DE60022996T2 - Verfahren zur herstellung von poly(1,4-cyclohexandicarboxylat) - Google Patents

Verfahren zur herstellung von poly(1,4-cyclohexandicarboxylat) Download PDF

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Publication number
DE60022996T2
DE60022996T2 DE60022996T DE60022996T DE60022996T2 DE 60022996 T2 DE60022996 T2 DE 60022996T2 DE 60022996 T DE60022996 T DE 60022996T DE 60022996 T DE60022996 T DE 60022996T DE 60022996 T2 DE60022996 T2 DE 60022996T2
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DE
Germany
Prior art keywords
diol
volatile
relatively non
reaction
cyclohexanedicarboxylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60022996T
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German (de)
English (en)
Other versions
DE60022996D1 (de
Inventor
Joseph Daniel BRUNELLE
Taeseok Jang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SABIC Global Technologies BV
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Application granted granted Critical
Publication of DE60022996D1 publication Critical patent/DE60022996D1/de
Publication of DE60022996T2 publication Critical patent/DE60022996T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6856—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/826—Metals not provided for in groups C08G63/83 - C08G63/86
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
DE60022996T 1999-03-30 2000-02-28 Verfahren zur herstellung von poly(1,4-cyclohexandicarboxylat) Expired - Fee Related DE60022996T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/281,529 US6084055A (en) 1999-03-30 1999-03-30 Method for preparing poly(1,4-cyclohexanedicarboxylates)
US281529 1999-03-30
PCT/US2000/005064 WO2000058382A2 (en) 1999-03-30 2000-02-28 Method for preparing poly(1,4-cyclohexane-dicarboxylates)

Publications (2)

Publication Number Publication Date
DE60022996D1 DE60022996D1 (de) 2005-11-10
DE60022996T2 true DE60022996T2 (de) 2006-06-29

Family

ID=23077688

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60022996T Expired - Fee Related DE60022996T2 (de) 1999-03-30 2000-02-28 Verfahren zur herstellung von poly(1,4-cyclohexandicarboxylat)

Country Status (6)

Country Link
US (1) US6084055A (enExample)
EP (2) EP1175455B1 (enExample)
JP (1) JP2002540269A (enExample)
DE (1) DE60022996T2 (enExample)
ES (1) ES2248058T3 (enExample)
WO (1) WO2000058382A2 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6458915B1 (en) * 2000-10-13 2002-10-01 Eastman Chemical Company Process for producing poly(1,4-cyclohexylenedimethylene 1,4-cyclohexanedicarboxylate) and the reactor grade polyester therefrom
US6448334B1 (en) 2000-12-19 2002-09-10 General Electric Company Translucent polycarbonate composition, method for preparation thereof, and articles derived therefrom
US6653440B2 (en) 2001-11-13 2003-11-25 Mitsubishi Gas Chemical Company Process for producing copolyester resin
ITMI20021293A1 (it) 2002-06-12 2003-12-12 Gen Electric Metodo per preparare poli(cicloesan-1,4-dicarbossilato) (i) da acido cicloesan-1,4-bicarbossilico e composizione
US6828410B2 (en) * 2002-07-10 2004-12-07 General Electric Company Method for preparing poly(cyclohexane-1,4-dicarboxylate)s from cyclohexane-1,4-dicarboxylic acid, and composition
EP1602683A4 (en) * 2003-03-11 2006-04-19 Mitsubishi Polyester Film Corp BIAXIALLY ORIENTED POLYESTER FOIL AND SEPARATE FOIL
US7169880B2 (en) * 2003-12-04 2007-01-30 Eastman Chemical Company Shaped articles from cycloaliphatic polyester compositions
US6930164B1 (en) 2004-06-15 2005-08-16 General Electric Company Telechelic ionomeric polyester and method of preparation thereof
DE102006027176B4 (de) * 2005-08-26 2015-08-06 Lurgi Zimmer Gmbh Verfahren und Vorrichtung zur Verringerung des Acetaldehydgehaltes von Polyestergranulat sowie Polyestergranulat
US8586701B2 (en) 2005-10-28 2013-11-19 Eastman Chemical Company Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7211634B1 (en) 2006-04-28 2007-05-01 Eastman Chemical Company Process for the preparation of polyesters containing 1,4-cyclohexanedimethanol
JP2008239783A (ja) * 2007-03-27 2008-10-09 Mitsubishi Chemicals Corp ポリエーテルエステルブロック共重合体およびその製造方法
KR20100087171A (ko) 2007-11-21 2010-08-03 이스트만 케미칼 컴파니 플라스틱 젖병, 다른 취입 성형된 제품, 및 이들의 제조 방법
US20100168328A1 (en) * 2008-12-30 2010-07-01 Ganesh Kannan Process for the manufacture of polycyclohexane dimethylene terephthalate copolymers from polyethylene terephthalate, and compositions and articles thereof
CN102698793A (zh) * 2012-06-06 2012-10-03 华东理工大学 一种用于环己烷催化氧化制环己醇和环己酮的催化剂
KR101690082B1 (ko) * 2016-10-11 2017-01-09 김석봉 생분해성 수지 조성물 및 그로부터 제조되는 생분해성 필름

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE592181A (enExample) * 1955-12-22
US4003883A (en) * 1975-10-28 1977-01-18 Eastman Kodak Company Polyesterether having commercially acceptable mold release characteristics
US4480086A (en) * 1983-09-09 1984-10-30 Eastman Kodak Company Radiation-resistant copolyesters
US4665153A (en) * 1986-05-20 1987-05-12 Eastman Kodak Company Copolyesterether bonding compositions and shaped articles utilizing the bonding compositions
US5399661A (en) * 1990-07-12 1995-03-21 General Electric Company Poly(alkylene cyclohexanedicarboxylate)-(alkylene terephthalate) copolyesters
NO912922L (no) * 1990-09-05 1992-03-06 Atochem North America Peroksyder for polymeriseringsreaksjoner.
DE4423141A1 (de) * 1994-07-01 1996-01-04 Hoechst Ag Polyester-Dispersionen als Additiv in Beschichtungsmitteln
US5633340A (en) * 1995-09-21 1997-05-27 Eastman Chemical Company Polyester molding compositions
US5859119A (en) * 1997-09-15 1999-01-12 General Electric Company Reinforced aliphatic polyester molding composition having improved ductility/flow properties

Also Published As

Publication number Publication date
JP2002540269A (ja) 2002-11-26
WO2000058382A3 (en) 2001-01-18
WO2000058382A2 (en) 2000-10-05
EP1175455B1 (en) 2005-10-05
ES2248058T3 (es) 2006-03-16
DE60022996D1 (de) 2005-11-10
US6084055A (en) 2000-07-04
EP1598385A1 (en) 2005-11-23
EP1175455A2 (en) 2002-01-30

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: SABIC INNOVATIVE PLASTICS IP B.V., BERGEN OP Z, NL

8328 Change in the person/name/address of the agent

Representative=s name: PATENT- UND RECHTSANWAELTE BARDEHLE, PAGENBERG, DO

8339 Ceased/non-payment of the annual fee