GB1464451A - Solid catalytic complexes and their use in olefin polymerization - Google Patents
Solid catalytic complexes and their use in olefin polymerizationInfo
- Publication number
- GB1464451A GB1464451A GB3742574A GB3742574A GB1464451A GB 1464451 A GB1464451 A GB 1464451A GB 3742574 A GB3742574 A GB 3742574A GB 3742574 A GB3742574 A GB 3742574A GB 1464451 A GB1464451 A GB 1464451A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compound
- obu
- iodine
- olefin polymerization
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
- B01J2531/56—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1464451 Olefin polymerization catalyst component CHUBU CHEMICAL Inc 27 Aug 1974 [8 Sept 1973 28 Dec 1973(3)] 37425/74 Heading C3P [Also in Division B1] Olefins are polymerized in the presence of (A) an organometallic compound of Groups I to III and (B) the reaction product of (a) magnesium, (b) an organic compound containing an hydroxyl group, (c) an organic oxygen-containing transition metal (Groups IVa to VIa) compound and (d) a compound containing at least one aluminium-halogen group, e.g. organoaluminium halide or aluminium trihalide. The product (B) may be obtained using additional ingredients such as a triorganoaluminium compound, hydrocarbons (as diluents) and iodine (as catalyst). Examples refer to the homopolymerization of ethylene and to the copolymerization thereof with propylene or butene in the presence of hydrogen and of catalysts prepared from, for instance, (A) i-Bu 3 Al or Et 3 Al, and (B) (a) Mg, (b) EtOH, phenol, octylalcohol, stearylalcohol, cyclopentanol, ethylene glycol and triphenylsilanol, (c) T : (OBu) 4 , Zr(OBu) 4 and OV(OBu) 3 and (d) AlEtU 2 , AlEtCl and AlCl 3 , and in some cases iodine, iodine and butylchloride, and AlEt 3 additionally, using hexane as diluent.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10148973A JPS5215110B2 (en) | 1973-09-08 | 1973-09-08 | |
JP253874A JPS5650725B2 (en) | 1973-12-28 | 1973-12-28 | |
JP253774A JPS5650724B2 (en) | 1973-12-28 | 1973-12-28 | |
JP253674A JPS5650723B2 (en) | 1973-12-28 | 1973-12-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1464451A true GB1464451A (en) | 1977-02-16 |
Family
ID=27453652
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3742574A Expired GB1464451A (en) | 1973-09-08 | 1974-08-27 | Solid catalytic complexes and their use in olefin polymerization |
Country Status (5)
Country | Link |
---|---|
CA (1) | CA1018297A (en) |
EG (1) | EG11354A (en) |
GB (1) | GB1464451A (en) |
HK (1) | HK43477A (en) |
MY (1) | MY7800002A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4513095A (en) * | 1980-11-24 | 1985-04-23 | National Distillers And Chemical Corporation | Intermetallic compounds of polymeric transition metal oxide alkoxides and catalytic use thereof |
GB2160535A (en) * | 1984-06-22 | 1985-12-24 | Enichem Polimeri | Zirconium and/or hafnium based catalyst for the polymerization of unsaturated compounds |
EP0275317A1 (en) * | 1986-06-23 | 1988-07-27 | Tosoh Corporation | Process for producing stereoregular polyolefins |
EP0376188A2 (en) * | 1988-12-27 | 1990-07-04 | Tosoh Corporation | Process for producing a polyolefin |
EP0500308A2 (en) * | 1991-02-19 | 1992-08-26 | Shell Oil Company | Olefin polymerization catalyst |
-
1974
- 1974-08-27 GB GB3742574A patent/GB1464451A/en not_active Expired
- 1974-08-30 CA CA208,205A patent/CA1018297A/en not_active Expired
- 1974-09-07 EG EG37374A patent/EG11354A/en active
-
1977
- 1977-08-25 HK HK43477A patent/HK43477A/en unknown
-
1978
- 1978-12-31 MY MY7800002A patent/MY7800002A/en unknown
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4513095A (en) * | 1980-11-24 | 1985-04-23 | National Distillers And Chemical Corporation | Intermetallic compounds of polymeric transition metal oxide alkoxides and catalytic use thereof |
GB2160535A (en) * | 1984-06-22 | 1985-12-24 | Enichem Polimeri | Zirconium and/or hafnium based catalyst for the polymerization of unsaturated compounds |
EP0275317A1 (en) * | 1986-06-23 | 1988-07-27 | Tosoh Corporation | Process for producing stereoregular polyolefins |
EP0275317A4 (en) * | 1986-06-23 | 1988-10-20 | Tosoh Corp | Process for producing stereoregular polyolefins. |
EP0376188A2 (en) * | 1988-12-27 | 1990-07-04 | Tosoh Corporation | Process for producing a polyolefin |
EP0376188A3 (en) * | 1988-12-27 | 1991-09-11 | Tosoh Corporation | Process for producing a polyolefin |
US5162464A (en) * | 1988-12-27 | 1992-11-10 | Tosoh Corporation | Process for producing a polyolefin |
EP0500308A2 (en) * | 1991-02-19 | 1992-08-26 | Shell Oil Company | Olefin polymerization catalyst |
EP0500308A3 (en) * | 1991-02-19 | 1992-10-21 | Shell Oil Company | Olefin polymerization catalyst |
Also Published As
Publication number | Publication date |
---|---|
CA1018297A (en) | 1977-09-27 |
EG11354A (en) | 1977-09-30 |
HK43477A (en) | 1977-09-02 |
MY7800002A (en) | 1978-12-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
PCNP | Patent ceased through non-payment of renewal fee |