DE60322684D1 - Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren - Google Patents
Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahrenInfo
- Publication number
- DE60322684D1 DE60322684D1 DE60322684T DE60322684T DE60322684D1 DE 60322684 D1 DE60322684 D1 DE 60322684D1 DE 60322684 T DE60322684 T DE 60322684T DE 60322684 T DE60322684 T DE 60322684T DE 60322684 D1 DE60322684 D1 DE 60322684D1
- Authority
- DE
- Germany
- Prior art keywords
- metal complexes
- polymerization processes
- substituted indenyl
- indenyl ligands
- ligands
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36470602P | 2002-03-14 | 2002-03-14 | |
PCT/US2003/006315 WO2003078483A1 (en) | 2002-03-14 | 2003-03-03 | Substituted indenyl metal complexes and polymerization process |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60322684D1 true DE60322684D1 (de) | 2008-09-18 |
Family
ID=28041952
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60322684T Expired - Lifetime DE60322684D1 (de) | 2002-03-14 | 2003-03-03 | Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren |
Country Status (13)
Country | Link |
---|---|
US (1) | US7098356B2 (de) |
EP (1) | EP1487886B1 (de) |
JP (2) | JP4624679B2 (de) |
KR (2) | KR101002620B1 (de) |
CN (1) | CN100484973C (de) |
AR (1) | AR038976A1 (de) |
AT (1) | ATE403684T1 (de) |
AU (1) | AU2003216476A1 (de) |
CA (1) | CA2477776C (de) |
DE (1) | DE60322684D1 (de) |
ES (1) | ES2307956T3 (de) |
SA (1) | SA03240063B1 (de) |
WO (1) | WO2003078483A1 (de) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE403684T1 (de) * | 2002-03-14 | 2008-08-15 | Dow Global Technologies Inc | Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren |
BRPI0508173B1 (pt) | 2004-03-17 | 2016-03-15 | Dow Global Technologies Inc | copolímeros em multibloco, polímero, copolímero, um derivado funcional, mistura homogênea de polímero, processo para a preparação de um copolímero em multibloco contendo propileno e processo para preparar um copolímero em multibloco contendo 4-metil-1-penteno |
RU2375381C2 (ru) | 2004-03-17 | 2009-12-10 | Дау Глобал Текнолоджиз Инк. | Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина |
JP5159302B2 (ja) | 2004-03-17 | 2013-03-06 | ダウ グローバル テクノロジーズ エルエルシー | エチレンコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
WO2006007094A2 (en) | 2004-06-16 | 2006-01-19 | Dow Global Technologies Inc. | Technique for selecting polymerization modifiers |
CA2600318A1 (en) | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation |
US9410009B2 (en) | 2005-03-17 | 2016-08-09 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
CN101142246B (zh) | 2005-03-17 | 2011-05-25 | 陶氏环球技术公司 | 用于形成有规立构/无规立构多嵌段共聚物的包含梭移剂的催化剂组合物 |
RU2008114492A (ru) | 2005-09-15 | 2009-10-20 | Дау Глобал Текнолоджиз Инк. (Us) | Контроль структуры и молекулярно-массового распределения полимеров посредством передающего по принципу челнока агента с множеством центров |
ITMI20070877A1 (it) | 2007-05-02 | 2008-11-03 | Dow Global Technologies Inc | Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari |
ITMI20070878A1 (it) | 2007-05-02 | 2008-11-03 | Dow Global Technologies Inc | Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali |
SG177774A1 (en) | 2009-07-29 | 2012-03-29 | Dow Global Technologies Llc | Multifunctional chain shuttling agents |
WO2011102990A2 (en) | 2010-02-19 | 2011-08-25 | Dow Global Technologies Llc | Process for polymerizing an olefin monomer and catalyst therefor |
KR101827023B1 (ko) | 2010-02-19 | 2018-02-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 금속-리간드 착체 및 촉매 |
WO2012103080A1 (en) | 2011-01-26 | 2012-08-02 | Dow Global Technologies Llc | Process for making a polyolefin-polysiloxane block copolymer |
US9296836B2 (en) | 2011-05-12 | 2016-03-29 | Dow Global Technologies Llc | Non-cyclopentadienyl-based chromium catalysts for olefin polymerization |
KR101212637B1 (ko) | 2011-06-09 | 2012-12-14 | 에스케이종합화학 주식회사 | 신규한 사이클로펜타[b]플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
CN103890023B (zh) | 2011-10-24 | 2016-11-16 | 三菱化学株式会社 | 热塑性弹性体组合物及其制造方法 |
KR101774615B1 (ko) * | 2013-12-02 | 2017-09-04 | 주식회사 엘지화학 | 인덴기를 갖는 메탈로센형 촉매 및 이를 이용한 올레핀 중합체의 제조방법 |
CN108026115B (zh) | 2015-09-30 | 2021-11-09 | 陶氏环球技术有限责任公司 | 可用于链穿梭的多头或双头组合物及其制备方法 |
EP3519456A1 (de) | 2016-09-30 | 2019-08-07 | Dow Global Technologies Llc | Gekappte mehr- oder doppelköpfige zusammensetzungen für kettenübertragung und verfahren zur herstellung davon |
EP3519474A1 (de) | 2016-09-30 | 2019-08-07 | Dow Global Technologies LLC | Verfahren zur herstellung von mehrfach- oder doppelkopfzusammensetzungen zur kettenübertragung |
EP3519455B1 (de) | 2016-09-30 | 2024-04-10 | Dow Global Technologies Llc | Mehr- oder doppelköpfige zusammensetzungen für kettenübertragung und verfahren zur herstellung davon |
KR20190123342A (ko) | 2017-03-15 | 2019-10-31 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중-블록 공중합체 형성을 위한 촉매 시스템 |
BR112019019129A2 (pt) | 2017-03-15 | 2020-04-14 | Dow Global Technologies Llc | sistema catalisador para formação de copolímero de múltiplos blocos |
WO2018170138A1 (en) | 2017-03-15 | 2018-09-20 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
CN110603274B (zh) | 2017-03-15 | 2022-09-30 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
US20200247936A1 (en) | 2017-03-15 | 2020-08-06 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
KR102643986B1 (ko) * | 2017-09-29 | 2024-03-07 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
WO2019064247A1 (ko) * | 2017-09-29 | 2019-04-04 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
SG11202009138QA (en) | 2018-03-19 | 2020-10-29 | Dow Global Technologies Llc | Silicon-terminated organo-metal compounds and processes for preparing the same |
US20220017657A1 (en) * | 2019-09-27 | 2022-01-20 | Lg Chem, Ltd. | Hybrid Supported Catalyst and Method of Preparing Polyolefin Using the Same |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
JP2545006B2 (ja) * | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
US5470993A (en) * | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
US5486632A (en) * | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
US5541349A (en) * | 1994-09-12 | 1996-07-30 | The Dow Chemical Company | Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom |
CN1098857C (zh) * | 1995-10-27 | 2003-01-15 | 陶氏化学公司 | 含有取代茚基的金属配合物和烯烃聚合方法 |
DE19543427C2 (de) | 1995-11-21 | 2003-01-30 | Infineon Technologies Ag | Chipmodul, insbesondere zum Einbau in eine Chipkarte |
JP2000516608A (ja) * | 1996-08-08 | 2000-12-12 | ザ ダウ ケミカル カンパニー | 2―ヘテロ原子置換シクロペンタジエニル含有金属錯体及びオレフィン重合方法 |
US6015868A (en) * | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
US5965756A (en) * | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
WO1998027102A1 (en) * | 1996-12-19 | 1998-06-25 | The Dow Chemical Company | 3-aryl substituted indenyl containing metal complexes and polymerization process |
KR100488833B1 (ko) * | 1997-04-30 | 2005-05-11 | 듀폰 다우 엘라스토마스 엘. 엘. 씨. | 에틸렌/알파-올레핀/디엔 공중합체 및 그의 제조 방법 |
US6150297A (en) * | 1997-09-15 | 2000-11-21 | The Dow Chemical Company | Cyclopentaphenanthrenyl metal complexes and polymerization process |
ATE403684T1 (de) * | 2002-03-14 | 2008-08-15 | Dow Global Technologies Inc | Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren |
-
2003
- 2003-03-03 AT AT03744610T patent/ATE403684T1/de not_active IP Right Cessation
- 2003-03-03 EP EP03744610A patent/EP1487886B1/de not_active Expired - Lifetime
- 2003-03-03 JP JP2003576482A patent/JP4624679B2/ja not_active Expired - Fee Related
- 2003-03-03 ES ES03744610T patent/ES2307956T3/es not_active Expired - Lifetime
- 2003-03-03 US US10/503,828 patent/US7098356B2/en not_active Expired - Lifetime
- 2003-03-03 AU AU2003216476A patent/AU2003216476A1/en not_active Abandoned
- 2003-03-03 WO PCT/US2003/006315 patent/WO2003078483A1/en active Application Filing
- 2003-03-03 KR KR1020047014479A patent/KR101002620B1/ko active IP Right Grant
- 2003-03-03 CA CA2477776A patent/CA2477776C/en not_active Expired - Fee Related
- 2003-03-03 KR KR1020107019516A patent/KR20100101024A/ko not_active Application Discontinuation
- 2003-03-03 CN CNB038060108A patent/CN100484973C/zh not_active Expired - Fee Related
- 2003-03-03 DE DE60322684T patent/DE60322684D1/de not_active Expired - Lifetime
- 2003-03-14 AR ARP030100906A patent/AR038976A1/es unknown
- 2003-04-02 SA SA03240063A patent/SA03240063B1/ar unknown
-
2010
- 2010-03-17 JP JP2010061305A patent/JP2010189396A/ja not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
CA2477776C (en) | 2011-11-15 |
JP2010189396A (ja) | 2010-09-02 |
WO2003078483A1 (en) | 2003-09-25 |
KR101002620B1 (ko) | 2010-12-21 |
KR20040091742A (ko) | 2004-10-28 |
ES2307956T3 (es) | 2008-12-01 |
AR038976A1 (es) | 2005-02-02 |
CN100484973C (zh) | 2009-05-06 |
CA2477776A1 (en) | 2003-09-25 |
SA03240063B1 (ar) | 2007-12-29 |
ATE403684T1 (de) | 2008-08-15 |
JP4624679B2 (ja) | 2011-02-02 |
KR20100101024A (ko) | 2010-09-15 |
US20050143536A1 (en) | 2005-06-30 |
US7098356B2 (en) | 2006-08-29 |
EP1487886B1 (de) | 2008-08-06 |
AU2003216476A1 (en) | 2003-09-29 |
CN1643004A (zh) | 2005-07-20 |
EP1487886A1 (de) | 2004-12-22 |
JP2005519969A (ja) | 2005-07-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ATE403684T1 (de) | Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren | |
DE60204686D1 (de) | 3-arylsubstituierte zyklopentadienyl-metal-komplexe und polymerisationsverfahren | |
DE60005185D1 (de) | Übergangsmetallkomplexe und olefin-polymerisationsverfahren | |
DE60001558D1 (de) | Di- und tri-heteroatom-substituierte metall-indenylkomplexe | |
DE60203235D1 (de) | Polymere Verbindung und ihre Verwendung in einer Elektrolumineszenzvorrichtung | |
FI20020195A (fi) | Metallikomplekseja, jotka sisältävät 2,6-diasyylipyridiiniligandin, ja niiden käyttö eteenin polymerointiin | |
DE60214640D1 (de) | Mikroprozessor mit verbesserten Taskverwaltungs- und Tabellenverwaltungsvorrichtungen | |
IL158865A0 (en) | Luminescent lanthanide complexes with imine ligands and devices made with such complexes | |
DE60234637D1 (de) | Ck und zusammenbauverfahren dafür | |
DE60333603D1 (de) | Mobile Vorrichtung und mobile Telefonvorrichtung mit Abbildungsfunktion | |
DE60335933D1 (de) | Polymere Verbindung und ihre Verwendung in einer Elektrolumineszenzvorrichtung | |
ATE550017T1 (de) | Lasofoxifen-tablette und ihre ummantelung | |
DE60221872D1 (de) | Kugelförmiges monodisperses metallteilchen | |
ATE227729T1 (de) | Substituierte indenyl enthaltende metallkomplexe und olefinpolymerisierungsverfahren. | |
DE60230645D1 (de) | Metallischer anschlusskontakt mit geschwächtem teil | |
DE60304648D1 (de) | Pumpe mit einem Einlass und zwei Auslässen | |
ATE409258T1 (de) | Flächiges metallelement und profilelement | |
NO995294D0 (no) | Olefinpolymerer fremstilt med substituerte indenylinneholdende metalkomplekser | |
ATE465810T1 (de) | Monocyclopentadienylkomplexe | |
DE60103083D1 (de) | Dreizähnige liganden und deren komplexe mit übergangsmetallen | |
DE10294477D2 (de) | Metallische Komponente mit Schutzbeschichtung | |
DE69910499D1 (de) | Metalldichtung mit zwei Halbwülsten | |
AU2003255268A8 (en) | Low work function metal complexes and uses thereof | |
DE50014688D1 (de) | Bleichaktive Metallkomplexe | |
DE60230089D1 (de) | Acryl-gummilatex mit bimodaler teilchenverteilung |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |