DE69600422T2 - Elektrode mit zwei Elektrokatalysatoren - Google Patents
Elektrode mit zwei ElektrokatalysatorenInfo
- Publication number
- DE69600422T2 DE69600422T2 DE69600422T DE69600422T DE69600422T2 DE 69600422 T2 DE69600422 T2 DE 69600422T2 DE 69600422 T DE69600422 T DE 69600422T DE 69600422 T DE69600422 T DE 69600422T DE 69600422 T2 DE69600422 T2 DE 69600422T2
- Authority
- DE
- Germany
- Prior art keywords
- electrode
- catalytic component
- catalytic
- anode
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010411 electrocatalyst Substances 0.000 title description 31
- 239000000446 fuel Substances 0.000 claims description 78
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 73
- 230000003197 catalytic effect Effects 0.000 claims description 59
- 239000003054 catalyst Substances 0.000 claims description 45
- 239000000463 material Substances 0.000 claims description 24
- 239000003792 electrolyte Substances 0.000 claims description 22
- 239000007789 gas Substances 0.000 claims description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 18
- 229910052760 oxygen Inorganic materials 0.000 claims description 18
- 239000001301 oxygen Substances 0.000 claims description 18
- 239000000376 reactant Substances 0.000 claims description 17
- 239000012528 membrane Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- 239000000758 substrate Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 238000003487 electrochemical reaction Methods 0.000 claims description 8
- 239000002322 conducting polymer Substances 0.000 claims description 7
- 229920001940 conductive polymer Polymers 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000005518 polymer electrolyte Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 231100000331 toxic Toxicity 0.000 claims description 6
- 230000002588 toxic effect Effects 0.000 claims description 6
- 239000010953 base metal Substances 0.000 claims description 4
- 238000010574 gas phase reaction Methods 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 66
- 239000010410 layer Substances 0.000 description 58
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 50
- 229910002091 carbon monoxide Inorganic materials 0.000 description 49
- 229910002092 carbon dioxide Inorganic materials 0.000 description 33
- 239000001569 carbon dioxide Substances 0.000 description 33
- 229910052697 platinum Inorganic materials 0.000 description 33
- 239000001257 hydrogen Substances 0.000 description 24
- 229910052739 hydrogen Inorganic materials 0.000 description 24
- 238000010926 purge Methods 0.000 description 24
- 230000000607 poisoning effect Effects 0.000 description 23
- 231100000572 poisoning Toxicity 0.000 description 20
- 238000011068 loading method Methods 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 16
- 238000006722 reduction reaction Methods 0.000 description 12
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 11
- 239000004810 polytetrafluoroethylene Substances 0.000 description 11
- 241000894007 species Species 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 10
- 229920000557 Nafion® Polymers 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 9
- 230000009467 reduction Effects 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 150000002431 hydrogen Chemical class 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 239000000123 paper Substances 0.000 description 8
