DE69402473T2 - Perfluorodioxole, ihre Herstellung und deren Homopolymere und Copolymere - Google Patents
Perfluorodioxole, ihre Herstellung und deren Homopolymere und CopolymereInfo
- Publication number
- DE69402473T2 DE69402473T2 DE69402473T DE69402473T DE69402473T2 DE 69402473 T2 DE69402473 T2 DE 69402473T2 DE 69402473 T DE69402473 T DE 69402473T DE 69402473 T DE69402473 T DE 69402473T DE 69402473 T2 DE69402473 T2 DE 69402473T2
- Authority
- DE
- Germany
- Prior art keywords
- copolymers
- perfluorodioxoles
- homopolymers
- production
- tetrafluoroethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D317/42—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Insulating Materials (AREA)
- Lubricants (AREA)
- Processes Specially Adapted For Manufacturing Cables (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI001445A IT1264662B1 (it) | 1993-07-05 | 1993-07-05 | Perflurodiossoli loro omopolimeri e copolimeri e loro impiego per il rivestimento di cavi elettrici |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69402473D1 DE69402473D1 (de) | 1997-05-15 |
DE69402473T2 true DE69402473T2 (de) | 1997-11-06 |
Family
ID=11366528
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69402473T Expired - Lifetime DE69402473T2 (de) | 1993-07-05 | 1994-06-24 | Perfluorodioxole, ihre Herstellung und deren Homopolymere und Copolymere |
Country Status (11)
Country | Link |
---|---|
US (4) | US5498682A (de) |
EP (1) | EP0633257B1 (de) |
JP (1) | JP3801661B2 (de) |
KR (1) | KR100323579B1 (de) |
AT (1) | ATE151421T1 (de) |
CA (1) | CA2127219A1 (de) |
DE (1) | DE69402473T2 (de) |
IT (1) | IT1264662B1 (de) |
MX (1) | MX9405088A (de) |
RU (1) | RU2139866C1 (de) |
TW (1) | TW273556B (de) |
Families Citing this family (67)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1266647B1 (it) * | 1993-10-29 | 1997-01-09 | Ausimont Spa | Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa |
IT1269517B (it) * | 1994-05-19 | 1997-04-01 | Ausimont Spa | Polimeri e copolimeri fluorurati contenenti strutture cicliche |
IT1270703B (it) | 1994-11-17 | 1997-05-07 | Ausimont Spa | Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati |
IT1272861B (it) * | 1995-01-04 | 1997-07-01 | Ausimont Spa | Copolimeri dell'etilene con tetrafluoroetilene e/o clorotrifluoroetilene,aventi migliorate proprieta' meccaniche alle alte temperature |
IT1272863B (it) * | 1995-01-04 | 1997-07-01 | Ausimont Spa | Copolimeri termoprocessabili del tetrafluoroetilene |
IT1282378B1 (it) * | 1996-04-24 | 1998-03-20 | Ausimont Spa | Perfluoroelastomeri a base di diossoli |
IT1288121B1 (it) * | 1996-07-01 | 1998-09-10 | Ausimont Spa | Copolimeri termoplastici del vinilidenfluoruro (vdf) |
IT1283136B1 (it) * | 1996-07-09 | 1998-04-07 | Ausimont Spa | Lattici acquosi a base di fluoropolimeri |
IT1285771B1 (it) * | 1996-10-04 | 1998-06-18 | Ausimont Spa | Accoppiati pife con substrati |
DE19708295A1 (de) | 1997-02-28 | 1998-09-10 | Nath Guenther | Flüssigkeitslichtleiter |
US6242547B1 (en) | 1997-04-15 | 2001-06-05 | E. I. Du Pont De Nemours And Company | Vinyl fluoride interpolymers of low crystallinity |
ATE363085T1 (de) * | 1997-12-15 | 2007-06-15 | Guenther Nath | Lichtleiter mit flüssigem kern |
US6469185B1 (en) | 1998-02-17 | 2002-10-22 | Ausimont S.P.A. | Perfluorodioxoles |
IT1298257B1 (it) * | 1998-02-17 | 1999-12-20 | Ausimont Spa | Perfluorodiossoli |
ITMI981505A1 (it) * | 1998-06-30 | 1999-12-30 | Ausimont Spa | Purificazione di polimeri fluorurati |
ITMI981506A1 (it) * | 1998-06-30 | 1999-12-30 | Ausimont Spa | Manufatti di fluoropolimeri amorfi |
US6737165B1 (en) * | 1998-08-06 | 2004-05-18 | Omlidon Technologies Llc | Melt-processible poly(tetrafluoroethylene) |
EP2305724A1 (de) | 1998-08-06 | 2011-04-06 | Omlidon Technologies LLC | Schmelzverarbeitbares Polytetrafluorethylen |
US7276287B2 (en) * | 2003-12-17 | 2007-10-02 | Eidgenössische Technische Hochschule Zürich | Melt-processible poly(tetrafluoroethylene) |
IT1312320B1 (it) | 1999-05-25 | 2002-04-15 | Ausimont Spa | Membrane di polimeri amorfi (per) fluorurati. |
US6221247B1 (en) | 1999-06-03 | 2001-04-24 | Cms Technology Holdings, Inc. | Dioxole coated membrane module for ultrafiltration or microfiltration of aqueous suspensions |
ITMI991269A1 (it) | 1999-06-08 | 2000-12-08 | Ausimont Spa | Miscele di dispersioni di fluoropolimeri |
ITMI991514A1 (it) | 1999-07-09 | 2001-01-09 | Ausimont Spa | Co polimeri peralogenati termoprocessabili del clorotrifluoroetilene |
TWI289568B (en) * | 1999-08-30 | 2007-11-11 | Shinetsu Chemical Co | Polymer compound, resist material, and pattern formation method |
IT1318487B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluoroelastomeri. |
US7534845B2 (en) | 2000-04-21 | 2009-05-19 | Solvay Solexis S.P.A. | Fluorovinyl ethers and polymers obtainable therefrom |
IT1318488B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluorovinileteri e polimeri da essi ottenibili. |
US6572679B2 (en) | 2000-05-19 | 2003-06-03 | Membrane Technology And Research, Inc. | Gas separation using organic-vapor-resistant membranes in conjunction with organic-vapor-selective membranes |
US6572680B2 (en) | 2000-05-19 | 2003-06-03 | Membrane Technology And Research, Inc. | Carbon dioxide gas separation using organic-vapor-resistant membranes |
US6544316B2 (en) | 2000-05-19 | 2003-04-08 | Membrane Technology And Research, Inc. | Hydrogen gas separation using organic-vapor-resistant membranes |
US6579341B2 (en) | 2000-05-19 | 2003-06-17 | Membrane Technology And Research, Inc. | Nitrogen gas separation using organic-vapor-resistant membranes |
US6592650B2 (en) | 2000-05-19 | 2003-07-15 | Membrane Technology And Research, Inc. | Gas separation using organic-vapor-resistant membranes and PSA |
US6361583B1 (en) | 2000-05-19 | 2002-03-26 | Membrane Technology And Research, Inc. | Gas separation using organic-vapor-resistant membranes |
US6361582B1 (en) | 2000-05-19 | 2002-03-26 | Membrane Technology And Research, Inc. | Gas separation using C3+ hydrocarbon-resistant membranes |
US6540813B2 (en) * | 2000-06-13 | 2003-04-01 | Praxair Technology, Inc. | Method of preparing composite gas separation membranes from perfluoropolymers |
IT1318595B1 (it) | 2000-06-23 | 2003-08-27 | Ausimont Spa | Microsfere di copolimeri termoprocessabili del tetrafluoroetilene. |
IT1318596B1 (it) * | 2000-06-23 | 2003-08-27 | Ausimont Spa | Copolimeri termoprocessbili del tfe. |
IT1318633B1 (it) | 2000-07-20 | 2003-08-27 | Ausimont Spa | Polveri fini di politetrafluoroetilene. |
EP1220344B2 (de) † | 2000-12-26 | 2012-08-01 | Asahi Glass Company, Limited | Festpolymer-Elektrolyt Membran Festpolymer Brennstoffzelle und Fluorpolymer |
DE60211315T2 (de) * | 2001-03-07 | 2007-05-24 | E.I. Dupont De Nemours And Co., Wilmington | Fluorenthaltende ethylencopolymere |
ATE366755T1 (de) | 2001-05-07 | 2007-08-15 | Solvay Solexis Spa | Amorphe perfluorierte polymere |
ITMI20010921A1 (it) | 2001-05-07 | 2002-11-07 | Ausimont Spa | Polimeri (per)fluorurati amorfi |
ITMI20012745A1 (it) * | 2001-12-21 | 2003-06-21 | Ausimont Spa | Copolimeri termoprocessabili del tfe |
US20030181616A1 (en) * | 2002-02-12 | 2003-09-25 | Brian Thomas | Halogenated monomers and polymers and process for making same |
IL148350A0 (en) * | 2002-02-25 | 2002-09-12 | J G Systems Inc | Processing and repairing emulsions and microemulsions for use in optical fibers |
US6723152B2 (en) | 2002-07-01 | 2004-04-20 | Praxair Technology, Inc. | Gas separation using membranes formed from blends of perfluorinated polymers |
US6896717B2 (en) * | 2002-07-05 | 2005-05-24 | Membrane Technology And Research, Inc. | Gas separation using coated membranes |
ITMI20021561A1 (it) * | 2002-07-16 | 2004-01-16 | Ausimont Spa | Copolimeri di tfe |
DE602004003342T2 (de) * | 2003-02-10 | 2007-06-14 | Nanoptics Inc., Gainesville | Methode und apparat zur herstellung optischer übertragungsmedien |
ITMI20030773A1 (it) * | 2003-04-15 | 2004-10-16 | Solvay Solexis Spa | Polimeri perfluorurati amorfi. |
ITMI20030774A1 (it) | 2003-04-15 | 2004-10-16 | Solvay Solexis Spa | Polimeri perfluorurati. |
ITMI20041801A1 (it) | 2004-09-21 | 2004-12-21 | Solvay Solexis Spa | Uso di lattici submicrometrici di perfluoropolimeri nella determinazione di interazione molecolari mediante laser light scattering (lls) |
ITMI20050817A1 (it) * | 2005-05-05 | 2006-11-06 | Solvay Solexis Spa | Processo di dealogenazione |
ITMI20052455A1 (it) * | 2005-12-22 | 2007-06-23 | Solvay Solexis Spa | Procedimento per la preparazione di fluoroalogenoeteri |
ITMI20060480A1 (it) | 2006-03-16 | 2007-09-17 | Solvay Solexis Spa | Usom di perfluoropolimeri nella dtermibnazione della costante di legame recettore-ligando |
BRPI0718011A2 (pt) * | 2006-10-27 | 2013-11-19 | Cms Technologies Holdings Inc | Remoção de água e metanol de fluídos. |
US20110266220A1 (en) * | 2009-01-07 | 2011-11-03 | Cms Technologies Holdings, Inc. | Separations with highly selective fluoropolymer membranes |
CN102770468B (zh) * | 2009-12-18 | 2016-08-10 | 索尔维特殊聚合物意大利有限公司 | 用于生产氟弹性体的方法 |
EP2722350A1 (de) | 2012-10-19 | 2014-04-23 | Solvay Specialty Polymers Italy S.p.A. | Amorphes fluoriniertes Polymer |
CN103694395B (zh) * | 2013-12-09 | 2016-04-13 | 中昊晨光化工研究院有限公司 | 偏氟乙烯共聚物及其制备方法 |
EP3607033A1 (de) * | 2017-04-03 | 2020-02-12 | Solvay Specialty Polymers Italy S.p.A. | Arbeitsfluidzusammensetzungen |
KR102642656B1 (ko) * | 2018-05-18 | 2024-02-29 | 에이지씨 가부시키가이샤 | 함불소 폴리머의 제조 방법 및 함불소 이온 교환 폴리머의 제조 방법 |
JP7286919B2 (ja) * | 2018-06-11 | 2023-06-06 | Agc株式会社 | 成形体及び複合体 |
RU2690460C1 (ru) * | 2018-10-24 | 2019-06-03 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) | Мембрана для разделения метансодержащей смеси газов и способ её получения |
JP2023530810A (ja) * | 2020-04-13 | 2023-07-20 | クロミス ファイバーオプティクス インコーポレイテッド | 非晶質架橋フッ素コポリマーからなるガス分離物品ならびにその製造方法および使用方法 |
WO2022272134A1 (en) | 2021-06-24 | 2022-12-29 | Vici Transition, Inc. | Laminates and 3d printers |
US11485814B1 (en) | 2022-05-10 | 2022-11-01 | Sparkling Tycoon Limited | Perfluoro copolymers |
Family Cites Families (39)
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BE560454A (de) * | 1957-03-29 | |||
US3642742A (en) * | 1969-04-22 | 1972-02-15 | Du Pont | Tough stable tetrafluoroethylene-fluoroalkyl perfluorovinyl ether copolymers |
US3635926A (en) * | 1969-10-27 | 1972-01-18 | Du Pont | Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers |
US3865845A (en) * | 1971-02-24 | 1975-02-11 | Paul Raphael Resnick | Fluorinated dioxoles |
US3978030A (en) * | 1973-08-01 | 1976-08-31 | E. I. Du Pont De Nemours And Company | Polymers of fluorinated dioxoles |
US4029868A (en) * | 1976-03-10 | 1977-06-14 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene terpolymers |
US4042634A (en) * | 1976-03-15 | 1977-08-16 | E. I. Du Pont De Nemours And Company | Fluorocarbon separation process |
JPS5838707A (ja) * | 1981-08-20 | 1983-03-07 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | パ−フルオロ−2,2−ジメチル−1,3−ジオキソ−ルの無定形共重合体 |
US4429143A (en) * | 1981-09-28 | 1984-01-31 | E. I. Du Pont De Nemours & Co. | Cyclic monomers derived from trifluoropyruvate esters |
US4485250A (en) * | 1981-11-19 | 1984-11-27 | E. I. Du Pont De Nemours And Company | Perfluorodioxole and its polymers |
US4558141A (en) * | 1981-11-19 | 1985-12-10 | E. I. Du Pont De Nemours And Company | Perfluorodioxole and its polymers |
US4399264A (en) * | 1981-11-19 | 1983-08-16 | E. I. Du Pont De Nemours & Co. | Perfluorodioxole and its polymers |
JPS59166516A (ja) * | 1983-02-01 | 1984-09-19 | Daikin Ind Ltd | 含フツ素共重合体 |
JPS6187764A (ja) * | 1984-10-04 | 1986-05-06 | Daikin Ind Ltd | 海洋外装材 |
US4621116A (en) * | 1984-12-07 | 1986-11-04 | E. I. Du Pont De Nemours And Company | Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt |
EP0185241B1 (de) * | 1984-12-19 | 1990-01-24 | Ausimont, U.S.A. | Terpolymer aus Chlortrifluorethylen oder Tetrafluorethylen, Ethylen und Perfluorisoalkoxyperfluoralkylethylen |
JPS61187764A (ja) * | 1985-02-14 | 1986-08-21 | Shikoku Kakoki Co Ltd | 容器入り豆腐の製造法 |
IT1184149B (it) * | 1985-03-11 | 1987-10-22 | Montefluos Spa | Processo per la preparazione di fluorossi-alo-composti |
IT1189092B (it) * | 1986-04-29 | 1988-01-28 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri fluorurati |
IT1204903B (it) * | 1986-06-26 | 1989-03-10 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri florati |
JP2551005B2 (ja) * | 1987-06-24 | 1996-11-06 | ダイキン工業株式会社 | 変性ポリテトラフルオロエチレンフアインパウダ−及びその製造方法 |
US5176958A (en) * | 1987-06-24 | 1993-01-05 | Daikin Industries Ltd. | Modified polytetrafluoroethylene fine powder and process for preparing the same |
JP2538267B2 (ja) * | 1987-07-17 | 1996-09-25 | 日本メクトロン株式会社 | 含フッ素弾性状共重合体の製造法 |
US4879362A (en) * | 1987-12-31 | 1989-11-07 | E. I. Dupont De Nemours And Company | Modified polytetrafluoroethylene resins |
US4846006A (en) * | 1988-04-04 | 1989-07-11 | Digital Equipment Corporation | Method and apparatus for testing linear motion devices |
US5233058A (en) * | 1988-07-25 | 1993-08-03 | E. I. Du Pont De Nemours And Company | Partially fluorinated compounds and polymers |
US4908410A (en) * | 1989-01-27 | 1990-03-13 | E. I. Du Pont De Nemours And Company | Modified polytetrafluoroethylene fine powder and preparation thereof |
JPH07609B2 (ja) * | 1989-08-28 | 1995-01-11 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | ハロゲン化2,2―ビス(パーハロアルキル)―1,3―ジオキソラン調製する方法 |
US5026801A (en) * | 1989-09-18 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Polyhalodihydrodioxins and polyhalodioxoles |
US5102965A (en) * | 1990-03-01 | 1992-04-07 | E. I. Du Pont De Nemours And Company | Base resistant fluoroelastomers with improved processibility and curability |
IT1247684B (it) * | 1990-03-28 | 1994-12-30 | Selenia Ind Elettroniche | Timbro elettronico da collegare ad un calcolatore in grado di stampare anche su superfici fisse. |
JP2853254B2 (ja) * | 1990-04-04 | 1999-02-03 | ダイキン工業株式会社 | クロロトリフルオロエチレン/パーフルオロ(アルキルビニルエーテル)共重合体 |
JPH0649359Y2 (ja) * | 1990-06-05 | 1994-12-14 | 株式会社スタッフ | ファクシミリ玩具 |
IT1249208B (it) * | 1990-06-07 | 1995-02-20 | Ausimont Srl | Processo per la preparazione di 1,3-diossolani alogenati e nuovi prodotti ottenuti |
US5235074A (en) * | 1990-06-07 | 1993-08-10 | Ausimont S.P.A. | Halogenated 1,3-dioxolanes |
IT1244708B (it) * | 1991-02-07 | 1994-08-08 | Ausimont Spa | Processo di dealogenazione di 1,3-diossolani |
IT1244709B (it) * | 1991-02-07 | 1994-08-08 | Ausimont Spa | Processo per la preaparazione di 1.3-diossoli |
US5182342A (en) * | 1992-02-28 | 1993-01-26 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon solvents for fluoromonomer polymerization |
GB2268982B (en) * | 1992-07-21 | 1996-03-13 | Dowty Aerospace Gloucester | Bearings |
-
1993
- 1993-07-05 IT IT93MI001445A patent/IT1264662B1/it active IP Right Grant
-
1994
- 1994-06-24 DE DE69402473T patent/DE69402473T2/de not_active Expired - Lifetime
- 1994-06-24 AT AT94109782T patent/ATE151421T1/de active
- 1994-06-24 EP EP94109782A patent/EP0633257B1/de not_active Expired - Lifetime
- 1994-06-30 CA CA002127219A patent/CA2127219A1/en not_active Abandoned
- 1994-07-01 US US08/270,149 patent/US5498682A/en not_active Expired - Lifetime
- 1994-07-01 RU RU94022753A patent/RU2139866C1/ru active
- 1994-07-04 TW TW083106080A patent/TW273556B/zh not_active IP Right Cessation
- 1994-07-04 MX MX9405088A patent/MX9405088A/es not_active IP Right Cessation
- 1994-07-05 KR KR1019940016033A patent/KR100323579B1/ko not_active IP Right Cessation
- 1994-07-05 JP JP17603294A patent/JP3801661B2/ja not_active Expired - Lifetime
-
1995
- 1995-06-06 US US08/466,387 patent/US5495028A/en not_active Expired - Lifetime
- 1995-11-21 US US08/560,196 patent/US5571932A/en not_active Expired - Lifetime
-
1996
- 1996-08-07 US US08/694,509 patent/US5646223A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
RU2139866C1 (ru) | 1999-10-20 |
RU94022753A (ru) | 1996-05-10 |
KR950003283A (ko) | 1995-02-16 |
JPH0770107A (ja) | 1995-03-14 |
ATE151421T1 (de) | 1997-04-15 |
MX9405088A (es) | 1995-01-31 |
ITMI931445A0 (it) | 1993-07-05 |
DE69402473D1 (de) | 1997-05-15 |
US5498682A (en) | 1996-03-12 |
TW273556B (de) | 1996-04-01 |
EP0633257A1 (de) | 1995-01-11 |
JP3801661B2 (ja) | 2006-07-26 |
US5571932A (en) | 1996-11-05 |
CA2127219A1 (en) | 1995-01-06 |
ITMI931445A1 (it) | 1995-01-05 |
EP0633257B1 (de) | 1997-04-09 |
US5495028A (en) | 1996-02-27 |
IT1264662B1 (it) | 1996-10-04 |
US5646223A (en) | 1997-07-08 |
KR100323579B1 (ko) | 2005-09-13 |
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