DE60311362T2 - Verfahren zur Herstellung von Molybdän-Schwefel Additiven, die wenig nicht-reagierten Schwefel enthalten und so erhaltene Additive - Google Patents
Verfahren zur Herstellung von Molybdän-Schwefel Additiven, die wenig nicht-reagierten Schwefel enthalten und so erhaltene Additive Download PDFInfo
- Publication number
- DE60311362T2 DE60311362T2 DE60311362T DE60311362T DE60311362T2 DE 60311362 T2 DE60311362 T2 DE 60311362T2 DE 60311362 T DE60311362 T DE 60311362T DE 60311362 T DE60311362 T DE 60311362T DE 60311362 T2 DE60311362 T2 DE 60311362T2
- Authority
- DE
- Germany
- Prior art keywords
- molybdenum
- additive
- sulfur
- oil
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000654 additive Substances 0.000 title claims abstract description 153
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical compound [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 title claims abstract description 53
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 42
- 239000011593 sulfur Substances 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 35
- 230000008569 process Effects 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 116
- 239000000203 mixture Substances 0.000 claims abstract description 69
- 150000001875 compounds Chemical class 0.000 claims abstract description 34
- 239000003446 ligand Substances 0.000 claims abstract description 33
- 238000006243 chemical reaction Methods 0.000 claims abstract description 32
- 239000010687 lubricating oil Substances 0.000 claims abstract description 30
- 239000005078 molybdenum compound Substances 0.000 claims abstract description 19
- 150000002752 molybdenum compounds Chemical class 0.000 claims abstract description 17
- 239000000376 reactant Substances 0.000 claims abstract description 14
- 239000011541 reaction mixture Substances 0.000 claims abstract description 10
- 238000009877 rendering Methods 0.000 claims abstract description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 47
- 229910052750 molybdenum Inorganic materials 0.000 claims description 38
- 239000003921 oil Substances 0.000 claims description 36
- 239000011733 molybdenum Substances 0.000 claims description 35
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 12
- 239000000460 chlorine Substances 0.000 claims description 12
- 229910052801 chlorine Inorganic materials 0.000 claims description 12
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 239000000446 fuel Substances 0.000 claims description 8
- 150000008117 polysulfides Polymers 0.000 claims description 8
- 125000004434 sulfur atom Chemical group 0.000 claims description 8
- 238000011065 in-situ storage Methods 0.000 claims description 6
- ZGSDJMADBJCNPN-UHFFFAOYSA-N [S-][NH3+] Chemical class [S-][NH3+] ZGSDJMADBJCNPN-UHFFFAOYSA-N 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 abstract description 14
- 230000007797 corrosion Effects 0.000 abstract description 14
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 150000002739 metals Chemical class 0.000 abstract description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 description 21
- 239000012530 fluid Substances 0.000 description 13
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 12
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- 239000012990 dithiocarbamate Substances 0.000 description 11
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 10
- 238000010790 dilution Methods 0.000 description 10
- 239000012895 dilution Substances 0.000 description 10
- 239000000523 sample Substances 0.000 description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 230000003993 interaction Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000032683 aging Effects 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 description 5
- 239000003085 diluting agent Substances 0.000 description 5
- 239000003879 lubricant additive Substances 0.000 description 5
