DE60318957D1 - Katalysator und prozess - Google Patents

Katalysator und prozess

Info

Publication number
DE60318957D1
DE60318957D1 DE60318957T DE60318957T DE60318957D1 DE 60318957 D1 DE60318957 D1 DE 60318957D1 DE 60318957 T DE60318957 T DE 60318957T DE 60318957 T DE60318957 T DE 60318957T DE 60318957 D1 DE60318957 D1 DE 60318957D1
Authority
DE
Germany
Prior art keywords
catalyst
carboxylic acid
base
alkoxide
hydroxy carboxylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60318957T
Other languages
English (en)
Other versions
DE60318957T2 (de
Inventor
Charles Mark Lindall
Neville Slack
Martin Graham Partridge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Application granted granted Critical
Publication of DE60318957D1 publication Critical patent/DE60318957D1/de
Publication of DE60318957T2 publication Critical patent/DE60318957T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223At least two oxygen atoms present in one at least bidentate or bridging ligand
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • B01J27/232Carbonates
    • B01J27/236Hydroxy carbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/03Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/84Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/85Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49Esterification or transesterification
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38Lanthanides other than lanthanum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49Hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201Oxygen-containing compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201Oxygen-containing compounds
    • B01J31/0211Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212Alkoxylates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE60318957T 2002-12-04 2003-12-01 Katalysator und prozess Expired - Lifetime DE60318957T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0228267.1A GB0228267D0 (en) 2002-12-04 2002-12-04 Catalyst and process
GB0228267 2002-12-04
PCT/GB2003/005180 WO2004050239A2 (en) 2002-12-04 2003-12-01 Catalyst and process

Publications (2)

Publication Number Publication Date
DE60318957D1 true DE60318957D1 (de) 2008-03-20
DE60318957T2 DE60318957T2 (de) 2009-01-22

Family

ID=9949042

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60318957T Expired - Lifetime DE60318957T2 (de) 2002-12-04 2003-12-01 Katalysator und prozess

Country Status (16)

Country Link
US (2) US8232222B2 (de)
EP (1) EP1567472B1 (de)
JP (1) JP4504197B2 (de)
KR (2) KR101135768B1 (de)
CN (1) CN100338011C (de)
AT (1) ATE385233T1 (de)
AU (1) AU2003285546A1 (de)
BR (2) BR0317034A (de)
DE (1) DE60318957T2 (de)
ES (1) ES2297243T3 (de)
GB (1) GB0228267D0 (de)
PL (1) PL215259B1 (de)
PT (1) PT1567472E (de)
RU (1) RU2316396C2 (de)
TW (1) TWI369248B (de)
WO (1) WO2004050239A2 (de)

Families Citing this family (31)

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GB0228267D0 (en) * 2002-12-04 2003-01-08 Johnson Matthey Plc Catalyst and process
US7226888B2 (en) 2004-08-06 2007-06-05 E. I. Du Pont De Nemours And Company Composition comprising titanium and aluminium and polyester production
TWI290953B (en) * 2005-07-22 2007-12-11 Chien-Tien Chen Nucleophilic acyl substitutions of acids or esters catalyzed by metal oxide complex, and the applications in fabricating biodiesel
TWI276642B (en) * 2005-07-22 2007-03-21 Chien-Tien Chen Nucleophilic acyl substituting polymerizations catalyzed by metal oxide complex
MX2009000628A (es) * 2006-07-18 2009-01-28 Cobarr Spa Compuestos metalicos oligosilsesquioxanos poliedricos para la fabricacion de polimeros de policondensacion.
US7745368B2 (en) * 2006-07-28 2010-06-29 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum compositions made with organic hydroxyacids
US7709595B2 (en) 2006-07-28 2010-05-04 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum solutions made with polyhydroxyl ether solvents
US7709593B2 (en) 2006-07-28 2010-05-04 Eastman Chemical Company Multiple feeds of catalyst metals to a polyester production process
US8563677B2 (en) * 2006-12-08 2013-10-22 Grupo Petrotemex, S.A. De C.V. Non-precipitating alkali/alkaline earth metal and aluminum solutions made with diols having at least two primary hydroxyl groups
US8802582B2 (en) * 2007-01-09 2014-08-12 Catalytic Solutions, Inc. High temperature ammonia SCR catalyst and method of using the catalyst
US7767175B2 (en) * 2007-01-09 2010-08-03 Catalytic Solutions, Inc. Ammonia SCR catalyst and method of using the catalyst
US7527776B2 (en) * 2007-01-09 2009-05-05 Catalytic Solutions, Inc. Ammonia SCR catalyst and method of using the catalyst
US7943097B2 (en) * 2007-01-09 2011-05-17 Catalytic Solutions, Inc. Reactor system for reducing NOx emissions from boilers
GB2447268A (en) * 2007-03-06 2008-09-10 Johnson Matthey Plc Process for polymerisation of a cyclic monomer
US8202962B2 (en) * 2008-10-31 2012-06-19 Grupo Petrotemex, S.A. De C.V. Integrated steam heating in polyester production process
US8017723B2 (en) 2008-10-31 2011-09-13 Grupo Petrotemex, S.A. De C.V. Steam heated polyester production process
GB201002278D0 (en) * 2010-02-11 2010-03-31 Johnson Matthey Plc composition and method of preparation
CN102477151B (zh) * 2010-11-25 2015-08-19 东丽纤维研究所(中国)有限公司 聚酯制备用催化剂及其制备方法以及生产聚酯的方法
PL2765149T3 (pl) * 2013-02-06 2019-06-28 Uhde Inventa-Fischer Gmbh Sposób wytwarzania katalizatora zawierającego tytan, katalizator zawierający tytan, sposób wytwarzania poliestru i poliester
CN103804190B (zh) * 2014-03-11 2016-04-20 南通龙翔化工有限公司 一种丁二酸二叔烷基酯的合成方法
RU2648983C1 (ru) * 2014-09-24 2018-03-29 Басф Се Способ получения сложных диэфиров терефталевой кислоты
US9981902B2 (en) 2015-10-23 2018-05-29 Columbia Insurance Company Process for production of an ester and diol from reclaimed carpet material
CN109666131B (zh) * 2017-10-17 2022-02-01 中国石油化工股份有限公司 聚对苯二甲酸丁二醇酯树脂的制备方法
CN111087583B (zh) * 2018-10-23 2022-11-04 中国石油化工股份有限公司 低端羧基pbt树脂的制备方法
CN109503819B (zh) * 2019-01-04 2021-09-21 中国科学院成都有机化学有限公司 一种合成pbt聚酯的方法
CN110964189B (zh) * 2019-06-21 2022-03-29 柏瑞克股份有限公司 用于酯化反应的催化剂及催化酯化反应的方法
CN111944136A (zh) * 2019-10-30 2020-11-17 柏瑞克股份有限公司 用于催化酯化反应的催化剂及其合成方法
CN113801311B (zh) * 2020-06-15 2023-08-29 中国石油化工股份有限公司 聚酯制备方法
CN113881027B (zh) * 2020-07-01 2023-06-06 中国石油化工股份有限公司 一种钛系聚酯催化剂及其制备方法和应用
EP4101817A1 (de) * 2021-06-11 2022-12-14 Clariant International Ltd Neuer titankatalysator für das polyesterherstellungsverfahren
CN116444777A (zh) * 2023-05-05 2023-07-18 喀什地区第一人民医院 一种聚酯和/或共聚酯、其制备方法以及所用催化剂

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GB0228267D0 (en) * 2002-12-04 2003-01-08 Johnson Matthey Plc Catalyst and process
GB0323386D0 (en) * 2003-10-07 2003-11-05 Johnson Matthey Plc Catalyst for manufacture of esters
GB2461871A (en) * 2008-07-12 2010-01-20 Alfred Thomas Hackett Dismantable gate

Also Published As

Publication number Publication date
ATE385233T1 (de) 2008-02-15
RU2316396C2 (ru) 2008-02-10
AU2003285546A8 (en) 2004-06-23
GB0228267D0 (en) 2003-01-08
US20120271030A1 (en) 2012-10-25
US8232222B2 (en) 2012-07-31
WO2004050239A2 (en) 2004-06-17
US8455387B2 (en) 2013-06-04
KR20050085340A (ko) 2005-08-29
DE60318957T2 (de) 2009-01-22
JP4504197B2 (ja) 2010-07-14
TW200500140A (en) 2005-01-01
CN1720216A (zh) 2006-01-11
KR101240113B1 (ko) 2013-03-07
PL377141A1 (pl) 2006-01-23
PT1567472E (pt) 2008-03-12
WO2004050239A3 (en) 2004-09-16
BR0310145B1 (pt) 2013-02-05
US20060155102A1 (en) 2006-07-13
KR20110134949A (ko) 2011-12-15
TWI369248B (en) 2012-08-01
KR101135768B1 (ko) 2012-04-16
JP2006509069A (ja) 2006-03-16
CN100338011C (zh) 2007-09-19
AU2003285546A1 (en) 2004-06-23
RU2005120775A (ru) 2006-01-20
ES2297243T3 (es) 2008-05-01
EP1567472A2 (de) 2005-08-31
PL215259B1 (pl) 2013-11-29
BR0317034A (pt) 2005-10-25
EP1567472B1 (de) 2008-01-30

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