DE60210107T2 - Elastische mischungen - Google Patents
Elastische mischungen Download PDFInfo
- Publication number
- DE60210107T2 DE60210107T2 DE60210107T DE60210107T DE60210107T2 DE 60210107 T2 DE60210107 T2 DE 60210107T2 DE 60210107 T DE60210107 T DE 60210107T DE 60210107 T DE60210107 T DE 60210107T DE 60210107 T2 DE60210107 T2 DE 60210107T2
- Authority
- DE
- Germany
- Prior art keywords
- composition according
- nitrile rubber
- hydrogenated
- rubber
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 40
- 229920000459 Nitrile rubber Polymers 0.000 claims description 30
- 150000002825 nitriles Chemical class 0.000 claims description 16
- 229920001971 elastomer Polymers 0.000 claims description 13
- 238000012360 testing method Methods 0.000 claims description 12
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 10
- 239000000945 filler Substances 0.000 claims description 10
- 239000005060 rubber Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 238000005984 hydrogenation reaction Methods 0.000 claims description 8
- 150000007524 organic acids Chemical class 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical group [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 claims description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- 150000002978 peroxides Chemical group 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 238000005299 abrasion Methods 0.000 description 11
- 150000001993 dienes Chemical class 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 6
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- PIMBTRGLTHJJRV-UHFFFAOYSA-L zinc;2-methylprop-2-enoate Chemical compound [Zn+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O PIMBTRGLTHJJRV-UHFFFAOYSA-L 0.000 description 4
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- 229920006170 Therban® Polymers 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- -1 Vinyl compound Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- RIPYNJLMMFGZSX-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C1=CC=CC=C1 RIPYNJLMMFGZSX-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229920013647 Krynac Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920013648 Perbunan Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 238000010057 rubber processing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
- C08L15/005—Hydrogenated nitrile rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002357089A CA2357089A1 (en) | 2001-09-07 | 2001-09-07 | Elastomeric compositions |
| CA2357089 | 2001-09-07 | ||
| PCT/CA2002/001363 WO2003022916A1 (en) | 2001-09-07 | 2002-09-06 | Elastomeric compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60210107D1 DE60210107D1 (de) | 2006-05-11 |
| DE60210107T2 true DE60210107T2 (de) | 2006-08-24 |
Family
ID=4169933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60210107T Expired - Lifetime DE60210107T2 (de) | 2001-09-07 | 2002-09-06 | Elastische mischungen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20030065076A1 (https=) |
| EP (1) | EP1427776B1 (https=) |
| JP (1) | JP2005501962A (https=) |
| CN (1) | CN1551899A (https=) |
| CA (1) | CA2357089A1 (https=) |
| DE (1) | DE60210107T2 (https=) |
| MX (1) | MXPA04001834A (https=) |
| RU (1) | RU2004110411A (https=) |
| TW (1) | TW574287B (https=) |
| WO (1) | WO2003022916A1 (https=) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040132886A1 (en) * | 2003-01-06 | 2004-07-08 | Jian Tao | Accelerator free nitrile gloves |
| CA2428222A1 (en) * | 2003-05-08 | 2004-11-08 | Bayer Inc. | Rubber compound comprising nitrile rubbers |
| CA2437406A1 (en) * | 2003-08-14 | 2005-02-14 | Bayer Inc. | Butyl compositions comprising nitrile polymers |
| CA2438111A1 (en) * | 2003-08-25 | 2005-02-25 | Bayer Inc. | Nitrile polymer compounds for magntic seal applications |
| CA2452910A1 (en) * | 2003-12-12 | 2005-06-12 | Bayer Inc. | Butyl rubber composition for tire treads |
| CA2490046A1 (en) * | 2004-12-10 | 2006-06-10 | Lanxess Inc. | Multistage process for the manufacture of peroxide-cured hxnbr-polyamide thermoplastic vulcanizates |
| CN1320047C (zh) * | 2005-05-18 | 2007-06-06 | 如东纺织橡胶有限公司 | 超低硬高弹不处理胶管及生产方法 |
| DE102005047115A1 (de) * | 2005-09-30 | 2007-04-05 | Lanxess Deutschland Gmbh | Vernetzbare Zusammensetzungen, Verfahren zu deren Herstellung und deren Verwendung |
| DE102005059625A1 (de) * | 2005-12-14 | 2007-06-21 | Lanxess Deutschland Gmbh | Mikrogel-enthaltende vulkanisierbare Zusammensetzung auf Basis von hydriertem Nitrilkautschuk |
| JP5340166B2 (ja) * | 2006-12-20 | 2013-11-13 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 低ヒステリシスゴムエラストマー |
| HK1203993A1 (en) * | 2012-02-29 | 2015-11-06 | 诺贝尔科学有限公司 | Method of making a polymer article and resulting article |
| CN104937022A (zh) * | 2013-01-28 | 2015-09-23 | 日本瑞翁株式会社 | 在油田或气井中使用的密封材料用交联性橡胶组合物和密封材料 |
| FR3012147B1 (fr) | 2013-10-22 | 2016-07-15 | Michelin & Cie | Pneumatique comprenant une composition comprenant un derive du diacrylate de zinc et un peroxyde |
| FR3030544B1 (fr) * | 2014-12-22 | 2017-01-13 | Michelin & Cie | Pneumatique comprenant une composition comprenant un derive d'acrylate polyfonctionnel et un peroxyde |
| FR3030543B1 (fr) | 2014-12-22 | 2017-01-13 | Michelin & Cie | Pneumatique comprenant une composition comprenant un derive d'acrylate polyfonctionnel et un peroxyde |
| WO2016118486A1 (en) * | 2015-01-19 | 2016-07-28 | Fina Technology, Inc. | Masterbatch formulation and formation |
| FR3033329A1 (fr) | 2015-03-05 | 2016-09-09 | Michelin & Cie | Pneumatique comprenant une composition comprenant un derive du diacrylate de zinc et un peroxyde |
| FR3038545A1 (fr) * | 2015-07-10 | 2017-01-13 | Michelin & Cie | Pneumatique comportant des melanges elastomeriques a bas taux de soufre |
| FR3063731A1 (fr) * | 2017-03-08 | 2018-09-14 | Compagnie Generale Des Etablissements Michelin | Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un acrylate de zinc |
| FR3063732A1 (fr) | 2017-03-08 | 2018-09-14 | Compagnie Generale Des Etablissements Michelin | Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate polyfonctionnel |
| FR3065959A1 (fr) | 2017-05-04 | 2018-11-09 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc a base d'un derive d'acrylate de zinc incorpore a partir d'un melange-maitre |
| WO2019086793A1 (fr) | 2017-10-30 | 2019-05-09 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant une amine specifique et un systeme de reticulation a base de peroxyde et d'un derive d'acrylate |
| WO2019106292A1 (fr) | 2017-11-29 | 2019-06-06 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouterie dont le systeme de reticulation comprend un coupage de peroxydes et un derive d'acrylate |
| WO2019121157A1 (de) * | 2017-12-21 | 2019-06-27 | Arlanxeo Deutschland Gmbh | Hnbr-vulkanisat mit verbesserter heissluftbeständigkeit |
| RU2755481C1 (ru) * | 2020-07-07 | 2021-09-16 | Общество с ограниченной ответственностью "Газпром 335" | Эластомерная композиция и способ ее получения |
| CN115960402B (zh) * | 2022-12-27 | 2024-07-30 | 宁国市赛科思橡胶有限公司 | 一种耐长时间高温的氢化丁腈混炼胶及其制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5264290A (en) * | 1988-01-29 | 1993-11-23 | The United States Of America As Represented By The Secretary Of The Army | Rubber compound for tracked vehicle track pads |
| US4843114A (en) * | 1988-01-29 | 1989-06-27 | The United States Of America As Represented By The Secretary Of The Army | Rubber compound for tracked vehicle track pads |
| DE69023597T2 (de) * | 1989-09-18 | 1996-05-02 | Nippon Zeon Co | Kautschukmischungen für Vorrichtungen zum Verhindern des Reifenschlupfes und Vorrichtung zum Verhindern des Reifenschlupfes. |
| JP2939489B2 (ja) * | 1989-12-08 | 1999-08-25 | 日本ゼオン株式会社 | ゴムロールおよびゴムロール用ゴム組成物 |
| JP3704783B2 (ja) * | 1996-01-31 | 2005-10-12 | 日本ゼオン株式会社 | 加硫性ゴム組成物およびフレオン用シール |
| CA2308876A1 (en) * | 2000-05-12 | 2001-11-12 | Bayer Inc. | Improved rubber composition |
| DE10102047A1 (de) * | 2001-01-17 | 2002-07-18 | Bayer Ag | Kautschukmischungen für Walzenbeläge |
-
2001
- 2001-09-07 CA CA002357089A patent/CA2357089A1/en not_active Abandoned
-
2002
- 2002-08-06 TW TW91117608A patent/TW574287B/zh active
- 2002-09-04 US US10/234,593 patent/US20030065076A1/en not_active Abandoned
- 2002-09-06 EP EP02759978A patent/EP1427776B1/en not_active Expired - Lifetime
- 2002-09-06 MX MXPA04001834A patent/MXPA04001834A/es unknown
- 2002-09-06 CN CNA028172841A patent/CN1551899A/zh active Pending
- 2002-09-06 RU RU2004110411/04A patent/RU2004110411A/ru not_active Application Discontinuation
- 2002-09-06 WO PCT/CA2002/001363 patent/WO2003022916A1/en not_active Ceased
- 2002-09-06 DE DE60210107T patent/DE60210107T2/de not_active Expired - Lifetime
- 2002-09-06 JP JP2003526985A patent/JP2005501962A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE60210107D1 (de) | 2006-05-11 |
| US20030065076A1 (en) | 2003-04-03 |
| JP2005501962A (ja) | 2005-01-20 |
| CN1551899A (zh) | 2004-12-01 |
| EP1427776A1 (en) | 2004-06-16 |
| WO2003022916A1 (en) | 2003-03-20 |
| EP1427776B1 (en) | 2006-03-22 |
| MXPA04001834A (es) | 2004-07-08 |
| RU2004110411A (ru) | 2005-10-20 |
| TW574287B (en) | 2004-02-01 |
| CA2357089A1 (en) | 2003-03-07 |
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