- 230000001050 lubricating effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- YVFVCBLPHSZOFJ-UHFFFAOYSA-J NC([S-])=S.NC([S-])=S.NC([S-])=S.NC([S-])=S.NC(S)=S.NC(S)=S.S.[Mo+4] Chemical compound NC([S-])=S.NC([S-])=S.NC([S-])=S.NC([S-])=S.NC(S)=S.NC(S)=S.S.[Mo+4] YVFVCBLPHSZOFJ-UHFFFAOYSA-J 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- -1 secondary alkylamine Chemical class 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000012991 xanthate Substances 0.000 description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ONQRRCCNRJPAEN-UHFFFAOYSA-M [K+].CCCCCCCCCCCCOP([O-])(=S)SCCCCCCCCCCCC Chemical compound [K+].CCCCCCCCCCCCOP([O-])(=S)SCCCCCCCCCCCC ONQRRCCNRJPAEN-UHFFFAOYSA-M 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CSNJTIWCTNEOSW-UHFFFAOYSA-N carbamothioylsulfanyl carbamodithioate Chemical compound NC(=S)SSC(N)=S CSNJTIWCTNEOSW-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000010688 mineral lubricating oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000008427 organic disulfides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- TZWAQMQVPQXPQA-UHFFFAOYSA-M potassium;dithiocarboxyazanide Chemical compound [K+].NC([S-])=S TZWAQMQVPQXPQA-UHFFFAOYSA-M 0.000 description 1
- 229940036310 program Drugs 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical class C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- MCYXWOCTIYEQRK-UHFFFAOYSA-K tripotassium dioxido-sulfanylidene-sulfido-lambda5-phosphane Chemical compound [K+].[K+].[K+].[O-]P([O-])([S-])=S MCYXWOCTIYEQRK-UHFFFAOYSA-K 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C333/14—Dithiocarbamic acids; Derivatives thereof
- C07C333/18—Esters of dithiocarbamic acids
- C07C333/20—Esters of dithiocarbamic acids having nitrogen atoms of dithiocarbamate groups bound to hydrogen atoms or to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/18—Complexes with metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/066—Organic compounds derived from inorganic acids or metal salts derived from Mo or W
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/09—Complexes with metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/20—Colour, e.g. dyes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/54—Fuel economy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/26—Two-strokes or two-cycle engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Form in which the lubricant is applied to the material being lubricated semi-solid; greasy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02078011 | 2002-07-08 | ||
| EP02078011 | 2002-07-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60311362D1 DE60311362D1 (de) | 2007-03-15 |
| DE60311362T2 true DE60311362T2 (de) | 2007-11-08 |
Family
ID=30129222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60311362T Expired - Lifetime DE60311362T2 (de) | 2002-07-08 | 2003-06-24 | Verfahren zur Herstellung von Molybdän-Schwefel Additiven, die wenig nicht-reagierten Schwefel enthalten und so erhaltene Additive |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7309680B2 (https=) |
| JP (2) | JP5435834B2 (https=) |
| CN (1) | CN1298822C (https=) |
| AT (1) | ATE352604T1 (https=) |
| CA (1) | CA2432993A1 (https=) |
| DE (1) | DE60311362T2 (https=) |
| MX (1) | MXPA03005852A (https=) |
| SG (1) | SG121781A1 (https=) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060025315A1 (en) * | 2004-07-30 | 2006-02-02 | Rebecca Oldfield | Method for lubricating surfaces |
| US8709989B2 (en) | 2004-10-19 | 2014-04-29 | Nippon Oil Corporation | Lubricant composition and antioxident composition |
| US7074381B1 (en) * | 2005-06-13 | 2006-07-11 | Infineum International Limited | Process for producing ammonium polythiomolybdate |
| JP5175462B2 (ja) * | 2006-09-04 | 2013-04-03 | 出光興産株式会社 | 内燃機関用潤滑油組成物 |
| EP2069462A1 (en) * | 2006-10-07 | 2009-06-17 | GKN Driveline International GmbH | Grease composition for use in constant velocity joints comprising at least one tri-nuclear molybdenum compound |
| EP2069463A1 (en) * | 2006-10-07 | 2009-06-17 | GKN Driveline International GmbH | Grease composition for use in constant velocity joints comprising at least two different molybdenum compounds |
| WO2008040383A1 (en) * | 2006-10-07 | 2008-04-10 | Gkn Driveline International Gmbh | Grease composition for use in constant velocity joints comprising at least one tri-nuclear molybdenum compound and a urea derivative thickener |
| JP5468728B2 (ja) | 2007-05-29 | 2014-04-09 | 出光興産株式会社 | 内燃機関用潤滑油組成物 |
| US8183189B2 (en) * | 2009-09-30 | 2012-05-22 | Chevron Oronite Company Llc | Preparation of a sulfurized molybdenum amide complex and additive compositions having low residual active sulfur |
| CA2773647C (en) * | 2009-09-30 | 2016-04-12 | Chevron Oronite Company Llc | Preparation of a sulfurized molybdenum amide complex and additive compositions having low residual active sulfur |
| US20110237474A1 (en) | 2010-03-25 | 2011-09-29 | R.T. Vanderbilt Company, Inc. | Ultra Low Phosphorus Lubricant Compositions |
| CN104471041A (zh) | 2012-06-06 | 2015-03-25 | 范德比尔特化学品有限责任公司 | 节油润滑油 |
| US20150147012A1 (en) * | 2013-11-27 | 2015-05-28 | Emerson Climate Technologies, Inc. | Bearing performance for compressors using high energy refrigerants with sulfur-based oil additives |
| JP2015063564A (ja) * | 2014-12-26 | 2015-04-09 | シェブロン・オロナイト・カンパニー・エルエルシー | 硫化モリブデンアミド錯体の製造および残留活性硫黄の少ない添加剤組成物 |
| CN105133002B (zh) * | 2015-08-29 | 2017-07-21 | 西北有色金属研究院 | 一种十三硫代钼酸铵晶体的制备方法 |
| US10883046B2 (en) | 2017-02-02 | 2021-01-05 | Nanoco 2D Materials Limited | Synthesis of luminescent 2D layered materials using an amine-met al complex and a slow sulfur-releasing precursor |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3509051A (en) | 1964-08-07 | 1970-04-28 | T R Vanderbilt Co Inc | Lubricating compositions containing sulfurized oxymolybdenum dithiocarbamates |
| NL131940C (https=) | 1965-10-28 | |||
| DE2508713C3 (de) | 1975-02-28 | 1979-04-12 | Adolf Schmids Erben Ag, Bern | Verfahren zur Aufarbeitung von gebrauchtem Mineralöl |
| FR2484442B1 (fr) * | 1980-02-01 | 1985-11-22 | Lubrizol Corp | Procede de preparation de compositions contenant du molybdene utiles pour une meilleure economie du combustible des moteurs a combustion interne |
| US4289635A (en) * | 1980-02-01 | 1981-09-15 | The Lubrizol Corporation | Process for preparing molybdenum-containing compositions useful for improved fuel economy of internal combustion engines |
| JPS61501925A (ja) * | 1984-04-16 | 1986-09-04 | ザ ル−ブリゾル コ−ポレイシヨン | 改良された性能を示す潤滑油および機能液用添加剤およびその製造方法 |
| JP3659598B2 (ja) * | 1995-02-15 | 2005-06-15 | 旭電化工業株式会社 | 硫化オキシモリブデンジチオカーバメートの製造方法 |
| FR2735785B1 (fr) | 1995-06-22 | 1997-08-08 | Chavet Bernard | Procede de raffinage d'huiles usagees par traitement alcalin |
| US6043200A (en) * | 1995-07-31 | 2000-03-28 | Exxon Chemical Patents, Inc. | Oleaginous compositions |
| DE69621324T2 (de) * | 1995-12-22 | 2003-01-02 | Japan Energy Corp., Tokio/Tokyo | Schmieröl für brennkraftmaschinen |
| US6232276B1 (en) * | 1996-12-13 | 2001-05-15 | Infineum Usa L.P. | Trinuclear molybdenum multifunctional additive for lubricating oils |
| CA2274706A1 (en) * | 1996-12-13 | 1998-06-18 | Daniella Maria Veronica Baxter | Lubricating oil compositions containing organic molybdenum complexes |
| US5888945A (en) * | 1996-12-13 | 1999-03-30 | Exxon Research And Engineering Company | Method for enhancing and restoring reduction friction effectiveness |
| US6358894B1 (en) * | 1996-12-13 | 2002-03-19 | Infineum Usa L.P. | Molybdenum-antioxidant lube oil compositions |
| JP4528439B2 (ja) * | 1997-12-12 | 2010-08-18 | インフィニューム ユーエスエイ リミテッド パートナーシップ | 三核モリブデン−イオウ化合物の製造方法及びそれらの潤滑剤用添加剤としての使用 |
| US6110878A (en) * | 1997-12-12 | 2000-08-29 | Exxon Chemical Patents Inc | Lubricant additives |
| US5895779A (en) * | 1998-03-31 | 1999-04-20 | Exxon Chemical Patents Inc | Lubricating oil having improved fuel economy retention properties |
| GB9813070D0 (en) * | 1998-06-17 | 1998-08-19 | Exxon Chemical Patents Inc | Lubricant compositions |
| US6074993A (en) * | 1999-10-25 | 2000-06-13 | Infineuma Usa L.P. | Lubricating oil composition containing two molybdenum additives |
| US6528463B1 (en) * | 2000-03-23 | 2003-03-04 | Ethyl Corporation | Oil soluble molybdenum compositions |
| ATE309315T1 (de) * | 2000-03-29 | 2005-11-15 | Infineum Int Ltd | Verfahren zur herstellung von schmierstoffadditiven |
| DE60117311T2 (de) * | 2000-03-29 | 2006-08-03 | Infineum International Ltd., Abingdon | Organische Molybdänkomplexe enthaltende Schmiermittelzusammensetzungen |
| US6953771B2 (en) * | 2001-03-23 | 2005-10-11 | Infineon International Limited | Lubricant compositions |
| US6852679B2 (en) * | 2002-02-20 | 2005-02-08 | Infineum International Ltd. | Lubricating oil composition |
-
2003
- 2003-06-20 CA CA002432993A patent/CA2432993A1/en not_active Abandoned
- 2003-06-24 DE DE60311362T patent/DE60311362T2/de not_active Expired - Lifetime
- 2003-06-24 AT AT03253981T patent/ATE352604T1/de not_active IP Right Cessation
- 2003-06-26 MX MXPA03005852A patent/MXPA03005852A/es active IP Right Grant
- 2003-07-01 US US10/611,228 patent/US7309680B2/en not_active Expired - Lifetime
- 2003-07-07 JP JP2003192694A patent/JP5435834B2/ja not_active Expired - Lifetime
- 2003-07-08 CN CNB031453694A patent/CN1298822C/zh not_active Expired - Lifetime
- 2003-07-08 SG SG200303962A patent/SG121781A1/en unknown
-
2013
- 2013-10-10 JP JP2013212733A patent/JP5620559B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ATE352604T1 (de) | 2007-02-15 |
| JP5435834B2 (ja) | 2014-03-05 |
| JP2014005474A (ja) | 2014-01-16 |
| MXPA03005852A (es) | 2005-01-10 |
| CN1298822C (zh) | 2007-02-07 |
| DE60311362D1 (de) | 2007-03-15 |
| CN1472292A (zh) | 2004-02-04 |
| JP5620559B2 (ja) | 2014-11-05 |
| CA2432993A1 (en) | 2004-01-08 |
| SG121781A1 (en) | 2006-05-26 |
| US7309680B2 (en) | 2007-12-18 |
| JP2004051985A (ja) | 2004-02-19 |
| US20040132627A1 (en) | 2004-07-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69711686T2 (de) | Molybdänkomplexe enthaltende schmiermittelzusammensetzungen | |
| DE60311362T2 (de) | Verfahren zur Herstellung von Molybdän-Schwefel Additiven, die wenig nicht-reagierten Schwefel enthalten und so erhaltene Additive | |
| DE60114687T2 (de) | Verfahren zur Herstellung von Schmierstoffadditiven | |
| DE69707714T2 (de) | Organische molybdänkomplexe enthaltende schmierölzusammensetzungen | |
| DE69824886T2 (de) | Verfahren zur herstellung von dreikernigen molybdenum-schwefel verbindungen und ihre verwendung als schmiermittelzusätze | |
| DE60300366T2 (de) | Eine Antioxydierungskombination von Schmiermitteladditiven enthaltend ein Molybdenkomplex und eine alkylierte Phenothiazin | |
| DE69423399T2 (de) | Verfahren zur Herstellung einer Molybdän-Oxysulfid-Dithiocarbamat enthaltenden Zusammensetzung, und eine Schmiermittelzusammensetzung, die die durch das Verfahren erhaltene Zusammensetzung enthält | |
| DE69826010T2 (de) | Verwendung von molybdänkomplexen in schmierölzusammensetzungen für dieselmotoren | |
| DE69918967T2 (de) | Schmieröl mit verbesserten brennstoffsparnis | |
| DE1568041A1 (de) | Organische schwefelhaltige Molybdaenverbindungen und Verfahren zu ihrer Herstellung | |
| DE1221226B (de) | Verfahren zur Herstellung von in Kohlenwasserstoffoelen loeslichen, basische Erdalkalimetallkomplexverbindungen der Carbon- und/oder Oelloeslichen organischen Sulfonsaeuren | |
| DE60300494T2 (de) | Phosphorothionate | |
| DE60206003T2 (de) | Dithiocarbamate mit Alkylthio- und Hydroxysubstituenten | |
| DE69416167T2 (de) | Basisches metallsalz der dithiocarbaminsäure und besagtes salz enthaltende schmierölzusammensetzung | |
| DE1594428A1 (de) | Verwendung von kolloidalen Metallcarbonatdispersionen als Zusaetze zu Schmieroelen,Brennstoffoelen oder Treibstoffen | |
| DE69415817T2 (de) | Schmiermittelzusammensetzungen enthaltend eine kombination von verschleissschutz-additiven | |
| DE69433335T2 (de) | Molybdän enthaltende Reibung herabsetzende Zusätze | |
| DE60117311T2 (de) | Organische Molybdänkomplexe enthaltende Schmiermittelzusammensetzungen | |
| EP0290899B1 (de) | Zusatzmittel für Bohrflüssigkeiten, Herstellung und Verwendung | |
| DE10216686A1 (de) | Thiadiazoldimer-Additive und diese enthaltende Schmierstoffzusammensetzungen | |
| DE69403322T2 (de) | Schmierstoffzusammensetzung die alkoxylierten aminsalze aus säuren enthält | |
| DE69511075T2 (de) | Schmiermittelzusammensetzungen | |
| DE2725649A1 (de) | Phosphorthionatderivate und deren verwendung in schmiermitteln | |
| DE69732486T2 (de) | Verwendung von Dithioethylen-Derivaten als Additiv zur Verbesserung der Kompatibilität mit den Fluorokohlenstoffelelastomeren | |
| EP1382659B1 (en) | Process for making molybdenum-sulfur additives containing little unreacted sulfur and additives obtained by the process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |