DE69701447T3 - Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung - Google Patents

Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung Download PDF

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Publication number
DE69701447T3
DE69701447T3 DE69701447T DE69701447T DE69701447T3 DE 69701447 T3 DE69701447 T3 DE 69701447T3 DE 69701447 T DE69701447 T DE 69701447T DE 69701447 T DE69701447 T DE 69701447T DE 69701447 T3 DE69701447 T3 DE 69701447T3
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DE
Germany
Prior art keywords
transition metal
group
reaction product
organic solvent
compound
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Expired - Lifetime
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DE69701447T
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German (de)
English (en)
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DE69701447T2 (de
DE69701447D1 (de
Inventor
S. Ove ANDELL
Harri Hokkanen
Marja Mustonen
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Borealis AS
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Borealis AS
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Publication of DE69701447T2 publication Critical patent/DE69701447T2/de
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Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69701447T 1996-01-26 1997-01-24 Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung Expired - Lifetime DE69701447T3 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI960363A FI104825B (fi) 1996-01-26 1996-01-26 Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
FI960363 1996-01-26
PCT/FI1997/000034 WO1997027224A1 (en) 1996-01-26 1997-01-24 Olefin polymerization catalyst system, producing and using it

Publications (3)

Publication Number Publication Date
DE69701447D1 DE69701447D1 (de) 2000-04-20
DE69701447T2 DE69701447T2 (de) 2000-09-14
DE69701447T3 true DE69701447T3 (de) 2007-07-12

Family

ID=8545089

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69701447T Expired - Lifetime DE69701447T3 (de) 1996-01-26 1997-01-24 Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung

Country Status (9)

Country Link
US (1) US6225423B1 (enExample)
EP (1) EP0876405B2 (enExample)
JP (1) JP2000504045A (enExample)
CN (1) CN1098281C (enExample)
AT (1) ATE190631T1 (enExample)
AU (1) AU1547497A (enExample)
DE (1) DE69701447T3 (enExample)
FI (1) FI104825B (enExample)
WO (1) WO1997027224A1 (enExample)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6136742A (en) * 1996-09-24 2000-10-24 Exxon Chemical Patents, Inc. Metallocene catalyst systems
US6977283B1 (en) 1998-04-07 2005-12-20 Exxonmobil Chemical Patents Inc. Polymerization process
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
EP2287211B1 (en) * 1998-10-27 2012-02-08 Westlake Longview Corporation Process for the polymerization of olefins; polyethylenes, and films and articles produced therefrom
JP2003511493A (ja) 1999-10-02 2003-03-25 ボレアリス テクノロジー オイ オレフィン重合用修飾担持触媒
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6593267B2 (en) 2000-12-18 2003-07-15 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US6933258B2 (en) 2000-12-19 2005-08-23 Univation Technologies, L.L.C. Catalyst composition and methods for its preparation and use in a polymerization process
JP2002338617A (ja) * 2001-05-22 2002-11-27 Sumitomo Chem Co Ltd ビニル化合物重合用触媒成分、ビニル化合物重合用触媒、ビニル化合物重合体の製造方法および遷移金属化合物の使用方法
GB0118010D0 (en) 2001-07-24 2001-09-19 Borealis Tech Oy Catalysts
RU2307838C2 (ru) * 2001-09-14 2007-10-10 Бп Корпорейшн Норт Америка Инк. Латентные металлоценовые каталитические системы для полимеризации олефинов
US6689852B2 (en) 2002-01-15 2004-02-10 Exxonmobil Research And Engineering Company Modifiers for improved olefin polymerization with activated neutral aluminum compounds
TWI300782B (en) 2002-08-29 2008-09-11 Ineos Europe Ltd Supported polymerisation catalysts
WO2004094487A1 (en) 2003-03-21 2004-11-04 Dow Global Technologies, Inc. Morphology controlled olefin polymerization process
WO2005019275A1 (en) * 2003-08-22 2005-03-03 Innovene Europe Limited Supported polymerisation catalysts
GB0319773D0 (en) * 2003-08-22 2003-09-24 Bp Chem Int Ltd Supported polymerisation catalysts
GB0402959D0 (en) * 2004-02-11 2004-03-17 Bp Chem Int Ltd Supported polymerisation catalysts
US7294599B2 (en) * 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
EP1731536A1 (en) * 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Supported polymerisation catalysts
JP5156197B2 (ja) * 2006-04-20 2013-03-06 日本ポリプロ株式会社 オレフィン重合体の製造方法
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
CN101802019B (zh) 2007-08-16 2014-01-08 尤尼威蒂恩技术有限责任公司 连续性添加剂及其在聚合工艺中的用途
KR101698618B1 (ko) 2009-01-08 2017-01-20 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀 중합 방법을 위한 첨가제
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
KR101678247B1 (ko) 2009-07-28 2016-11-21 유니베이션 테크놀로지즈, 엘엘씨 지지된 기하학적 구속 촉매를 사용한 중합 방법
US8858525B2 (en) * 2009-11-20 2014-10-14 Cryovac, Inc. Noise dampening film
BR112013016116B1 (pt) 2010-12-22 2020-04-28 Univation Tech Llc processo de polimerização e sistema catalisador
EP2610269A1 (en) 2011-12-28 2013-07-03 Saudi Basic Industries Corporation Catalyst composition and method for preparing the same
EP3080200B1 (en) 2013-12-09 2018-11-14 Univation Technologies, LLC Feeding polymerization additives to polymerization processes
EP4105246A4 (en) 2020-03-25 2023-09-06 Japan Polypropylene Corporation Catalyst for olefin polymerization, production method for catalyst for olefin polymerization, and production method for olefin polymer using said catalyst for olefin polymerization
KR102513518B1 (ko) 2020-12-23 2023-03-22 디엘케미칼 주식회사 메탈로센 올레핀 중합 공정용 대전방지제를 이용한 올레핀 중합 방법

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2154242A (en) 1984-02-03 1985-09-04 Bp Chem Int Ltd Continuous slurry process for producing olefin (co)polymers
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
DE3789500T2 (de) 1987-02-02 1994-08-04 Fina Technology Verfahren zur Verbesserung der Effektivität eines vorpolymerisierten Katalysators.
DE68919156T3 (de) * 1988-08-05 2002-08-14 Fina Technology, Inc. Verfahren zur Herstellung grosser symmetrischer Polymerteilchen.
WO1992005208A1 (en) 1990-09-14 1992-04-02 Exxon Chemical Patents Inc. IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY
DE4120006A1 (de) 1991-06-18 1992-12-24 Basf Ag Durch vorpolymerisation getraegerte katalysatorsysteme zur herstellung von polyalk-1-enen
DE4121368A1 (de) 1991-06-28 1993-01-07 Hoechst Ag Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen
DE4139262A1 (de) 1991-11-29 1993-06-03 Basf Ag Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
EP0567952B1 (en) 1992-04-29 1997-12-03 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
ES2167336T3 (es) 1992-08-05 2002-05-16 Exxonmobil Chem Patents Inc Catalizadores ionicos soportados de metal de transicion para la polimerizacion de olefinas.
ES2148204T3 (es) 1992-09-04 2000-10-16 Bp Chem Int Ltd Composiciones cataliticas y procedimiento para la preparacion de poliolefinas.
DE4242486A1 (de) 1992-12-16 1994-06-23 Basf Ag Propylen-Homopolymere
US5347024A (en) 1993-03-19 1994-09-13 The Dow Chemical Company Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation
CA2163789C (en) * 1993-05-25 2006-10-24 Terry John Burkhardt Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof
JPH08512063A (ja) 1993-06-24 1996-12-17 エクソン・ケミカル・パテンツ・インク モノシクロペンタジエニル遷移金属触媒系による非晶質ポリ−α−オレフィンの製造方法
DE69422410T2 (de) 1993-08-06 2000-07-06 Exxon Chemical Patents, Inc. Polymerisationskataylsatoren, ihre herstellung und verwendung
US5466649A (en) 1993-10-15 1995-11-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
DE4337232A1 (de) 1993-10-30 1995-05-04 Basf Ag Racemische Metallocenkomplexe und Verfahren zu ihrer Herstellung
EP0729477B1 (en) 1993-11-19 1999-10-27 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
DE4344688A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5416179A (en) * 1994-03-16 1995-05-16 Phillips Petroleum Company Catalyst compositions and olefin polymerization
IT1273615B (it) † 1995-05-05 1997-07-08 Enichem Spa Catalizzatore a migliorata attivita' per la (co)polimerizzazione dell'etilene

Also Published As

Publication number Publication date
JP2000504045A (ja) 2000-04-04
ATE190631T1 (de) 2000-04-15
CN1098281C (zh) 2003-01-08
US6225423B1 (en) 2001-05-01
DE69701447T2 (de) 2000-09-14
EP0876405A1 (en) 1998-11-11
CN1211995A (zh) 1999-03-24
AU1547497A (en) 1997-08-20
FI104825B (fi) 2000-04-14
FI960363L (fi) 1997-07-27
EP0876405B2 (en) 2007-01-03
EP0876405B1 (en) 2000-03-15
WO1997027224A1 (en) 1997-07-31
DE69701447D1 (de) 2000-04-20
FI960363A0 (fi) 1996-01-26

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8363 Opposition against the patent
8366 Restricted maintained after opposition proceedings