RU2017118768A - Биаксиально растянутая пористая пленка - Google Patents

Биаксиально растянутая пористая пленка Download PDF

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RU2017118768A
RU2017118768A RU2017118768A RU2017118768A RU2017118768A RU 2017118768 A RU2017118768 A RU 2017118768A RU 2017118768 A RU2017118768 A RU 2017118768A RU 2017118768 A RU2017118768 A RU 2017118768A RU 2017118768 A RU2017118768 A RU 2017118768A
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film according
film
longitudinal direction
transverse direction
approximately
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RU2017118768A
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RU2017118768A3 (ru
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Василий А. ТОПОЛКАРАЕВ
Райан Дж. МАКИНИНИ
Стивен Р. СТОППЕР
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Кимберли-Кларк Ворлдвайд, Инк.
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Publication of RU2017118768A publication Critical patent/RU2017118768A/ru

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
    • B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
    • B29C55/14—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively
    • B29C55/143—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively firstly parallel to the direction of feed and then transversely thereto
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001—Combinations of extrusion moulding with other shaping operations
    • B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07—Flat, e.g. panels
    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/285—Feeding the extrusion material to the extruder
    • B29C48/297—Feeding the extrusion material to the extruder at several locations, e.g. using several hoppers or using a separate additive feeding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B29C48/402—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders the screws having intermeshing parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B29C48/405—Intermeshing co-rotating screws
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/465—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using rollers
    • B29C48/467—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using rollers using single rollers, e.g. provided with protrusions, closely surrounded by a housing with movement of the material in the axial direction
    • B29C48/468—Cavity transfer mixing devices, i.e. a roller and surrounding barrel both provided with cavities; Barrels and rollers therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50—Details of extruders
    • B29C48/505—Screws
    • B29C48/565—Screws having projections other than the thread, e.g. pins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911—Cooling
    • B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
    • B29C48/914—Cooling of flat articles, e.g. using specially adapted supporting means cooling drums
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00—Producing flat articles, e.g. films or sheets
    • B29D7/01—Films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B32B27/205—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents the fillers creating voids or cavities, e.g. by stretching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/327—Layered products comprising a layer of synthetic resin comprising polyolefins comprising polyolefins obtained by a metallocene or single-site catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92514—Pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10—Polymers of propylene
    • B29K2023/12—PP, i.e. polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2463/00—Use of EP, i.e. epoxy resins or derivatives thereof as filler

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)

Claims (22)

1. Пленка, которая содержит термопластичную композицию, которая содержит непрерывную фазу, которая включает полиолефиновый матричный полимер, и добавку-нановключение, диспергированную в непрерывной фазе в форме дискретных доменов, где пленка биаксиально растянута в продольном направлении и поперечном направлении с образованием пористой сети в композиции, где пористая сеть содержит нанопоры, имеющие осевой размер и размер в поперечном сечении, при этом максимальный размер в поперечном сечении нанопор составляет приблизительно 800 нанометров или меньше, и при этом дополнительно по меньшей мере часть нанопор ориентирована в поперечном направлении так, что осевой размер, как правило, проходит в поперечном направлении, а размер в поперечном сечении, как правило, проходит в продольном направлении.
2. Пленка по п. 1, где нанопоры имеют максимальный осевой размер в диапазоне от приблизительно 100 до приблизительно 5000 нанометров.
3. Пленка по п. 1, где по меньшей мере часть нанопор ориентирована в продольном направлении так, что осевой размер, как правило, проходит в продольном направлении, а размер в поперечном сечении, как правило, проходит в поперечном направлении.
4. Пленка по п. 1, где соотношение сторон нанопор составляет от приблизительно 1 до приблизительно 100.
5. Пленка по п. 1, где пористая сеть также содержит множество микропор, которые имеют максимальный размер в поперечном сечении, составляющий приблизительно 0,2 микрометра или больше.
6. Пленка по п. 1, где полиолефиновый матричный полимер имеет показатель текучести расплава, составляющий от приблизительно 0,5 до приблизительно 80 грамм за 10 минут, определенный при нагрузке, составляющей 2160 грамм, и при 230°C в соответствии с ASTM D1238.
7. Пленка по п. 1, где полиолефиновый матричный полимер представляет собой, по сути, изотактический гомополимер или сополимер полипропилена, содержащий по меньшей мере приблизительно 90% по весу пропилена.
8. Пленка по п. 1, где непрерывная фаза составляет от приблизительно 60 вес. % до приблизительно 99 вес. % термопластичной композиции.
9. Пленка по п. 1, где добавка-нановключение представляет собой полиэпоксид.
10. Пленка по п. 1, где соотношение показателя текучести расплава полиолефинового матричного полимера и показателя текучести расплава добавки-нановключения составляет от приблизительно 0,2 до приблизительно 8.
11. Пленка по п. 1, где добавка-нановключение находится в форме наноразмерных доменов, где наноразмерные домены имеют максимальный размер в поперечном сечении, составляющий от приблизительно 1 нанометра до приблизительно 1000 нанометров.
12. Пленка по п. 1, где добавка-нановключение составляет от приблизительно 0,05 вес. % до приблизительно 20 вес. % композиции в пересчете на вес непрерывной фазы.
13. Пленка по п. 1, где композиция дополнительно содержит добавку-микровключение, диспергированную в непрерывной фазе в форме дискретных доменов.
14. Пленка по п. 1, где полимер в добавке-микровключении имеет температуру стеклования, составляющую приблизительно 0°C или больше.
15. Пленка по п. 1, где термопластичная композиция дополнительно содержит модификатор поверхности раздела фаз.
16. Пленка по п. 1, где пленка характеризуется максимальным удлинением в продольном направлении, составляющим приблизительно 50% или больше, и максимальным удлинением в поперечном направлении, составляющим приблизительно 25% или больше.
17. Пленка по п. 1, где пленка характеризуется скоростью проникновения водяного пара, составляющей приблизительно 300 г/м2/24 часа или больше.
18. Пленка по п. 1, где пленка характеризуется значением мутности, составляющим приблизительно 20% или меньше, и/или суммарной светопропускаемостью в диапазоне длин волн 400-800 нанометров, составляющей приблизительно 75% или больше, что определено в соответствии с ASTM D1003-13, процедура A.
19. Слоистый материал, содержащий пленку по п. 1 и дополнительный слой.
20. Способ образования пленки по п. 1, при этом способ предусматривает биаксиальное растягивание пленки в продольном направлении и в поперечном направлении.
21. Способ по п. 20, где пленку растягивают в продольном направлении и поперечном направлении при температуре, ниже температуры плавления матричного полимера.
22. Способ по п. 20, где пленку растягивают в продольном направлении и поперечном направлении до степени растягивания, составляющей от приблизительно 1,1 до приблизительно 5,0.
RU2017118768A 2014-11-26 2015-11-17 Биаксиально растянутая пористая пленка RU2017118768A (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462084712P 2014-11-26 2014-11-26
US62/084,712 2014-11-26
US201462090427P 2014-12-11 2014-12-11
US62/090,427 2014-12-11
PCT/US2015/061081 WO2016085709A1 (en) 2014-11-26 2015-11-17 Biaxially stretched porous film

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RU2017118768A3 RU2017118768A3 (ru) 2018-11-30
RU2017118768A true RU2017118768A (ru) 2018-11-30

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EP (1) EP3224033B1 (ru)
KR (1) KR101854581B1 (ru)
CN (1) CN107107431B (ru)
AU (1) AU2015353884B2 (ru)
BR (1) BR112017009046B1 (ru)
MX (1) MX2017005867A (ru)
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AU2015353884A1 (en) 2017-06-08
MX2017005867A (es) 2017-06-26
RU2017118768A3 (ru) 2018-11-30
BR112017009046B1 (pt) 2021-10-05
US20170305061A1 (en) 2017-10-26
KR20170083086A (ko) 2017-07-17
EP3224033B1 (en) 2019-09-11
CN107107431A (zh) 2017-08-29
US11148347B2 (en) 2021-10-19
AU2015353884B2 (en) 2020-07-02
CN107107431B (zh) 2020-03-06
BR112017009046A2 (pt) 2018-02-06

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