DE3224033A1 - Verfahren zur herstellung von aetherverbindungen durch katalytische hydrogenolyse - Google Patents

Verfahren zur herstellung von aetherverbindungen durch katalytische hydrogenolyse

Info

Publication number
DE3224033A1
DE3224033A1 DE19823224033 DE3224033A DE3224033A1 DE 3224033 A1 DE3224033 A1 DE 3224033A1 DE 19823224033 DE19823224033 DE 19823224033 DE 3224033 A DE3224033 A DE 3224033A DE 3224033 A1 DE3224033 A1 DE 3224033A1
Authority
DE
Germany
Prior art keywords
catalyst
ether
reaction
compound
catalytic hydrogenolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19823224033
Other languages
German (de)
English (en)
Other versions
DE3224033C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html
Inventor
Tadamichi Aoki
Tadashi Ayusawa
Yutaka Ibaraki Nomura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP56099766A external-priority patent/JPS584739A/ja
Priority claimed from JP57059756A external-priority patent/JPS58177929A/ja
Application filed by Mitsubishi Petrochemical Co Ltd filed Critical Mitsubishi Petrochemical Co Ltd
Publication of DE3224033A1 publication Critical patent/DE3224033A1/de
Application granted granted Critical
Publication of DE3224033C2 publication Critical patent/DE3224033C2/de
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/28—Preparation of ethers by reactions not forming ether-oxygen bonds from acetals, e.g. by dealcoholysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE19823224033 1981-06-29 1982-06-28 Verfahren zur herstellung von aetherverbindungen durch katalytische hydrogenolyse Granted DE3224033A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP56099766A JPS584739A (ja) 1981-06-29 1981-06-29 接触水素化分解によるエ−テル化合物の製法
JP57059756A JPS58177929A (ja) 1982-04-12 1982-04-12 エ−テル化合物の連続的製法

Publications (2)

Publication Number Publication Date
DE3224033A1 true DE3224033A1 (de) 1983-01-05
DE3224033C2 DE3224033C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1990-04-26

Family

ID=26400826

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19823224033 Granted DE3224033A1 (de) 1981-06-29 1982-06-28 Verfahren zur herstellung von aetherverbindungen durch katalytische hydrogenolyse

Country Status (2)

Country Link
US (1) US4479017A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE3224033A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0293739A1 (de) * 1987-06-03 1988-12-07 BASF Aktiengesellschaft Verfahren zur Herstellung von 4-Isopropyl-cyclohexylmethanol bzw. dessen Alkylethern
EP0432949A3 (en) * 1989-12-07 1991-09-25 Imperial Chemical Industries Plc Production of polyalkylene glycol ethers
WO1992016488A1 (de) * 1991-03-13 1992-10-01 Henkel Kommanditgesellschaft Auf Aktien Verfahren zur herstellung von malonsäure
WO1993002033A1 (de) * 1991-07-20 1993-02-04 Henkel Kommanditgesellschaft Auf Aktien Verfahren zur herstellung von polyolethern
EP0490221A3 (en) * 1990-12-14 1993-03-24 Hoechst Aktiengesellschaft Method for the production of unsaturated ethers
EP0616994A3 (en) * 1993-03-15 1994-11-09 Kao Corp Process for the preparation of ether alcohols by hydrogenolysis of cyclic ketals.
EP0810194A1 (de) * 1996-05-30 1997-12-03 Hoechst Aktiengesellschaft Verfahren zur Herstellung von 3-Oxyalkylpropan-1-olen
US5856531A (en) * 1996-10-21 1999-01-05 Eastman Chemical Company Preparation of 3-methytetra-hydrofuran from 2,3-dihydrofuran
US5912364A (en) * 1996-10-21 1999-06-15 Eastman Chemical Company Process for the preparation of 3-methyltetrahydrofuran

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100320620B1 (ko) * 1992-06-04 2002-01-16 도미나가 가즈토 수소화능력을 가진 고체촉매를 이용한 에테르화합물의제조방법
EP0658155A4 (en) * 1993-07-07 1996-01-24 Bp Chem Int Ltd METHOD FOR CONVERTING ACETATES IN ETHER.
WO1996033154A1 (fr) * 1995-04-20 1996-10-24 Idemitsu Kosan Co., Ltd. Procede de production de composes d'ether
JP3802314B2 (ja) * 1999-11-02 2006-07-26 花王株式会社 エーテルの製法
CN107082742A (zh) * 2008-08-25 2017-08-22 陶氏环球技术有限责任公司 多元醇醚和制备它们的方法
US20110207969A1 (en) * 2010-02-23 2011-08-25 Olken Michael M Process for making polyol ethers
US8829206B2 (en) 2011-06-24 2014-09-09 Eastman Chemical Company Production of cyclic acetals or ketals using solid acid catalysts
US9000229B2 (en) 2011-06-24 2015-04-07 Eastman Chemical Company Production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US9056313B2 (en) 2011-06-24 2015-06-16 Eastman Chemical Company Catalysts for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US8829207B2 (en) 2011-06-24 2014-09-09 Eastman Chemical Company Production of cyclic acetals by reactive distillation
US8969598B2 (en) 2011-06-24 2015-03-03 Eastman Chemical Company Production of cyclic acetals or ketals using liquid-phase acid catalysts
US8785697B2 (en) 2011-06-24 2014-07-22 Eastman Chemical Company Nickel modified catalyst for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US9388105B2 (en) 2011-06-24 2016-07-12 Eastman Chemical Company Production of hydroxy ether hydrocarbons by liquid phase hydrogenolysis of cyclic acetals or cyclic ketals
GB201717210D0 (en) 2017-10-19 2017-12-06 Bp Plc Selective acetalization/etherification process
GB201717211D0 (en) 2017-10-19 2017-12-06 Bp Plc Etherification process
GB201818905D0 (en) 2018-11-20 2019-01-02 Bp Plc Process for making ethers via enol ethers

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE911849C (de) * 1938-09-10 1954-05-20 Degussa Verfahren zur Herstellung aliphatischer oder alizyklischer Diaether
DE1234199B (de) * 1963-09-30 1967-02-16 Shell Int Research Verfahren zur Herstellung von Mono- oder Diaethern von Glykolen durch Hydrogenolyse von cylischen Ketalen
JPS50108207A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1974-02-06 1975-08-26
JPS5134106A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1974-07-16 1976-03-23 Hoechst Ag
US4088700A (en) * 1976-09-27 1978-05-09 Texaco Development Corporation Process for the hydrogenolysis of dioxolanes
JPS53130612A (en) * 1977-04-15 1978-11-14 Hoechst Ag Process for preparing ethlenfglycoldimethylether
JPS5432598A (en) * 1977-08-18 1979-03-09 Kuraray Co Ltd Preparation of polyoxyalkylene glycol diether
JPS5671031A (en) * 1979-11-12 1981-06-13 Mitsubishi Petrochem Co Ltd Preparation of glycol dialkyl ether

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA727675A (en) * 1966-02-08 B. Ashton Joseph Ketal hydrogenolysis
CA473097A (en) * 1951-04-24 E. Staff Charles Preparation of diethers of the glycols
US2425042A (en) * 1943-12-01 1947-08-05 Carbide & Carbon Chem Corp Glycol diethers

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE911849C (de) * 1938-09-10 1954-05-20 Degussa Verfahren zur Herstellung aliphatischer oder alizyklischer Diaether
DE1234199B (de) * 1963-09-30 1967-02-16 Shell Int Research Verfahren zur Herstellung von Mono- oder Diaethern von Glykolen durch Hydrogenolyse von cylischen Ketalen
JPS50108207A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1974-02-06 1975-08-26
JPS5134106A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1974-07-16 1976-03-23 Hoechst Ag
US4088700A (en) * 1976-09-27 1978-05-09 Texaco Development Corporation Process for the hydrogenolysis of dioxolanes
JPS53130612A (en) * 1977-04-15 1978-11-14 Hoechst Ag Process for preparing ethlenfglycoldimethylether
JPS5432598A (en) * 1977-08-18 1979-03-09 Kuraray Co Ltd Preparation of polyoxyalkylene glycol diether
JPS5671031A (en) * 1979-11-12 1981-06-13 Mitsubishi Petrochem Co Ltd Preparation of glycol dialkyl ether

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
FREIFELDER, M.: in Practical Catalytic Hy- drogenation, 1971, S. 517-518 *
J. Chem. Soc., 1963, 5598-5600 *
J. Org. Chem., 1961, 26, S. 1026-1028 *
Monatsheft, 1932, 60, S. 317 *
Organic Synthese, 1946, Bd. 1, 26, S. 77 *
Synthetic Org. Chemistry, 1953, S. 261-278 *

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4847425A (en) * 1987-06-03 1989-07-11 Basf Aktiengesellschaft Prepartion of 4-isopropylcyclohexylmethanol and its alkyl ethers
EP0293739A1 (de) * 1987-06-03 1988-12-07 BASF Aktiengesellschaft Verfahren zur Herstellung von 4-Isopropyl-cyclohexylmethanol bzw. dessen Alkylethern
EP0432949A3 (en) * 1989-12-07 1991-09-25 Imperial Chemical Industries Plc Production of polyalkylene glycol ethers
EP0490221A3 (en) * 1990-12-14 1993-03-24 Hoechst Aktiengesellschaft Method for the production of unsaturated ethers
US5354911A (en) * 1990-12-14 1994-10-11 Hoechst Aktiengesellschaft Process for the preparation of unsaturated ethers
WO1992016488A1 (de) * 1991-03-13 1992-10-01 Henkel Kommanditgesellschaft Auf Aktien Verfahren zur herstellung von malonsäure
WO1993002033A1 (de) * 1991-07-20 1993-02-04 Henkel Kommanditgesellschaft Auf Aktien Verfahren zur herstellung von polyolethern
US5446210A (en) * 1991-07-20 1995-08-29 Henkel Kommanditgesellschaft Auf Aktien Process for the production of polyol ethers
EP0616994A3 (en) * 1993-03-15 1994-11-09 Kao Corp Process for the preparation of ether alcohols by hydrogenolysis of cyclic ketals.
US5446208A (en) * 1993-03-15 1995-08-29 Kao Corporation Process for producing ether alcohols by hydrogenolysis of cyclic ketal
EP0810194A1 (de) * 1996-05-30 1997-12-03 Hoechst Aktiengesellschaft Verfahren zur Herstellung von 3-Oxyalkylpropan-1-olen
US5780687A (en) * 1996-05-30 1998-07-14 Hoechst Aktiengesellschaft Process for preparing 3-oxyalkylpropan-1-ols
US5856531A (en) * 1996-10-21 1999-01-05 Eastman Chemical Company Preparation of 3-methytetra-hydrofuran from 2,3-dihydrofuran
US5912364A (en) * 1996-10-21 1999-06-15 Eastman Chemical Company Process for the preparation of 3-methyltetrahydrofuran

Also Published As

Publication number Publication date
DE3224033C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1990-04-26
US4479017A (en) 1984-10-23

Similar Documents

Publication Publication Date Title
DE3224033A1 (de) Verfahren zur herstellung von aetherverbindungen durch katalytische hydrogenolyse
DE2628987C3 (de) Verfahren zur Herstellung von C↓3↓-C↓5↓-Alkanolen
DE3125228C2 (de) Verfahren zur Herstellung von Ethylenglykol durch Hydrierung von Glykolaldehyd mit Wasserstoff
DE69908777T2 (de) Flüssigphase katalytisches Hydrierungsverfahren zur Umwandlung von Aldehyden in die entsprechenden Alkohole
DE2538364A1 (de) Verfahren zur herstellung von butandiolen
EP0004104B2 (de) Verfahren zur Herstellung von 2,2,6,6-Tetramethylpiperidon-(4)
DE2855504B2 (de) Verfahren zur Herstellung von Methacrolein
DE1234199B (de) Verfahren zur Herstellung von Mono- oder Diaethern von Glykolen durch Hydrogenolyse von cylischen Ketalen
DE2235992C3 (de) Verfahren zur Herstellung gesättigter aliphatischer Amine
EP0476400B1 (de) Verfahren zur Abtrennung von Cyclohexen aus Gemischen mit Benzol und Cyclohexan
DE2706862A1 (de) Verfahren zur hydrierung von aethylenischen aldehyden
DE68920543T2 (de) Herstellungsverfahren von Homoallylalkoholen.
EP0162387B1 (de) Verfahren zur Herstellung von Ketonen durch Isomerisierung von Aldehyden
DE3107518A1 (de) Verfahren zur herstellung von estern und aethern der glykolsaeure
EP0193801B1 (de) Verfahren zur kontinuierlichen Homologisierung von Methanol
DE3335186C2 (de) Verfahren zur Herstellung von Dinitrophenylethern
DE2737511A1 (de) Verfahren zur herstellung von ketonen
JP3342973B2 (ja) ヒドロキシアルカナールの製造方法
EP0340702B1 (de) Verfahren zur Herstellung von Hydroxybenzaldehyden
DE69100154T2 (de) Verfahren zur Herstellung von Halogenmethylpivalaten.
DE19815634A1 (de) Verfahren zur Herstellung von 3-Methoxy-1-propanol
DE3332253A1 (de) Verfahren zur herstellung von alkylchloriden aus alkohol-ethergemischen, die bei der celluloseveretherung entstehen
DE19635703A1 (de) Verfahren zur Herstellung von Alkindiolen oder Gemischen von Alkindiolen mit Alkinmonoolen
DE3020298C2 (de) Verfahren zur Herstellung von 2,2,4,5,5-Pentamethyl-3-formyl-3-pyrrolin
EP0093892B1 (de) Verfahren zur Herstellung von aromatischen Aminen

Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
D2 Grant after examination
8364 No opposition during term of opposition