DE602004006965T2 - Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen - Google Patents

Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen Download PDF

Info

Publication number
DE602004006965T2
DE602004006965T2 DE602004006965T DE602004006965T DE602004006965T2 DE 602004006965 T2 DE602004006965 T2 DE 602004006965T2 DE 602004006965 T DE602004006965 T DE 602004006965T DE 602004006965 T DE602004006965 T DE 602004006965T DE 602004006965 T2 DE602004006965 T2 DE 602004006965T2
Authority
DE
Germany
Prior art keywords
radical
transition metal
hydrogen
carbon atoms
different
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE602004006965T
Other languages
German (de)
English (en)
Other versions
DE602004006965D1 (de
Inventor
Robert L. Jones
Naka Seidel
Michael 69124 ELDER
John A. Lake Placid EWEN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10305227A external-priority patent/DE10305227A1/de
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of DE602004006965D1 publication Critical patent/DE602004006965D1/de
Application granted granted Critical
Publication of DE602004006965T2 publication Critical patent/DE602004006965T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE602004006965T 2003-02-07 2004-02-05 Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen Expired - Lifetime DE602004006965T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE10305227A DE10305227A1 (de) 2003-02-07 2003-02-07 Polymerisationskatalysatoren, Organoübergangsmetallverbindungen, Verfahren zur Herstellung von Polyolefinen und Polyolefine
DE10305227 2003-02-07
US45448203P 2003-03-13 2003-03-13
US454482P 2003-03-13
PCT/EP2004/001050 WO2004069881A1 (en) 2003-02-07 2004-02-05 Polymerization catalysts, organic transition metal compounds, process for preparing polyolefins and polyolefins

Publications (2)

Publication Number Publication Date
DE602004006965D1 DE602004006965D1 (de) 2007-07-26
DE602004006965T2 true DE602004006965T2 (de) 2008-02-21

Family

ID=32851843

Family Applications (1)

Application Number Title Priority Date Filing Date
DE602004006965T Expired - Lifetime DE602004006965T2 (de) 2003-02-07 2004-02-05 Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen

Country Status (6)

Country Link
US (1) US7544749B2 (enExample)
EP (1) EP1590377B1 (enExample)
JP (1) JP2006516668A (enExample)
AT (1) ATE364637T1 (enExample)
DE (1) DE602004006965T2 (enExample)
WO (1) WO2004069881A1 (enExample)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7301040B2 (en) 2005-08-18 2007-11-27 Fina Technology, Inc. Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom
WO2011099583A1 (ja) * 2010-02-12 2011-08-18 国立大学法人埼玉大学 立体選択的オレフィン重合用触媒及び立体選択的ポリオレフィンの製造方法
EP2582710B1 (en) * 2010-06-18 2016-08-10 Ramot at Tel Aviv University, Ltd. Salalen ligands and organometallic complexes
CN104379680B (zh) 2012-08-03 2017-11-28 埃克森美孚化学专利公司 具有长链支化的乙烯基封端的聚烯烃
US8957171B2 (en) 2012-08-03 2015-02-17 Exxonmobil Chemical Patents Inc. Catalysts comprising salan ligands
CN104379541B (zh) 2012-08-03 2018-02-23 埃克森美孚化学专利公司 含Salan配体的非‑对称催化剂
US9365661B2 (en) 2012-08-03 2016-06-14 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified salan catalyst compounds
US9382349B2 (en) 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
EP2880098B1 (en) 2012-08-03 2018-01-10 ExxonMobil Chemical Patents Inc. Halogenated catalysts comprising salan ligands
WO2014070502A1 (en) 2012-11-02 2014-05-08 Exxonmobil Chemical Patents Inc. Supported salan catalysts
SG11201506868UA (en) 2013-03-13 2015-09-29 Exxonmobil Chem Patents Inc Diphenylamine salan catalyst
CN105392776B (zh) 2013-06-20 2019-02-12 埃克森美孚化学专利公司 硫代-Salalen催化剂
WO2014204625A1 (en) 2013-06-20 2014-12-24 Exxonmobil Chemical Patents Inc. Salenol catalyst
CN105142777B (zh) 2013-06-20 2017-12-26 埃克森美孚化学专利公司 长桥Salen催化剂
JP6336870B2 (ja) * 2013-09-30 2018-06-06 日本ポリプロ株式会社 ビフェノール化合物及びそれを用いるオレフィン重合用触媒並びにオレフィン重合体の製造方法
EP3080073B1 (en) 2013-12-13 2018-10-24 ExxonMobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
JP2015182992A (ja) * 2014-03-26 2015-10-22 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒、および、オレフィン系重合体の製造方法
WO2015152974A1 (en) 2014-03-31 2015-10-08 Exxonmobil Chemical Patents Inc. Phenylene-bridged salalen catalysts
BR112018015128A2 (pt) * 2016-01-25 2018-12-18 Reliance Industries Ltd processo para preparar um complexo de ligante de imina de metal de transição com base de schiff

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL96810A0 (en) 1990-01-02 1991-09-16 Exxon Chemical Patents Inc Supported ionic metallocene catalysts for olefin polymerization and methods for the preparation thereof
BR9508119A (pt) 1994-06-24 1997-08-12 Exxon Chemical Patents Inc Sistemas de catalisador de polimerização produção e uso dos mesmos
JP3181920B2 (ja) * 1996-04-22 2001-07-03 日本ポリオレフィン株式会社 ポリオレフィン製造用触媒及びポリオレフィンの製造方法
CA2262493A1 (en) 1997-03-07 1998-09-17 Targor Gmbh Method for producing olefin polymers with a higher melting point
TW420693B (en) * 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
DE19733017A1 (de) * 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
US6521561B1 (en) 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
US7053160B1 (en) 1998-11-25 2006-05-30 Basell Polyolefine Gmbh Metallocene monohalogenides
WO2002012171A1 (en) * 2000-08-05 2002-02-14 Korea Institute Of Science And Technology Method for preparing chiral compound by asymmetric ring opening reactions of epoxides
CA2420465A1 (en) * 2000-08-22 2002-02-28 Exxonmobil Chemical Patents Inc. Polypropylene polymers
JP2002179724A (ja) * 2000-12-14 2002-06-26 Tonen Chem Corp マンガン錯体含有触媒成分および触媒並びにそれを用いるポリオレフィンの製造方法
JP2002268030A (ja) * 2001-03-07 2002-09-18 Fuji Xerox Co Ltd 光書き込み型記録媒体
JP2002308843A (ja) * 2001-04-06 2002-10-23 Mitsubishi Rayon Co Ltd オレフィン類重合触媒及びオレフィン系重合体の製造方法
JP2002338616A (ja) * 2001-05-14 2002-11-27 Sumitomo Chem Co Ltd オレフィン重合用触媒の評価方法

Also Published As

Publication number Publication date
JP2006516668A (ja) 2006-07-06
EP1590377A1 (en) 2005-11-02
EP1590377B1 (en) 2007-06-13
US7544749B2 (en) 2009-06-09
ATE364637T1 (de) 2007-07-15
DE602004006965D1 (de) 2007-07-26
WO2004069881A1 (en) 2004-08-19
US20060100092A1 (en) 2006-05-11

Similar Documents

Publication Publication Date Title
DE602004006965T2 (de) Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen
DE69738304T2 (de) Katalysator zur Alpha-Olefinpolymerisation
DE69817357T2 (de) Katalysator für die herstellung von olefinpolymeren
DE10358082A1 (de) Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
DE112011100521T5 (de) Katalysator für ethylenische Polymerisation und Verfahren zur Herstellung von ethylenischem Polymer
DE10359341A1 (de) Monocyclopentadienylkomplexe
DE102004027332A1 (de) Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE60011507T2 (de) Katalysator basierend auf einem Übergangsmetall aus den Gruppen 8, 9 und 10 für die Polymerisation von Olefinen
DE10352139A1 (de) Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem und Verfahren zur Herstellung von Polyolefinen
DE10130229A1 (de) Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
EP1373283A1 (de) Non-metallocene, verfahren zur herstellung von diesen und deren verwendung zur polymerisation von olefinen
DE102005057559A1 (de) Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE102004032581A1 (de) Polymerisationskatalysatoren, Hauptgruppenkoordinationsverbindungen, Verfahren zur Herstellung von Polyolefinen und Polyolefine
DE10057009A1 (de) Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
DE60205795T2 (de) Übergangsmetallverbindung, Katalysator für die Olefinpolymerisation und Verwendung des Katalysators für die Olefinpolymerisation
WO2002066522A1 (de) Übergangsmetallverbindung als katalysatorbestandteil, und verwendung zur herstellung von polyolefinen
DE10344659A1 (de) Polymerisationskatalysatoren, Verfahren zur Herstellung von Polyolefinen, Organoübergangsmetallverbindungen und Liganden
DE10305227A1 (de) Polymerisationskatalysatoren, Organoübergangsmetallverbindungen, Verfahren zur Herstellung von Polyolefinen und Polyolefine
DE10213191A1 (de) Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
DE102004056104A1 (de) Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme
DE10324541A1 (de) Organoübergangsmetallverbindung mit einem speziellen Substitutionsmuster, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE10208252A1 (de) Konvalent fixierte Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
DE60212361T2 (de) Olefinpolymerisationsverfahren mit übergangsmetallkomplexen
DE60303928T2 (de) Übergangsmetallverbindungen, deren herstellung und verwendung in katalysatorsystemen für die polymerisation und copolymerisation von olefinen
DE102005014395A1 (de) Monocyclopentadienylkomplexe

Legal Events

Date Code Title Description
8364 No opposition during term of opposition