DE349639T1 - Alpha-olefin-polymere. - Google Patents

Alpha-olefin-polymere.

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Publication number
DE349639T1
DE349639T1 DE198989903015T DE89903015T DE349639T1 DE 349639 T1 DE349639 T1 DE 349639T1 DE 198989903015 T DE198989903015 T DE 198989903015T DE 89903015 T DE89903015 T DE 89903015T DE 349639 T1 DE349639 T1 DE 349639T1
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Prior art keywords
olefin
olefin polymer
polymer
mixture
tertiary
Prior art date
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Pending
Application number
DE198989903015T
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English (en)
Inventor
R. Curtis Wickliffe Oh 44092 Scharf
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Lubrizol Corp
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Lubrizol Corp
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Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Publication of DE349639T1 publication Critical patent/DE349639T1/de
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/06—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing butene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C10M137/10—Thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/08—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/02—Bearings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/06—Instruments or other precision apparatus, e.g. damping fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/251—Alcohol-fuelled engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C10N2040/28—Rotary engines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (39)

O 3 4 3 &Egr; EP 89 90 3015.9 The Lubrizol Corporation Deutsche Übersetzung der Patentansprüche nach Art. 67(1) EPÜ Patentansprüche
1. Verfahren zur Herstellung eines a-Olefin-Polymers, umfassend das Zusammenbringen mindestens eines a-Olefins mit einem Katalysatorsystem, das ein tertiäres Organohalogenid und einen Lewis-Säure-Katalysator umfaßt, unter Polymerisationsbedingungen, um so das a-Olefin-Polymer zu erhalten.
2. Verfahren nach Anspruch 1, wobei das a-Olefin 4 bis etwa 30 Kohlenstoffatome enthält.
3. Verfahren nach Anspruch 1, wobei das tertiäre Organohalogenid ein tertiäres Alkylhalogenid ist.
4. Verfahren nach Anspruch 1, wobei der Lewis-Säure-Katalysator ein Aluminiumhalogenid ist.
5. Verfahren nach Anspruch 1, welches bei etwa -20 bis etwa 400C durchgeführt wird.
6. Verfahren nach Anspruch 1, wobei das a-Olefin—Polymer ein Copolymer ist.
7. Verfahren nach Anspruch 3, wobei das tertiäre Alkylhalogenid 4 bis etwa 12 Kohlenstoffatome im Alkylrest enthält.
8. Verfahren nach Anspruch 4, wobei der Lewis-Säure-Katalysator Aluminiumchlorid ist.
9. Verfahren nach Anspruch 1, wobei das a-Olefin-Polymer eine Flüssigkeit ist.
10. Verfahren nach Anspruch 1, wobei das a-Olefin-Polymer ein Homopolymer ist.
11. Verfahren nach Anspruch 2, wobei das a-Olefin etwa C6 bis etwa C16 ist.
12. Verfahren nach Anspruch 7, wobei das tertiäre Alkylhalogenid aus der Gruppe ausgewählt ist, die aus tertiären Amyl- und tertiären Butylhalogeniden und Gemischen davon besteht.
13. Verfahren nach Anspruch 10, wobei das a-Olefin C12 ist.
14. Verfahren nach Anspruch 5, wobei die Temperatur etwa -5 bis etwa 3O0C beträgt.
15. Verfahren nach Anspruch 6, wobei das a-Olefin ein C8- und C12-Olefingemisch ist.
16. Verfahren nach Anspruch 1, durchgeführt in Gegenwart einer aktivierenden Menge einer protischen Verbindung.
17. Produkt nach Anspruch 6, wobei das a-Olefin ein Gemisch von Cy- und Cg-Olefinen ist.
18. Verfahren nach Anspruch 1, wobei das a-Olefin ein normales Olefin ist.
19. Verfahren nach Anspruch 6, wobei das a-Olefin ein Cg-, C12" und C16-Olefingemisch ist.
20. Verfahren nach Anspruch 1, wobei ein aprotisches Lösungsmittel verwendet wird.
21. Verfahren nach Anspruch 20, wobei das aprotische Lösungsmittel ein halogeniertes Lösungsmittel ist.
22. Verfahren nach Anspruch 20, wobei das aprotische Lösungsmittel ausgewählt ist aus der Gruppe, die aus Ethylendichlorid, Methylenchlorid und Tetrachlorkohlenstoff und Gemischen davon besteht.
23. Verfahren nach Anspruch 6, wobei das a-Olefin ein C6- und C10-Gemisch ist.
24. Verfahren nach Anspruch 20, wobei das Lösungsmittel eine doppelte Dichlorverbindung ist.
25. Verfahren nach Anspruch 6, wobei das a-Olefin ein Cg- und C·^-Gemisch ist.
26. Verfahren nach Anspruch 22, wobei das aprotische Lösungsmittel Methylenchlorid ist.
27. Verfahren nach Anspruch 3, wobei das tertiäre Alkylhalogenid das Chlorid ist.
28. Verfahren nach Anspruch 6, wobei das a-Olefin ein Co-,
C10- und C1 ,.-Gemisch ist.
29. Verfahren nach Anspruch 1, wobei das a-Olefin-Polymer im wesentlichen frei von aromatischem Gehalt ist.
30. Das Produkt des Verfahrens von Anspruch 1.
31. Das Produkt von Beispiel 30 mit einem Zahlenmittel des Molekulargewichts von 2000 bis etwa 100 000.
32. a-Olefin-Polymer-Zusammensetzung mit einer polymodalen Verteilung mit Molekulargewichts-Maxima bei 2000 bis 5000 und bei 50 000 bis 75 000.
l: J t &Ggr; &idigr; · «· · I
33. &agr;-Olefin-Polymer nach Anspruch 32, erhalten aus einem a-Olefin mit 4 bis etwa 30 Kohlenstoffatomen und Gemischen davon.
34. &agr;-Olefin-Polymer nach Anspruch 32, wobei die polymodale Verteilung bimodal ist.
35. &agr;-Olefin-Polymer nach Anspruch 32, erhalten aus einem a-Olefin mit 6 bis etwa 16 Kohlenstoffatomen.
36. &agr;-Olefin-Polymer nach Anspruch 32, wobei die Molekulargewichts-Maxima 3500 bis 4500 und 55 000 bis 65 000 sind.
37. Verfahren zur Herstellung eines Propylen-Polymers, umfassend das Zusammenbringen von Propylen mit einem Katalysatorsystem, das Aluminiumchlorid und mindestens ein tertiäres Niederalkylchlorid umfaßt, unter Polymerisationsbedingungen in Gegenwart einer aktivierenden Menge Wasser, und unter Verwendung eines halogenierten Lösungsmittels, um so das Propylenpolymer zu erhalten.
38. Schmieröl, funktioneile Flüssigkeit oder Fett, enthaltend das &agr;-Olefin-Polymer von Anspruch 30.
39. Schmieröl, funktioneile Flüssigkeit oder Fett, enthaltend das &agr;-Olefin-Polymer von Anspruch 32.
DE198989903015T 1987-12-29 1988-12-14 Alpha-olefin-polymere. Pending DE349639T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/139,392 US4968853A (en) 1987-12-29 1987-12-29 Alpha-olefin polymers
PCT/US1988/004467 WO1989006247A2 (en) 1987-12-29 1988-12-14 Alpha-olefin polymers

Publications (1)

Publication Number Publication Date
DE349639T1 true DE349639T1 (de) 1990-06-13

Family

ID=22486420

Family Applications (3)

Application Number Title Priority Date Filing Date
DE198989903015T Pending DE349639T1 (de) 1987-12-29 1988-12-14 Alpha-olefin-polymere.
DE3852132T Expired - Fee Related DE3852132T2 (de) 1987-12-29 1988-12-14 Verfahren zur Herstellung von Alpha-Olefin-Polymeren.
DE3855892T Expired - Fee Related DE3855892T2 (de) 1987-12-29 1988-12-14 Alpha-Olefinpolymere

Family Applications After (2)

Application Number Title Priority Date Filing Date
DE3852132T Expired - Fee Related DE3852132T2 (de) 1987-12-29 1988-12-14 Verfahren zur Herstellung von Alpha-Olefin-Polymeren.
DE3855892T Expired - Fee Related DE3855892T2 (de) 1987-12-29 1988-12-14 Alpha-Olefinpolymere

Country Status (9)

Country Link
US (3) US4968853A (de)
EP (2) EP0604408B1 (de)
JP (1) JP2765739B2 (de)
AT (2) ATE114161T1 (de)
AU (1) AU608702B2 (de)
CA (1) CA1312696C (de)
DE (3) DE349639T1 (de)
WO (1) WO1989006247A2 (de)
ZA (1) ZA889678B (de)

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EP0604408B1 (de) 1997-04-23
EP0349639A1 (de) 1990-01-10
JP2765739B2 (ja) 1998-06-18
ATE152137T1 (de) 1997-05-15
AU3214389A (en) 1989-08-01
US5345024A (en) 1994-09-06
DE3855892D1 (de) 1997-05-28
DE3852132T2 (de) 1995-06-01
CA1312696C (en) 1993-01-12
ATE114161T1 (de) 1994-12-15
DE3852132D1 (de) 1994-12-22
US5364994A (en) 1994-11-15
EP0349639B1 (de) 1994-11-17
AU608702B2 (en) 1991-04-11
US4968853A (en) 1990-11-06
DE3855892T2 (de) 1997-09-18
EP0604408A1 (de) 1994-06-29
WO1989006247A3 (en) 1989-07-27
WO1989006247A2 (en) 1989-07-13
JPH04500529A (ja) 1992-01-30
ZA889678B (en) 1989-09-27

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