- 229920000049 Carbon (fiber) Polymers 0.000 description 7
- 239000004917 carbon fiber Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 229910052707 ruthenium Inorganic materials 0.000 description 7
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 6
- 238000013459 approach Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 239000002001 electrolyte material Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- -1 polytetrafluoroethylene Polymers 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 231100000167 toxic agent Toxicity 0.000 description 4
- 239000003440 toxic substance Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 238000010248 power generation Methods 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- CFQCIHVMOFOCGH-UHFFFAOYSA-N platinum ruthenium Chemical compound [Ru].[Pt] CFQCIHVMOFOCGH-UHFFFAOYSA-N 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 101100311330 Schizosaccharomyces pombe (strain 972 / ATCC 24843) uap56 gene Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000009718 spray deposition Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 101150018444 sub2 gene Proteins 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9507012.4A GB9507012D0 (en) | 1995-04-05 | 1995-04-05 | Improved electrode |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69600422D1 DE69600422D1 (de) | 1998-08-20 |
| DE69600422T2 true DE69600422T2 (de) | 1998-12-10 |
Family
ID=10772537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69600422T Expired - Lifetime DE69600422T2 (de) | 1995-04-05 | 1996-04-03 | Elektrode mit zwei Elektrokatalysatoren |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5795669A (enExample) |
| EP (1) | EP0736921B1 (enExample) |
| JP (2) | JPH0927326A (enExample) |
| AU (1) | AU5048596A (enExample) |
| CA (1) | CA2173563A1 (enExample) |
| DE (1) | DE69600422T2 (enExample) |
| GB (1) | GB9507012D0 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004024915B4 (de) * | 2003-05-21 | 2011-08-18 | Kabushikikaisha Equos Research | Auf einer Feststoffpolyelektrolytmembran angeordnete Brennstoffzellen-Luftelektrode und Brennstoffzelle mit dieser |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19615562C1 (de) * | 1996-04-19 | 1997-10-09 | Zsw | Vorrichtung und Verfahren zur kombinierten Reinigung und Kompression von CO-haltigem Wasserstoff sowie Verwendung des mit dem Verfahren erhaltenen Wasserstoffs als Brenngas in Brennstoffzellen |
| DE19721437A1 (de) * | 1997-05-21 | 1998-11-26 | Degussa | CO-toleranter Anodenkatalysator für PEM-Brennstoffzellen und Verfahren zu seiner Herstellung |
| DE19744028C2 (de) * | 1997-10-06 | 2000-03-09 | Forschungszentrum Juelich Gmbh | Elektrode mit aufgebrachten, kohlenmonoxidempfindlichen Katalysatorpartikeln sowie deren Verwendung |
| US6096448A (en) * | 1997-12-23 | 2000-08-01 | Ballard Power Systems Inc. | Method and apparatus for operating an electrochemical fuel cell with periodic fuel starvation at the anode |
| US6329089B1 (en) | 1997-12-23 | 2001-12-11 | Ballard Power Systems Inc. | Method and apparatus for increasing the temperature of a fuel cell |
| US6472090B1 (en) | 1999-06-25 | 2002-10-29 | Ballard Power Systems Inc. | Method and apparatus for operating an electrochemical fuel cell with periodic reactant starvation |
| US6291091B1 (en) | 1997-12-24 | 2001-09-18 | Ballard Power Systems Inc. | Continuous method for manufacturing a Laminated electrolyte and electrode assembly |
| FR2775622A1 (fr) * | 1998-03-03 | 1999-09-03 | Atochem Elf Sa | Catalyseur bimetallique supporte a base de platine ou d'argent, son procede de fabrication et son utilisation pour les cellules electrochimiques |
| US6524874B1 (en) * | 1998-08-05 | 2003-02-25 | Micron Technology, Inc. | Methods of forming field emission tips using deposited particles as an etch mask |
| GB9826940D0 (en) * | 1998-12-09 | 1999-02-03 | Johnson Matthey Plc | Electrode |
| GB9914023D0 (en) * | 1999-06-17 | 1999-08-18 | Johnson Matthey Plc | Gas diffusion substrate and electrode |
| US6300000B1 (en) * | 1999-06-18 | 2001-10-09 | Gore Enterprise Holdings | Fuel cell membrane electrode assemblies with improved power outputs and poison resistance |
| US6936370B1 (en) | 1999-08-23 | 2005-08-30 | Ballard Power Systems Inc. | Solid polymer fuel cell with improved voltage reversal tolerance |
| WO2001015247A2 (en) * | 1999-08-23 | 2001-03-01 | Ballard Power Systems Inc. | Fuel cell anode structure for voltage reversal tolerance |
| US6183894B1 (en) | 1999-11-08 | 2001-02-06 | Brookhaven Science Associates | Electrocatalyst for alcohol oxidation in fuel cells |
| DE19962686A1 (de) * | 1999-12-23 | 2001-07-26 | Siemens Ag | Membran-Elektroden-Einheit für eine Brennstoffzelle und Herstellungsverfahren dazu |
| US6447942B1 (en) * | 2000-03-13 | 2002-09-10 | Energy Conversion Devices, Inc. | Alkaline fuel cell |
| US6492056B1 (en) * | 2000-03-13 | 2002-12-10 | Energy Conversion Devices, Inc. | Catalytic hydrogen storage composite material and fuel cell employing same |
| JP4974403B2 (ja) | 2000-05-31 | 2012-07-11 | 日本ゴア株式会社 | 固体高分子電解質型燃料電池 |
| DE10037072A1 (de) * | 2000-07-29 | 2002-02-14 | Omg Ag & Co Kg | Membran-Elektrodeneinheit für Polymerelektrolyt-Brennstoffzellen und Verfahren zu ihrer Herstellung |
| GB0022895D0 (en) | 2000-09-19 | 2000-11-01 | Johnson Matthey Plc | Anode structure |
| WO2002027821A2 (en) | 2000-09-27 | 2002-04-04 | Proton Energy Systems, Inc. | Electrode catalyst composition, electrode and membrane electrode assembly for electrochemical cells |
| US20040185325A1 (en) * | 2000-10-27 | 2004-09-23 | Faguy Peter M | Fuel cell having improved catalytic layer |
| JP3649686B2 (ja) * | 2001-11-02 | 2005-05-18 | 本田技研工業株式会社 | 固体高分子型燃料電池用電極の製造方法 |
| DE10159476A1 (de) * | 2001-12-04 | 2003-07-17 | Omg Ag & Co Kg | Verfahren zur Herstellung von Membran-Elektrodeneinheiten für Brennstoffzellen |
| US20030190517A1 (en) * | 2002-04-08 | 2003-10-09 | John Elter | Fuel cell |
| JP3621078B2 (ja) * | 2002-06-20 | 2005-02-16 | 田中貴金属工業株式会社 | 高分子固体電解質形燃料電池の燃料極 |
| US7112386B2 (en) * | 2002-09-04 | 2006-09-26 | Utc Fuel Cells, Llc | Membrane electrode assemblies with hydrogen peroxide decomposition catalyst |
| US7473485B2 (en) * | 2002-09-04 | 2009-01-06 | Utc Power Corporation | Extended electrodes for PEM fuel cell applications |
| US7507494B2 (en) * | 2004-03-04 | 2009-03-24 | Utc Power Corporation | Extended catalyzed layer for minimizing cross-over oxygen and consuming peroxide |
| WO2004032263A2 (de) * | 2002-09-27 | 2004-04-15 | Bayer Materialscience Ag | Verfahren zur herstellung einer gasdiffusionselektrode |
| EP1435672A1 (de) * | 2002-12-30 | 2004-07-07 | Umicore AG & Co. KG | Katalysatorhaltiges Gasverteilersubstrat für Brennstoffzellen sowie Verfahren zu dessen Herstellung |
| US7960072B2 (en) | 2003-04-04 | 2011-06-14 | GM Global Technology Operations LLC | MEA with catalyst for oxidation of carbon monoxide |
| DE10325324A1 (de) * | 2003-06-04 | 2004-12-30 | Umicore Ag & Co.Kg | Membran-Elektroden-Einheit für Direkt-Methanol-Brennstoffzellen und Verfahren zu ihrer Herstellung |
| NO325620B1 (no) * | 2003-10-21 | 2008-06-30 | Revolt Technology Ltd | Elektrode, fremgangsmate for fremstilling derav, metall/luft-brenselcelle og metallhydrid-battericelle |
| CN100521313C (zh) * | 2003-10-27 | 2009-07-29 | 中国科学院大连化学物理研究所 | 用于质子交换膜燃料电池的膜电极结构及其制备方法 |
| US8057847B2 (en) * | 2003-10-31 | 2011-11-15 | Utc Fuel Cells, Llc | Method for preparing membranes and membrane electrode assemblies with hydrogen peroxide decomposition catalyst |
| GB0411733D0 (en) | 2004-05-26 | 2004-06-30 | Johnson Matthey Plc | Anode structure |
| US7855021B2 (en) * | 2004-12-22 | 2010-12-21 | Brookhaven Science Associates, Llc | Electrocatalysts having platium monolayers on palladium, palladium alloy, and gold alloy core-shell nanoparticles, and uses thereof |
| US9005331B2 (en) | 2004-12-22 | 2015-04-14 | Brookhaven Science Associates, Llc | Platinum-coated non-noble metal-noble metal core-shell electrocatalysts |
| US7691780B2 (en) * | 2004-12-22 | 2010-04-06 | Brookhaven Science Associates, Llc | Platinum- and platinum alloy-coated palladium and palladium alloy particles and uses thereof |
| CN101120466B (zh) | 2004-12-28 | 2010-06-16 | Utc电力公司 | 带有过氧化氢分解催化剂的膜电极装置 |
| JP5232637B2 (ja) * | 2005-03-25 | 2013-07-10 | インスティトゥーツ ナショナル デ ラ レシェルシェ サイエンティフィック | ナノメートル・フィラメント状構造体の堆積方法および装置 |
| US8115373B2 (en) | 2005-07-06 | 2012-02-14 | Rochester Institute Of Technology | Self-regenerating particulate trap systems for emissions and methods thereof |
| US7790304B2 (en) * | 2005-09-13 | 2010-09-07 | 3M Innovative Properties Company | Catalyst layers to enhance uniformity of current density in membrane electrode assemblies |
| CN100468836C (zh) * | 2005-12-14 | 2009-03-11 | 胜光科技股份有限公司 | 燃料电池的膜电极组及其制造方法 |
| TWI342082B (en) * | 2005-12-30 | 2011-05-11 | Ind Tech Res Inst | Electrode structure |
| KR100709198B1 (ko) | 2006-04-28 | 2007-04-18 | 삼성에스디아이 주식회사 | 직접 산화형 연료 전지용 스택 및 이를 포함하는 직접산화형 연료 전지 시스템 |
| KR100738062B1 (ko) * | 2006-05-16 | 2007-07-10 | 삼성에스디아이 주식회사 | 막 전극 접합체 및 이를 이용한 연료전지 |
| KR100846478B1 (ko) * | 2006-05-16 | 2008-07-17 | 삼성에스디아이 주식회사 | 담지 촉매, 그 제조방법 및 이를 이용한 연료전지 |
| JP2008034157A (ja) * | 2006-07-27 | 2008-02-14 | Toyota Motor Corp | 燃料電池 |
| US7608358B2 (en) | 2006-08-25 | 2009-10-27 | Bdf Ip Holdings Ltd. | Fuel cell anode structure for voltage reversal tolerance |
| CA2664373A1 (en) * | 2006-09-28 | 2008-04-03 | Basf Fuel Cell Gmbh | Structures for gas diffusion electrodes |
| JP2008243776A (ja) * | 2007-03-29 | 2008-10-09 | Electric Power Dev Co Ltd | 固体高分子電解質型燃料電池およびその膜電極接合体 |
| EP1978582A1 (en) * | 2007-04-05 | 2008-10-08 | Atotech Deutschland Gmbh | Process for the preparation of electrodes for use in a fuel cell |
| US20090081527A1 (en) * | 2007-09-24 | 2009-03-26 | Ping He | Fuel cell system |
| JP5158334B2 (ja) * | 2007-10-05 | 2013-03-06 | 信越化学工業株式会社 | 燃料電池用電極触媒の製造方法 |
| US8669015B2 (en) * | 2009-04-02 | 2014-03-11 | Samsung Electronics Co., Ltd. | Solid-state fuel cell including anode and cathode chemical electrolyte protection layers and a hydrogen ion conductive solid oxide dense film |
