DE3781133T2 - Herstellung von polymilchsaeure und copolymeren daraus. - Google Patents

Herstellung von polymilchsaeure und copolymeren daraus.

Info

Publication number
DE3781133T2
DE3781133T2 DE8787202432T DE3781133T DE3781133T2 DE 3781133 T2 DE3781133 T2 DE 3781133T2 DE 8787202432 T DE8787202432 T DE 8787202432T DE 3781133 T DE3781133 T DE 3781133T DE 3781133 T2 DE3781133 T2 DE 3781133T2
Authority
DE
Germany
Prior art keywords
lactide
dissolved
organic solvent
water
polylactic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE8787202432T
Other languages
German (de)
English (en)
Other versions
DE3781133D1 (de
Inventor
Vries Klaas Sybren De
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo Nobel NV
Original Assignee
Akzo NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo NV filed Critical Akzo NV
Publication of DE3781133D1 publication Critical patent/DE3781133D1/de
Application granted granted Critical
Publication of DE3781133T2 publication Critical patent/DE3781133T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08Lactones or lactides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D319/00Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D319/101,4-Dioxanes; Hydrogenated 1,4-dioxanes
    • C07D319/121,4-Dioxanes; Hydrogenated 1,4-dioxanes not condensed with other rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
DE8787202432T 1986-12-19 1987-12-07 Herstellung von polymilchsaeure und copolymeren daraus. Expired - Fee Related DE3781133T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL8603231 1986-12-19

Publications (2)

Publication Number Publication Date
DE3781133D1 DE3781133D1 (de) 1992-09-17
DE3781133T2 true DE3781133T2 (de) 1993-06-24

Family

ID=19849020

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8787202432T Expired - Fee Related DE3781133T2 (de) 1986-12-19 1987-12-07 Herstellung von polymilchsaeure und copolymeren daraus.

Country Status (8)

Country Link
US (1) US4797468A (https=)
EP (1) EP0275581B1 (https=)
JP (1) JPS63165430A (https=)
AT (1) ATE79386T1 (https=)
CA (1) CA1331193C (https=)
DE (1) DE3781133T2 (https=)
ES (1) ES2052551T3 (https=)
GR (1) GR3006204T3 (https=)

Families Citing this family (127)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3708916A1 (de) * 1987-03-19 1988-09-29 Boehringer Ingelheim Kg Verfahren zur reinigung resorbierbarer polyester
WO1988010260A1 (fr) * 1987-06-16 1988-12-29 Boehringer Ingelheim Kg ''meso-lactide'' et son procede de preparation
US5214159A (en) * 1987-06-16 1993-05-25 Boehringer Ingelheim Gmbh Meso-lactide
US5319107A (en) * 1990-09-18 1994-06-07 Biopak Technology, Ltd. Method to produce cyclic esters
US5274127A (en) * 1990-09-18 1993-12-28 Biopak Technology, Ltd. Lactide production from dehydration of aqueous lactic acid feed
US5767222A (en) * 1988-08-08 1998-06-16 Chronopol, Inc. Degradable polydioxaneone-based materials
US5424346A (en) * 1988-08-08 1995-06-13 Ecopol, Llc Biodegradable replacement of crystal polystyrene
US6323307B1 (en) 1988-08-08 2001-11-27 Cargill Dow Polymers, Llc Degradation control of environmentally degradable disposable materials
US5180765A (en) * 1988-08-08 1993-01-19 Biopak Technology, Ltd. Biodegradable packaging thermoplastics from lactides
JP2714454B2 (ja) * 1988-11-07 1998-02-16 三井東圧化学株式会社 生体吸収性ポリエステルの製造方法
US5149833A (en) * 1989-05-26 1992-09-22 Boehringer Ingelheim Gmbh Process for preparing D,L-Lactide
DE3917178A1 (de) * 1989-05-26 1990-11-29 Boehringer Ingelheim Kg Verbessertes verfahren zur herstellung von d,l-lactid
US5091544A (en) * 1990-05-08 1992-02-25 E. I. Du Pont De Nemours And Company Process for rapid conversion of oligomers to cyclic esters
AU8283391A (en) * 1990-07-13 1992-02-04 E.I. Du Pont De Nemours And Company High yield recycle process for lactide
US5076983A (en) * 1990-07-16 1991-12-31 E. I. Du Pont De Nemours And Company Polyhydroxy acid films
US5332839A (en) * 1990-09-18 1994-07-26 Biopak Technology, Ltd. Catalytic production of lactide directly from lactic acid
US5117008A (en) * 1990-10-23 1992-05-26 E. I. Du Pont De Nemours And Company Solvent scrubbing recovery of lactide and other dimeric cyclic esters
US5089632A (en) * 1991-01-30 1992-02-18 E. I. Du Pont De Nemours And Company Process for preparing cyclic esters using a fluorocarbon
US5264617A (en) * 1991-11-22 1993-11-23 E. I. Du Pont De Nemours And Company Preparation of alkyl esters by depolymerization
US5264626A (en) * 1991-11-22 1993-11-23 E. I. Du Pont De Nemours And Company Rapid depolymerization of polyhydroxy acids
US5229528A (en) * 1991-11-22 1993-07-20 E. I. Du Pont De Nemours And Company Rapid depolymerization of polyhydroxy acids
US5264614A (en) * 1991-11-22 1993-11-23 E. I. Du Pont De Nemours And Company Recovery of polyhydroxy acids
US5268507A (en) * 1991-11-22 1993-12-07 E. I. Du Pont De Nemours And Company Preparation of amide derivatives of hydroxy acids
ATE466897T1 (de) * 1992-01-24 2010-05-15 Cargill Inc Kontinuierliches verfahren zur herstellung von lactid und lactid polymeren
US5258488A (en) * 1992-01-24 1993-11-02 Cargill, Incorporated Continuous process for manufacture of lactide polymers with controlled optical purity
US5247059A (en) * 1992-01-24 1993-09-21 Cargill, Incorporated Continuous process for the manufacture of a purified lactide from esters of lactic acid
US6005067A (en) * 1992-01-24 1999-12-21 Cargill Incorporated Continuous process for manufacture of lactide polymers with controlled optical purity
US5247058A (en) * 1992-01-24 1993-09-21 Cargill, Incorporated Continuous process for manufacture of lactide polymers with controlled optical purity
US6326458B1 (en) 1992-01-24 2001-12-04 Cargill, Inc. Continuous process for the manufacture of lactide and lactide polymers
US5142023A (en) * 1992-01-24 1992-08-25 Cargill, Incorporated Continuous process for manufacture of lactide polymers with controlled optical purity
US5236560A (en) * 1992-03-13 1993-08-17 E. I. Du Pont De Nemours And Company Solventless dimeric cyclic ester distillation process
US5675021A (en) * 1992-03-19 1997-10-07 Chronopol, Inc. Method to produce and purify cyclic esters
US5420304A (en) * 1992-03-19 1995-05-30 Biopak Technology, Ltd. Method to produce cyclic esters
US5686630A (en) * 1993-09-29 1997-11-11 Chronopol, Inc. Purifying cyclic esters by aqueous solvent extraction
IT1256918B (it) * 1992-08-04 1995-12-27 Mini Ricerca Scient Tecnolog Procedimento per la produzione di poli acido lattico.
US5264592A (en) * 1992-09-08 1993-11-23 Camelot Technologies Inc. Lactide melt recrystallization
US5278256A (en) * 1992-09-16 1994-01-11 E. I. Du Pont De Nemours And Company Rapidly degradable poly (hydroxyacid) compositions
US5338822A (en) * 1992-10-02 1994-08-16 Cargill, Incorporated Melt-stable lactide polymer composition and process for manufacture thereof
DE69330046T2 (de) * 1992-10-02 2001-11-15 Cargill, Inc. Schmelzstabiles lactidpolymergewebe und verfahren zu seiner herstellung
NZ256978A (en) * 1992-10-02 1996-05-28 Cargill Inc Paper product coated with a poly(lactide) composition comprising no more than 5 wt % lactide monomer, the poly(lactide) having a number average mw of 10,000 to 200,000
US6005068A (en) 1992-10-02 1999-12-21 Cargill Incorporated Melt-stable amorphous lactide polymer film and process for manufacture thereof
US5631066A (en) * 1993-01-25 1997-05-20 Chronopol, Inc. Process for making metalized films and films produced therefrom
CA2115472C (en) 1993-02-17 2002-08-13 William George O'brien Melt crystallization purification of lactides
US5618911A (en) * 1993-08-19 1997-04-08 Toyo Boseki Kabushiki Kaisha Polymer containing lactic acid as its constituting unit and method for producing the same
EP0738159A1 (en) * 1993-12-10 1996-10-23 The Procter & Gamble Company pH-MODIFIED POLYMER COMPOSITIONS WITH ENHANCED BIODEGRADABILITY
US5639466A (en) * 1994-02-24 1997-06-17 Chronopol, Inc. Method for packaging foodstuffs
US5521278A (en) * 1994-08-18 1996-05-28 Ecological Chemical Products Integrated process for the manufacture of lactide
US5719256A (en) * 1995-10-19 1998-02-17 Mitsu Toatsu Chemicals, Inc. Process for preparing polycondensation polymer compound
JPH10109983A (ja) * 1996-10-04 1998-04-28 Mitsubishi Gas Chem Co Inc 環状エステルの製造方法および精製方法
US6362308B1 (en) 2000-08-10 2002-03-26 Alkermes Controlled Therapeutics Inc. Ii Acid end group poly(d,l-lactide-co-glycolide) copolymers high glycolide content
DE602006018078D1 (de) * 2006-07-14 2010-12-16 Kimberly Clark Co Biologisch abbaubarer aliphatisch-aromatischer copolyester zur verwendung in vliesstoffen
KR101297937B1 (ko) 2006-07-14 2013-08-19 킴벌리-클라크 월드와이드, 인크. 부직 웹에 사용하기 위한 생분해성 지방족 폴리에스테르
MX2009000527A (es) * 2006-07-14 2009-01-27 Kimberly Clark Co Acido polilactico biodegradable para su uso en telas no tejidas.
MX2009002159A (es) * 2006-08-31 2009-03-11 Kimberly Clark Co Peliculas biodegradables con alta capacidad para respirar.
JP2010513594A (ja) * 2006-12-15 2010-04-30 キンバリー クラーク ワールドワイド インコーポレイテッド 繊維の形成に使用する生分解性ポリエステル
WO2008073101A1 (en) * 2006-12-15 2008-06-19 Kimberly-Clark Worldwide, Inc. Biodegradable polylactic acids for use in forming fibers
KR101422317B1 (ko) * 2007-08-22 2014-07-30 킴벌리-클라크 월드와이드, 인크. 다성분 생분해성 필라멘트 및 그로부터 형성되는 부직 웹
US10848347B2 (en) 2007-08-31 2020-11-24 Level 3 Communications, Llc Managing virtual local area network domains
US10313191B2 (en) 2007-08-31 2019-06-04 Level 3 Communications, Llc System and method for managing virtual local area networks
EP2220277A2 (en) * 2007-12-13 2010-08-25 Kimberly-Clark Worldwide, Inc. Biodegradable fibers formed from a thermoplastic composition containing polylactic acid and a polyether copolymer
US8227658B2 (en) 2007-12-14 2012-07-24 Kimberly-Clark Worldwide, Inc Film formed from a blend of biodegradable aliphatic-aromatic copolyesters
US7998888B2 (en) * 2008-03-28 2011-08-16 Kimberly-Clark Worldwide, Inc. Thermoplastic starch for use in melt-extruded substrates
US8338508B2 (en) * 2008-05-14 2012-12-25 Kimberly-Clark Worldwide, Inc. Water-sensitive film containing an olefinic elastomer
US8147965B2 (en) 2008-05-14 2012-04-03 Kimberly-Clark Worldwide, Inc. Water-sensitive film containing thermoplastic polyurethane
WO2009145778A1 (en) * 2008-05-30 2009-12-03 Kimberly-Clark Worldwide, Inc. Polylactic acid fibers
US8759446B2 (en) 2008-06-30 2014-06-24 Fina Technology, Inc. Compatibilized polypropylene and polylactic acid blends and methods of making and using same
US8268913B2 (en) * 2008-06-30 2012-09-18 Fina Technology, Inc. Polymeric blends and methods of using same
US8545971B2 (en) * 2008-06-30 2013-10-01 Fina Technology, Inc. Polymeric compositions comprising polylactic acid and methods of making and using same
US8759279B2 (en) * 2008-06-30 2014-06-24 Kimberly-Clark Worldwide, Inc. Fragranced biodegradable film
US8188185B2 (en) * 2008-06-30 2012-05-29 Kimberly-Clark Worldwide, Inc. Biodegradable packaging film
US8927617B2 (en) 2008-06-30 2015-01-06 Kimberly-Clark Worldwide, Inc. Fragranced water-sensitive film
CA2742361C (en) * 2008-11-07 2013-07-30 Samyang Corporation Highly purified polylactic acid or a derivative thereof, a salt of the same, and purification method thereof
US8329601B2 (en) 2008-12-18 2012-12-11 Kimberly-Clark Worldwide, Inc. Biodegradable and renewable film
US8283006B2 (en) * 2008-12-18 2012-10-09 Kimberly-Clark Worldwide, Inc. Injection molding material containing starch and plant protein
US8968787B2 (en) 2010-05-24 2015-03-03 Micro Powders, Inc. Composition comprising biodegradable polymers for use in a cosmetic composition
US10753023B2 (en) 2010-08-13 2020-08-25 Kimberly-Clark Worldwide, Inc. Toughened polylactic acid fibers
US8936740B2 (en) 2010-08-13 2015-01-20 Kimberly-Clark Worldwide, Inc. Modified polylactic acid fibers
US8900834B2 (en) 2010-10-28 2014-12-02 Total Research & Technology Feluy S.A. Process for polylactic acid production using monascus
US8461262B2 (en) 2010-12-07 2013-06-11 Kimberly-Clark Worldwide, Inc. Polylactic acid fibers
US20120245321A1 (en) 2011-03-25 2012-09-27 Hyundai Motor Company Manufacturing lactide from lactic acid
US20120245322A1 (en) 2011-03-25 2012-09-27 Hyundai Motor Company Manufacturing lactide from lactic acid
KR101326521B1 (ko) 2011-05-26 2013-11-07 현대자동차주식회사 유산으로부터 락타이드의 제조 방법
US20130210621A1 (en) 2012-02-10 2013-08-15 Kimberly-Clark Worldwide, Inc. Breathable Film Formed from a Renewable Polyester
US10858762B2 (en) 2012-02-10 2020-12-08 Kimberly-Clark Worldwide, Inc. Renewable polyester fibers having a low density
US8980964B2 (en) 2012-02-10 2015-03-17 Kimberly-Clark Worldwide, Inc. Renewable polyester film having a low modulus and high tensile elongation
US8637130B2 (en) 2012-02-10 2014-01-28 Kimberly-Clark Worldwide, Inc. Molded parts containing a polylactic acid composition
US8975305B2 (en) 2012-02-10 2015-03-10 Kimberly-Clark Worldwide, Inc. Rigid renewable polyester compositions having a high impact strength and tensile elongation
US9040598B2 (en) 2012-02-10 2015-05-26 Kimberly-Clark Worldwide, Inc. Renewable polyester compositions having a low density
KR20150096688A (ko) 2012-12-19 2015-08-25 킴벌리-클라크 월드와이드, 인크. 저밀도 섬유 및 그 형성방법
WO2014199276A1 (en) 2013-06-12 2014-12-18 Kimberly-Clark Worldwide, Inc. Polymeric material for use in thermal insulation
ES2837999T3 (es) 2013-06-12 2021-07-01 Kimberly Clark Co Material polimérico con una distribución multimodal del tamaño de los poros
MX378767B (es) 2013-06-12 2025-03-10 Kimberly Clark Co Material de poliolefina que tiene baja densidad.
EP3007575B1 (en) 2013-06-12 2021-09-01 Kimberly-Clark Worldwide, Inc. Garment containing a porous polymeric material
US11965083B2 (en) 2013-06-12 2024-04-23 Kimberly-Clark Worldwide, Inc. Polyolefin material having a low density
RU2630792C2 (ru) 2013-06-12 2017-09-13 Кимберли-Кларк Ворлдвайд, Инк. Методика инициации порообразования
KR102202850B1 (ko) 2013-06-12 2021-01-14 킴벌리-클라크 월드와이드, 인크. 건물 단열재
MX383673B (es) 2013-06-12 2025-03-14 Kimberly Clark Co Fibras de poliolefina porosas.
WO2015187198A1 (en) 2014-06-06 2015-12-10 Kimberly-Clark Worldwide, Inc. Hollow porous fibers
KR101467202B1 (ko) * 2013-06-21 2014-12-01 한국화학연구원 젖산으로부터 락타이드 직접 제조용 성형 촉매 및 이의 제조 방법
MX364107B (es) 2013-08-09 2019-04-11 Kimberly Clark Co Sistema de suministro para agentes activos.
MX364997B (es) 2013-08-09 2019-05-16 Kimberly Clark Co Material polimerico anisotropico.
KR101831079B1 (ko) 2013-08-09 2018-02-21 킴벌리-클라크 월드와이드, 인크. 복수모드 포어 분포를 갖는 미세입자
BR112016002589B1 (pt) 2013-08-09 2021-08-03 Kimberly-Clark Worldwide, Inc Material polimérico flexível moldado, membro tubular, e, método de moldagem de um material polimérico
US10919229B2 (en) 2013-08-09 2021-02-16 Kimberly-Clark Worldwide, Inc. Polymeric material for three-dimensional printing
JP2016527374A (ja) 2013-08-09 2016-09-08 キンバリー クラーク ワールドワイド インコーポレイテッド 高分子材料の空隙率を選択的に制御するための技術
WO2015066588A1 (en) 2013-11-04 2015-05-07 The Procter & Gamble Company Thermoplastic polymer compositions having co-continuous plate-like morphology
WO2015187520A1 (en) 2014-06-02 2015-12-10 The Procter & Gamble Company Multi-layered thermoplastic polymer films comprising polylactic acid
CN107124874A (zh) 2014-06-06 2017-09-01 金伯利-克拉克环球有限公司 由多孔聚合物片材形成的热成型制品
RU2017118768A (ru) 2014-11-26 2018-11-30 Кимберли-Кларк Ворлдвайд, Инк. Биаксиально растянутая пористая пленка
WO2016085712A1 (en) 2014-11-26 2016-06-02 Kimberly-Clark Worldwide, Inc. Annealed porous polyolefin material
US10869790B2 (en) 2015-01-30 2020-12-22 Kimberly-Clark Worldwide, Inc. Absorbent article package with reduced noise
CN107205871B (zh) 2015-01-30 2019-11-29 金伯利-克拉克环球有限公司 用于吸收制品的具有降低的噪声的膜
US10843372B1 (en) * 2015-06-22 2020-11-24 Purdue Research Foundation Methods and compositions for preparing particle boards
EP3387173B1 (en) 2015-12-11 2021-02-03 Kimberly-Clark Worldwide, Inc. Multi-stage drawing technique for forming porous fibers
CN108368656B (zh) 2015-12-11 2022-08-12 金伯利-克拉克环球有限公司 用于形成多孔纤维的方法
WO2017106267A1 (en) 2015-12-17 2017-06-22 Kimberly-Clark Worldwide, Inc. Color-changing polymeric material
US20260042897A1 (en) 2022-08-02 2026-02-12 Sk Leaveo Co., Ltd. Biodegradable resin composition and biodegradable molded article comprising same
EP4563636A4 (en) 2022-08-02 2025-10-29 Sk Leaveo Co Ltd METHOD FOR PREPARING A BIODEGRADABLE RESIN COMPOSITION, BIODEGRADABLE RESIN COMPOSITION SO PREPARED AND BIODEGRADABLE MOLDED PRODUCT COMPRISING IT
KR102953201B1 (ko) 2023-05-26 2026-04-15 에스케이리비오 주식회사 생분해성 수지 조성물 및 이를 포함하는 생분해성 성형품
KR20240176689A (ko) 2023-06-16 2024-12-24 에스케이리비오 주식회사 생분해성 수지 조성물 및 이를 포함하는 생분해성 원사
KR102877044B1 (ko) 2023-07-05 2025-10-24 에스케이리비오 주식회사 생분해성 수지 조성물 및 이를 포함하는 생분해성 성형품
KR20250020901A (ko) 2023-08-04 2025-02-11 에스케이리비오 주식회사 생분해성 수지 조성물 및 이를 포함하는 생분해성 성형품
KR20250035159A (ko) 2023-09-05 2025-03-12 에스케이리비오 주식회사 생분해성 부직포의 제조 방법 및 이에 의해 제조된 생분해성 부직포
US20250075031A1 (en) 2023-09-05 2025-03-06 Sk Leaveo Co., Ltd. Eco-friendly biodegradable resin composition and biodegradable nonwoven fabric
WO2025076732A1 (en) 2023-10-11 2025-04-17 The Procter & Gamble Company A biodegradable flexible package with a personal care composition
EP4556517A1 (en) 2023-11-14 2025-05-21 SK leaveo Co., Ltd. Biodegradable resin composition and biodegradable molded article including the same
JP2025089271A (ja) 2023-12-01 2025-06-12 エスケー リーヴィオ カンパニー リミテッド 生分解性樹脂組成物、及びこれを含む生分解性成形品

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6609613A (https=) * 1966-07-08 1968-01-09
US3457280A (en) * 1967-06-12 1969-07-22 American Cyanamid Co Alpha-glycolide and methods for the isolation thereof
US3435008A (en) * 1967-08-22 1969-03-25 American Cyanamid Co Method for preparation of isomerically pure beta-glycolide and polymerization method for glycolide compositions employing partial hydrolyzate of said beta-glycolide
US3597449A (en) * 1967-11-16 1971-08-03 American Cyanamid Co Stable glycolide and lactide composition
US3839297A (en) * 1971-11-22 1974-10-01 Ethicon Inc Use of stannous octoate catalyst in the manufacture of l(-)lactide-glycolide copolymer sutures
US4048256A (en) * 1976-06-01 1977-09-13 American Cyanamid Company Normally-solid, bioabsorbable, hydrolyzable, polymeric reaction product
US4539981A (en) * 1982-11-08 1985-09-10 Johnson & Johnson Products, Inc. Absorbable bone fixation device
JPS6136321A (ja) * 1984-07-27 1986-02-21 Daicel Chem Ind Ltd 新規なポリマ−およびその樹脂組成物
US4727163A (en) * 1985-07-11 1988-02-23 E. I. Du Pont De Nemours And Company Process for preparing highly pure cyclic esters
US4650851A (en) * 1986-03-19 1987-03-17 Pfizer Hospital Products Group, Inc. Purification of glycolide

Also Published As

Publication number Publication date
CA1331193C (en) 1994-08-02
US4797468A (en) 1989-01-10
EP0275581B1 (en) 1992-08-12
ATE79386T1 (de) 1992-08-15
EP0275581A1 (en) 1988-07-27
DE3781133D1 (de) 1992-09-17
JPS63165430A (ja) 1988-07-08
ES2052551T3 (es) 1994-07-16
GR3006204T3 (https=) 1993-06-21

Similar Documents

Publication Publication Date Title
DE3781133T2 (de) Herstellung von polymilchsaeure und copolymeren daraus.
DE3688213T2 (de) Polymer, seine herstellung und verwendung.
DE69320467T2 (de) Verfahren zur herstellung von cyclischen estern aus hydroxysäuren und deren derivaten
DE69103159T2 (de) Herstellung von Lactid durch Dehydrierung einer mit wässeriger Milchsäure beschickten Vorlage.
DE1295828B (de) Verfahren zur Herstellung von im wesentlichen amorphen Polyamiden
DE69302098T2 (de) Zusammensetzungen von hexitan-fettsäureestern
EP0941216B1 (de) Verfahren zur herstellung von arylcyanaten
WO1998028263A1 (de) Kreatin-pyruvate und verfahren zu deren herstellung
DE60317581T2 (de) Verfahren zur reiningung von lactid
DE1963645C3 (de) Verfahren zur Herstellung von Penicillinen
DE69729041T2 (de) Herstellungsverfahren und Reinigungsverfahren für cyclische Ester
DE68909573T2 (de) Verfahren zur Gewinnung von Milchsäure aus Lösungen, die sie enthalten.
EP0026311A1 (de) Verfahren zur Herstellung von sehr reinem epsilon-Caprolacton
DE69715638T2 (de) Verfahren zur Herstellung von gereinigtem kristallinen Iohexol
DE69600144T2 (de) Verfahren zur Reinigung und Krystallisierung von Iopamidol
DE2163539C3 (de) Herstellung von Epsilon-Caprolactam und O-Acetylcyclohexanonoxim
EP1517731B1 (de) Verfahren zur herstellung einer spezifischen kristallmodifikation von 2-(2-chlor-4-mesyl-benzoyl)-cyclohexan-1,3-dion
DE2453365A1 (de) Verfahren zur herstellung von n-trimethylsilylacetamid
DE2854152C2 (https=)
DE60002922T2 (de) Verfahren zur herstellung und isolierung von 9-deoxo-9(z)-hydroxyiminoerythromycin a
EP3424914A1 (de) Verfahren zur extraktion von 5-hydroxymethylfurfural (5-hmf)
DE2244179C3 (de) D-threo-l-p-substituierte Phenyl-2dichloracetamidopropan-I.S-diol-ester, Verfahren zu ihrer Herstellung und diese Verbindungen enthaltende Arzneimittel
DE865901C (de) Verfahren zur Herstellung von monomeren und polymeren Vinylaminen
DE2138857B2 (de) Verfahren zur herstellung von 2,3- disubstituierten 1,3-butadienen
DE3830861C2 (https=)

Legal Events

Date Code Title Description
8332 No legal effect for de
8370 Indication related to discontinuation of the patent is to be deleted
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: AKZO NOBEL N.V., ARNHEIM/ARNHEM, NL

8339 Ceased/non-payment of the annual fee