RU2016107419A - Анизотропный полимерный материал - Google Patents

Анизотропный полимерный материал Download PDF

Info

Publication number
RU2016107419A
RU2016107419A RU2016107419A RU2016107419A RU2016107419A RU 2016107419 A RU2016107419 A RU 2016107419A RU 2016107419 A RU2016107419 A RU 2016107419A RU 2016107419 A RU2016107419 A RU 2016107419A RU 2016107419 A RU2016107419 A RU 2016107419A
Authority
RU
Russia
Prior art keywords
zone
material according
polymer material
polymer
ratio
Prior art date
Application number
RU2016107419A
Other languages
English (en)
Inventor
Василий А. ТОПОЛКАРАЕВ
Райан Дж. МАКИНИНИ
Нил Т. ШОЛ
Марк М. МЛЕЗИВА
Original Assignee
Кимберли-Кларк Ворлдвайд, Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Кимберли-Кларк Ворлдвайд, Инк. filed Critical Кимберли-Кларк Ворлдвайд, Инк.
Publication of RU2016107419A publication Critical patent/RU2016107419A/ru

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/35Composite foams, i.e. continuous macromolecular foams containing discontinuous cellular particles or fragments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/04Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/20Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
    • B29C44/22Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length consisting of at least two parts of chemically or physically different materials, e.g. having different densities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/3415Heating or cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/201Pre-melted polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/08Ingredients agglomerated by treatment with a binding agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869Acids or derivatives thereof
    • C08L23/0884Epoxide containing esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/04Polyesters derived from hydroxycarboxylic acids
    • B29K2067/046PLA, i.e. polylactic acid or polylactide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16Fillers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/25Solid
    • B29K2105/253Preform
    • B29K2105/256Sheets, plates, blanks or films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2423/00Use of polyalkenes or derivatives thereof as filler
    • B29K2423/04Polymers of ethylene
    • B29K2423/08Use of copolymers of ethylene as filler
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2423/00Use of polyalkenes or derivatives thereof as filler
    • B29K2423/10Polymers of propylene
    • B29K2423/14Copolymers of polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • B29L2007/002Panels; Plates; Sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • B29L2007/008Wide strips, e.g. films, webs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10Homopolymers or copolymers of propene
    • C08J2423/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10Homopolymers or copolymers of propene
    • C08J2423/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/14Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Claims (40)

1. Полимерный материал, где полимерный материал образован из термопластичной композиции, содержащей непрерывную фазу, которая содержит матричный полимер, и дополнительно где добавка микровключения и добавка нановключения диспергированы в непрерывной фазе в форме дискретных доменов, где полимерный материал определяет первую зону, которая граничит со второй зоной, где поровая сеть образована внутри первой зоны так, что первая зона обладает большим объемом пор, чем вторая зона.
2. Полимерный материал по п. 1, где средний объем пор материала внутри первой зоны составляет от приблизительно 15% до приблизительно 80% на см3, предпочтительно от приблизительно 20% до приблизительно 70% и более предпочтительно от приблизительно 30% до приблизительно 60% на кубический сантиметр.
3. Полимерный материал по п. 2, где средний объем пор материала внутри второй зоны составляет менее 15% и предпочтительно от 0% до приблизительно 10%.
4. Полимерный материал по п. 1, где отношение показателя плотности материала внутри первой зоны к показателю плотности материала внутри второй зоны составляет от приблизительно 0,1 до приблизительно 0,95, предпочтительно от приблизительно 0,2 до приблизительно 0,9 и более предпочтительно от приблизительно 0,3 до приблизительно 0,8.
5. Полимерный материал по п. 1, где плотность материала внутри первой зоны составляет приблизительно 1,2 г/см3 или меньше, предпочтительно приблизительно 1,0 г/см3 или меньше, более предпочтительно от приблизительно 0,2 г/см3 до приблизительно 0,8 г/см3 и еще более предпочтительно от приблизительно 0,1 г/см3 до приблизительно 0,5 г/см3.
6. Полимерный материал по п. 1, где отношение показателя скорости проникновения водяных паров материала внутри первой зоны к показателю скорости проникновения водяных паров материала внутри второй зоны составляет от приблизительно 0,1 до приблизительно 0,95, предпочтительно от приблизительно 0,2 до приблизительно 0,9 и более предпочтительно от приблизительно 0,3 до приблизительно 0,8.
7. Полимерный материал по п. 1, где скорость проникновения водяных паров материала внутри первой зоны составляет приблизительно 500 г/м2-24 часа или больше, предпочтительно приблизительно 1000 г/м2-24 часа или больше и более предпочтительно от приблизительно 3000 до приблизительно 15000 г/м2-24 часа.
8. Полимерный материал по п. 1, где отношение показателя модуля упругости материала внутри первой зоны к показателю модуля упругости материала внутри второй зоны составляет от приблизительно 0,1 до приблизительно 0,95, предпочтительно от приблизительно 0,2 до приблизительно 0,9 и более предпочтительно от приблизительно 0,3 до приблизительно 0,8.
9. Полимерный материал по п. 1, где модуль упругости материала внутри первой зоны составляет приблизительно 2400 МПа или меньше, предпочтительно приблизительно 2200 МПа или меньше, более предпочтительно от приблизительно 50 МПа до приблизительно 2000 МПа и еще более предпочтительно от приблизительно 100 МПа до приблизительно 1000 МПа.
10. Полимерный материал по п. 1, где отношение показателя ударной вязкости по Шарпи для образца с надрезом материала внутри первой зоны к показателю ударной вязкости по Шарпи для образца с надрезом материала внутри второй зоны составляет от приблизительно 0,1 до приблизительно 0,95, предпочтительно от приблизительно 0,2 до приблизительно 0,9 и более предпочтительно от приблизительно 0,3 до приблизительно 0,8.
11. Полимерный материал по п. 1, где ударная вязкость по Шарпи для образца с надрезом внутри первой зоны составляет приблизительно 10 кДж/м2 или больше, предпочтительно приблизительно 20 кДж/м2 или больше, более предпочтительно приблизительно 35 кДж/м2 или больше и еще более предпочтительно от приблизительно 45 кДж/м2 до приблизительно 100 кДж/м2.
12. Полимерный материал по п. 1, где отношение показателя теплопередачи материала внутри первой зоны к показателю теплопередачи материала внутри второй зоны составляет от приблизительно 0,1 до приблизительно 0,95, предпочтительно от приблизительно 0,2 до приблизительно 0,9 и более предпочтительно от приблизительно 0,3 до приблизительно 0,8.
13. Полимерный материал по п. 1, где теплопередача внутри первой зоны составляет приблизительно 1000 Вт/м2K или меньше, предпочтительно от приблизительно 10 до приблизительно 800 Вт/м2K, более предпочтительно от приблизительно 20 до приблизительно 500 Вт/м2K и еще более предпочтительно от приблизительно 40 до приблизительно 200 Вт/м2K.
14. Полимерный материал по п. 1, где поровая сеть содержит множество нанопор, имеющих средний размер поперечного сечения приблизительно 800 нанометров или меньше и предпочтительно от приблизительно 10 до приблизительно 100 нанометров.
15. Полимерный материал по п. 14, где нанопоры составляют приблизительно 20 об. % или больше от общего объема пор материала внутри первой зоны.
16. Полимерный материал по п. 15, где поровая сеть дополнительно содержит микропоры.
17. Полимерный материал по п. 16, где отношение сторон микропор составляет от приблизительно 1 до приблизительно 30.
18. Полимерный материал по п. 1, где непрерывная фаза составляет от приблизительно 60 вес. % до приблизительно 99 вес. % термопластичной композиции.
19. Полимерный материал по п. 1, где матричный полимер включает сложный полиэфир или полиолефин.
20. Полимерный материал по п. 19, где сложный полиэфир имеет температуру стеклования приблизительно 0°C или больше.
21. Полимерный материал по п. 19, где сложный полиэфир включает полимолочную кислоту.
22. Полимерный материал по п. 1, где добавка микровключения является полимерной.
23. Полимерный материал по п. 22, где добавка микровключения включает полиолефин.
24. Полимерный материал по п. 23, где полиолефин представляет собой гомополимер пропилена, сополимер пропилена/α-олефина, сополимер этилена/α-олефина или их комбинацию.
25. Полимерный материал по п. 1, где отношение параметра растворимости матричного полимера к параметру растворимости добавки микровключения составляет от приблизительно 0,5 до приблизительно 1,5, отношение показателя текучести расплава матричного полимера к показателю текучести расплава добавки микровключения составляет от приблизительно 0,2 до приблизительно 8, и/или отношение модуля упругости Юнга матричного полимера к модулю упругости Юнга добавки микровключения составляет от приблизительно 1 до приблизительно 250.
26. Полимерный материал по п. 1, где добавка нановключения является полимерной.
27. Полимерный материал по п. 26, где добавка нановключения представляет собой функционализированный полиолефин.
28. Полимерный материал по п. 26, где добавка нановключения является реакционноспособной.
29. Полимерный материал по п. 28, где добавка нановключения представляет собой полиэпоксид.
30. Полимерный материал по п. 1, где добавка микровключения составляет от приблизительно 1 вес. % до приблизительно 30 вес. % композиции, исходя из веса непрерывной фазы.
31. Полимерный материал по п. 1, где добавка нановключения составляет от приблизительно 0,05 вес. % до приблизительно 20 вес. % композиции, исходя из веса непрерывной фазы.
32. Полимерный материал по п. 1, где термопластичная композиция дополнительно содержит модификатор поверхности раздела фаз.
33. Полимерный материал по п. 1, где материал определяет несколько первых зон, несколько вторых зон или их комбинацию, при этом по меньшей мере одна из первых зон граничит по меньшей мере с одной из вторых зон.
34. Полимерный материал по п. 1, где вторая зона расположена между двумя первыми зонами.
35. Способ образования полимерного материала по п. 1, при этом способ включает растягивание первой зоны полимерного материала для обеспечения поровой сети.
36. Способ по п. 35, где вторую зону не растягивают.
37. Способ по п. 35, где вторую зону растягивают в меньшей степени, чем первую зону.
38. Способ по п. 35, где вторую зону растягивают и после этого подвергают термической обработке.
39. Способ по п. 35, где первую зону растягивают при температуре от приблизительно -50°C до приблизительно 125°C, предпочтительно от приблизительно -25°C до приблизительно 100°C и более предпочтительно от приблизительно -20°C до приблизительно 50°C.
40. Cпособ по п. 35, где первую зону растягивают при температуре, которая по меньшей мере на приблизительно 10°C, предпочтительно по меньшей на приблизительно 20°C и более предпочтительно по меньшей мере на приблизительно 30°C ниже температуры стеклования матричного полимера и/или добавки микровключения.
RU2016107419A 2013-08-09 2014-06-06 Анизотропный полимерный материал RU2016107419A (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201361863929P 2013-08-09 2013-08-09
US61/863,929 2013-08-09
US201361907614P 2013-11-22 2013-11-22
US61/907,614 2013-11-22
PCT/IB2014/062035 WO2015019201A1 (en) 2013-08-09 2014-06-06 Anisotropic polymeric material

Publications (1)

Publication Number Publication Date
RU2016107419A true RU2016107419A (ru) 2017-09-06

Family

ID=52460723

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2016107419A RU2016107419A (ru) 2013-08-09 2014-06-06 Анизотропный полимерный материал

Country Status (12)

Country Link
US (1) US9957369B2 (ru)
EP (1) EP3030606B1 (ru)
JP (1) JP2016528348A (ru)
KR (1) KR102204028B1 (ru)
CN (1) CN105492513B (ru)
AU (1) AU2014304179B2 (ru)
BR (1) BR112016002218B1 (ru)
MX (1) MX364997B (ru)
RU (1) RU2016107419A (ru)
SG (1) SG11201601708QA (ru)
WO (1) WO2015019201A1 (ru)
ZA (1) ZA201601545B (ru)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11965083B2 (en) 2013-06-12 2024-04-23 Kimberly-Clark Worldwide, Inc. Polyolefin material having a low density
US10752745B2 (en) * 2013-06-12 2020-08-25 Kimberly-Clark Worldwide, Inc. Polyolefin film for use in packaging
MX2015016830A (es) * 2013-06-12 2016-04-04 Kimberly Clark Co Material polimerico para usar en aislamiento termico.
RU2631796C2 (ru) * 2013-06-12 2017-09-26 Кимберли-Кларк Ворлдвайд, Инк. Полимерный материал с мультимодальным распределением пор по размеру
SG11201601708QA (en) 2013-08-09 2016-04-28 Kimberly Clark Co Anisotropic polymeric material
RU2016107432A (ru) * 2013-08-09 2017-09-04 Кимберли-Кларк Ворлдвайд, Инк. Методика избирательной регуляции пористости полимерного материала
BR112016002589B1 (pt) * 2013-08-09 2021-08-03 Kimberly-Clark Worldwide, Inc Material polimérico flexível moldado, membro tubular, e, método de moldagem de um material polimérico
BR112017009619B1 (pt) 2014-11-26 2021-10-05 Kimberly-Clark Worldwide, Inc. Material de poliolefina, fibra, trama não tecida, artigo absorvente, e, método para formação de um material de poliolefina
EP3256527B1 (en) * 2015-02-13 2022-07-27 Acoustic Space Pty Ltd A sheet material with a cellular structure and/or a process for producing same
CA2973473C (en) 2015-03-23 2022-07-26 Emd Millipore Corporation Abrasion resistant film for biocontainers
WO2017106267A1 (en) * 2015-12-17 2017-06-22 Kimberly-Clark Worldwide, Inc. Color-changing polymeric material
WO2018144241A1 (en) * 2017-01-31 2018-08-09 Kimberly-Clark Worldwide, Inc. Porous polyester material
US11724002B2 (en) 2017-02-28 2023-08-15 Kimberly-Clark Worldwide, Inc. Technique for forming porous fibers
WO2018229204A1 (en) * 2017-06-15 2018-12-20 Unilever Plc Frozen confection product packaging
CN112016805B (zh) * 2020-07-23 2023-06-06 上海工程技术大学 一种磁流变液性能评价方法及系统

Family Cites Families (214)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3338992A (en) 1959-12-15 1967-08-29 Du Pont Process for forming non-woven filamentary structures from fiber-forming synthetic organic polymers
US3423255A (en) 1965-03-31 1969-01-21 Westinghouse Electric Corp Semiconductor integrated circuits and method of making the same
DE2048006B2 (de) 1969-10-01 1980-10-30 Asahi Kasei Kogyo K.K., Osaka (Japan) Verfahren und Vorrichtung zur Herstellung einer breiten Vliesbahn
DE1950669C3 (de) 1969-10-08 1982-05-13 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zur Vliesherstellung
CA948388A (en) 1970-02-27 1974-06-04 Paul B. Hansen Pattern bonded continuous filament web
US3726955A (en) 1971-01-11 1973-04-10 Phillips Petroleum Co Process for producing filaments and yarns of blended incompatible polymers
GB1453447A (en) 1972-09-06 1976-10-20 Kimberly Clark Co Nonwoven thermoplastic fabric
US4100324A (en) 1974-03-26 1978-07-11 Kimberly-Clark Corporation Nonwoven fabric and method of producing same
US4055702A (en) 1974-03-29 1977-10-25 M & T Chemicals Inc. Additive-containing fibers
US4282735A (en) 1979-04-02 1981-08-11 Van Mark Products Corporation Brake for sheet metal or the like
US4375718A (en) 1981-03-12 1983-03-08 Surgikos, Inc. Method of making fibrous electrets
US4731266A (en) 1981-06-03 1988-03-15 Rhone-Poulenc, S.A. Water-resistant polyvinyl alcohol film and its application to the preparation of gas-impermeable composite articles
US4374888A (en) 1981-09-25 1983-02-22 Kimberly-Clark Corporation Nonwoven laminate for recreation fabric
US4405688A (en) 1982-02-18 1983-09-20 Celanese Corporation Microporous hollow fiber and process and apparatus for preparing such fiber
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4557132A (en) 1984-02-03 1985-12-10 Tapco Products Company, Inc. Sheet bending brake
JPS60168511A (ja) 1984-02-10 1985-09-02 Japan Vilene Co Ltd エレクトレツトフイルタの製造方法
JPS6190705A (ja) 1984-10-09 1986-05-08 Terumo Corp 中空糸膜の製造方法
US4698372A (en) 1985-09-09 1987-10-06 E. I. Du Pont De Nemours And Company Microporous polymeric films and process for their manufacture
JPS6269822A (ja) 1985-09-19 1987-03-31 Chisso Corp 熱接着性複合繊維
ES2029475T3 (es) 1986-05-16 1992-08-16 Imperial Chemical Industries Plc Fibras y tubos fibrosos huecos.
US4741944A (en) 1986-07-30 1988-05-03 Kimberly-Clark Corporation Wet wipe and wipe dispensing arrangement
US4789699A (en) 1986-10-15 1988-12-06 Kimberly-Clark Corporation Ambient temperature bondable elastomeric nonwoven web
JPS63135569A (ja) 1986-11-18 1988-06-07 三井東圧化学株式会社 通気性防水不織布
DE3781133T2 (de) 1986-12-19 1993-06-24 Akzo Nv Herstellung von polymilchsaeure und copolymeren daraus.
US4766029A (en) 1987-01-23 1988-08-23 Kimberly-Clark Corporation Semi-permeable nonwoven laminate
US4770931A (en) 1987-05-05 1988-09-13 Eastman Kodak Company Shaped articles from polyester and cellulose ester compositions
US5179164A (en) 1988-02-20 1993-01-12 Basf Aktiengesellschaft Thermoplastic polypropylene/polyamide molding composition
JPH01293102A (ja) 1988-05-23 1989-11-27 Tokuyama Soda Co Ltd 微多孔性中空糸膜及びその製造方法
USD315990S (en) 1988-08-04 1991-04-09 Kimberly-Clark Corporation Embossed wipe or similar article
US5252642A (en) 1989-03-01 1993-10-12 Biopak Technology, Ltd. Degradable impact modified polyactic acid
US5218071A (en) 1988-12-26 1993-06-08 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers
US5169706A (en) 1990-01-10 1992-12-08 Kimberly-Clark Corporation Low stress relaxation composite elastic material
KR960004143B1 (ko) 1990-04-10 1996-03-27 도오요오 보오세끼 가부시끼가이샤 공동 함유 폴리에스테르계 필름 및 적층체
US5213881A (en) 1990-06-18 1993-05-25 Kimberly-Clark Corporation Nonwoven web with improved barrier properties
US5464688A (en) 1990-06-18 1995-11-07 Kimberly-Clark Corporation Nonwoven web laminates with improved barrier properties
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
CA2048905C (en) 1990-12-21 1998-08-11 Cherie H. Everhart High pulp content nonwoven composite fabric
US5232642A (en) 1991-02-08 1993-08-03 Mitsubishi Rayon Co., Ltd. Process of making porous polypropylene hollow fiber membrane of large pore diameter
US5169712A (en) 1991-08-23 1992-12-08 Amoco Corporation Porous film composites
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5743129A (en) 1991-11-26 1998-04-28 Tapco International Corporation Heavy duty sheet bending brake
US6326458B1 (en) 1992-01-24 2001-12-04 Cargill, Inc. Continuous process for the manufacture of lactide and lactide polymers
US5470944A (en) 1992-02-13 1995-11-28 Arch Development Corporation Production of high molecular weight polylactic acid
CA2098889A1 (en) 1992-07-06 1994-01-07 Takashi Chinuki Slow-releasing medicated resin moldings and process for producing the same
US5330348A (en) 1992-08-05 1994-07-19 E. I. Du Pont De Nemours And Company Spinneret for the production of hollow filaments
US5382400A (en) 1992-08-21 1995-01-17 Kimberly-Clark Corporation Nonwoven multicomponent polymeric fabric and method for making same
US5336552A (en) 1992-08-26 1994-08-09 Kimberly-Clark Corporation Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer
US5350624A (en) 1992-10-05 1994-09-27 Kimberly-Clark Corporation Abrasion resistant fibrous nonwoven composite structure
US5322728A (en) 1992-11-24 1994-06-21 Exxon Chemical Patents, Inc. Fibers of polyolefin polymers
IT1256260B (it) 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Polipropilene atattico
US5472775A (en) 1993-08-17 1995-12-05 The Dow Chemical Company Elastic materials and articles therefrom
US6093665A (en) 1993-09-30 2000-07-25 Kimberly-Clark Worldwide, Inc. Pattern bonded nonwoven fabrics
CA2192336C (en) 1993-12-07 1999-10-26 Klementina Khait Reconstituted polymeric materials
CA2116081C (en) 1993-12-17 2005-07-26 Ann Louise Mccormack Breathable, cloth-like film/nonwoven composite
CA2123330C (en) 1993-12-23 2004-08-31 Ruth Lisa Levy Ribbed clothlike nonwoven fabric and process for making same
USD358035S (en) 1994-01-10 1995-05-09 Kimberly-Clark Corporation Embossed wipe
US5422377A (en) 1994-04-06 1995-06-06 Sandia Corporation Microporous polymer films and methods of their production
US5571619A (en) 1994-05-24 1996-11-05 Exxon Chemical Patents, Inc. Fibers and oriented films of polypropylene higher α-olefin copolymers
US5503785A (en) 1994-06-02 1996-04-02 Stratasys, Inc. Process of support removal for fused deposition modeling
US5714573A (en) 1995-01-19 1998-02-03 Cargill, Incorporated Impact modified melt-stable lactide polymer compositions and processes for manufacture thereof
US5539056A (en) 1995-01-31 1996-07-23 Exxon Chemical Patents Inc. Thermoplastic elastomers
US5540332A (en) 1995-04-07 1996-07-30 Kimberly-Clark Corporation Wet wipes having improved dispensability
US5770682A (en) 1995-07-25 1998-06-23 Shimadzu Corporation Method for producing polylactic acid
DE69631305T2 (de) 1995-07-25 2004-11-18 Toyota Jidosha K.K., Toyota Verfahren zur Herstellung von Polymilchsäure
DE69618227T2 (de) 1995-11-01 2002-08-14 Kimberly-Clark Worldwide, Inc. Mit antimikrobiellen zusammensetzungen getränkte tücher
US5764521A (en) 1995-11-13 1998-06-09 Stratasys Inc. Method and apparatus for solid prototyping
US6060638A (en) 1995-12-22 2000-05-09 Kimberly-Clark Worldwide, Inc. Matched permeability liner/absorbent structure system for absorbent articles and the like
JP3588907B2 (ja) 1996-03-22 2004-11-17 トヨタ自動車株式会社 ポリ乳酸の製造方法
USD384819S (en) 1996-03-22 1997-10-14 Kimberly-Clark Corporation Top surface of a wipe
US5667635A (en) 1996-09-18 1997-09-16 Kimberly-Clark Worldwide, Inc. Flushable premoistened personal wipe
US5843057A (en) 1996-07-15 1998-12-01 Kimberly-Clark Worldwide, Inc. Film-nonwoven laminate containing an adhesively-reinforced stretch-thinned film
US5766760A (en) 1996-09-04 1998-06-16 Kimberly-Clark Worldwide, Inc. Microporous fibers with improved properties
US6028018A (en) 1996-07-24 2000-02-22 Kimberly-Clark Worldwide, Inc. Wet wipes with improved softness
USD384508S (en) 1996-08-22 1997-10-07 Kimberly-Clark Worldwide, Inc. Wipe
US5948528A (en) 1996-10-30 1999-09-07 Basf Corporation Process for modifying synthetic bicomponent fiber cross-sections and bicomponent fibers thereby produced
USD390708S (en) 1996-10-31 1998-02-17 Kimberly-Clark Worldwide, Inc. Pattern for a bonded fabric
US5962112A (en) 1996-12-19 1999-10-05 Kimberly-Clark Worldwide, Inc. Wipers comprising point unbonded webs
TW526066B (en) 1996-12-27 2003-04-01 Kimberly Clark Co Stable and breathable films of improved toughness, their products, and the method of making the same
US6037281A (en) 1996-12-27 2000-03-14 Kimberly-Clark Worldwide, Inc. Cloth-like, liquid-impervious, breathable composite barrier fabric
US6015764A (en) 1996-12-27 2000-01-18 Kimberly-Clark Worldwide, Inc. Microporous elastomeric film/nonwoven breathable laminate and method for making the same
US5947944A (en) 1996-12-30 1999-09-07 Kimberly-Clark Worldwide, Inc. Stretched-thinned films comprising low crystallinity polymers and laminates thereof
US5931823A (en) 1997-03-31 1999-08-03 Kimberly-Clark Worldwide, Inc. High permeability liner with improved intake and distribution
US6228923B1 (en) 1997-04-02 2001-05-08 Stratasys, Inc. Water soluble rapid prototyping support and mold material
US6070107A (en) 1997-04-02 2000-05-30 Stratasys, Inc. Water soluble rapid prototyping support and mold material
US5932497A (en) 1997-09-15 1999-08-03 Kimberly-Clark Worldwide, Inc. Breathable elastic film and laminate
US5997981A (en) 1997-09-15 1999-12-07 Kimberly-Clark Worldwide, Inc. Breathable barrier composite useful as an ideal loop fastener component
US5968643A (en) 1997-09-16 1999-10-19 Kimberly-Clark Worldwide, Inc. Microporous film with improved properties
US5800758A (en) 1997-09-16 1998-09-01 Kimberly-Clark Worldwide, Inc. Process for making microporous films with improved properties
US6090325A (en) 1997-09-24 2000-07-18 Fina Technology, Inc. Biaxially-oriented metallocene-based polypropylene films
US6197404B1 (en) 1997-10-31 2001-03-06 Kimberly-Clark Worldwide, Inc. Creped nonwoven materials
US6057024A (en) 1997-10-31 2000-05-02 Kimberly-Clark Worldwide, Inc. Composite elastic material with ribbon-shaped filaments
US6197237B1 (en) 1997-12-22 2001-03-06 Kimberly Clark Corporation Method of making a multicomponent fiber and nonwoven web containing the same
US6071451A (en) 1997-12-31 2000-06-06 Kimberly-Clark Worldwide, Inc. Process for making a nonwoven, porous fabric from polymer composite materials
US6004124A (en) 1998-01-26 1999-12-21 Stratasys, Inc. Thin-wall tube liquifier
US6235825B1 (en) 1998-03-05 2001-05-22 Mitsui Chemicals, Inc. Polylactic acid resin composition and film therefrom
US6348258B1 (en) 1998-06-25 2002-02-19 Kimberly-Clark Worldwide, Inc. Breathable film having organic filler
USD418305S (en) 1998-09-24 2000-01-04 Kimberly-Clark Worldwide, Inc. Wipe
US6431477B1 (en) 1998-10-20 2002-08-13 Pallmann Maschinenfabrik Gmbh & Co. Kg Gas flow-type chipping machine
US6479003B1 (en) 1998-11-18 2002-11-12 Northwestern University Processes of mixing, compatibilizing, and/or recylcing blends of polymer materials through solid state shear pulverization, and products by such processes
AR022137A1 (es) 1998-12-31 2002-09-04 Kimberly Clark Co Una composicion de materia, una pelicula y un articulo que comprenden dicha composicion
US6103255A (en) 1999-04-16 2000-08-15 Rutgers, The State University Porous polymer scaffolds for tissue engineering
US7754807B2 (en) 1999-04-20 2010-07-13 Stratasys, Inc. Soluble material and process for three-dimensional modeling
EP1194274B1 (en) 1999-04-20 2017-03-22 Stratasys, Inc. Process for three-dimensional modeling
US6776602B2 (en) 1999-04-20 2004-08-17 Stratasys, Inc. Filament cassette and loading system
US6440437B1 (en) 2000-01-24 2002-08-27 Kimberly-Clark Worldwide, Inc. Wet wipes having skin health benefits
US6500563B1 (en) 1999-05-13 2002-12-31 Exxonmobil Chemical Patents Inc. Elastic films including crystalline polymer and crystallizable polymers of propylene
US6461457B1 (en) 1999-06-30 2002-10-08 Kimberly-Clark Worldwide, Inc. Dimensionally stable, breathable, stretch-thinned, elastic films
USD428267S (en) 1999-08-27 2000-07-18 Kimberly-Clark Worldwide, Inc. Repeating pattern for a bonded fabric
US20030113528A1 (en) 1999-09-17 2003-06-19 Wilson Moya Patterned porous structures
JP3258302B2 (ja) 1999-10-26 2002-02-18 三菱樹脂株式会社 生分解性2軸延伸フィルム
FR2808470B1 (fr) 2000-05-03 2003-04-11 Trioplanex France Film multicouche microporeux respirable a impermeabilite renforcee aux liquides et procede de production
US6494390B1 (en) 2000-05-24 2002-12-17 Northwestern University Solid state shear pulverization of multicomponent polymeric waste
TW539705B (en) 2000-06-30 2003-07-01 Tonen Sekiyukagaku Kk Process for preparing heat curable resin micro-porous film
US6391932B1 (en) * 2000-08-08 2002-05-21 Shipley Company, L.L.C. Porous materials
US6818173B1 (en) 2000-08-10 2004-11-16 Northwestern University Polymeric blends formed by solid state shear pulverization and having improved melt flow properties
JP3922872B2 (ja) * 2000-09-27 2007-05-30 ユニ・チャーム株式会社 開孔フィルムを有する吸収性物品
US6914018B1 (en) 2000-10-27 2005-07-05 Kimberly-Clark Worldwide, Inc. Biaxial stretch, breathable laminate with cloth-like aesthetics and method for making same
US6582810B2 (en) 2000-12-22 2003-06-24 Kimberly-Clark Worldwide, Inc. One-step method of producing an elastic, breathable film structure
US20030180525A1 (en) 2000-12-28 2003-09-25 Strack David Craige Cross-directional extendible films having high breathability and low outer dampness
US6838403B2 (en) 2000-12-28 2005-01-04 Kimberly-Clark Worldwide, Inc. Breathable, biodegradable/compostable laminates
US20020122828A1 (en) 2001-03-02 2002-09-05 Jun Liu Hybrid porous materials for controlled release
US6660211B2 (en) 2001-04-23 2003-12-09 Kimberly-Clark Worldwide, Inc. Methods of making biodegradable films having enhanced ductility and breathability
US6905759B2 (en) 2001-04-23 2005-06-14 Kimberly Clark Worldwide, Inc. Biodegradable films having enhanced ductility and breathability
US6824680B2 (en) 2001-05-07 2004-11-30 New Jersey Institute Of Technology Preparation of microporous films from immiscible blends via melt processing and stretching
CN100347355C (zh) 2001-06-15 2007-11-07 可乐丽股份有限公司 复合纤维
US6866807B2 (en) 2001-09-21 2005-03-15 Stratasys, Inc. High-precision modeling filament
US8684739B2 (en) 2002-03-14 2014-04-01 Mycone Dental Supply Co., Inc. Durable film coating compositions having sustained slow-release capability, and methods of use therefor
WO2003106162A1 (en) 2002-06-17 2003-12-24 Tredegar Film Products Corporation Extruded super absorbent web
SI1518011T1 (sl) 2002-06-28 2013-09-30 Neokidney Holding B.V. Postopek za pripravo funkcionalnih poroznih vlaken
US20040002273A1 (en) 2002-07-01 2004-01-01 Kimberly-Clark Worldwide, Inc. Liquid repellent nonwoven protective material
CN1312335C (zh) 2002-08-05 2007-04-25 东丽株式会社 多孔纤维
KR101061028B1 (ko) 2002-10-23 2011-08-31 도레이 카부시키가이샤 고분자 혼성체 섬유, 섬유구조체, 고분자 혼성체 펠릿 및 그들의 제조방법
WO2004043663A2 (en) 2002-11-05 2004-05-27 Material Sciences Corporation Method of producing exfoliated polymer-clay nanocomposite and polymer-clay nanocomposite produced therefrom
US20050054255A1 (en) 2003-09-08 2005-03-10 Kimberly-Clark Worldwide, Inc. Nonwoven fabric liner and diaper including a nonwoven laminate liner
DE10348876B4 (de) 2003-10-21 2014-04-03 Jnc Corporation Poröse Polyolefinmembran
US20050112363A1 (en) 2003-11-21 2005-05-26 Xin Ning Biodegradable polymer compositions for a breathable film
US20050119359A1 (en) 2003-12-02 2005-06-02 Shelby Marcus D. Void-containing polyester shrink film
US7354973B2 (en) 2003-12-12 2008-04-08 E.I. Du Pont De Nemours And Company Toughened poly(lactic acid) compositions
US7368503B2 (en) 2003-12-22 2008-05-06 Eastman Chemical Company Compatibilized blends of biodegradable polymers with improved rheology
US7175693B2 (en) * 2004-01-30 2007-02-13 United Technologies Corporation Method for preventing fuel infiltration into microporous polymer membranes
US20050221075A1 (en) 2004-03-31 2005-10-06 Travelute Frederick L Iii Low density light weight filament and fiber
DE102004050003B4 (de) 2004-10-14 2009-10-01 Pallmann Maschinenfabrik Gmbh & Co Kg Vorrichtung zum Zerkleinern von Aufgabegut mit Kühlluftkanal
TWI265090B (en) 2004-11-01 2006-11-01 Lg Chemical Ltd Multi-layer container having barrier property
US7445735B2 (en) * 2004-12-07 2008-11-04 Daramic Llc Method of making microporous material
US7619132B2 (en) 2004-12-30 2009-11-17 Kimberly-Clark Worldwide, Inc. Degradable breathable multilayer film with improved properties and method of making same
JP2010150721A (ja) 2008-12-26 2010-07-08 Toray Ind Inc ポリマーアロイ繊維ならびに繊維構造体
CA2625343A1 (en) 2005-10-19 2007-04-26 Toray Industries, Inc. Crimped yarn, method for manufacture thereof, and fiber structure
DE602005023671D1 (de) 2005-12-15 2010-10-28 Kimberly Clark Co Biologisch abbaubare mehrkomponentenfasern
WO2007074790A1 (ja) 2005-12-26 2007-07-05 Nisshinbo Industries, Inc. ポリオレフィン・ポリエステル系フィルム
US7914891B2 (en) 2005-12-28 2011-03-29 Kimberly-Clark Worldwide, Inc. Wipes including microencapsulated delivery vehicles and phase change materials
WO2007094477A1 (ja) 2006-02-14 2007-08-23 Nec Corporation ポリ乳酸系樹脂組成物及び成形体
US7604470B2 (en) 2006-04-03 2009-10-20 Stratasys, Inc. Single-motor extrusion head having multiple extrusion lines
US8927443B2 (en) 2006-04-07 2015-01-06 Kimberly-Clark Worldwide, Inc. Biodegradable nonwoven laminate
US20100121295A1 (en) 2006-04-28 2010-05-13 The Procter & Gamble Company Products comprising polymeric webs with nanoparticles
US20070264897A1 (en) 2006-05-15 2007-11-15 The Procter & Gamble Company Polymeric webs with nanoparticles
FR2902434B1 (fr) 2006-06-16 2008-08-01 Arkema France Composition d'acide polylactique presentant une resistance aux chocs amelioree
FR2902433A1 (fr) 2006-06-16 2007-12-21 Arkema France Materiau composite a base d'acide polylactique et de polyamide presentant une resistance aux chocs amelioree, son procede de fabrication et utilisation
US9089627B2 (en) 2006-07-11 2015-07-28 Abbott Cardiovascular Systems Inc. Stent fabricated from polymer composite toughened by a dispersed phase
KR101297865B1 (ko) 2006-07-14 2013-08-19 킴벌리-클라크 월드와이드, 인크. 부직 웹에 사용하기 위한 생분해성 폴리락트산
JP5272728B2 (ja) 2006-08-23 2013-08-28 Jsr株式会社 熱可塑性樹脂組成物及びそれを用いた成形品
US7803244B2 (en) 2006-08-31 2010-09-28 Kimberly-Clark Worldwide, Inc. Nonwoven composite containing an apertured elastic film
BRPI0621962B1 (pt) * 2006-08-31 2018-05-29 Kimberly-Clark Worldwide, Inc. Película respirável tendo uma camada de base, laminado respirável, artigo absorvente e método para formação de uma película respirável
US7557167B2 (en) 2006-09-28 2009-07-07 Gore Enterprise Holdings, Inc. Polyester compositions, methods of manufacturing said compositions, and articles made therefrom
US7910041B1 (en) 2006-11-27 2011-03-22 Stratasys, Inc. Build materials containing nanofibers for use with extrusion-based layered depositions systems
MX2009006136A (es) 2006-12-15 2009-08-07 Kimberly Clark Co Acidos polilacticos biodegradables para uso en la formacion de fibras.
EP2096141A4 (en) 2006-12-22 2014-06-25 Unitika Ltd BIODEGRADABLE POLYESTER RESIN COMPOSITION AND MOLDED BODY, FOAM BODY AND MOLDED CONTAINER OBTAINED FROM THE BIODEGRADABLE POLYESTER RESIN COMPOSITION
US7779521B2 (en) 2006-12-22 2010-08-24 Kimberly-Clark Worldwide, Inc. Hydroentangled nonwoven fabrics, process, products and apparatus
CA2667183A1 (en) 2006-12-27 2008-07-03 Toray Industries, Inc. Resin composition and molded article
SI2117834T1 (sl) 2007-02-05 2011-07-29 Lankhorst Pure Composites Bv Raztezani poliolefinski materiali in iz njih izdelani predmeti
EP2117793B1 (en) 2007-02-12 2014-07-16 Stratasys, Inc. Pump system
US8030382B2 (en) 2007-02-23 2011-10-04 Teijin Limited Polylactic acid composition
JP5309628B2 (ja) 2007-03-23 2013-10-09 住友化学株式会社 多孔質フィルム
JP5298383B2 (ja) 2007-04-25 2013-09-25 Esファイバービジョンズ株式会社 嵩高性、柔軟性に優れた熱接着性複合繊維及びこれを用いた繊維成形品
US7625200B2 (en) 2007-07-31 2009-12-01 Stratasys, Inc. Extrusion head for use in extrusion-based layered deposition modeling
ES2644494T3 (es) 2007-09-11 2017-11-29 Dow Global Technologies Llc Composiciones y artículos preparados a partir de las mismas
US8287677B2 (en) 2008-01-31 2012-10-16 Kimberly-Clark Worldwide, Inc. Printable elastic composite
MX2010013139A (es) 2008-05-30 2011-03-04 Kimberly Clark Worldwide Incorporated Fibras de acido polilactico.
US8530577B2 (en) 2008-06-30 2013-09-10 Fina Technology, Inc. Compatibilized polypropylene heterophasic copolymer and polylactic acid blends for injection molding applications
US8545971B2 (en) 2008-06-30 2013-10-01 Fina Technology, Inc. Polymeric compositions comprising polylactic acid and methods of making and using same
US8268913B2 (en) 2008-06-30 2012-09-18 Fina Technology, Inc. Polymeric blends and methods of using same
US8759446B2 (en) * 2008-06-30 2014-06-24 Fina Technology, Inc. Compatibilized polypropylene and polylactic acid blends and methods of making and using same
US8642701B2 (en) 2008-06-30 2014-02-04 Fina Technology, Inc. Polypropylene and polylactic acid blends of injection stretch blow molding applications
US20110132519A1 (en) 2008-06-30 2011-06-09 Fina Technology, Inc. Polyolefin polylactic acid blends for easy open packaging applications
JP2012507562A (ja) 2008-10-30 2012-03-29 ダビド リウ 微小球性多孔質生体適合性足場並びにその製造方法及び装置
MX2012005237A (es) 2009-11-09 2012-06-13 Basf Se Proceso para la obtencion de peliculas de contraccion.
EP2504384B1 (en) 2009-11-25 2018-03-21 Dow Global Technologies LLC Nanoporous polymeric foam having high porosity
US8466337B2 (en) 2009-12-22 2013-06-18 Kimberly-Clark Worldwide, Inc. Biodegradable and breathable film
CN102115576B (zh) 2009-12-31 2014-09-17 金伯利-克拉克环球有限公司 天然生物聚合物热塑性膜
US8435631B2 (en) * 2010-04-15 2013-05-07 Ppg Industries Ohio, Inc. Microporous material
EP2412426A1 (de) 2010-07-30 2012-02-01 Schaefer Kalk GmbH & Co. KG Poröse Hohlfaser
US8936740B2 (en) 2010-08-13 2015-01-20 Kimberly-Clark Worldwide, Inc. Modified polylactic acid fibers
US10753023B2 (en) 2010-08-13 2020-08-25 Kimberly-Clark Worldwide, Inc. Toughened polylactic acid fibers
US20120164905A1 (en) 2010-08-13 2012-06-28 Kimberly-Clark Worldwide, Inc. Modified Polylactic Acid Fibers
US8512024B2 (en) 2011-01-20 2013-08-20 Makerbot Industries, Llc Multi-extruder
US8586192B2 (en) 2011-02-15 2013-11-19 Fina Technology, Inc. Compatibilized polymeric compositions comprising polyolefin-polylactic acid copolymers and methods of making the same
US20120214944A1 (en) 2011-02-18 2012-08-23 Fina Technology, Inc. Polyolefin polylactic acid in-situ blends
US8628718B2 (en) 2011-02-18 2014-01-14 Fina Technology, Inc. Modified polylactic acid, polymeric blends and methods of making the same
JP5755016B2 (ja) * 2011-04-28 2015-07-29 株式会社林技術研究所 発泡樹脂成形体
BR112013029041A2 (pt) 2011-05-13 2017-06-27 Mylan Group adesivos secos
EP3124236A1 (en) 2011-06-17 2017-02-01 Fiberweb, Inc. Vapor permeable, substantially water impermeable multilayer article
US20130210621A1 (en) 2012-02-10 2013-08-15 Kimberly-Clark Worldwide, Inc. Breathable Film Formed from a Renewable Polyester
US8980964B2 (en) 2012-02-10 2015-03-17 Kimberly-Clark Worldwide, Inc. Renewable polyester film having a low modulus and high tensile elongation
US10858762B2 (en) 2012-02-10 2020-12-08 Kimberly-Clark Worldwide, Inc. Renewable polyester fibers having a low density
US9040598B2 (en) 2012-02-10 2015-05-26 Kimberly-Clark Worldwide, Inc. Renewable polyester compositions having a low density
US8637130B2 (en) 2012-02-10 2014-01-28 Kimberly-Clark Worldwide, Inc. Molded parts containing a polylactic acid composition
US8975305B2 (en) 2012-02-10 2015-03-10 Kimberly-Clark Worldwide, Inc. Rigid renewable polyester compositions having a high impact strength and tensile elongation
WO2014097007A1 (en) 2012-12-19 2014-06-26 Kimberly-Clark Worldwide, Inc. Low density fibers and methods for forming same
MX363276B (es) 2013-06-12 2019-03-15 Kimberly Clark Co Tejido multifuncional.
MX2015016830A (es) 2013-06-12 2016-04-04 Kimberly Clark Co Material polimerico para usar en aislamiento termico.
EP3008121B1 (en) 2013-06-12 2018-04-25 Kimberly-Clark Worldwide, Inc. Energy absorbing member
SG11201601708QA (en) 2013-08-09 2016-04-28 Kimberly Clark Co Anisotropic polymeric material
AU2014304189B2 (en) 2013-08-09 2019-03-21 Kimberly-Clark Worldwide, Inc. Delivery system for active agents
RU2016107432A (ru) * 2013-08-09 2017-09-04 Кимберли-Кларк Ворлдвайд, Инк. Методика избирательной регуляции пористости полимерного материала

Also Published As

Publication number Publication date
ZA201601545B (en) 2017-09-27
CN105492513B (zh) 2019-03-08
SG11201601708QA (en) 2016-04-28
US20160177048A1 (en) 2016-06-23
JP2016528348A (ja) 2016-09-15
AU2014304179A1 (en) 2016-03-03
KR102204028B1 (ko) 2021-01-18
BR112016002218A2 (pt) 2017-08-01
EP3030606B1 (en) 2021-09-08
MX2016001389A (es) 2016-05-05
EP3030606A1 (en) 2016-06-15
US9957369B2 (en) 2018-05-01
AU2014304179B2 (en) 2017-08-17
MX364997B (es) 2019-05-16
KR20160040713A (ko) 2016-04-14
EP3030606A4 (en) 2017-03-22
CN105492513A (zh) 2016-04-13
WO2015019201A1 (en) 2015-02-12
BR112016002218B1 (pt) 2021-12-14

Similar Documents

Publication Publication Date Title
RU2016107419A (ru) Анизотропный полимерный материал
RU2016107432A (ru) Методика избирательной регуляции пористости полимерного материала
JP2016528348A5 (ru)
JP2016527374A5 (ru)
RU2015155675A (ru) Полимерный материал для применения в теплоизоляции
RU2015156304A (ru) Полиолефиновая пленка для применения в упаковке
RU2014134973A (ru) Воздухопроницаемая пленка, образованная из возобновляемого сложного полиэфира
RU2015155638A (ru) Полимерный материал с мультимодальным распределением пор по размеру
JP2008518047A5 (ru)
JP2016523293A5 (ru)
RU2016107693A (ru) Гибкий полимерный материал со свойствами сохранения формы
RU2017118768A (ru) Биаксиально растянутая пористая пленка
RU2010120693A (ru) Многослойные пленки
RU2016148011A (ru) Полые пористые волокна
RU2016148475A (ru) Термоформованное изделие, образованное из пористого полимерного листа
RU2018125648A (ru) Композиция полипропилена с малой массой, армированная волокном
RU2015149952A (ru) Полиэтилен высокой плотности
JP2015505573A5 (ru)
RU2016107222A (ru) Микрочастицы, характеризующиеся многомодальным распределением пор
RU2017122432A (ru) Полипропиленовые пленки с улучшенными оптическими и механическими свойствами
RU2005112215A (ru) Полипропиленовые волокна для нетканых материалов из расплава
RU2015144843A (ru) Полипропиленовая композиция с улучшенной ударной прочностью для применения в трубах
Hou et al. Porous poly (l-lactide)/poly (d-lactide) blend film with enhanced flexibility and heat resistance via constructing a regularly oriented pore structure
MX368760B (es) Composiciones de poliolefina y articulos fabricados a partir de las mismas.
RU2018121091A (ru) Многостадийный способ вытягивания для формования пористых волокон

Legal Events

Date Code Title Description
FA92 Acknowledgement of application withdrawn (lack of supplementary materials submitted)

Effective date: 20180131