| US8815468B2 (en) * | 2009-06-24 | 2014-08-26 | Ford Global Technologies, Llc | Layered electrodes and membrane electrode assemblies employing the same |
| DE102019211127A1 (de) * | 2019-07-26 | 2021-01-28 | Greenerity Gmbh | Membranelektrodenanordnung und Brennstoffzelle |
| CN112825366A (zh) * | 2019-11-21 | 2021-05-21 | 中国科学院大连化学物理研究所 | 基于贫氢重整气进料高温质子膜燃料电池膜电极及制备与应用 |
| CN116137341B (zh) * | 2023-04-19 | 2023-07-21 | 安徽华曙科技有限公司 | 以植物为原料的发电装置及其发电方法 |
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| DE1233834B (de) * | 1958-03-05 | 1967-02-09 | Siemens Ag | Elektrode fuer Elektrolyseure und Brennstoff-elemente mit oberflaechlicher Doppelskelett-Katalysator-Struktur |
| GB1074561A (en) * | 1963-06-20 | 1967-07-05 | Tokyo Shibaura Electric Co | Fuel cells |
| JPS5768142A (en) * | 1980-10-14 | 1982-04-26 | Hitachi Ltd | Electrode catalyst for fuel cell and its production |
| JPS61109257A (ja) * | 1984-11-01 | 1986-05-27 | Fuji Electric Co Ltd | 燃料電池の燃料電極 |
| WO1987005445A1 (en) * | 1986-02-28 | 1987-09-11 | National Research Development Corporation | Electrode for oxidising methanol |
| GB2190399A (en) * | 1986-05-02 | 1987-11-18 | Nat Res Dev | Multi-metal electrode |
| US4787964A (en) * | 1987-05-11 | 1988-11-29 | Caterpillar Industrial Inc. | Gas diffusion electrodes, electrochemical cells and methods exhibiting improved voltage performance |
| JPH01309262A (ja) * | 1988-06-06 | 1989-12-13 | Hitachi Ltd | 電極触媒及びこれを用いた燃料電池 |
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| AU8547391A (en) * | 1990-08-08 | 1992-03-02 | Physical Sciences, Inc. | Generation of electricity with fuel cell using alcohol fuel |
| JPH04141233A (ja) * | 1990-09-29 | 1992-05-14 | Stonehard Assoc Inc | 電極触媒 |
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| JP2842150B2 (ja) * | 1992-06-02 | 1998-12-24 | 株式会社日立製作所 | 固体高分子型燃料電池 |
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| US5523177A (en) * | 1994-10-12 | 1996-06-04 | Giner, Inc. | Membrane-electrode assembly for a direct methanol fuel cell |
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-
1995
- 1995-04-05 GB GBGB9507012.4A patent/GB9507012D0/en active Pending
-
1996
- 1996-04-03 EP EP96302406A patent/EP0736921B1/en not_active Expired - Lifetime
- 1996-04-03 DE DE69600422T patent/DE69600422T2/de not_active Expired - Lifetime
- 1996-04-04 AU AU50485/96A patent/AU5048596A/en not_active Abandoned
- 1996-04-04 CA CA002173563A patent/CA2173563A1/en not_active Abandoned
- 1996-04-05 US US08/628,161 patent/US5795669A/en not_active Expired - Lifetime
- 1996-04-05 JP JP8084265A patent/JPH0927326A/ja not_active Withdrawn
-
2007
- 2007-01-24 JP JP2007014078A patent/JP5270098B2/ja not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004024915B4 (de) * | 2003-05-21 | 2011-08-18 | Kabushikikaisha Equos Research | Auf einer Feststoffpolyelektrolytmembran angeordnete Brennstoffzellen-Luftelektrode und Brennstoffzelle mit dieser |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0736921A1 (en) | 1996-10-09 |
| JP2007180038A (ja) | 2007-07-12 |
| JP5270098B2 (ja) | 2013-08-21 |
| EP0736921B1 (en) | 1998-07-15 |
| US5795669A (en) | 1998-08-18 |
| CA2173563A1 (en) | 1996-10-06 |
| JPH0927326A (ja) | 1997-01-28 |
| GB9507012D0 (en) | 1995-05-31 |
| AU5048596A (en) | 1996-10-17 |
| DE69600422D1 (de) | 1998-08-20 |
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