DE3043895C2 - Verfahren zur Herstellung eines Alkalimonofluorophosphats - Google Patents
Verfahren zur Herstellung eines AlkalimonofluorophosphatsInfo
- Publication number
- DE3043895C2 DE3043895C2 DE3043895A DE3043895A DE3043895C2 DE 3043895 C2 DE3043895 C2 DE 3043895C2 DE 3043895 A DE3043895 A DE 3043895A DE 3043895 A DE3043895 A DE 3043895A DE 3043895 C2 DE3043895 C2 DE 3043895C2
- Authority
- DE
- Germany
- Prior art keywords
- reaction
- reaction vessel
- alkali
- temperature
- vessel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 34
- 239000003513 alkali Substances 0.000 title claims description 17
- 229940074371 monofluorophosphate Drugs 0.000 title claims description 6
- 238000002360 preparation method Methods 0.000 title claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 65
- 239000011734 sodium Substances 0.000 claims description 39
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 11
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- DWYMPOCYEZONEA-UHFFFAOYSA-L fluoridophosphate Chemical compound [O-]P([O-])(F)=O DWYMPOCYEZONEA-UHFFFAOYSA-L 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 3
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims description 2
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 2
- DEXLEWOLIJQEEE-UHFFFAOYSA-K [Na+].[O-]P([O-])(=O)OP(=O)([O-])O.[K+].P(=O)(O)(O)O.[Na+] Chemical compound [Na+].[O-]P([O-])(=O)OP(=O)([O-])O.[K+].P(=O)(O)(O)O.[Na+] DEXLEWOLIJQEEE-UHFFFAOYSA-K 0.000 claims 1
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 239000007858 starting material Substances 0.000 description 11
- 238000004458 analytical method Methods 0.000 description 10
- 229910001385 heavy metal Inorganic materials 0.000 description 10
- 235000013024 sodium fluoride Nutrition 0.000 description 9
- 239000011775 sodium fluoride Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 6
- 238000003682 fluorination reaction Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 4
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 235000011180 diphosphates Nutrition 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- DWYMPOCYEZONEA-UHFFFAOYSA-N fluorophosphoric acid Chemical compound OP(O)(F)=O DWYMPOCYEZONEA-UHFFFAOYSA-N 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000005341 metaphosphate group Chemical group 0.000 description 3
- 229940048084 pyrophosphate Drugs 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- FXNRKXSSLJKNGH-UHFFFAOYSA-L dipotassium;fluoro-dioxido-oxo-$l^{5}-phosphane Chemical compound [K+].[K+].[O-]P([O-])(F)=O FXNRKXSSLJKNGH-UHFFFAOYSA-L 0.000 description 2
- 229940091249 fluoride supplement Drugs 0.000 description 2
- 238000010309 melting process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- XGRSAFKZAGGXJV-UHFFFAOYSA-N 3-azaniumyl-3-cyclohexylpropanoate Chemical compound OC(=O)CC(N)C1CCCCC1 XGRSAFKZAGGXJV-UHFFFAOYSA-N 0.000 description 1
- 241001673391 Entandrophragma candollei Species 0.000 description 1
- 229910013804 M2HPO4 Inorganic materials 0.000 description 1
- 229910013926 M4P2O7 Inorganic materials 0.000 description 1
- 229910017736 MH2PO4 Inorganic materials 0.000 description 1
- 241001460678 Napo <wasp> Species 0.000 description 1
- FYIFITNFHGKSOB-UHFFFAOYSA-J P(=O)([O-])([O-])[O-].[K+].[K+].P(=O)([O-])(O)O.[Na+].[Na+] Chemical compound P(=O)([O-])([O-])[O-].[K+].[K+].P(=O)([O-])(O)O.[Na+].[Na+] FYIFITNFHGKSOB-UHFFFAOYSA-J 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229960004711 sodium monofluorophosphate Drugs 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/455—Phosphates containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54150757A JPS594370B2 (ja) | 1979-11-22 | 1979-11-22 | アルカリモノフルオロホスフエ−トの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3043895A1 DE3043895A1 (de) | 1981-09-03 |
| DE3043895C2 true DE3043895C2 (de) | 1983-02-10 |
Family
ID=15503741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3043895A Expired DE3043895C2 (de) | 1979-11-22 | 1980-11-21 | Verfahren zur Herstellung eines Alkalimonofluorophosphats |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4374108A (enExample) |
| JP (1) | JPS594370B2 (enExample) |
| BE (1) | BE886280A (enExample) |
| DE (1) | DE3043895C2 (enExample) |
| FR (1) | FR2470091A1 (enExample) |
| GB (1) | GB2063231B (enExample) |
| IT (1) | IT1134389B (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58181710A (ja) * | 1982-04-13 | 1983-10-24 | Central Glass Co Ltd | アルカリモノフルオロホスフエ−トの製造方法 |
| CA2099127A1 (en) * | 1990-12-24 | 1992-06-25 | Hans-Walter Swidersky | Method for manufacturing alkali monofluorophosphate |
| JP5715725B2 (ja) * | 2013-06-07 | 2015-05-13 | ステラケミファ株式会社 | ジフルオロリン酸塩の精製方法 |
| JP7449141B2 (ja) * | 2020-03-31 | 2024-03-13 | 三井化学株式会社 | アルカリモノフルオロホスフェート組成物の製造方法 |
| JP7469108B2 (ja) * | 2020-03-31 | 2024-04-16 | 三井化学株式会社 | フッ化無機化合物粒子の製造方法 |
| CN111960398A (zh) * | 2020-08-27 | 2020-11-20 | 湖北九宁化学科技有限公司 | 一种单氟磷酸锂的制备方法 |
| CA3241969A1 (en) | 2021-12-22 | 2023-06-29 | Veronique Gouverneur | Caf2-based fluorination reagents, methods of preparation and uses thereof |
| WO2024256871A2 (en) * | 2023-06-15 | 2024-12-19 | Fluorok Limited | Fluorination methods, reagents, fluorinated compositions, and methods of manufacture |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2408784A (en) * | 1943-03-11 | 1946-10-08 | Ozark Chemical Company | Anhydrous monofluorophosphoric acid and method of producing it |
| US2481807A (en) * | 1947-11-28 | 1949-09-13 | Ozark Mahoning Co | Method of producing monofluorophosphates |
| DE1224280B (de) * | 1964-11-12 | 1966-09-08 | Albert Ag Chem Werke | Verfahren zur Herstellung von Metallfluor-phosphaten |
| DE1567405A1 (de) * | 1965-12-23 | 1970-04-16 | Albert Ag Chem Werke | Verfahren zur Herstellung von Metallfluorphosphaten |
| GB1142687A (en) | 1966-03-09 | 1969-02-12 | Albert Ag Chem Werke | Improvements in or relating to the preparation of fluorophosphates |
| FR1475556A (fr) * | 1966-04-13 | 1967-03-31 | Fr Albert Soc | Procédé pour la préparation de fluorphosphates métalliques |
| US3463605A (en) * | 1966-06-13 | 1969-08-26 | Ozark Mahoning Co | Process and apparatus for production of alkali metal monofluorophosphate |
| AT295473B (de) * | 1967-04-08 | 1972-01-10 | Albert Ag Chem Werke | Vorrichtung zur Durchführung des Verfahrens zur kontinuierlichen Herstellung von Alkalimonofluorophosphaten |
| DE1667413B1 (de) * | 1967-04-08 | 1970-04-23 | Albert Ag Chem Werke | Verfahren zur kontinuierlichen Herstellung von Alkalimonofluorphosphaten und Vorrichtung zur Durchfuehrung des Verfahrens |
| GB1370641A (en) * | 1971-04-28 | 1974-10-30 | Ici Ltd | Complex aluminium phosphates |
| SU512171A1 (ru) | 1974-10-17 | 1976-04-30 | Белорусский технологический институт им.С.М.Кирова | Способ получени монофторфосфатов щелочных и щелочноземельных металлов |
-
1979
- 1979-11-22 JP JP54150757A patent/JPS594370B2/ja not_active Expired
-
1980
- 1980-11-05 GB GB8035503A patent/GB2063231B/en not_active Expired
- 1980-11-20 US US06/208,685 patent/US4374108A/en not_active Expired - Lifetime
- 1980-11-20 IT IT26125/80A patent/IT1134389B/it active
- 1980-11-21 BE BE0/202880A patent/BE886280A/fr not_active IP Right Cessation
- 1980-11-21 FR FR8024771A patent/FR2470091A1/fr active Granted
- 1980-11-21 DE DE3043895A patent/DE3043895C2/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB2063231A (en) | 1981-06-03 |
| JPS594370B2 (ja) | 1984-01-30 |
| IT8026125A0 (it) | 1980-11-20 |
| IT1134389B (it) | 1986-08-13 |
| GB2063231B (en) | 1983-05-25 |
| BE886280A (fr) | 1981-03-16 |
| US4374108A (en) | 1983-02-15 |
| DE3043895A1 (de) | 1981-09-03 |
| FR2470091A1 (fr) | 1981-05-29 |
| FR2470091B1 (enExample) | 1984-12-21 |
| JPS5673610A (en) | 1981-06-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |