DE69216654T2 - Olefinpolymerisationskatalysator - Google Patents
OlefinpolymerisationskatalysatorInfo
- Publication number
- DE69216654T2 DE69216654T2 DE69216654T DE69216654T DE69216654T2 DE 69216654 T2 DE69216654 T2 DE 69216654T2 DE 69216654 T DE69216654 T DE 69216654T DE 69216654 T DE69216654 T DE 69216654T DE 69216654 T2 DE69216654 T2 DE 69216654T2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- olefin
- polymerization
- titanium
- halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 23
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000002685 polymerization catalyst Substances 0.000 title claims abstract description 22
- -1 alkylaluminum halide Chemical class 0.000 claims abstract description 54
- 239000010936 titanium Substances 0.000 claims abstract description 32
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 30
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 28
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000007787 solid Substances 0.000 claims abstract description 22
- 150000002989 phenols Chemical class 0.000 claims abstract description 18
- 239000011777 magnesium Substances 0.000 claims abstract description 16
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 14
- 239000004711 α-olefin Substances 0.000 claims abstract description 14
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 7
- 229920000098 polyolefin Polymers 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 4
- 239000003054 catalyst Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 claims description 6
- 150000004820 halides Chemical class 0.000 claims description 5
- 150000001450 anions Chemical class 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- OFHCOWSQAMBJIW-AVJTYSNKSA-N alfacalcidol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C OFHCOWSQAMBJIW-AVJTYSNKSA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 description 22
- 239000003085 diluting agent Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 9
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
- 239000002002 slurry Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 150000004703 alkoxides Chemical class 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 239000002243 precursor Substances 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 5
- 150000005826 halohydrocarbons Chemical class 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 229910003074 TiCl4 Inorganic materials 0.000 description 4
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 4
- NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 229910019438 Mg(OC2H5)2 Inorganic materials 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002681 magnesium compounds Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- ASHGTJPOSUFTGB-UHFFFAOYSA-N 3-methoxyphenol Chemical compound COC1=CC=CC(O)=C1 ASHGTJPOSUFTGB-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 2
- 239000003701 inert diluent Substances 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- HFZWRUODUSTPEG-UHFFFAOYSA-N 2,4-dichlorophenol Chemical compound OC1=CC=C(Cl)C=C1Cl HFZWRUODUSTPEG-UHFFFAOYSA-N 0.000 description 1
- LMLAXOBGXCTWBJ-UHFFFAOYSA-N 2,4-diethylphenol Chemical compound CCC1=CC=C(O)C(CC)=C1 LMLAXOBGXCTWBJ-UHFFFAOYSA-N 0.000 description 1
- SLUKQUGVTITNSY-UHFFFAOYSA-N 2,6-di-tert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLUKQUGVTITNSY-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 1
- GZFGOTFRPZRKDS-UHFFFAOYSA-N 4-bromophenol Chemical compound OC1=CC=C(Br)C=C1 GZFGOTFRPZRKDS-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- JVVRCYWZTJLJSG-UHFFFAOYSA-N 4-dimethylaminophenol Chemical compound CN(C)C1=CC=C(O)C=C1 JVVRCYWZTJLJSG-UHFFFAOYSA-N 0.000 description 1
- RVDLHGSZWAELAU-UHFFFAOYSA-N 5-tert-butylthiophene-2-carbonyl chloride Chemical compound CC(C)(C)C1=CC=C(C(Cl)=O)S1 RVDLHGSZWAELAU-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical class [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
- 229920001585 atactic polymer Polymers 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- JGJWEXOAAXEJMW-UHFFFAOYSA-N dimethyl naphthalene-1,2-dicarboxylate Chemical compound C1=CC=CC2=C(C(=O)OC)C(C(=O)OC)=CC=C21 JGJWEXOAAXEJMW-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 description 1
- XBKBZMOLSULOEA-UHFFFAOYSA-L methylaluminum(2+);dibromide Chemical compound C[Al](Br)Br XBKBZMOLSULOEA-UHFFFAOYSA-L 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- OUULRIDHGPHMNQ-UHFFFAOYSA-N stibane Chemical class [SbH3] OUULRIDHGPHMNQ-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- LGROXJWYRXANBB-UHFFFAOYSA-N trimethoxy(propan-2-yl)silane Chemical compound CO[Si](OC)(OC)C(C)C LGROXJWYRXANBB-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/657,036 US5122494A (en) | 1991-02-19 | 1991-02-19 | Olefin polymerization catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69216654D1 DE69216654D1 (de) | 1997-02-27 |
| DE69216654T2 true DE69216654T2 (de) | 1997-05-07 |
Family
ID=24635594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69216654T Expired - Fee Related DE69216654T2 (de) | 1991-02-19 | 1992-02-18 | Olefinpolymerisationskatalysator |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US5122494A (enExample) |
| EP (1) | EP0500308B1 (enExample) |
| JP (1) | JP2774896B2 (enExample) |
| KR (1) | KR100205525B1 (enExample) |
| AT (1) | ATE147766T1 (enExample) |
| CA (1) | CA2061303C (enExample) |
| DE (1) | DE69216654T2 (enExample) |
| ES (1) | ES2100282T3 (enExample) |
| GR (1) | GR3022972T3 (enExample) |
| TW (1) | TW245723B (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5414063A (en) * | 1993-03-30 | 1995-05-09 | Huntsman Polypropylene Corporation | Process for the production of polypropylene |
| DE4323233A1 (de) * | 1993-07-12 | 1995-01-19 | Huels Chemische Werke Ag | Verfahren zur Herstellung von amorphen oder wenig kristallinen Co- oder Terpolymeren aus Olefinen |
| BE1008702A3 (fr) | 1994-09-22 | 1996-07-02 | Solvay | Procede de polymerisation d'olefines. |
| US5550194A (en) * | 1995-01-31 | 1996-08-27 | Shell Oil Company | Process for making graft block copolymers by grafting anionic polymer chains onto functionalized polyolefins |
| US5543458A (en) * | 1995-01-31 | 1996-08-06 | Shell Oil Company | Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones |
| US5693713A (en) * | 1995-05-30 | 1997-12-02 | Shell Oil Company | Process for making block graft copolymers by grafting halosilanes onto polyolefin/diene polymers |
| JP3823429B2 (ja) * | 1996-06-28 | 2006-09-20 | 住友化学株式会社 | 触媒系及びオレフィンの反応方法 |
| US6100351A (en) * | 1997-01-07 | 2000-08-08 | Huntsman Polymers Corporation | Olefin polymerization process and products thereof |
| US5948720A (en) * | 1997-01-07 | 1999-09-07 | Huntsman Polymers Corporation | Catalyst for the production of flexible polyolefin compositions, methods for making and using same, and products thereof |
| US6080818A (en) * | 1997-03-24 | 2000-06-27 | Huntsman Polymers Corporation | Polyolefin blends used for non-woven applications |
| US6100337A (en) | 1998-05-18 | 2000-08-08 | Shell Oil Company | Functionalized thermoplastic elastomer |
| PL364858A1 (en) * | 1999-06-30 | 2004-12-27 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed metal alkoxide complexes and polymerization catalysts made therefrom |
| TR200103809T2 (tr) | 1999-06-30 | 2002-05-21 | Union Carbide Chemicals & Plastics Technology Corporation | Magnezyum/geçiş metali alkoksid komplekslerinin yapılma yöntemleri ve bunlardan yapılan polimerizasyon katalizörleri |
| US6238426B1 (en) * | 1999-07-19 | 2001-05-29 | Light Sciences Corporation | Real-time monitoring of photodynamic therapy over an extended time |
| US6248831B1 (en) | 1999-12-06 | 2001-06-19 | Union Carbide Chemicals & Plastics Technology Corporation | High strength polyethylene film |
| US6358372B1 (en) * | 2000-07-11 | 2002-03-19 | Union Carbide Chemicals & Plastics Technology Corporation | Method of reducing formation of precipitates in solvent recovery system |
| KR100533442B1 (ko) | 2000-11-29 | 2005-12-06 | 릴라이언스 인더스트리즈 리미티드 | 저급 α-알켄 중합 불균질 고체 촉매, 이의 제조방법 및 이를 사용한 저급 α-알켄의 중합방법 |
| US6790319B2 (en) * | 2000-12-01 | 2004-09-14 | Mitsui Chemicals, Inc. | Method for recovering titanium compound, process for preparing titanium halide, and process for preparing catalyst for polymer production |
| US6969747B2 (en) * | 2002-01-25 | 2005-11-29 | Reliance Industries Limited | Olefin polymerization titanium catalyst |
| WO2005012371A2 (en) * | 2003-05-12 | 2005-02-10 | Union Carbide Chemicals & Plastics Technology Corporation | Process for control of polymer fines in a gas-phase polymerization |
| CN101001885B (zh) * | 2004-08-09 | 2011-05-25 | 陶氏环球技术公司 | 用于制备聚合物的负载型双(羟基芳基芳氧基)催化剂 |
| EP1778744B1 (en) | 2004-08-09 | 2015-03-25 | Union Carbide Chemicals & Plastics Technology LLC | Robust spray-dried ziegler-natta procatalyst and polymerization process employing same |
| JP2008509276A (ja) * | 2004-08-09 | 2008-03-27 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | スプレー乾燥された頑丈なチーグラー・ナッタプロカタリスト、およびこれを用いた重合方法 |
| EP2279215B1 (en) * | 2008-03-14 | 2011-11-16 | Saudi Basic Industries Corporation | A catalyst system and a process for the production of polyethylene in the presence of this catalyst system |
| US20110159287A1 (en) * | 2008-04-17 | 2011-06-30 | Saudi Basic Industries Corporation | Process for the Production of Ultra High Molecular Weight Polyethylene |
| EP2284199A1 (en) | 2009-08-14 | 2011-02-16 | Saudi Basic Industries Corporation | A catalyst system and a process for the production of polyethylene |
| US20160145359A1 (en) | 2013-06-29 | 2016-05-26 | Dow Global Technologies Llc | A polyethylene composition and process for polymerizing the same |
| ES2963034T3 (es) | 2013-08-19 | 2024-03-25 | Dow Global Technologies Llc | Método para producir un polímero a base de etileno en un procedimiento de polimerización usando un agente de autolimitación |
| WO2015073221A1 (en) | 2013-11-15 | 2015-05-21 | Dow Global Technologies Llc | A polyolefin composition and method of producing the same |
| CN104140482B (zh) * | 2014-08-06 | 2017-03-15 | 淄博新塑化工有限公司 | 一种用于烯烃聚合的催化剂添加剂及其催化剂 |
| US10370527B2 (en) | 2014-12-11 | 2019-08-06 | Dow Global Technologies Llc | Polyethylene compositions having living hinge properties |
| AR114620A1 (es) | 2017-12-15 | 2020-09-30 | Dow Global Technologies Llc | Formulación que contiene una composición de polietileno de alta densidad y cinta de goteo para microirrigación que la contiene |
| AR119038A1 (es) | 2019-06-11 | 2021-11-17 | Dow Global Technologies Llc | Tapas o cierres moldeados por inyección y métodos de estos |
| MX2023006540A (es) | 2020-12-21 | 2023-06-16 | Dow Global Technologies Llc | Composiciones de polietileno para aplicaciones de cierre. |
| WO2022165018A1 (en) | 2021-01-29 | 2022-08-04 | Dow Global Technologies Llc | Thermoplastic compositions comprising bimodal polyethylene and articles manufactured therefrom |
| AR128480A1 (es) | 2022-02-11 | 2024-05-15 | Dow Global Technologies Llc | Composiciones de polietileno de densidad media bimodal |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1464451A (en) * | 1973-09-08 | 1977-02-16 | Chubu Chem Inc | Solid catalytic complexes and their use in olefin polymerization |
| JPS56811A (en) * | 1979-06-18 | 1981-01-07 | Mitsui Petrochem Ind Ltd | Preparation of olefin polymer or copolymer |
| US4525554A (en) * | 1981-03-04 | 1985-06-25 | Mitsubishi Chemical Industries Ltd. | Process for polymerizing olefin |
| JPS5827704A (ja) * | 1981-08-12 | 1983-02-18 | Sumitomo Chem Co Ltd | ポリオレフインの製造方法 |
| US4472521A (en) * | 1982-12-20 | 1984-09-18 | Stauffer Chemical Company | Supported catalyst for polymerization of olefins |
| US4540679A (en) * | 1984-03-23 | 1985-09-10 | Amoco Corporation | Magnesium hydrocarbyl carbonate supports |
| US4728705A (en) * | 1986-02-28 | 1988-03-01 | Shell Oil Company | Olefin polymerization catalyst composition |
| US4710482A (en) * | 1986-06-18 | 1987-12-01 | Shell Oil Company | Olefin polymerization catalyst component |
| DE3780260T2 (de) * | 1986-11-20 | 1993-02-11 | Mitsubishi Chem Ind | Verfahren zur herstellung von olefinpolymeren. |
| FR2624122B1 (fr) * | 1987-12-03 | 1991-11-08 | Solvay | Procede pour la polymerisation des alpha-olefines, complexes catalytiques solides utilisables pour cette polymerisation et procede pour leur preparation |
| US5146028A (en) * | 1990-10-18 | 1992-09-08 | Shell Oil Company | Olefin polymerization catalyst and process of polymerization |
-
1991
- 1991-02-19 US US07/657,036 patent/US5122494A/en not_active Expired - Fee Related
-
1992
- 1992-02-17 CA CA002061303A patent/CA2061303C/en not_active Expired - Fee Related
- 1992-02-18 EP EP92301300A patent/EP0500308B1/en not_active Expired - Lifetime
- 1992-02-18 ES ES92301300T patent/ES2100282T3/es not_active Expired - Lifetime
- 1992-02-18 KR KR1019920002529A patent/KR100205525B1/ko not_active Expired - Fee Related
- 1992-02-18 DE DE69216654T patent/DE69216654T2/de not_active Expired - Fee Related
- 1992-02-18 AT AT92301300T patent/ATE147766T1/de not_active IP Right Cessation
- 1992-02-18 TW TW081101171A patent/TW245723B/zh active
- 1992-02-19 JP JP4032053A patent/JP2774896B2/ja not_active Expired - Fee Related
- 1992-03-16 US US07/852,044 patent/US5371157A/en not_active Expired - Fee Related
-
1997
- 1997-03-31 GR GR970400648T patent/GR3022972T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2774896B2 (ja) | 1998-07-09 |
| US5122494A (en) | 1992-06-16 |
| EP0500308A3 (en) | 1992-10-21 |
| ATE147766T1 (de) | 1997-02-15 |
| GR3022972T3 (en) | 1997-06-30 |
| CA2061303A1 (en) | 1992-08-20 |
| EP0500308A2 (en) | 1992-08-26 |
| KR100205525B1 (ko) | 1999-07-01 |
| KR920016475A (ko) | 1992-09-24 |
| JPH07173210A (ja) | 1995-07-11 |
| CA2061303C (en) | 2000-05-02 |
| EP0500308B1 (en) | 1997-01-15 |
| DE69216654D1 (de) | 1997-02-27 |
| TW245723B (enExample) | 1995-04-21 |
| US5371157A (en) | 1994-12-06 |
| ES2100282T3 (es) | 1997-06-16 |
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