DE69701447T3 - Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung - Google Patents

Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung Download PDF

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Publication number
DE69701447T3
DE69701447T3 DE69701447T DE69701447T DE69701447T3 DE 69701447 T3 DE69701447 T3 DE 69701447T3 DE 69701447 T DE69701447 T DE 69701447T DE 69701447 T DE69701447 T DE 69701447T DE 69701447 T3 DE69701447 T3 DE 69701447T3
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DE
Germany
Prior art keywords
transition metal
group
reaction product
organic solvent
compound
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Expired - Lifetime
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DE69701447T
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German (de)
English (en)
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DE69701447D1 (de
DE69701447T2 (de
Inventor
S. Ove ANDELL
Harri Hokkanen
Marja Mustonen
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Borealis AS
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Borealis AS
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Publication of DE69701447D1 publication Critical patent/DE69701447D1/de
Application granted granted Critical
Publication of DE69701447T2 publication Critical patent/DE69701447T2/de
Publication of DE69701447T3 publication Critical patent/DE69701447T3/de
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69701447T 1996-01-26 1997-01-24 Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung Expired - Lifetime DE69701447T3 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI960363 1996-01-26
FI960363A FI104825B (fi) 1996-01-26 1996-01-26 Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
PCT/FI1997/000034 WO1997027224A1 (en) 1996-01-26 1997-01-24 Olefin polymerization catalyst system, producing and using it

Publications (3)

Publication Number Publication Date
DE69701447D1 DE69701447D1 (de) 2000-04-20
DE69701447T2 DE69701447T2 (de) 2000-09-14
DE69701447T3 true DE69701447T3 (de) 2007-07-12

Family

ID=8545089

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69701447T Expired - Lifetime DE69701447T3 (de) 1996-01-26 1997-01-24 Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung

Country Status (9)

Country Link
US (1) US6225423B1 (enExample)
EP (1) EP0876405B2 (enExample)
JP (1) JP2000504045A (enExample)
CN (1) CN1098281C (enExample)
AT (1) ATE190631T1 (enExample)
AU (1) AU1547497A (enExample)
DE (1) DE69701447T3 (enExample)
FI (1) FI104825B (enExample)
WO (1) WO1997027224A1 (enExample)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6136742A (en) * 1996-09-24 2000-10-24 Exxon Chemical Patents, Inc. Metallocene catalyst systems
US6977283B1 (en) 1998-04-07 2005-12-20 Exxonmobil Chemical Patents Inc. Polymerization process
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
EP2277923B1 (en) * 1998-10-27 2011-10-12 Westlake Longview Corporation Process for the polymerization of olefins; polyethylenes, and films and articles produced therefrom
DE60018775T2 (de) 1999-10-02 2005-08-11 Borealis Technology Oy Geträgerter und modifizierter katalysator für die polymerisation von olefine
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6593267B2 (en) 2000-12-18 2003-07-15 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US6933258B2 (en) 2000-12-19 2005-08-23 Univation Technologies, L.L.C. Catalyst composition and methods for its preparation and use in a polymerization process
JP2002338617A (ja) * 2001-05-22 2002-11-27 Sumitomo Chem Co Ltd ビニル化合物重合用触媒成分、ビニル化合物重合用触媒、ビニル化合物重合体の製造方法および遷移金属化合物の使用方法
GB0118010D0 (en) 2001-07-24 2001-09-19 Borealis Tech Oy Catalysts
RU2307838C2 (ru) * 2001-09-14 2007-10-10 Бп Корпорейшн Норт Америка Инк. Латентные металлоценовые каталитические системы для полимеризации олефинов
US6689852B2 (en) 2002-01-15 2004-02-10 Exxonmobil Research And Engineering Company Modifiers for improved olefin polymerization with activated neutral aluminum compounds
TWI300782B (en) * 2002-08-29 2008-09-11 Ineos Europe Ltd Supported polymerisation catalysts
JP4742221B2 (ja) 2003-03-21 2011-08-10 ダウ グローバル テクノロジーズ エルエルシー モルホロジー制御オレフィン重合プロセス
GB0319773D0 (en) * 2003-08-22 2003-09-24 Bp Chem Int Ltd Supported polymerisation catalysts
JP5296982B2 (ja) * 2003-08-22 2013-09-25 イネオス ユーロープ リミテッド 担持重合触媒
GB0402959D0 (en) * 2004-02-11 2004-03-17 Bp Chem Int Ltd Supported polymerisation catalysts
US7294599B2 (en) * 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
EP1731536A1 (en) * 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Supported polymerisation catalysts
JP5156197B2 (ja) * 2006-04-20 2013-03-06 日本ポリプロ株式会社 オレフィン重合体の製造方法
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
EP2183286B1 (en) 2007-08-16 2012-12-12 Univation Technologies, LLC Continuity additives and their use in polymerization processes
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
JP5661645B2 (ja) 2009-01-08 2015-01-28 ユニベーション・テクノロジーズ・エルエルシー ポリオレフィン重合プロセス用の添加剤
WO2011017092A1 (en) 2009-07-28 2011-02-10 Univation Technologies, Llc Polymerization process using a supported constrained geometry catalyst
US8858525B2 (en) * 2009-11-20 2014-10-14 Cryovac, Inc. Noise dampening film
ES2640318T3 (es) 2010-12-22 2017-11-02 Univation Technologies, Llc Aditivo para procedimientos de polimerización de olefinas
EP2610269A1 (en) 2011-12-28 2013-07-03 Saudi Basic Industries Corporation Catalyst composition and method for preparing the same
JP2016539234A (ja) 2013-12-09 2016-12-15 ユニベーション・テクノロジーズ・エルエルシー 重合プロセスへの重合添加剤の供給
US12404353B2 (en) 2020-03-25 2025-09-02 Japan Polypropylene Corporation Olefin polymerization catalyst, olefin polymerization catalyst production method, and olefin polymer production method using the olefin polymerization catalyst
KR102513518B1 (ko) 2020-12-23 2023-03-22 디엘케미칼 주식회사 메탈로센 올레핀 중합 공정용 대전방지제를 이용한 올레핀 중합 방법

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2154242A (en) 1984-02-03 1985-09-04 Bp Chem Int Ltd Continuous slurry process for producing olefin (co)polymers
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
ES2050670T3 (es) 1987-02-02 1994-06-01 Fina Technology Procedimiento para aumentar la eficacia de un catalizador prepolimerizado.
EP0354893B2 (en) * 1988-08-05 2002-03-13 Fina Technology, Inc. Process for producing large symmetrical polymer particles
DE69117520T2 (de) 1990-09-14 1996-08-01 Exxon Chemical Patents Inc Ionischer katalysator zur herstellung von polyalphaolefinen mit kontrollierter takticität
DE4120006A1 (de) 1991-06-18 1992-12-24 Basf Ag Durch vorpolymerisation getraegerte katalysatorsysteme zur herstellung von polyalk-1-enen
DE4121368A1 (de) 1991-06-28 1993-01-07 Hoechst Ag Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen
DE4139262A1 (de) 1991-11-29 1993-06-03 Basf Ag Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
EP0567952B1 (en) 1992-04-29 1997-12-03 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
EP0702700B1 (en) 1992-08-05 2001-11-07 ExxonMobil Chemical Patents Inc. Supported ionic transition metal catalysts for olefin polymerization
ES2148204T3 (es) 1992-09-04 2000-10-16 Bp Chem Int Ltd Composiciones cataliticas y procedimiento para la preparacion de poliolefinas.
DE4242486A1 (de) 1992-12-16 1994-06-23 Basf Ag Propylen-Homopolymere
US5347024A (en) 1993-03-19 1994-09-13 The Dow Chemical Company Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation
AU683899B2 (en) * 1993-05-25 1997-11-27 Exxon Chemical Patents Inc. Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof
EP0705283B1 (en) 1993-06-24 1999-01-13 Exxon Chemical Patents Inc. PROCESS FOR PRODUCING AMORPHOUS POLY-$g(a)-OLEFINS WITH A MONOCYCLOPENTADIENYL TRANSITION METAL CATALYST SYSTEM
DE69422410T2 (de) 1993-08-06 2000-07-06 Exxon Chemical Patents, Inc. Polymerisationskataylsatoren, ihre herstellung und verwendung
US5466649A (en) 1993-10-15 1995-11-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
DE4337232A1 (de) 1993-10-30 1995-05-04 Basf Ag Racemische Metallocenkomplexe und Verfahren zu ihrer Herstellung
EP0729477B1 (en) 1993-11-19 1999-10-27 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
DE4344688A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5416179A (en) * 1994-03-16 1995-05-16 Phillips Petroleum Company Catalyst compositions and olefin polymerization
IT1273615B (it) † 1995-05-05 1997-07-08 Enichem Spa Catalizzatore a migliorata attivita' per la (co)polimerizzazione dell'etilene

Also Published As

Publication number Publication date
FI960363L (fi) 1997-07-27
FI104825B (fi) 2000-04-14
FI960363A0 (fi) 1996-01-26
AU1547497A (en) 1997-08-20
ATE190631T1 (de) 2000-04-15
CN1211995A (zh) 1999-03-24
US6225423B1 (en) 2001-05-01
EP0876405A1 (en) 1998-11-11
EP0876405B2 (en) 2007-01-03
WO1997027224A1 (en) 1997-07-31
DE69701447D1 (de) 2000-04-20
CN1098281C (zh) 2003-01-08
DE69701447T2 (de) 2000-09-14
EP0876405B1 (en) 2000-03-15
JP2000504045A (ja) 2000-04-04

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8363 Opposition against the patent
8366 Restricted maintained after opposition proceedings