备不饱和炔的混合金属氧化物催化剂的制法 | |
| CN1092540C (zh) | 丙烯氨氧化流化床催化剂 | |
| CN1086154C (zh) | 丙烯氨氧化催化剂 | |
| JP4889149B2 (ja) | アクリロニトリル生産用触媒 | |
| CN1060410C (zh) | 丙烯腈流化床含锂催化剂 | |
| CN1169619C (zh) | 一种复合多金属氧化物催化剂及制备方法 | |
| CN1798607A (zh) | 新型杂化多元酸催化剂及其制备方法 | |
| CN1063101C (zh) | 生产丙烯腈的流化床催化剂 | |
| CN1102434C (zh) | 制备氧化锑钒基氧化反应和氨氧化反应改进催化剂的方法 | |
| CN86101301A (zh) | 催化组合物 | |
| CN1173396A (zh) | 新型经过金属离子交换的磷钒化合物和采用这种化合物的固体酸性催化剂 | |
| CN1081488C (zh) | 氨氧化丙烯制丙烯腈催化剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: O AND D AMERICA CO., LTD. Free format text: FORMER OWNER: THE STANDARD OIL CO. Effective date: 20070309 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C56 | Change in the name or address of the patentee |
Owner name: BRITISH NIOS AMERICA LLC CO., LTD. Free format text: FORMER NAME OR ADDRESS: INNOVENE AMERICA CO., LTD. Owner name: INNOVENE AMERICA CO., LTD. Free format text: FORMER NAME OR ADDRESS: O AND D AMERICA CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder |
Address after: Delaware, USA Patentee after: INEOS USA LLC Address before: Illinois, USA Patentee before: Innovene USA LLC Address after: Illinois, USA Patentee after: Innovene USA LLC Address before: Illinois, USA Patentee before: O and D USA LLC |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20070309 Address after: Illinois, USA Patentee after: O and D USA LLC Address before: Ohio, USA Patentee before: The Standard Oil Co. |
|
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |