DE3325503C2 - - Google Patents
Info
- Publication number
- DE3325503C2 DE3325503C2 DE3325503A DE3325503A DE3325503C2 DE 3325503 C2 DE3325503 C2 DE 3325503C2 DE 3325503 A DE3325503 A DE 3325503A DE 3325503 A DE3325503 A DE 3325503A DE 3325503 C2 DE3325503 C2 DE 3325503C2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- dishwashing detergent
- thixotropic
- component
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 claims description 54
- 238000004851 dishwashing Methods 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 30
- 239000006260 foam Substances 0.000 claims description 23
- 230000009974 thixotropic effect Effects 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000000460 chlorine Substances 0.000 claims description 19
- 229910052801 chlorine Inorganic materials 0.000 claims description 19
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 18
- 239000007844 bleaching agent Substances 0.000 claims description 16
- 239000002562 thickening agent Substances 0.000 claims description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 9
- 239000004115 Sodium Silicate Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 8
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- 229910021647 smectite Inorganic materials 0.000 claims description 7
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 229960000892 attapulgite Drugs 0.000 claims description 6
- 230000036571 hydration Effects 0.000 claims description 6
- 238000006703 hydration reaction Methods 0.000 claims description 6
- 229910052625 palygorskite Inorganic materials 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- -1 alkali metal tripolyphosphate Chemical class 0.000 claims description 4
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 3
- 239000004927 clay Substances 0.000 claims 3
- 230000002378 acidificating effect Effects 0.000 claims 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims 1
- 150000008041 alkali metal carbonates Chemical class 0.000 claims 1
- 239000002518 antifoaming agent Substances 0.000 claims 1
- 239000003112 inhibitor Substances 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 239000000047 product Substances 0.000 description 19
- 238000004140 cleaning Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 7
- 235000011121 sodium hydroxide Nutrition 0.000 description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000000375 suspending agent Substances 0.000 description 6
- 238000005187 foaming Methods 0.000 description 5
- 229910052573 porcelain Inorganic materials 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000012530 fluid Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000013016 damping Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000000994 depressogenic effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 150000004687 hexahydrates Chemical class 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000000284 resting effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000012928 buffer substance Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000013325 dietary fiber Nutrition 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 150000004712 monophosphates Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001935 peptisation Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003008 phosphonic acid esters Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- GIPRGFRQMWSHAK-UHFFFAOYSA-M sodium;2-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=CC=C1S([O-])(=O)=O GIPRGFRQMWSHAK-UHFFFAOYSA-M 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3958—Bleaching agents combined with phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49761583A | 1983-05-24 | 1983-05-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3325503A1 DE3325503A1 (de) | 1984-11-29 |
| DE3325503C2 true DE3325503C2 (enrdf_load_stackoverflow) | 1992-06-11 |
Family
ID=23977588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3325503A Granted DE3325503A1 (de) | 1983-05-24 | 1983-07-15 | Wasserhaltige, thixotropes geschirrwaschmittel fuer automatische geschirrspuelmaschinen |
Country Status (13)
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4555360A (en) * | 1984-06-22 | 1985-11-26 | The Procter & Gamble Company | Mild detergent compositions |
| NZ212921A (en) * | 1984-08-13 | 1988-06-30 | Colgate Palmolive Co | Process for the manufacture of thixotropic detergent compositions |
| NZ212920A (en) * | 1984-08-13 | 1989-04-26 | Colgate Palmolive Co | Thixotropic automatic dishwasher detergent compositions containing polymeric carboxylic acid |
| DE3440848A1 (de) * | 1984-11-08 | 1986-05-22 | Hans 8900 Augsburg Biermaier | Verfahren und vorrichtung zum regeln der schaumbildung bei tank-waschmaschinen, insbesondere desinfektions-spuelmaschinen |
| US4801395A (en) * | 1986-08-07 | 1989-01-31 | Colgate-Palmolive Company | Thixotropic clay aqueous suspensions containing long chain saturated fatty acid stabilizers |
| US4752409A (en) * | 1985-06-14 | 1988-06-21 | Colgate-Palmolive Company | Thixotropic clay aqueous suspensions |
| US5057237A (en) * | 1985-06-14 | 1991-10-15 | Colgate Palmolive Co. | Thixotropic liquid automatic dishwasher detergent composition with improved physical stability |
| US5064553A (en) * | 1989-05-18 | 1991-11-12 | Colgate-Palmolive Co. | Linear-viscoelastic aqueous liquid automatic dishwasher detergent composition |
| US5413727A (en) * | 1985-06-14 | 1995-05-09 | Colgate Palmolive Co. | Thixotropic aqueous compositions containing long chain saturated fatty acid stabilizers |
| NZ216342A (en) * | 1985-06-14 | 1989-08-29 | Colgate Palmolive Co | Aqueous thixotropic dishwasher compositions containing fatty acid metal salts as stabiliser |
| US5427707A (en) * | 1985-06-14 | 1995-06-27 | Colgate Palmolive Co. | Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer |
| GR862954B (en) * | 1986-01-07 | 1987-05-08 | Colgate Palmolive Co | Thixotropic aqueous suspensions |
| EP0264975A1 (en) * | 1986-08-18 | 1988-04-27 | The Procter & Gamble Company | Thickened aqueous dishwashing compositions |
| US4857226A (en) * | 1986-10-29 | 1989-08-15 | Colgate-Palmolive Company | Thixotropic clay aqueous suspensions containing polyacrylic acid polymer or copolymer stabilizers |
| US4836946A (en) * | 1987-08-21 | 1989-06-06 | Colgate-Palmolive Company | Thixotropic clay aqueous suspensions containing alkali metal fatty acid salt stabilizers |
| GB8719776D0 (en) * | 1987-08-21 | 1987-09-30 | Unilever Plc | Machine dishwashing compositions |
| ZA885894B (en) * | 1987-08-21 | 1990-04-25 | Colgate Palmolive Co | Thixotropic clay aqueous suspensions containing polycarboxylic acids and metal salts thereof stabilizers |
| NZ226174A (en) * | 1987-09-23 | 1991-03-26 | Colgate Palmolive Co | Aqueous cleaning composition; no- or low-phosphorus built mixture |
| NZ226289A (en) * | 1987-09-29 | 1990-09-26 | Colgate Palmolive Co | Gel-like aqueous dishwashing composition with sodium silicate and silica anti-filming agent |
| GB8726308D0 (en) * | 1987-11-10 | 1987-12-16 | Unilever Plc | Machine dishwashing composition |
| BR8807290A (pt) * | 1987-11-12 | 1990-03-27 | Unilever Nv | Composicao de limpeza aquosa e tixotropica e processo para prepara-la |
| US5160448A (en) * | 1987-12-30 | 1992-11-03 | Lever Brothers Company, Division Of Conopco, Inc. | Gel detergent compositions containing a clay and a cross-linked polycarboxylic polymer |
| US5047167A (en) * | 1987-12-30 | 1991-09-10 | Lever Brothers Company, Division Of Conopco, Inc. | Clear viscoelastic detergent gel compositions containing alkyl polyglycosides |
| US5141664A (en) * | 1987-12-30 | 1992-08-25 | Lever Brothers Company, A Division Of Conopco, Inc. | Clear detergent gel compositions having opaque particles dispersed therein |
| US4836948A (en) * | 1987-12-30 | 1989-06-06 | Lever Brothers Company | Viscoelastic gel detergent compositions |
| DE3800483A1 (de) * | 1988-01-11 | 1989-07-20 | Henkel Kgaa | Chlorstabile entschaeumer fuer aktivchlor enthaltende reinigungsmittel, insbesondere geschirreinigungsmittel |
| US4867896A (en) * | 1988-02-17 | 1989-09-19 | Lever Brothers Company | Cleaning compositions containing cross-linked polymeric thickeners and hypochlorite bleach |
| GB2219596A (en) * | 1988-06-09 | 1989-12-13 | Procter & Gamble | Liquid automatic dishwashing compositions having enhanced stability |
| US4988452A (en) * | 1988-06-09 | 1991-01-29 | The Procter & Gamble Company | Liquid automatic dishwashing detergent compositions containing bleach-stable nonionic surfactant |
| US4859358A (en) * | 1988-06-09 | 1989-08-22 | The Procter & Gamble Company | Liquid automatic dishwashing compositions containing metal salts of hydroxy fatty acids providing silver protection |
| US4950416A (en) * | 1988-10-19 | 1990-08-21 | Vista Chemical Company | Liquid dishwasher detergent composition |
| US4971717A (en) * | 1989-04-28 | 1990-11-20 | Colgate-Palmolive Co. | Aqueous liquid automatic dishwashing detergent composition with improved anti-filming and anti-spotting properties |
| US5185096A (en) * | 1991-03-20 | 1993-02-09 | Colgate-Palmolive Co. | Aqueous liquid automatic dishwashing detergent composition comprising hypochlorite bleach and bleach stabilizer |
| EP0407187A3 (en) * | 1989-07-07 | 1991-07-17 | Unilever Plc | Aqueous thixotropic cleaning composition |
| US5169552A (en) * | 1989-10-04 | 1992-12-08 | The Procter & Gamble Company | Stable thickened liquid cleaning composition containing bleach |
| DE19730648A1 (de) * | 1997-07-17 | 1999-01-21 | Henkel Kgaa | Verwendung von Elektrolytgemischen als Sequestriermittel |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1571501A (en) * | 1976-01-23 | 1980-07-16 | Unilever Ltd | Detergent compositions |
| DE2750528A1 (de) * | 1976-11-15 | 1978-05-24 | Procter & Gamble | Verfahren zum sauberhalten eines toilettenbeckens |
| US4116849A (en) * | 1977-03-14 | 1978-09-26 | The Procter & Gamble Company | Thickened bleach compositions for treating hard-to-remove soils |
| US4116851A (en) * | 1977-06-20 | 1978-09-26 | The Procter & Gamble Company | Thickened bleach compositions for treating hard-to-remove soils |
| DE3138425A1 (de) * | 1981-09-26 | 1983-04-14 | Henkel KGaA, 4000 Düsseldorf | "verwendung eines pastoesen reinigers in geschirrspuelmaschinen" |
| SE453834B (sv) * | 1982-01-18 | 1988-03-07 | Colgate Palmolive Co | Komposition av geltyp med tixotropa egenskaper avsedd for automatiska diskmaskiner |
-
1983
- 1983-07-13 AU AU16793/83A patent/AU565792B2/en not_active Ceased
- 1983-07-15 DE DE3325503A patent/DE3325503A1/de active Granted
- 1983-07-15 DK DK328083A patent/DK159555C/da not_active IP Right Cessation
- 1983-07-15 GB GB08319158A patent/GB2140450B/en not_active Expired
- 1983-07-15 NZ NZ204916A patent/NZ204916A/en unknown
- 1983-07-15 CH CH3902/83A patent/CH655325A5/de not_active IP Right Cessation
- 1983-07-15 ZA ZA835186A patent/ZA835186B/xx unknown
- 1983-07-15 SE SE8303996A patent/SE459660B/sv not_active IP Right Cessation
- 1983-07-15 CA CA000432542A patent/CA1222426A/en not_active Expired
- 1983-07-16 JP JP58130139A patent/JPS59226099A/ja active Pending
- 1983-07-18 FR FR8311811A patent/FR2546527B1/fr not_active Expired
-
1990
- 1990-06-28 SG SG459/90A patent/SG45990G/en unknown
- 1990-10-18 HK HK847/90A patent/HK84790A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU565792B2 (en) | 1987-10-01 |
| DK159555C (da) | 1991-04-02 |
| AU1679383A (en) | 1984-11-29 |
| HK84790A (en) | 1990-10-25 |
| FR2546527B1 (fr) | 1987-09-04 |
| GB2140450B (en) | 1987-07-01 |
| JPS59226099A (ja) | 1984-12-19 |
| SE8303996D0 (sv) | 1983-07-15 |
| DK159555B (da) | 1990-10-29 |
| GB2140450A (en) | 1984-11-28 |
| SE8303996L (sv) | 1984-11-25 |
| GB8319158D0 (en) | 1983-08-17 |
| ZA835186B (en) | 1985-02-27 |
| CA1222426A (en) | 1987-06-02 |
| DK328083D0 (da) | 1983-07-15 |
| SE459660B (sv) | 1989-07-24 |
| CH655325A5 (de) | 1986-04-15 |
| DE3325503A1 (de) | 1984-11-29 |
| NZ204916A (en) | 1985-11-08 |
| SG45990G (en) | 1990-08-17 |
| DK328083A (da) | 1984-11-25 |
| FR2546527A1 (fr) | 1984-11-30 |
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| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: STOLBERG-WERNIGERODE, GRAF ZU, U., DIPL.-CHEM. DR.RER.NAT. SUCHANTKE, J., DIPL.-ING. HUBER, A., DIPL.-ING. KAMEKE, VON, A., DIPL.-CHEM. DR.RER.NAT., PAT.-ANWAELTE, 2000 HAMBURG |
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| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |