ATE403684T1 - Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren - Google Patents

Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren

Info

Publication number
ATE403684T1
ATE403684T1 AT03744610T AT03744610T ATE403684T1 AT E403684 T1 ATE403684 T1 AT E403684T1 AT 03744610 T AT03744610 T AT 03744610T AT 03744610 T AT03744610 T AT 03744610T AT E403684 T1 ATE403684 T1 AT E403684T1
Authority
AT
Austria
Prior art keywords
metal complexes
polymerization processes
substituted indenyl
indenyl ligands
ligands
Prior art date
Application number
AT03744610T
Other languages
English (en)
Inventor
David Graf
Jorge Soto
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Application granted granted Critical
Publication of ATE403684T1 publication Critical patent/ATE403684T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT03744610T 2002-03-14 2003-03-03 Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren ATE403684T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US36470602P 2002-03-14 2002-03-14

Publications (1)

Publication Number Publication Date
ATE403684T1 true ATE403684T1 (de) 2008-08-15

Family

ID=28041952

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03744610T ATE403684T1 (de) 2002-03-14 2003-03-03 Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren

Country Status (13)

Country Link
US (1) US7098356B2 (de)
EP (1) EP1487886B1 (de)
JP (2) JP4624679B2 (de)
KR (2) KR101002620B1 (de)
CN (1) CN100484973C (de)
AR (1) AR038976A1 (de)
AT (1) ATE403684T1 (de)
AU (1) AU2003216476A1 (de)
CA (1) CA2477776C (de)
DE (1) DE60322684D1 (de)
ES (1) ES2307956T3 (de)
SA (1) SA03240063B1 (de)
WO (1) WO2003078483A1 (de)

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ATE403684T1 (de) * 2002-03-14 2008-08-15 Dow Global Technologies Inc Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren
BRPI0508173B1 (pt) 2004-03-17 2016-03-15 Dow Global Technologies Inc copolímeros em multibloco, polímero, copolímero, um derivado funcional, mistura homogênea de polímero, processo para a preparação de um copolímero em multibloco contendo propileno e processo para preparar um copolímero em multibloco contendo 4-metil-1-penteno
CN1934150A (zh) 2004-03-17 2007-03-21 陶氏环球技术公司 用于形成乙烯共聚物的包括穿梭剂的催化剂组合物
EP2221329B1 (de) 2004-03-17 2014-11-26 Dow Global Technologies LLC Katalysatorzusammensetzung mit einem Ketten-Übertragungsreagens zur Herstellung von Ethylen-Multiblockcopolymeren
JP5188178B2 (ja) 2004-06-16 2013-04-24 ダウ グローバル テクノロジーズ エルエルシー 重合調整剤を選択するための技術
BRPI0609849B1 (pt) 2005-03-17 2017-05-09 Dow Global Technologies Inc copolímero multibloco, processo de solução contínuo para preparar um copolímero multibloco, derivado funcionalizado, mistura polimérica homogênea e polímero
EP3424966B1 (de) 2005-03-17 2020-05-27 Dow Global Technologies Llc Katalysatorzusammensetzung mit transportwirkstoff zur taktischen/ataktischen multiblock-copolymer-formierung
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
AR058448A1 (es) 2005-09-15 2008-02-06 Dow Global Technologies Inc Control de arquitectura del polimero y distribucoin de peso molecular va el agente de transferencia multi- centrado
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
BR112012001942B1 (pt) 2009-07-29 2019-10-22 Dow Global Technologies Llc agente de permuta de cadeia multifuncional, processo para preparar um agente de permuta de cadeia multifuncional, processo para preparar uma composição multifuncional, composição multifuncional, processo para preparar um agente de permuta de cadeia multifuncional contendo poli-radical poliolefina, poliolefina telequélica, processo para preparar uma poliolefina com funcionalidade terminal e separador de bateria
CN102822180B (zh) 2010-02-19 2016-06-15 陶氏环球技术有限责任公司 金属配体配合物和催化剂
SG183310A1 (en) 2010-02-19 2012-09-27 Dow Global Technologies Llc Process for polymerizing an olefin monomer and catalyst therefor
WO2012103080A1 (en) 2011-01-26 2012-08-02 Dow Global Technologies Llc Process for making a polyolefin-polysiloxane block copolymer
US9296836B2 (en) 2011-05-12 2016-03-29 Dow Global Technologies Llc Non-cyclopentadienyl-based chromium catalysts for olefin polymerization
KR101212637B1 (ko) 2011-06-09 2012-12-14 에스케이종합화학 주식회사 신규한 사이클로펜타［ｂ］플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR101858787B1 (ko) 2011-10-24 2018-05-16 미쯔비시 케미컬 주식회사 열가소성 엘라스토머 조성물 및 그 제조 방법
KR101774615B1 (ko) * 2013-12-02 2017-09-04 주식회사 엘지화학 인덴기를 갖는 메탈로센형 촉매 및 이를 이용한 올레핀 중합체의 제조방법
EP3356374B1 (de) 2015-09-30 2025-09-24 Dow Global Technologies LLC Zwei- oder mehrendige kompositionen geeignet für revesible kettenübertragung und verfahren zur deren hertellung
TW201840572A (zh) 2016-09-30 2018-11-16 美商陶氏全球科技有限責任公司 適用於鏈梭移之多頭或雙頭組合物及其製備方法
EP4435013A3 (de) 2016-09-30 2024-12-25 Dow Global Technologies LLC Verfahren zur herstellung von mehr- oder doppelköpfigen zusammensetzungen für kettenübertragung
TWI756272B (zh) 2016-09-30 2022-03-01 美商陶氏全球科技有限責任公司 適用於鏈梭移之封端多頭或雙頭組合物及其製備方法
KR102710284B1 (ko) 2017-03-15 2024-09-27 다우 글로벌 테크놀로지스 엘엘씨 다중-블록 공중합체 형성을 위한 촉매 시스템
CN110612315B (zh) 2017-03-15 2022-08-26 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
EP3596146B1 (de) 2017-03-15 2023-07-19 Dow Global Technologies LLC Katalysatorsystem für mehrblockcopolymerbildung
CN110582518B (zh) 2017-03-15 2022-08-09 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
US20200247936A1 (en) 2017-03-15 2020-08-06 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
KR102643986B1 (ko) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
WO2019064247A1 (ko) * 2017-09-29 2019-04-04 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
JP2021518463A (ja) 2018-03-19 2021-08-02 ダウ グローバル テクノロジーズ エルエルシー シリコン終端化有機金属化合物およびそれを調製するためのプロセス
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Also Published As

Publication number Publication date
AU2003216476A1 (en) 2003-09-29
CA2477776C (en) 2011-11-15
CN1643004A (zh) 2005-07-20
CN100484973C (zh) 2009-05-06
KR20100101024A (ko) 2010-09-15
DE60322684D1 (de) 2008-09-18
KR101002620B1 (ko) 2010-12-21
AR038976A1 (es) 2005-02-02
EP1487886B1 (de) 2008-08-06
US20050143536A1 (en) 2005-06-30
JP4624679B2 (ja) 2011-02-02
JP2005519969A (ja) 2005-07-07
KR20040091742A (ko) 2004-10-28
ES2307956T3 (es) 2008-12-01
EP1487886A1 (de) 2004-12-22
JP2010189396A (ja) 2010-09-02
US7098356B2 (en) 2006-08-29
SA03240063B1 (ar) 2007-12-29
WO2003078483A1 (en) 2003-09-25
CA2477776A1 (en) 2003-09-25

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