DE69203081T2 - Leitfähige Dickfilmpaste für Kraftfahrzeugfenster. - Google Patents
Leitfähige Dickfilmpaste für Kraftfahrzeugfenster.Info
- Publication number
- DE69203081T2 DE69203081T2 DE69203081T DE69203081T DE69203081T2 DE 69203081 T2 DE69203081 T2 DE 69203081T2 DE 69203081 T DE69203081 T DE 69203081T DE 69203081 T DE69203081 T DE 69203081T DE 69203081 T2 DE69203081 T2 DE 69203081T2
- Authority
- DE
- Germany
- Prior art keywords
- glass
- silver
- paste
- thick film
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011521 glass Substances 0.000 claims description 54
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 50
- 239000000203 mixture Substances 0.000 claims description 49
- 229910052709 silver Inorganic materials 0.000 claims description 45
- 239000004332 silver Substances 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 24
- 238000010304 firing Methods 0.000 claims description 21
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 21
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 17
- 239000004020 conductor Substances 0.000 claims description 16
- 239000000156 glass melt Substances 0.000 claims description 14
- 238000002844 melting Methods 0.000 claims description 14
- 230000008018 melting Effects 0.000 claims description 12
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 12
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 238000005245 sintering Methods 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 239000005357 flat glass Substances 0.000 claims description 5
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 238000007650 screen-printing Methods 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 2
- GEYXPJBPASPPLI-UHFFFAOYSA-N manganese(III) oxide Inorganic materials O=[Mn]O[Mn]=O GEYXPJBPASPPLI-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 description 41
- 230000000996 additive effect Effects 0.000 description 38
- 239000003086 colorant Substances 0.000 description 26
- 210000003298 dental enamel Anatomy 0.000 description 24
- 238000007792 addition Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 11
- 229910052718 tin Inorganic materials 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000004040 coloring Methods 0.000 description 7
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 7
- 230000001965 increasing effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000011572 manganese Substances 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 229910000679 solder Inorganic materials 0.000 description 6
- -1 Ag2SO4 and Ag2S Chemical class 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 4
- 229910000423 chromium oxide Inorganic materials 0.000 description 4
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 235000013980 iron oxide Nutrition 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910000367 silver sulfate Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000007832 Na2SO4 Substances 0.000 description 3
- 238000006124 Pilkington process Methods 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000005388 borosilicate glass Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000005329 float glass Substances 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 239000005751 Copper oxide Substances 0.000 description 2
- 239000004150 EU approved colour Substances 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- 239000001293 FEMA 3089 Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000005385 borate glass Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 description 2
- 229910000431 copper oxide Inorganic materials 0.000 description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 2
- 239000006259 organic additive Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229940100890 silver compound Drugs 0.000 description 2
- 150000003379 silver compounds Chemical class 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 229940116411 terpineol Drugs 0.000 description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 description 2
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910002477 CuCr2O4 Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 229910052946 acanthite Inorganic materials 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000002468 ceramisation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- JGDFBJMWFLXCLJ-UHFFFAOYSA-N copper chromite Chemical compound [Cu]=O.[Cu]=O.O=[Cr]O[Cr]=O JGDFBJMWFLXCLJ-UHFFFAOYSA-N 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- FULFYAFFAGNFJM-UHFFFAOYSA-N oxocopper;oxo(oxochromiooxy)chromium Chemical compound [Cu]=O.O=[Cr]O[Cr]=O FULFYAFFAGNFJM-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- FSJWWSXPIWGYKC-UHFFFAOYSA-M silver;silver;sulfanide Chemical compound [SH-].[Ag].[Ag+] FSJWWSXPIWGYKC-UHFFFAOYSA-M 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- RCIVOBGSMSSVTR-UHFFFAOYSA-L stannous sulfate Chemical compound [SnH2+2].[O-]S([O-])(=O)=O RCIVOBGSMSSVTR-UHFFFAOYSA-L 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- PGWMQVQLSMAHHO-UHFFFAOYSA-N sulfanylidenesilver Chemical class [Ag]=S PGWMQVQLSMAHHO-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000012956 testing procedure Methods 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 229910000375 tin(II) sulfate Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
- H01B1/16—Conductive material dispersed in non-conductive inorganic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/09—Use of materials for the conductive, e.g. metallic pattern
- H05K1/092—Dispersed materials, e.g. conductive pastes or inks
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Glass Compositions (AREA)
- Conductive Materials (AREA)
- Parts Printed On Printed Circuit Boards (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/801,918 US5302557A (en) | 1991-12-03 | 1991-12-03 | Automotive glass thick film conductor paste |
| US07/847,340 US5296413A (en) | 1991-12-03 | 1992-03-06 | Automotive glass thick film conductor paste |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69203081D1 DE69203081D1 (de) | 1995-07-27 |
| DE69203081T2 true DE69203081T2 (de) | 1996-01-04 |
Family
ID=27122396
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69203081T Expired - Fee Related DE69203081T2 (de) | 1991-12-03 | 1992-11-20 | Leitfähige Dickfilmpaste für Kraftfahrzeugfenster. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5296413A (enExample) |
| EP (1) | EP0545166B1 (enExample) |
| JP (1) | JP2582514B2 (enExample) |
| KR (1) | KR950007703B1 (enExample) |
| CN (1) | CN1036739C (enExample) |
| DE (1) | DE69203081T2 (enExample) |
| MY (1) | MY108144A (enExample) |
| TW (1) | TW231356B (enExample) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3173679B2 (ja) * | 1992-12-21 | 2001-06-04 | セントラル硝子株式会社 | 車輌窓ガラス用セラミックカラー組成物及びそれを用いた車輌窓ガラスの製法 |
| EP0642473A1 (fr) * | 1993-03-26 | 1995-03-15 | Saint-Gobain Vitrage International | Procede de fabrication d'un vitrage emaille feuillete et composition d'email utilisee |
| FR2705335B1 (fr) * | 1993-05-13 | 1995-07-21 | Saint Gobain Vitrage Int | Composition pour l'émaillage de substrats en verre, application aux vitrages feuilletés et produits obtenus. |
| FR2713623B1 (fr) * | 1993-12-08 | 1997-05-09 | Cerdec France Sa | Paillettes et leur utilisation pour la décoration du verre, de la porcelaine et de la céramique dont les parois sont verticales. |
| JPH0899610A (ja) * | 1994-09-30 | 1996-04-16 | Tsutsunaka Plast Ind Co Ltd | 防曇性能を有する合成樹脂製窓材およびその製造方法 |
| GB9518033D0 (en) * | 1995-09-05 | 1995-11-08 | Cookson Matthey Ceramics Plc | Composition |
| FR2757150B1 (fr) * | 1996-12-12 | 1999-01-22 | Saint Gobain Vitrage | Procede d'emaillage de substrats en verre, composition d'email utilisee et produits obtenus |
| US5783507A (en) * | 1997-01-16 | 1998-07-21 | Cerdec Corporation | Partially crystallizing lead-free enamel composition for automobile glass |
| EP0895252A1 (en) * | 1997-07-29 | 1999-02-03 | E.I. Du Pont De Nemours And Company | Thick film silver termination composition |
| JP3484983B2 (ja) * | 1998-07-28 | 2004-01-06 | 株式会社村田製作所 | 導電性ペースト及びガラス回路基板 |
| US6287996B1 (en) * | 1998-09-14 | 2001-09-11 | Asahi Glass Company Ltd. | Ceramic color composition and process for producing a curved glass plate |
| US6217821B1 (en) * | 1999-06-02 | 2001-04-17 | E. I. Du Pont De Nemours And Company | Method of forming distortion-free circuits |
| DE19939737A1 (de) * | 1999-08-21 | 2001-02-22 | Dmc2 Degussa Metals Catalysts | Verfahren zur Herstellung schwarzer recyclingfähiger Glasemails, Glasfarbe hierfür und damit emaillierte Glassubstrate |
| JP4461542B2 (ja) * | 2000-01-20 | 2010-05-12 | 旭硝子株式会社 | 車両用窓ガラス |
| US7157023B2 (en) * | 2001-04-09 | 2007-01-02 | E. I. Du Pont De Nemours And Company | Conductor compositions and the use thereof |
| JP3932858B2 (ja) | 2001-10-23 | 2007-06-20 | 株式会社村田製作所 | 導電性ペースト |
| GB0307547D0 (en) * | 2003-04-01 | 2003-05-07 | Du Pont | Conductor composition V |
| US7138347B2 (en) * | 2003-08-14 | 2006-11-21 | E. I. Du Pont De Nemours And Company | Thick-film conductor paste for automotive glass |
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| KR100899197B1 (ko) * | 2007-04-18 | 2009-05-26 | 제일모직주식회사 | 착색 유리프릿을 포함하는 전극 형성용 페이스트 조성물 및이를 이용하여 제조된 전극을 포함하는 플라즈마디스플레이 패널 |
| CN101816044A (zh) * | 2007-10-18 | 2010-08-25 | E.I.内穆尔杜邦公司 | 导电组合物以及用于制造半导体装置的方法：含镁添加剂 |
| CN101816045A (zh) * | 2007-10-18 | 2010-08-25 | E.I.内穆尔杜邦公司 | 无铅导电组合物以及用于制造半导体装置的方法:含镁添加剂 |
| WO2009101919A1 (ja) * | 2008-02-13 | 2009-08-20 | Nippon Sheet Glass Company, Limited | 導電性セラミックス焼結体付き窓ガラス |
| US20100167032A1 (en) | 2008-12-29 | 2010-07-01 | E.I.Du Pont De Nemours And Company | Front electrode for pdp |
| CN101462832B (zh) * | 2009-01-12 | 2013-07-17 | 付明 | 一种环保型汽车挡风玻璃除霜加热线银浆料 |
| JPWO2010150832A1 (ja) * | 2009-06-25 | 2012-12-10 | 日本板硝子株式会社 | 導電性セラミックス焼結体付き窓ガラス及びその製造方法 |
| CN102013282A (zh) * | 2010-12-21 | 2011-04-13 | 昆明理工大学 | 玻璃除雾加热线专用银浆及其制备方法 |
| JP6408695B2 (ja) | 2014-08-28 | 2018-10-17 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | 銅含有導電性ペースト、及び銅含有導電性ペーストから作製された電極 |
| WO2016029398A1 (en) | 2014-08-28 | 2016-03-03 | E.I. Du Pont De Nemours And Company | Solar cells with copper electrodes |
| US9951231B2 (en) | 2014-08-28 | 2018-04-24 | E I Du Pont De Nemours And Company | Copper-containing conductive pastes and electrodes made therefrom |
| EP3076401A1 (en) | 2015-03-27 | 2016-10-05 | Heraeus Deutschland GmbH & Co. KG | Electro-conductive pastes comprising a metal compound |
| KR20170132837A (ko) | 2015-03-27 | 2017-12-04 | 헤레우스 도이칠란트 게엠베하 운트 코. 카게 | 산화물 첨가제를 포함하는 전기-전도성 페이스트 |
| WO2017006714A1 (ja) * | 2015-07-03 | 2017-01-12 | 株式会社村田製作所 | 導電性ペースト、及びガラス物品 |
| CN106494105A (zh) * | 2015-09-07 | 2017-03-15 | 东莞奔迅汽车玻璃有限公司 | 一种钢化玻璃银线印刷方法和一种钢化玻璃 |
| CN109785991B (zh) * | 2017-11-10 | 2020-07-31 | 上海宝银电子材料有限公司 | 一种客车前挡玻璃用的抗氧化银浆及其制备方法 |
| CN109785992A (zh) * | 2017-11-10 | 2019-05-21 | 上海宝银电子材料有限公司 | 一种汽车玻璃用防高温扩散银浆及其制备方法 |
| CN115206583B (zh) * | 2022-08-26 | 2025-03-25 | 厦门翰森达电子科技有限公司 | 汽车玻璃用抗氧化导电银浆及其应用 |
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| DE1957622A1 (de) * | 1969-11-15 | 1971-05-27 | Siemens Ag | Hochtemperaturbestaendige Emailschutzschicht |
| US3844796A (en) * | 1969-12-08 | 1974-10-29 | Owens Illinois Inc | Colored glass compositions |
| US3775154A (en) * | 1971-08-12 | 1973-11-27 | Corning Glass Works | Decorating glass-ceramic materials |
| US4029605A (en) * | 1975-12-08 | 1977-06-14 | Hercules Incorporated | Metallizing compositions |
| JPS5333752A (en) * | 1976-09-09 | 1978-03-29 | Matsushita Electric Works Ltd | Electric toothbrush |
| CA1129560A (en) * | 1978-09-01 | 1982-08-10 | E. I. Du Pont De Nemours And Company | Thick film silver conductor compositions for fine line electrodes |
| US4357742A (en) * | 1980-05-27 | 1982-11-09 | The Bendix Corporation | Electric brush contact forming apparatus |
| US4446059A (en) * | 1982-04-15 | 1984-05-01 | E. I. Du Pont De Nemours & Co. | Conductor compositions |
| US4623389A (en) * | 1985-04-22 | 1986-11-18 | Ppg Industries, Inc. | Electroconductive silver composition |
| US4728781A (en) * | 1985-04-22 | 1988-03-01 | Ppg Industries, Inc. | Heated backlights |
| US4939090A (en) * | 1986-05-06 | 1990-07-03 | United States Of America As Represented By The Secretary Of Agriculture | Method of reacting immiscible liquids with a catalyst-impregnated membrane |
| JPH01242441A (ja) * | 1988-03-24 | 1989-09-27 | Alps Electric Co Ltd | 接合用ガラス組成物 |
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| JPH01258304A (ja) * | 1988-04-06 | 1989-10-16 | Dai Ichi Kogyo Seiyaku Co Ltd | 導電性ペースト |
| JPH01258303A (ja) * | 1988-04-06 | 1989-10-16 | Dai Ichi Kogyo Seiyaku Co Ltd | 導電性ペースト |
| JPH0777085B2 (ja) * | 1989-02-28 | 1995-08-16 | 株式会社村田製作所 | フェライトチップ部品 |
| EP0466344B1 (en) * | 1990-07-12 | 1995-12-13 | Ford Motor Company Limited | A ceramic paint composition |
-
1992
- 1992-03-06 US US07/847,340 patent/US5296413A/en not_active Expired - Fee Related
- 1992-11-20 EP EP92119772A patent/EP0545166B1/en not_active Expired - Lifetime
- 1992-11-20 DE DE69203081T patent/DE69203081T2/de not_active Expired - Fee Related
- 1992-11-26 MY MYPI92002160A patent/MY108144A/en unknown
- 1992-12-02 TW TW081109664A patent/TW231356B/zh active
- 1992-12-02 KR KR1019920023030A patent/KR950007703B1/ko not_active Expired - Fee Related
- 1992-12-02 JP JP4323058A patent/JP2582514B2/ja not_active Expired - Lifetime
- 1992-12-03 CN CN92114295A patent/CN1036739C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5296413A (en) | 1994-03-22 |
| TW231356B (enExample) | 1994-10-01 |
| MY108144A (en) | 1996-08-30 |
| KR950007703B1 (ko) | 1995-07-14 |
| JP2582514B2 (ja) | 1997-02-19 |
| EP0545166A1 (en) | 1993-06-09 |
| CN1072940A (zh) | 1993-06-09 |
| CN1036739C (zh) | 1997-12-17 |
| DE69203081D1 (de) | 1995-07-27 |
| EP0545166B1 (en) | 1995-06-21 |
| JPH05290623A (ja) | 1993-11-05 |
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